scholarly journals ACCUMULATION OF HEAVY METALS IN THE SOILS OF FOOTHAL AREAS OF KRASNODAR KRAY

2019 ◽  
Vol 14 (1) ◽  
pp. 22-26
Author(s):  
Анастасия Забашта ◽  
Anastasiya Zabashta ◽  
Николай Забашта ◽  
Nikolay Zabashta
Keyword(s):  
Heavy Metals ◽  
Agricultural Land ◽  
Agricultural Soils ◽  
Chemical Elements ◽  
Arable Land ◽  
Mineral Fertilizers ◽  
North Caucasus ◽  
Lead And Cadmium ◽  
Maximum Permissible Concentrations ◽  
Mobile Forms

The accumulation of heavy metals, primarily from the soil, takes place in the water and fodder plants. Sources are pesticides, polluted air and precipitation. Hazardous chemical elements in certain quantities enter plants from soil. It should be added that ballast substances from mineral fertilizers containing heavy metals are also found in the soil. It has been established that on the flat-foothill massif of the North Caucasus, the constant component of solid precipitation are such elements as chromium, nickel, lead, manganese and silver. Cadmium was not detected in most precipitation samples (less than 1.0 µg / l), but its concentrations exceeded the maximum permissible concentrations by 4–8 times, although its sources were not identified. Therefore, an agrochemical survey of agricultural land has been carried out and it has been established that the content of mobile forms of copper and zinc in the soils of the foothill areas does not exceed the maximum permissible concentrations. Meadow grass stands do not accumulate zinc, copper, lead and cadmium in quantities exceeding the maximum allowable levels. In general, in the foothill areas of the Krasnodar Territory, hay contains 11.0–25.0 mg/kg of zinc, 1.8–9.0 mg/kg of copper, 0.2–2.0 mg/kg of lead, and 0.06– 0.24 mg/kg cadmium. Studies have shown that the agricultural soils of the foothill areas do not contain exceeding MPC values of mobile forms of zinc and copper. But there are local foci containing lead in small quantities. In hay from arable land and natural forage lands, the amount of heavy metals does not exceed MDU.

scholarly journals ENVIRONMENTAL EFFICIENCY OF PERENNIAL LEGUMES AS PRECURSORS OF WINTER WHEAT GROWN IN THE CONDITIONS OF AGRICULTURAL LAND POLLUTION WITH HEAVY METALS

2020 ◽  
pp. 167-176
Author(s):  
Serhii Razanov
Keyword(s):  
Heavy Metals ◽  
Winter Wheat ◽  
Potassium Chloride ◽  
Ammonium Nitrate ◽  
Crop Rotation ◽  
Agricultural Land ◽  
Spring Barley ◽  
Mineral Fertilizers ◽  
Lead And Cadmium ◽  
Intensive Farming

The aim of the research was to study the effect of the inclusion of different types of perennial leguminous plants as winter wheat precursors in the crop rotation on the rate of accumulation of heavy metals in the soil compared to traditional winter wheat predecessors. The objectives of the research are to develop measures to reduce the accumulation of heavy metals in agricultural soils under conditions of modern crop rotation, limited by the number of crops grown and winter wheat. The accumulations of heavy metals in soils were calculated during the cultivation of the main crops of crop rotation with intensive fertilizer. The concentration of heavy metals in the soil was determined before and after the cultivation of legume precursors. Field studies were carried out during 2013-2017. On gray podzolized medium loamy soils of the Agronomichesky Research Institute of Vinnytsia National Agrarian University. We calculated the volumes of heavy metals with optimal rates of mineral fertilizer application for the most common types of crops grown in crop rotation. Four types of perennial grasses were sown: sowing alfalfa, meadow clover, horned lamb, sainfoin and eastern goatskin. After their four years of use, winter wheat was sown. The control was the predecessors in the following sequence: winter wheat - sunflower - winter wheat - corn. Laboratory studies of the content of mobile forms of heavy metals in soil were carried out in the Vinnytsia branch of the State Center for the Protection of Soil Fertility. Analysis of soil contamination with heavy metals during fertilization of major cereals showed that the amount of mineral fertilizers is from 257 kg/ha to 571 kg/ha for ammonium nitrate, from 175 to 225 kg/ha for double superphosphate and from 58 to 75 kg/ha on potassium chloride. According to the volume of mineral fertilizers used in the cultivation of winter wheat, 1944 mg / ha of lead and 339 mg / ha of cadmium enter the soil. Of these, with ammonium nitrate - 51.4% and 7.4%, respectively, with double superphosphate - 39.6% and 41.3% and with potassium chloride - 9.0% and 51.3%. When growing corn per 1 ha with mineral fertilizers, 2357 mg of lead and 434 mg of cadmium are applied, of which with ammonium nitrate - 48.4% and 6.7%, respectively, with double superphosphate - 42% and 41% and with potassium chloride. - 9.6% and 51.8%. Cultivation of spring barley leads to the receipt of mineral fertilizers to soils 1458 mg/ha of lead and 327 mg/ha of cadmium, of which with ammonium nitrate - respectively 35.2% and 4.0%, with double superphosphate - 52.8% and 42.8% and with potassium chloride - 12.0% and 53.2%. Mineral fertilization of winter rape leads to the entry into the soil per 1 ha of 2223 mg of lead and 390 mg of cadmium, of which with ammonium nitrate - respectively 51.4% and 7.4%, with double superphosphate - 39.6% and 41% and with potassium chloride - 9.0% and 51.5%. With mineral fertilizers for growing sunflower in the soil per 1 ha gets 2073 mg of lead and 427 mg of cadmium, of which with ammonium nitrate - respectively 41.4% and 5.2%, double superphosphate - 47.8% and 42.2 % and potassium chloride - 10.8% and 52.6%. The positive effect of growing leguminous perennial herbs on the decrease in the concentration of heavy metals in the soil and grain of winter wheat has been established. Under the conditions of intensive farming by Vinnitskaya, lead and cadmium fall into the soil for the use of mineral fertilizers in accordance with 1944 mg/ha and 339 mg/ha for growing winter wheat, 2357 mg/ha and 434 mg/ha for growing corn, 1458 mg/ha and 327 mg/ha when growing spring barley, 2223 mg/ha and 390 mg/ha when growing sunflower. The four-year cultivation of perennial leguminous grasses under intensive farming reduced the concentration of lead in the soil from 1.33 to 3.2 times and cadmium from 37 to 54 times compared with cereal crops, which contributed to improving the quality of winter wheat grain by reducing the concentration of lead from 1 7 to 2.4 times and cadmium from 1.4 times to 2.1 times. Key words: legumes, precursors, winter wheat, heavy metals, pollution.

The effects of silt fields of Bortnytska aeration station on ecological state of land and water in the adjacent areas

2021 ◽  
pp. 114-128
Author(s):  
M. V. Yatsiuk ◽  
A. M. Shevchenko ◽  
R. P. Bozhenko ◽  
S. M. Lyutnitsky
Keyword(s):  
Heavy Metals ◽  
Agricultural Land ◽  
Ecological State ◽  
Crop Failure ◽  
Maximum Permissible Concentrations ◽  
Mobile Forms ◽  
Exchangeable Magnesium ◽  
Agricultural Use ◽  
Almost All ◽  
The Impact

The article highlights the results of research on assessing the ecological state of the land near the silt fields №1 and №3 of Bortnytska aeration station in the Zolochiv village community of Boryspil district in Kyiv region. The presence of previously recorded increased content of heavy metals in soils compared to the background content, both in terms of their gross content and the content of mobile forms was confirmed within the certain areas near the silt fields. For the elements-pollutants (Zn, Cu, Cr, Pb) at some points within the agricultural land, exceeding the values ​​of their gross content and the content of mobile forms (Zn, Cu) of the maximum permissible concentrations was recorded at 1.1-6.2 and 1.1 -2.6 times, respectively. The average values ​​of heavy metals content for floodplains (settlement) and agricultural land near silt fields indicate their prevailing values ​​for the latter in almost all elements, as well as exceeding the background values ​​and maximum permissible concentrations for the land where silt deposits were previously applied as fertilizers. Within the surveyed areas, soils are classified as unsalted, but the increased content of exchangeable magnesium may adversely affect soil fertility. Increased mineralization and content of ammonium and nitrates in groundwater are observed near silt fields, which is obviously related to the impact of silt water and can lead to deterioration of groundwater quality in the area of ​​their transit and discharge, in particular within the village Gnidyn. The area of ​​land with an extremely dangerous pollution rate in terms of total heavy metal is about 300 hectares, with a dangerous pollution rate is 260 hectares, and the estimated damage from crop failure may be 1.65 million UAH/year and 0.3 million UAH/year respectively. Within the areas adjacent to the silt fields, the condition of soils, water resources, cultivated products and the health of the population should be constantly monitored, especially when using the polluted land for agricultural use or housing.

scholarly journals Investigation upon the Edible Snail’s Potential as Source of Selenium for Human Health and Nutrition Observing its Food Chemical Contaminant Risk Factor with Heavy Metals

1970 ◽  
Vol 66 (2) ◽  
Author(s):  
Adrian TOADER-WILLIAMS ◽  
Nadezhda GOLUBKINA
Keyword(s):  
Heavy Metals ◽  
Agricultural Land ◽  
Helix Pomatia ◽  
Selenium Concentration ◽  
Food Product ◽  
Human Consumption ◽  
Snail Species ◽  
Agricultural Activity ◽  
Lead And Cadmium ◽  
Terrestrial Snails

Being much appreciated all over the world for their high nutritional values, escargots or terrestrial snails are farmed in many countries. Within the last few years, snail farming started to become a very popular activity in Romania too. It represents an ecological type of agricultural activity that can also be certified as biological, organic farming if the soil’s conditions and the technology are as such. Extensive amount of research offers details on the physiology of the edible snail species as well as regarding their biochemical content and their nutritional value. No much research reflects snail’s ability to bioaccumulate selenium. In the same time, a lot of research demonstrated the snail’s ability to accumulate contaminants such as heavy metals. Using fluorimetric analysis, we investigated selenium accumulation in meat and shell of edible terrestrial snails Helix pomatia and Eobania vermiculata Muller gathered from different regions of Moldova Republic, Ukraine and Russia. The meat selenium concentration in terrestrial snails reflects the ability of those invertebrates to accumulate high selenium contents. Based on the intake recommendations, snails can be a very good source of selenium for human consumption. Depending upon the soil mineral content and level of contamination, the snails will accumulate large quantities of heavy metals such as lead and cadmium, therefore making the snails a very high-risk food product. Therefore, it is very important a careful selection of the agricultural land designated for snail farming. Additives containing selenium may be a way to supplement snail’s diet.

scholarly journals THE ROLE OF PH IN HEAVY METAL CONTAMINATION OF URBAN SOIL

2014 ◽  
Vol 22 (4) ◽  
pp. 311-318 ◽  
Author(s):  
Asta KAZLAUSKAITĖ-JADZEVIČĖ ◽  
Jonas VOLUNGEVIČIUS ◽  
Virginija GREGORAUSKIENĖ ◽  
Saulius MARCINKONIS
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Urban Soil ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Chemical Elements ◽  
Chemical Reactivity ◽  
Atomic Emission ◽  
Parent Material ◽  
Ph Level

The aim of this study to assess interdependence between urban soil pH and its accumulation of heavy metals. The article meant to be a contribution to a better knowledge of peculiarities and diagnostics of urban soil and its anthropogenic transformation. The hypothesis assumes that relationship between urban soil pH and its accumulation of heavy metals may be determined by the origin and age of parent material as well as the nature and degree of the anthropogenic impact. The spatial variability of topsoil pH level was performed in 100 points in eldership of Šnipiškės of the city Vilnius. Laboratory analysis was based on ISO 10390:2005. Samples were collected from 20 cm topsoil layer in the same sampling points where have been analysed concentrations of topsoil chemical elements using optical atomic emission spectrophotometry. The contamination of urban soils exhibits somewhat different compared to agricultural soils. In contradiction to earlier studies in Lithuanian agricultural soils where strong correlation between soil pH and Cr, Cd, Pb, Ni, Cu and Zd found, the conducted analysis shows a statistically reliable, but very weak (<0.3) correlation between the soil pH and concentration of contaminants. The proof to this correlation is provided by an existing relationship between pH and the concentration of copper (r = 0.20), mercury (r = 0.15), strontium (r = –0.12) and the overall contamination index (r = 0.12). The applied statistical analysis, however, failed to reveal the nature of interdependence between the soil pH and its contamination with studied heavy metals there concentration of contaminant chemical elements depends on the pH range of the soil and, conversely, the chemical reactivity of the soil changes affect on the concentration of studied chemical elements.

scholarly journals MONITORING OF SOILS CONTAMINATION OF SOME REGIONS OF THE REPUBLIC OF ARMENIA WITH HEAVY METALS

2017 ◽  
Vol 17 ◽  
pp. 275-283
Author(s):  
G. A. Hambaryan ◽  
A. V. Santrosyan ◽  
Yu. R. Ishkhanyan
Keyword(s):  
Heavy Metals ◽  
Maximum Permissible Concentration ◽  
Chemical Elements ◽  
Ecological Monitoring ◽  
Ecological Condition ◽  
Background Concentration ◽  
Climatic Zones ◽  
Paradoxical Situation ◽  
Maximum Permissible Concentrations ◽  
The Republic

The paper is devoted to the problems of soils contamination of some regions of the Republic ofArmenia and a city of Yerevan with heavy metals. The results of analyses of the selected soil tests for the purpose ofdefinition of their contamination degree with heavy metals are listed. The statistical data on the background concentration of heavy metals in various soil-climatic zones of the Republic of Armenia, not influenced with appreciable anthropogenous impact is also given. The comparative analysis on presence of polluting chemical elements in soil is carried out for the approved norms of maximum permissible concentration and background indicators. The authors consider possible negative influences on environment as a result of soils contamination, in particular on biological activity of soil and processes of its self-cleaning. It’s noticed that maximum permissible concentrations are mainly developed only from hygienic positions which do not consider the variety ofsoils, in particular, their properties. As an example there are described the results of soils researches of some regions of the Republic of Armenia and there is noticed that a paradoxical situation arises when background contents toxic elements in soils exceed the established values of maximum permissible concentration. In the paper there is arisen the question on necessity of working out and introducing in practice ecological monitoring of the system of tentatively permissible quantity of chemical elements in soil, taking into account background concentration of heavy metals in various soil-climatic zones. Introduction of the specified system will allow reasonably and, what very important, reliably to estimate an ecological condition of soils and to define the influence of contamination on qualitative characteristics of soil as a result of anthropogenous influence.

scholarly journals The Content of Mobile Forms of Heavy Metals in Soils in the Territory of the Recreation Zone «Victory Park» (Saratov)

2020 ◽  
Vol 20 (4) ◽  
pp. 256-261
Author(s):  
Aleksandr S. Sheshnev ◽  
◽  
Vitaliy N. Eremin ◽  
Mikhail V. Reshetnikov ◽  
Oksana V. Teslinova ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Soil Cover ◽  
Maximum Permissible Concentrations ◽  
Mobile Forms ◽  
Geochemical Condition ◽  
Nickel Lead ◽  
Heavy Metals In Soils ◽  
Recreation Zone

The soil cover in the territory of the large recreational zone «Victory Park», which performs environmental, memorial and educational functions, was studied. According to the analysis results of mobile forms of heavy metals concentrations the assessment of the current sanitaryhygienic and ecologic-geochemical condition of soils was carried out. An excess of the maximum permissible concentrations in most of the samples for nickel, lead, and copper was found.

scholarly journals Вміст важких металів у ґрунтах захисних лісових насаджень призалізничних територій

2018 ◽  
pp. 123-130
Author(s):  
В. В. Гупал ◽  
І. Р. Чорнявська
Keyword(s):  
Heavy Metals ◽  
Chemical Elements ◽  
Manganese Content ◽  
Forest Plantations ◽  
Test Plot ◽  
Cobalt Chromium ◽  
Hazard Class ◽  
Mobile Forms ◽  
Forest Reclamation ◽  
Protective Forest

Описано поліфункціональне значення захисних лісових насаджень на шляхах залізничного транспорту та вказано на необхідність вивчення їх лісомеліоративних функцій. Проведено дослідження щодо шкідливого впливу залізничного транспорту на довкілля та істотного забруднення ґрунту рухомими формами важких металів у захисних лісових насадженнях різної конструкції уздовж транспортних магістралей. Надано геохімічну оцінку ґрунтів за вмістом важких металів через гранично допустиму концентрацію (ГДК) та класифікацію хімічних елементів за класами небезпечності. Досліджено залежність між вмістом важких металів у ґрунті та відстанню від колійного полотна. Виявлено рівень забруднення під впливом техногенного середовища залізниць та поширення з відстанню від залізничного полотна рухомих форм свинцю, кадмію, цинку, міді, нікелю, кобальту, хрому, заліза та марганцю у ґрунтах захисних лісових насаджень. The polyfunctional value of protective forest plantations on railway has been described. The necessity of studying their forest reclamation functions is indicated. Constant pollution of the environment requires the immediate solution of urgent environmental and economic problems to ensure a clean future. The influence of railway transport on the environment has been studied. Studies have been carried out on significant soil contamination by mobile forms of heavy metals in protective forest plantations along transport routes. The geochemical assessment of soils by the content of heavy metals is given in accordance with the maximum permissible concentration (MPC). Heavy metals were considered in accordance with the classification of chemical elements by hazard class. The dependence between the content of heavy metals in the soil and the distance from the track has been investigated. The level of pollution and the spread of mobile forms of lead, cadmium, zinc, copper, nickel, cobalt, chromium, iron and manganese in the soils of protective forest plantations under the influence of the technogenic environment of railways was revealed. Compounds of heavy metals extend approximately at the same distance from the track and do not exceed the MPC, with the exception of manganese. At the control section, experiments showed that all chemical elements, except manganese, were at a minimum. After analyzing the test plot data, we found that the proportion of Mn in them is the greatest, (55% in average), and zinc, lead and iron fluctuate – about 9%, which is 6 times less than the manganese content. The rest of heavy metals (Cd, Cu, Co, Ni, Cr) occupy insignificant percentages in the soil, which range up to 5%.

scholarly journals EVALUATION OF REMOVAL OF HEAVY METALS WITH PHYTOMASS ANNUAL HERBS WHEN USING VARIOUS FERTILIZER SYSTEMS

2021 ◽  
pp. 4-6
Author(s):  
A. Ilinskiy
Keyword(s):  
Heavy Metals ◽  
Mineral Fertilizer ◽  
Mineral Fertilizers ◽  
Total Removal ◽  
Lead And Cadmium ◽  
Removal Of Heavy Metals ◽  
Annual Grasses ◽  
Copper Zinc ◽  
Fertilizer System

Under the conditions of a lysimetric experiment on podzolic chernozem, it was found that the use of dolomite flour contributed to a decrease in the mobility of metals and their translocation into crop products, which was reflected in a decrease in their removal relative to the background. The use of mineral fertilizers by increasing the yield of phytomass contributed to an increase in the removal of copper, zinc, lead and cadmium from the soil. The largest total removal of copper, zinc, lead and cadmium with the phytomass of annual grasses (8,035 mg/m2) is observed when using a mineral fertilizer system, and the smallest removal of the indicated metals is observed when using lime without manure (5,092 mg/m2).

scholarly journals ANALYSIS OF BIOLOGICAL ABSORPTION COEFFICIENTS OF HEAVY METALS FOR FODDER BEET

2020 ◽  
Vol 6 (2(71)) ◽  
pp. 9-12
Author(s):  
Andrey Ilinskiy
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Copper Content ◽  
Mineral Fertilizers ◽  
Absorption Coefficients ◽  
Fodder Beet ◽  
Lead And Cadmium ◽  
Root Crops ◽  
Copper Zinc ◽  
By Products

The results of a field lysimetric experiment on podzolized сhernozem to study the coefficients of biological absorption of heavy metals and trace elements for root crops and tops of fodder beets using various systems of mineral fertilizers are presented. Analysis of the empirical series of accumulation of elements in the main and byproducts of fodder beet plants showed that the level of accumulation of zinc, lead and cadmium in root crops is significantly lower than in the tops, and the copper content is relatively evenly distributed between the main and by-products according to the variants of the experiment. In the variant with an increased agrochemical background, there was a decrease in the content of copper, zinc and lead in the main and by-products of feed beets, which may be due to the effect of biological dilution when using mineral fertilizers.

scholarly journals Communities of oribatid mites and heavy metal accumulation in oribatid species in agricultural soils in Egypt impacted by waste water

2010 ◽  
Vol 46 (No. 4) ◽  
pp. 159-170 ◽  
Author(s):  
H.M. El-Sharabasy ◽  
A. Ibrahim
Keyword(s):  
Waste Water ◽  
Heavy Metals ◽  
Heavy Metal ◽  
Agricultural Land ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Diversity Index ◽  
Heavy Metal Accumulation ◽  
Oribatid Mites ◽  
The Body

The continued use of waste water for irrigation of agricultural fields in Egypt may lead to accumulation of heavy metals in soils and adverse effects on soil-living communities. We investigated responses of oribatid communities to heavy metal contamination in mango plantations irrigated by the Ismailia canal in the Suez region. Mean concentrations of heavy metals determined in irrigation water were considerably above the recommended levels. Concentrations of metals in agricultural soil were however below the permissible levels. A comparison with concentrations of a typical uncontaminated soil in this area revealed that the Ismailia water canal used for irrigation of agricultural land has elevated levels of heavy metals. The results of our ecological survey showed that the abundance and structure of the soil oribatid communities were not influenced by levels of heavy metals in the soil. We also showed that the diversity index can be a valuable tool for assessing the possible impact of pollutants on different species of oribatid mites. The oribatid species appeared to be accumulating different amounts of heavy metals when characterised by their bioconcentration factors. Most species were poor zinc accumulators. The accumulation of heavy metals in the body of oribatids was not strictly determined by their body size or by the trophic level. In conclusion, our study showed that mango plantations impacted by waste water from the Ismailia canal are accumulating heavy metals in their soils above the background concentrations, but ecological effects on soil-living communities are not apparent yet.

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