scholarly journals THE ROLE OF PH IN HEAVY METAL CONTAMINATION OF URBAN SOIL

2014 ◽  
Vol 22 (4) ◽  
pp. 311-318 ◽  
Author(s):  
Asta KAZLAUSKAITĖ-JADZEVIČĖ ◽  
Jonas VOLUNGEVIČIUS ◽  
Virginija GREGORAUSKIENĖ ◽  
Saulius MARCINKONIS
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Urban Soil ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Chemical Elements ◽  
Chemical Reactivity ◽  
Atomic Emission ◽  
Parent Material ◽  
Ph Level

The aim of this study to assess interdependence between urban soil pH and its accumulation of heavy metals. The article meant to be a contribution to a better knowledge of peculiarities and diagnostics of urban soil and its anthropogenic transformation. The hypothesis assumes that relationship between urban soil pH and its accumulation of heavy metals may be determined by the origin and age of parent material as well as the nature and degree of the anthropogenic impact. The spatial variability of topsoil pH level was performed in 100 points in eldership of Šnipiškės of the city Vilnius. Laboratory analysis was based on ISO 10390:2005. Samples were collected from 20 cm topsoil layer in the same sampling points where have been analysed concentrations of topsoil chemical elements using optical atomic emission spectrophotometry. The contamination of urban soils exhibits somewhat different compared to agricultural soils. In contradiction to earlier studies in Lithuanian agricultural soils where strong correlation between soil pH and Cr, Cd, Pb, Ni, Cu and Zd found, the conducted analysis shows a statistically reliable, but very weak (<0.3) correlation between the soil pH and concentration of contaminants. The proof to this correlation is provided by an existing relationship between pH and the concentration of copper (r = 0.20), mercury (r = 0.15), strontium (r = –0.12) and the overall contamination index (r = 0.12). The applied statistical analysis, however, failed to reveal the nature of interdependence between the soil pH and its contamination with studied heavy metals there concentration of contaminant chemical elements depends on the pH range of the soil and, conversely, the chemical reactivity of the soil changes affect on the concentration of studied chemical elements.

scholarly journals Features of Heavy Metal Contamination of Agricultural Soils in the Kursk Region of Russia and Economic Assessment of Restoration

2021 ◽  
Vol 110 ◽  
pp. 01022
Author(s):  
Vladimir Tomakov ◽  
Maxim Tomakov
Keyword(s):  
Heavy Metals ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Chemical Elements ◽  
Statistical Processing ◽  
Economic Assessment ◽  
Local Areas ◽  
Lead Zinc ◽  
Quantitative Spectral Analysis ◽  
Kursk Region

Kursk region of Russia has unique fertile soils. Heavy metals are among the factors that pollute the soil. The article is devoted to the study of the spatial distribution of heavy metals in soils. The relevance of the study is that the value of the soil is determined by its value for obtaining environmentally friendly agricultural products. Data on the content of heavy metals in the soil can prevent intensive cultivation of crops. The task of the work is to identify heavy metals that predominate in the soils of various landscapes of the Kursk region. The assessment of soil contamination with chemical elements was carried out in the course of geo-ecological studies of black earth soils in the Kursk region of Russia. The selected soil samples were examined by semi-quantitative spectral analysis. The results obtained were subjected to statistical processing. It was found that cobalt is the main pollutant in the vast majority of sampling points. In other zones, molybdenum, lead, zinc, and chromium predominate in approximately equal amounts. Soils in the surveyed area belong to the permissible category of contamination with chemical elements. Soil remediation should be applied in local areas.

A Comprehensive Review of Minerals, Trace Elements, and Heavy Metals in Saffron

2022 ◽  
Vol 23 ◽  
Author(s):  
Sayyed Mohammad Ali Noori ◽  
Mohammad Hashemi ◽  
Sajjad Ghasemi
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Chemical Elements ◽  
Absorption Spectrometry ◽  
Atomic Emission ◽  
Emission Spectrometry ◽  
Inductively Coupled ◽  
Wide Range ◽  
The World

Abstract: Saffron is one of the most expensive spices in the world, and its popularity as a tasty food additive is spreading rapidly through many cultures and cuisines. Minerals and heavy metals are minor components found in saffron, which play a key role in the identification of the geographical origin, quality control, and food traceability, while they also affect human health. The chemical elements in saffron are measured using various analytical methods, such as techniques based on spectrometry or spectroscopy, including atomic emission spectrometry, atomic absorption spectrometry, inductively coupled plasma optical emission spectrometry, and inductively coupled plasma mass spectrometry. The present study aimed to review the published articles about heavy metals and minerals in saffron across the world. To date, 64 chemical elements have been found in different types of saffron, which could be divided into three groups of macro-elements, trace elements, and heavy metals (trace elements with a lower gravity/greater than five times that of water and other inorganic sources). Furthermore, the chemical elements in the saffron samples of different countries have a wide range of concentrations. These differences may be affected by geographical condition such as physicochemical properties of the soil, weather and other environmental conditions like saffron cultivation and its genotype.

Heavy Metal Contamination in Swampy Agricultural Soils of Kokona, Nasarawa, Nigeria

2020 ◽  
pp. 28-33
Author(s):  
Usman Rilwan ◽  
Auta Abdullahi Abbas ◽  
Hudu Abdulrahman
Keyword(s):  
Heavy Metals ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Soil Samples ◽  
Limit Set ◽  
X Ray ◽  
Heavy Metals Accumulation ◽  
Regulatory Bodies ◽  
Safe Limit

Absorption of heavy metals through swampy agricultural soils may have serious consequences on human health. Present study determined the levels of Chromium (Cr), Nickel (Ni), Copper (Cu), Zinc (Zn), Arsenic (As), Cadmium (Cd) and Lead (Pb) using X- Ray Spectrometry in 10 swampy agricultural soils. The result of this study revealed that, the heavy metals with their respective concentrations (Cr (278.1), Ni (462.1), Cu (314.1), Zn (502.8), As (13.5), Cd (524.5) and Pb (295.5)) were found in the soil samples in mg/kg. It also pointed out that the concentration of the heavy metals in the all soil samples for all locations in decreasing order was Cd > Zn >Ni > Cu >Pb > Cr >As. The concentration in swampy agricultural soils from Kokona was obviously higher than the safe limit set by the regulatory bodies which may be because of the geological activities in the studied area. Hence, heavy metals accumulation in swampy agricultural soils is a big concern in Kokona where people’s daily meal largely contains rice or rice based products which are mostly cultivated in swampy agricultural soils.

HEAVY METALS IN CULTIVATED SOILS AND IN CEREAL CROPS IN ALBERTA

1977 ◽  
Vol 57 (3) ◽  
pp. 329-339 ◽  
Author(s):  
M. J. DUDAS ◽  
S. PAWLUK
Keyword(s):  
Heavy Metals ◽  
Plant Material ◽  
Surface Soil ◽  
Agricultural Soils ◽  
Essential Elements ◽  
Local Scale ◽  
Parent Material ◽  
Cereal Crops ◽  
Lead And Zinc ◽  
Cereal Grain

The content of cadmium, cobalt, copper, mercury, manganese, nickel, strontium, lead and zinc in several agricultural soils in Alberta was investigated. The abundances of these heavy metals were found to be low and represent levels naturally present in uncontaminated soils. Both pedogenesis and nature of parent material influenced the levels of heavy metals in surface soil horizons. On a local scale, drainage and groundwater effects contributed significantly to heavy metal redistribution in soil. Levels of heavy metals were also determined in seeds and straw of cereal grain crops grown on the soils of this study. Vegetative samples generally contained low amounts of heavy metals and for some of the physiologically essential elements (Cu, Mn, Zn), amounts in the plant material were at or near deficiency levels. Amounts of cadmium, mercury and lead were generally significantly higher in straw than in respective seed samples.

scholarly journals HEAVY METALS POLLUTION OF WHEAT FIELDS (SOIL AND LEAVES) SAMPLED FROM BASRAH AND MAYSAN PROVINCES

2020 ◽  
Vol 17 (35) ◽  
pp. 315-326
Author(s):  
Qusai Hattab MADHI ◽  
Mohammed Hamza ABASS ◽  
Abdulnabi Abdul Ameer MATROOD
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Negative Correlation ◽  
Agricultural Soils ◽  
Significant Negative Correlation ◽  
Soil Characteristics ◽  
Lead Content ◽  
Significant Difference ◽  
Heavy Metals Pollution ◽  
Wheat Leaves

This study was conducted to estimate the level of some heavy metals, mainly Lead (Pb), cadmium (Cd), chromium (Cr) and cobalt (Co) in the soil and wheat leaves of some wheat fields in Basra and Maysan province; the sampling areas were Al-Qurna, Al-Madinah, Al-Amara, Kumit, Ali Al-Sharqi, and Ali Al-Gharbi. It was performed the analysis using the Flame Atomic Spectrophotometer. The results indicated an increase in the concentrations of above mentioned these heavy metals in all examined areas; the levels in agricultural soils were found to be exceeding the internationally permissible limits according to EU-2000 standards, the highest levels of pollution were observed at Al- Qurna site with significant differences than other sites for both available and total HMs concentrations in soils. Indicating that the arrangement of the metals according to their available concentrations in the analyzed soil was as follows: lead (21.32 )˃ cobalt (14.63) ˃ chromium (11.06) ˃ cadmium (1.15) as mg/Kg of soil. Additionally, results showed that the highest lead content in the wheat leaves was examined in the Qurna fields (0.175 mg/kg), followed by Amara with a concentration of 0.136 mg/kg. The lowest concentration of lead was observed in wheat leaves in the Kumit fields (0.007 mg/kg). In terms of Cd concentration in wheat leaves, the highest level was observed in Al-Qurna, with a significant difference from other fields, reaching 0.009 mg/kg. The lowest concentration of this HM was recorded in Ali Al-Gharbi, which reached 0.002 mg/kg. The results of the correlation between the available concentration of heavy metals elements and soil characteristics revealed a significant correlation between the soil pH and lead, cadmium, and chromium available concentrations, whereas no correlation with cobalt and a significant correlation between soil EC and lead was observed and a highly significant negative correlation with the cobalt. Results proved the high levels of pollution in all examined areas in Basra and Maysan provinces.

scholarly journals Communities of oribatid mites and heavy metal accumulation in oribatid species in agricultural soils in Egypt impacted by waste water

2010 ◽  
Vol 46 (No. 4) ◽  
pp. 159-170 ◽  
Author(s):  
H.M. El-Sharabasy ◽  
A. Ibrahim
Keyword(s):  
Waste Water ◽  
Heavy Metals ◽  
Heavy Metal ◽  
Agricultural Land ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Diversity Index ◽  
Heavy Metal Accumulation ◽  
Oribatid Mites ◽  
The Body

The continued use of waste water for irrigation of agricultural fields in Egypt may lead to accumulation of heavy metals in soils and adverse effects on soil-living communities. We investigated responses of oribatid communities to heavy metal contamination in mango plantations irrigated by the Ismailia canal in the Suez region. Mean concentrations of heavy metals determined in irrigation water were considerably above the recommended levels. Concentrations of metals in agricultural soil were however below the permissible levels. A comparison with concentrations of a typical uncontaminated soil in this area revealed that the Ismailia water canal used for irrigation of agricultural land has elevated levels of heavy metals. The results of our ecological survey showed that the abundance and structure of the soil oribatid communities were not influenced by levels of heavy metals in the soil. We also showed that the diversity index can be a valuable tool for assessing the possible impact of pollutants on different species of oribatid mites. The oribatid species appeared to be accumulating different amounts of heavy metals when characterised by their bioconcentration factors. Most species were poor zinc accumulators. The accumulation of heavy metals in the body of oribatids was not strictly determined by their body size or by the trophic level. In conclusion, our study showed that mango plantations impacted by waste water from the Ismailia canal are accumulating heavy metals in their soils above the background concentrations, but ecological effects on soil-living communities are not apparent yet.

Risk Implications of Heavy Metal Contamination in Agricultural Soil and Crop Productivity

2018 ◽  
pp. 238-258
Author(s):  
Archana ◽  
Ajai Kumar Jaitly
Keyword(s):  
Heavy Metals ◽  
Contaminated Soils ◽  
Metal Contamination ◽  
Agricultural Soil ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Anthropogenic Activities ◽  
Crop Productivity ◽  
Cobalt Chromium ◽  
Lead Nickel

Heavy metals especially lead, nickel, cadmium, copper, cobalt, chromium and mercury are more toxic and chief contaminants of the environment. Agricultural soils in many parts of the world are slightly to moderately polluted with heavy metals due to increase in geologic and anthropogenic activities (use of phosphate fertilizers, sewage sludge application, dust from smelters, industrial waste). Plants growing on these contaminated soils showed toxicity symptoms that results in reduce growth and activity which declined the productivity and posing threats to agro-ecosystems. They put plants under stress and affect their physiology. In this chapter, we have summarized the effects of heavy metals on plants including both symptoms and productivity.

scholarly journals Vertical Distribution and Controlling Factors Exploration of Sc, V, Co, Ni, Mo and Ba in Six Soil Profiles of The Mun River Basin, Northeast Thailand

2020 ◽  
Vol 17 (5) ◽  
pp. 1745
Author(s):  
Wenxiang Zhou ◽  
Guilin Han ◽  
Man Liu ◽  
Chao Song ◽  
Xiaoqiang Li ◽  
...  
Keyword(s):  
Heavy Metals ◽  
River Basin ◽  
Soil Ph ◽  
Soil Texture ◽  
Heavy Metal Contamination ◽  
Geoaccumulation Index ◽  
Controlling Factors ◽  
Soil Profiles ◽  
Northeast Thailand ◽  
Mo Content

Exploring the enrichment and controlling factors of heavy metals in soils is essential because heavy metals can cause severe soil contamination and threaten human health when they are excessively enriched in soils. Soil samples (total 103) from six soil profiles (T1 to T6) in the Mun River Basin, Northeast Thailand, were collected for the analyses of the content of heavy metals, including Sc, V, Co, Ni, Mo, Ba. The average contents of soil heavy metals decrease in the following order: Ba, V, Ni, Sc, Co, and Mo (T1, T3, T4 and T5); Ni, V, Ba, Co, Sc, Mo, and Ba (T2); Ba, V, Sc, Ni, Mo, and Co (T6). An enrichment factor (EF) and geoaccumulation index were calculated to assess the degree of heavy metal contamination in the soils. The EFs of these heavy metals in most samples range from 0 to 1.5, which reveals that most heavy metals are slightly enriched. Geoaccumulation indexes show that only the topsoil of T1 and T2 is slightly contaminated by Ba, Sc, Ni, and V. Soil organic carbon (SOC), soil pH and soil texture are significantly positively correlated with most heavy metals, except for a negative correlation between soil pH and Mo content. In conclusion, the influence of heavy metals on soils in the study area is slight and SOC, soil pH, soil texture dominate the behavior of heavy metals.

scholarly journals The Heavy Metal Hazard of undiscovered World War I and II graves in Poland

2018 ◽  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
World War I ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Chemical Elements ◽  
World War ◽  
Human Settlements ◽  
Mass Graves

<p>The purpose of this research is to identify and characterize the poorly investigated problem of heavy metal contamination originating from World War I and II mass graves. Chemical elements pass systematically into the soil from metal weapons, buttons, badges, and other objects. As a result, the soil and groundwater become highly saturated with heavy metals relative to metals from communal waste. A review of previous analyses of the areas surrounding localized graves in southeast Poland revealed chemicals leached from burials to have a significant impact on the environment and groundwater. This review highlights the danger posed by mass graves that are frequently located near human settlements and rivers. However, the exact locations of the majority of mass graves are unknown and the heavy metal hazard warrants their identification and reburial in an appropriate place.</p>

scholarly journals ACCUMULATION OF HEAVY METALS IN THE SOILS OF FOOTHAL AREAS OF KRASNODAR KRAY

2019 ◽  
Vol 14 (1) ◽  
pp. 22-26
Author(s):  
Анастасия Забашта ◽  
Anastasiya Zabashta ◽  
Николай Забашта ◽  
Nikolay Zabashta
Keyword(s):  
Heavy Metals ◽  
Agricultural Land ◽  
Agricultural Soils ◽  
Chemical Elements ◽  
Arable Land ◽  
Mineral Fertilizers ◽  
North Caucasus ◽  
Lead And Cadmium ◽  
Maximum Permissible Concentrations ◽  
Mobile Forms

The accumulation of heavy metals, primarily from the soil, takes place in the water and fodder plants. Sources are pesticides, polluted air and precipitation. Hazardous chemical elements in certain quantities enter plants from soil. It should be added that ballast substances from mineral fertilizers containing heavy metals are also found in the soil. It has been established that on the flat-foothill massif of the North Caucasus, the constant component of solid precipitation are such elements as chromium, nickel, lead, manganese and silver. Cadmium was not detected in most precipitation samples (less than 1.0 µg / l), but its concentrations exceeded the maximum permissible concentrations by 4–8 times, although its sources were not identified. Therefore, an agrochemical survey of agricultural land has been carried out and it has been established that the content of mobile forms of copper and zinc in the soils of the foothill areas does not exceed the maximum permissible concentrations. Meadow grass stands do not accumulate zinc, copper, lead and cadmium in quantities exceeding the maximum allowable levels. In general, in the foothill areas of the Krasnodar Territory, hay contains 11.0–25.0 mg/kg of zinc, 1.8–9.0 mg/kg of copper, 0.2–2.0 mg/kg of lead, and 0.06– 0.24 mg/kg cadmium. Studies have shown that the agricultural soils of the foothill areas do not contain exceeding MPC values of mobile forms of zinc and copper. But there are local foci containing lead in small quantities. In hay from arable land and natural forage lands, the amount of heavy metals does not exceed MDU.

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