Magnetic and Optical Anisotropy in Garnets Induced by Linearly Polarized Light

Author(s):  
I.I. Davidenko ◽  
M. Fally ◽  
R. A. Rupp ◽  
B. Sugg
1998 ◽  
Vol 537 ◽  
Author(s):  
H. Shen ◽  
M. Wraback ◽  
J. Pamulapati ◽  
S. Liang ◽  
C. Gorla ◽  
...  

AbstractIn this paper, we present a detailed study of high quality (110) ZnO films, epitaxially grown on R-plane sapphire substrates by metal-organic chemical vapor deposition (MOCVD). The epitaxial relationships are (1120) ZnO//(0112) Al2O3 and {0001} ZnO//[0111] A12O3 as confirmed by X-ray diffraction (θ-2θ, and φ-scan) and high-resolution cross-sectional transmission electron microscopy (HR-TEM). Low temperature photoluminescence (PL) indicates the ZnO thin films are almost strain free. Optical absorption and reflection measurements with linearly polarized light indicate a strong optical anisotropy. The polarization rotation towards the C-axis associated with the optical anisotropy is utilized to demonstrate an optically addressed ultra-fast, ultraviolet light modulator.


e-Polymers ◽  
2006 ◽  
Vol 6 (1) ◽  
Author(s):  
Ewa Schab-Balcerzak ◽  
Beate Sapich ◽  
Joachim Stumpe ◽  
Anna Sobolewska ◽  
Andrzej Miniewicz

AbstractNovel photochromic polyesterimides (PEIs) with two different types of azobenzene units as side groups have been synthesized from 2,2’-{4-[(4- nitrophenyl)-azo} phenyl]iminobis(ethyl benzene-1,2-dicarboxylic acid anhydride-4- carboxylate) and diamines: 2,4-diamino-4’-methylazobenzene and 2,4-diamino-4’- (trifluoromethoxy)azobenzene. An analogous polyesterimide with one azobenzene group based on 1,3-phenylendiamine has been prepared to compare with these PEIs. Molecular structural characterization for these polymers has been achieved by FTIR, 1H NMR and UV-Vis spectroscopy. These amorphous polyesterimides are thermally stable up to 260°C as follows from the thermogravimetric analysis (TGA). The glass transition temperatures (Tg) for the resulting polyimides have been determined from DSC thermograms and are in the range of 141-210°C. The irradiation with linearly polarized light of an Ar+ laser results in the induction of optical anisotropy within the initially isotropic films. Light induced optical anisotropy in polymer films has been studied by examining the value of generated dichroism using Ar+ laser (λ = 488 nm) and by holographic polarization grating recording performed at λ = 514.5 nm. The value of photoinduced dichroism is in the range of 0.15-0.26. The induction of dichroism and kinetics of grating inscription have been investigated in relation to the presence of the second type of azobenzene group in the polymer and its substitution.


2003 ◽  
Vol 12 (04) ◽  
pp. 495-511 ◽  
Author(s):  
L. M. BLINOV ◽  
R. BARBERI ◽  
F. CIUCHI ◽  
M. P. DE SANTO ◽  
G. CIPPARRONE ◽  
...  

A comparative study of photo-induced optical anisotropy was carried out on Langmuir–Blodgett films prepared from five different amphiphilic azobenzene derivatives. The anisotropy was induced by a linearly polarized pump beam of an Ar-ion laser at λ=514 nm and monitored by a linearly polarized probe beam of a He–Ne laser at λ=633 nm . Large optical anisotropy up to 0.35 has been induced. Holographic gratings were recorded by two left circularly polarized beams of the Ar-ion laser and time evolution of the first-order diffraction efficiency of the probe beam was recorded in an automatic regime. In such a geometry, the spatial modulation of refraction index reaches 0.14. The experimental data is consistent with a model for a photo-induced collective chromophore realignment in the heterogeneous domain structure of the films studied. The influence of an electric field of the corona discharge on the grating recording process was also studied and polar diffraction gratings have been prepared by a spatially periodic photo-poling process.


Symmetry ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 760
Author(s):  
Masahiro Takase ◽  
Shiomi Yagi ◽  
Tomoyuki Haraguchi ◽  
Shabana Noor ◽  
Takashiro Akitsu

Three dinuclear metal complexes (comprised of six-coordinated nNi2L and five-coordinated nCu2L and nZn2L) were confirmed by means of elemental analysis, UV-vis and IR spectra, and single X-ray crystal structural analysis in a spectroscopic study. The stable structures of these nNi2L, nCu2L, and nZn2L complexes in poly(vinylalcohol) (PVA) films were analyzed using UV-vis spectra. The molecular orientation of hybrid PVA film materials after linearly polarized light irradiation was analyzed to obtain the polarized spectra and dichroic ratio. Among the three materials, nNi2L and nZn2L complexes indicated an increasing optical anisotropy that depended on the flexibility of the complexes. We have included a discussion on the formation of the pseudo-crystallographic symmetry of the components in a soft matter (PVA films).


Author(s):  
M. Davidenko ◽  
I. Davidenko ◽  
V. Kravchenko ◽  
O. Mokrinska ◽  
V. Pavlov ◽  
...  

The films of polymeric composites containing monomers of azobenzene dyes or azobenzene lateral groups chemically bonded to the main polymer chain demonstrate photoactive properties, and can be used in electrooptical light modulators and in recording media (RM) for polarization holography. Photoinduced optical anisotropy (PIA) appears under influence of linearly polarized light caused by the processes of trans-cis-izomerization of the azobenzene groups. This process is determining for application of the considered materials as RM for polarization holography. The films of polymeric polarization sensitive media based on a copolymer of styrene with nonyl methacrylate doped with azobenzene-type dyes with different electron-acceptor substituents are obtained in this work. In the films of copolymer the holograms of the plane wave front were registered for parallel and orthogonal orientations of polarization vectors of the object and reference light beams. Their photoelectrophysical, in particular photodielectric, and information properties are investigated. It was established, that when the mutual orientation of the recording beams changes from the orthogonal to parallel orientation the diffraction efficiency of the holograms increases in the case of using azo dye with the maximum number of auxochromic substituents in the molecule. The effect of the diffraction efficiency dependence on the chromophores structure is connected with the deepening of dye color. The photo-induced optical anisotropy in the films appears due to a change of the concentration ratio of trans- and cis-isomers of azobenzene dye fragments. This conclusion is confirmed by the photodielectric measurements data, namely, by the negative sign of the photodielectric effect, observed experimentally in the investigated thin film structures. It was shown, that investigated compositions can be used as information media for polarization holography.


2020 ◽  
pp. 65-69
Author(s):  
Nataliia Mykhailivna Kovtun ◽  
Ihor Volodymyrovych Kaplin

The parameters of interference patterns observed on the cornea in a polarized light in pathology of extraocular muscles were quantitatively evaluated. A study of the shape of 147 interference patterns observed on the cornea in a polarized light showed that the horizontal deviation of an eye in 56 % of cases was caused by the displacement of the attachment of the upper rectus muscle towards the inner rectus muscle. During illumination of the cornea of a live eye with polarized light, a specific interference pattern in the form of a rhombus formed by rainbow stripes (isochromes) is observed. It is established that such an interference pattern is the result of the influence of extraocular muscles on the cornea. The findings showed that the weakening of the force of one of muscles leads to asymmetric distortion of the shape of the interference rhombus, which is manifested with a reduced length of the corresponding section of the diagonal. On the contrary, as the force of the muscle increases, the corresponding section of the diagonal enhances. The displacement of the attachment site of direct extraocular muscle along the line of action is equivalent to a change in effort on its part, indicated appropriately by the shape of the interference rhombus. As the muscle moves away from the line of action, the angle of the interference rhombus is shifted away from the corresponding meridian. Key words: polarized light, optical anisotropy, cornea, extra−ocular muscles, interference picture.


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1718
Author(s):  
Qian Kong ◽  
Manna Gu ◽  
Xiangyu Zeng ◽  
Rui Sun ◽  
Yuqin Zhang ◽  
...  

Manipulation of multichannel vector beams (VBs) with metasurfaces is an important topic and holds potential applications in information technology. In this paper, we propose a novel metasurface for the generation of dual VBs, which is composed of orthogonal slit pairs arranged on multiple groups of combined semicircular rings (CSRs). A group of CSRs include a right-shifted set and a left-shifted set of semicircular rings, and each set of semicircular rings has two halves of circles with different radii, sharing the same shifted center. Under the illumination of linearly polarized light, the two shifted sets of semicircular rings generate the two VBs at the shifted center positions on the observation plane. The slit units of each set are designed with independent rotation order and initial orientation angle. By adjusting the linear polarization of illumination, both two VBs with their orders and polarization states are independently controlled simultaneously. The principle and design are demonstrated by the finite-difference time domain (FDTD) simulation. The work is of significance for miniatured devices of VB generators and for related applications.


2020 ◽  
Vol 126 (9) ◽  
Author(s):  
Joachim Jelken ◽  
Carsten Henkel ◽  
Svetlana Santer

Abstract We study the peculiar response of photo-sensitive polymer films irradiated with a certain type of interference pattern where one interfering beam is S-polarized, while the second one is P-polarized. The polymer film, although in a glassy state, deforms following the local polarization distribution of the incident light, and a surface relief grating (SRG) appears whose period is half the optical one. All other types of interference patterns result in the matching of both periods. The topographical response is triggered by the alignment of photo-responsive azobenzene containing polymer side chains orthogonal to the local electrical field, resulting in a bulk birefringence grating (BBG). We investigate the process of dual grating formation (SRG and BBG) in a polymer film utilizing a dedicated set-up that combines probe beam diffraction and atomic force microscopy (AFM) measurements, and permits acquiring in situ and in real-time information about changes in local topography and birefringence. We find that the SRG maxima appear at the positions of linearly polarized light (tilted by 45° relative to the grating vector), causing the formation of the half-period topography. This permits to inscribe symmetric and asymmetric topography gratings with sub-wavelength period, while changing only slightly the polarization of one of the interfering beams. We demonstrate an easy generation of sawtooth profiles (blazed gratings) with adjustable shape. With these results, we have taken a significant step in understanding the photo-induced deformation of azo-polymer films.


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