Superplasticizer and Silica Fume Addition Effects on Heat of Hydration of Mortar Mixes with Low Water-Cementitious Materials Ratio

10.14359/663 ◽  
1999 ◽  
Vol 96 (5) ◽  
Keyword(s):  
Silica Fume ◽  
Cementitious Materials ◽  
Heat Of Hydration

scholarly journals Influence of quartz powder and silica fume on the performance of Portland cement

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Ludmila Rodrigues Costa Tavares ◽  
Joaquim Francisco Tavares Junior ◽  
Leonardo Martins Costa ◽  
Augusto Cesar da Silva Bezerra ◽  
Paulo Roberto Cetlin ◽  
...  
Keyword(s):  
Portland Cement ◽  
Silica Fume ◽  
Electrical Resistance ◽  
Cementitious Materials ◽  
Pozzolanic Reaction ◽  
Heat Of Hydration ◽  
Supplementary Cementitious Materials ◽  
Cementitious Composites ◽  
Quartz Powder ◽  
Hydration Properties

AbstractSupplementary cementitious materials interact chemically and physically with cement, influencing the formation of hydrate compounds. Many authors have analyzed the filler and pozzolanic effect. However, few studies have explored the influence of these effects on hydration, properties in the fresh and hardened states, and durability parameters of cementitious composites separately. This study investigates the influence of the replacement of 20% of Portland cement for silica fume (SF) or a 20-µm medium diameter quartz powder (QP) on the properties of cementitious composites from the first hours of hydration to a few months of curing. The results indicate that SF is pozzolanic and that QP has no pozzolanic activity. The use of SF and QP reduces the released energy at early times to the control paste, indicating that these materials reduce the heat of hydration. The microstructure with fewer pores of SF compounds indicates that the pozzolanic reaction reduced pore size and binding capability, resulting in equivalent mechanical properties, reduced permeability and increased electrical resistance of the composites. SF and QP increase the carbonation depth of the composites. SF and QP composites are efficient in the inhibition of the alkali-aggregate reaction. The results indicate that, unlike the filler effect, the occurrence of pozzolanic reaction strongly influences electrical resistance, reducing the risk of corrosion of the reinforcement inserted in the concrete.

scholarly journals Effect of a Nitrite/Nitrate-Based Accelerator on the Strength Development and Hydrate Formation in Cold-Weather Cementitious Materials

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1006
Author(s):  
Akira Yoneyama ◽  
Heesup Choi ◽  
Masumi Inoue ◽  
Jihoon Kim ◽  
Myungkwan Lim ◽  
...  
Keyword(s):  
Calcium Nitrate ◽  
Hydrate Formation ◽  
Frost Damage ◽  
Cementitious Materials ◽  
Heat Of Hydration ◽  
Cold Weather ◽  
Strength Development ◽  
Hardened Cement ◽  
Tricalcium Aluminate ◽  
Nitrite Nitrate

Recently, there has been increased use of calcium-nitrite and calcium-nitrate as the main components of chloride- and alkali-free anti-freezing agents to promote concrete hydration in cold weather concreting. As the amount of nitrite/nitrate-based accelerators increases, the hydration of tricalcium aluminate (C3A phase) and tricalcium silicate (C3S phase) in cement is accelerated, thereby improving the early strength of cement and effectively preventing initial frost damage. Nitrite/nitrate-based accelerators are used in larger amounts than usual in low temperature areas below −10 °C. However, the correlation between the hydration process and strength development in concrete containing considerable nitrite/nitrate-based accelerators remains to be clearly identified. In this study, the hydrate composition (via X-ray diffraction and nuclear magnetic resonance), pore structures (via mercury intrusion porosimetry), and crystal form (via scanning electron microscopy) were determined, and investigations were performed to elucidate the effect of nitrite/nitrate-based accelerators on the initial strength development and hydrate formation of cement. Nitrite/nitrate-AFm (aluminate-ferret-monosulfate; AFm) was produced in addition to ettringite at the initial stage of hydration of cement by adding a nitrite/nitrate-based accelerator. The amount of the hydrates was attributed to an increase in the absolute amounts of NO2− and NO3− ions reacting with Al2O3 in the tricalcium aluminate (C3A phase). Further, by effectively filling the pores, it greatly contributed to the enhancement of the strength of the hardened cement product, and the degree of the contribution tended to increase with the amount of addition. On the other hand, in addition to the occurrence of cracks due to the release of a large amount of heat of hydration, the amount of expansion and contraction may increase, and it is considered necessary to adjust the amount used for each concrete work.

Use of Algerian Natural Mineral Deposit as Supplementary Cementitious Materials

2018 ◽  
Vol 34 ◽  
pp. 48-58 ◽  
Author(s):  
Karima Arroudj ◽  
Saida Dorbani ◽  
Mohamed Nadjib Oudjit ◽  
Arezki Tagnit-Hamou
Keyword(s):  
Mechanical Strength ◽  
Calcium Hydroxide ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Pozzolanic Reaction ◽  
Heat Of Hydration ◽  
Cement Industry ◽  
Supplementary Cementitious Materials ◽  
Natural Mineral ◽  
Different Ages

Much of the current research on concrete engineering has been focused on including siliceous additions as supplementary cementitious materials (SCMs). Silica reacts with Calcium hydroxide release during cement hydration, and produces more C-S-H. The latter contributes to increase compactness, mechanical strengths and sustainability of concrete. This paper explores the hydration characteristics of cement paste based on various natural mineral additions, that are very abundant in Algeria and present a high silica content (ground natural pozzolana “PZ” and ground dune sand “DS”). For this purpose, several analyses were carried out on modified cement pastes and mortars. TheseSCMswere introduced by replacement levels of 15, 20 and 25 by weight of cement. We first, studied the effect of these SCMs on the heat of hydration and mechanical strength of mortars at different ages. The evolution of hydration of modified paste was studied, by using Thermal analysis (TG/TDA) at different ages, to analyze the Calcium Hydroxide (CH) content of the modified pastes. It is shown that the CH content of the mixes including SCMs is lower than that of the plain cement paste, indicating that silica reacts with the cement paste through a pozzolanic reaction. Increased pozzolanic activity results in higher amounts of Calcium Silicate Hydrate in the paste, which in turn results in higher compressive strength for modified cement mortars. Due to its crystalline morphology, the ground DS particles present a partial pozzolanic effect, compared to PZ which is semi-crystalline. Modified mortars by 20% DS can be the optimal composition. It presents satisfactory results: good mechanical strength and low heat of hydration. It can lead to an economic and sustainable concrete. Ground DS is very abounded in Africa and free of any impurities and can be a good alternativeSCMsin cement industry.

Packing Density Improvement for Improving Strength of Cement Paste

2019 ◽  
Vol 943 ◽  
pp. 124-128 ◽  
Author(s):  
Jian Jian Chen ◽  
Hong Niao Chen ◽  
Gu Li
Keyword(s):  
Silica Fume ◽  
Packing Density ◽  
Water Film ◽  
High Strength ◽  
Cementitious Materials ◽  
Maximum Strength ◽  
Depth Analysis ◽  
Fuel Ash ◽  
Pulverized Fuel ◽  
Pulverized Fuel Ash

To design a mix for high-strength concrete is not easy, one of the methods is to improve the packing density of the cementitious materials. To study the effect of packing density on strength, a comprehensive research program using superfine pulverized fuel ash and silica fume was carried out. Results showed that a high superfine pulverized fuel ash and silica fume ratios could result in a lower optimum W/CM ratio for maximum strength. Depth analysis illustrated that the optimum water film thickness for maximum strength is always at around 0.01 to 0.05 μm, regardless of the SPFA and SF ratios.

Improvements on Mechanical Property and Microstructure of Cementitious Composite Incorporated with Silica Fume and Carbon Nanotube

2019 ◽  
Vol 298 ◽  
pp. 167-171
Author(s):  
Gu Yue Han ◽  
Jian Lin Luo
Keyword(s):  
Compressive Strength ◽  
Carbon Nanotube ◽  
Silica Fume ◽  
Cementitious Materials ◽  
Filler Loading ◽  
Cement Matrix ◽  
Ultrasonic Dispersion ◽  
Integrated Network ◽  
Positive Effects ◽  
Ultrafine Silica

Nano-size fillers (ultrafine silica fume (USF) or/and multi-walled carbon nanotube (MWCT)) were incorporated into cement matrix to fabricate nano-fillers reinforced cementitious materials (NFRCs) with surfactant ultrasonic dispersion and subsequently mix cast process. The flexural and compressive strengths of four groups NFRCs with varied nano-filler loading were comprehensively investigated. Results show, there are positive effects on the flexural and compressive strength of NFRCs with nano-fillers loading, especially when USF and MWCT are incorporated simultaneously, and the correspondent maximal flexural and compressive strength can increase by above 17%, 28% with respect to the baseline, respectively. The pozzolan infilling effect of USF and the crack-bridging effect of dispersed MWCT result in the dense and integrated network microstructures of cured NFRC.

scholarly journals Study of Hydration and Microstructure of Mortar Containing Coral Sand Powder Blended with SCMs

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4248
Author(s):  
Xingxing Li ◽  
Ying Ma ◽  
Xiaodong Shen ◽  
Ya Zhong ◽  
Yuwei Li
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Silica Fume ◽  
Dilution Effect ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Limestone Powder ◽  
Chemical Effect ◽  
Granulated Blast Furnace Slag ◽  
Coral Sand

The utilization of coral waste is an economical way of using concrete in coastal and offshore constructions. Coral waste with more than 96% CaCO3 can be ground to fines and combined with supplementary cementitious materials (SCMs) such as fly ash, silica fume, granulated blast furnace slag in replacing Portland cement to promote the properties of cement concrete. The effects of coral sand powder (CSP) compared to limestone powder (LSP) blended with SCMs on hydration and microstructure of mortar were investigated. The result shows CSP has higher activity than LSP when participating in the chemical reaction. The chemical effect among CSP, SCMs, and ordinary Portland cement (OPC) results in the appearance of the third hydration peak, facilitating the production of carboaluminate. CSP-SCMs mortar has smaller interconnected pores on account of the porous character of CSP as well as the filler and chemical effect. The dilution effect of CSP leads to the reduction of compressive strength of OPC-CSP and OPC-CSP-SCMs mortars. The synergic effects of CSP with slag and silica fume facilitate the development of compressive strength and lead to a compacted isolation and transfer zone (ITZ) in mortar.

scholarly journals The Compressive Strength of High-Performance Concrete and Ultrahigh-Performance

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
E. H. Kadri ◽  
S. Aggoun ◽  
S. Kenai ◽  
A. Kaci
Keyword(s):  
Experimental Data ◽  
Compressive Strength ◽  
Silica Fume ◽  
High Performance ◽  
High Performance Concrete ◽  
Cementitious Materials ◽  
Strength Gain ◽  
Proposed Model ◽  
Partial Cement Replacement ◽  
Better Than

The compressive strength of silica fume concretes was investigated at low water-cementitious materials ratios with a naphthalene sulphonate superplasticizer. The results show that partial cement replacement up to 20% produce, higher compressive strengths than control concretes, nevertheless the strength gain is less than 15%. In this paper we propose a model to evaluate the compressive strength of silica fume concrete at any time. The model is related to the water-cementitious materials and silica-cement ratios. Taking into account the author's and other researchers’ experimental data, the accuracy of the proposed model is better than 5%.

Unsaturated ion diffusion in cementitious materials – The effect of slag and silica fume

2018 ◽  
Vol 108 ◽  
pp. 31-37 ◽  
Author(s):  
Nilla Olsson ◽  
Barbara Lothenbach ◽  
Véronique Baroghel-Bouny ◽  
Lars-Olof Nilsson
Keyword(s):  
Silica Fume ◽  
Cementitious Materials ◽  
Ion Diffusion

MECHANICAL AND DURABILITY CHARACTERISTICS OF GGBS DOLOMITE GEOPOLYMER CONCRETE

2019 ◽  
Vol 6 (1) ◽  
Author(s):  
Aikot Pallikkara Shashikala ◽  
Praveen Nagarajan ◽  
Saranya Parathi
Keyword(s):  
Fly Ash ◽  
Silica Fume ◽  
Rice Husk ◽  
Rice Husk Ash ◽  
Setting Time ◽  
Cementitious Materials ◽  
Strength Properties ◽  
Industrial Wastes ◽  
Geopolymer Concrete ◽  
By Products

Production of Portland cement causes global warming due to the emission of greenhouse gases to the environment. The need for reducing the amount of cement is necessary from sustainability point of view. Alkali activated and geopolymeric binders are used as alternative to cement. Industrial by-products such as fly ash, ground granulated blast furnace slag (GGBS), silica fume, rice husk ash etc. are commonly used for the production of geopolymer concrete. This paper focuses on the development of geopolymer concrete from slag (100% GGBS). Effect of different cementitious materials such as lime, fly ash, metakaolin, rice husk ash, silica fume and dolomite on strength properties of slag (GGBS) based geopolymer concrete are also discussed. It is observed that the addition of dolomite (by-products from rock crushing plants) into slag based geopolymer concrete reduces the setting time, enhances durability and improves rapidly the early age strength of geopolymer concrete. Development of geopolymer concrete with industrial by-products is a solution to the disposal of the industrial wastes. The quick setting concrete thus produced can reduce the cost of construction making it sustainable also.

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