scholarly journals Petrographic and geochemical interpretations of source provenance and tectonic setting of the Lokoja Sandstone, Bida Basin, Nigeria

2020 ◽  
Vol 8 (2) ◽  
pp. 279
Author(s):  
G. U. Ozulu ◽  
A. U. Okoro ◽  
V. O. Ndubueze
Keyword(s):  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Source Area ◽  
Climatic Conditions ◽  
Source Rocks ◽  
Heavy Minerals ◽  
Petrographic Analysis ◽  
Moderate Degree ◽  
X Ray

The petrography and geochemistry of major and trace elements distribution pattern for the Lokoja Sandstones, Southern Bida Basin, Nigeria; were used to interpret their provenance, weathering conditions and paleotectonic setting. A total of seven (7) representative sandstone samples were selected for petrographic, heavy minerals and inorganic geochemical analyses; that is X- ray diffraction (XRD), X-ray fluorescence (XRF) and Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Results of the petrographic analysis showed 52.14 % quartz, 39.29 % feldspar, 2.00 % rock fragments, 5.14 % matrix and cement fraction as well as 1.43 % unfilled voids. Results of major elements and oxides suggests intermediate to felsic source rocks while the dominance of Na-rich feldspar to the k-feldspar and high value of Fe2O3+MgO shows contribution from ferromagnesian minerals of mafic igneous source provenance and oceanic island arc region. Average concentrations of designated trace elements in the studied sandstones are low in concentrations. The lower concentrations of Cr, Co, and Ni and higher concentrations of Zr, Ba, and Sr suggest a felsic progenitor rock. But significantly high values of Ni (7.02 ppm), La/Co (7.99), and Ni/Co (3.28) as well as the low concentration value of Y, (3.23 ppm) suggests contributions from mafic source rocks. Low average ratios for La/Co, Th/Co, Th/Sc, Ni/Co, Cr/Ni, Cr/Sc, Cr/Th, Ni/Co, Cr/Ni, Cr/Th, Cr/Sc, Th/Sc, La/Co and Th/Co also suggest a felsic source provenance. An average CIA value of 78.04% is indicative of an intense recycling in the source area while an average MIA value of 56.13% suggests a moderate degree of weathering. The high clay matrix and feldspar content have been used to classify the sandstones as feldspathic greywackes deposited in dry arid climatic conditions under a basement uplifted tectonic setting.   

scholarly journals Provenance Studies of Sandstone Facies Exposed Near Igbile Southwestern Nigeria: Petrographic and Geochemical Approach

2014 ◽  
Vol 6 (2) ◽  
pp. 47 ◽  
Author(s):  
Ikhane P. R. ◽  
Akintola A. I. ◽  
Bankole S. I. ◽  
Oyinboade Y. T.
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Source Area ◽  
Rock Fragment ◽  
Petrographic Analysis ◽  
Humid Climate ◽  
Southwestern Nigeria ◽  
Plagioclase Feldspar

The petrography, as well as the major, trace and rare earth element compositions of ten (10) sandstone samples of Maastrichtian Afowo Formation exposed near Igbile, Southwestern Nigeria, have been investigated to determine their provenance, source area weathering conditions, paleoclimate and tectonic setting using petrographic analysis and Inductively Coupled Plasma - Mass Spectrometry (ICP-MS). Results of the petrographic analysis revealed that quartz is the most dominant detrital mineral with (86%) followed by weathered plagioclase feldspar (5.10%) and rock fragments (10.9%). The quartz grain is sub-angular to sub-rounded in shape and the sandstones were classified as quartz arenites, sublitharenites and subarkoses based on framework composition of quartz, feldspar and rock fragment plots. This suggests a recycled orogen source for the sandstones and deposition in a humid climate, evidenced by the weathered feldspars. Eleven (11) major, seventeen (17) trace and fourteen (14) rare earth elements were obtained from the geochemical analysis. The major elements values range in concentration from 0.01%–81.39% with SiO2 being the dominant oxide followed by Al2O3 and Fe2O3 constituting over 95% of the major oxides; K2O, TiO2, Na2O, CaO, MgO and P2O5 made up the remaining 5%. The average ratio of SiO2/Al2O3 valued 4.31 for the sandstone is appreciably high indicating that it has been heavily weathered. The trace elements range in concentration from 0.2 ppm–1651.2 ppm with Zr being the most dominant element an indication of orogenic recycling. The rare earth elements range in concentration from 0.01 ppm–163.7 ppm with Ce having the highest concentration, depicting that the sandstones were deposited in an oxidizing environment. Also, the trace element relationship illustrated from the spider plot shows chemical coherence and uniformity of the sandstones. The chondrite normalized rare earth elements (REE) plot shows enrichment in the Light REE over the heavy REE for the sediment with strong negative Eu anomaly values between (0.57–0.69) suggesting a felsic provenance derived from upper continental crust for the sandstones.

Petrography and geochemistry of the siliciclastic Araba Formation (Cambrian), east Sinai, Egypt: implications for provenance, tectonic setting and source weathering

2015 ◽  
Vol 154 (1) ◽  
pp. 1-23 ◽  
Author(s):  
HOSSAM A. TAWFIK ◽  
IBRAHIM M. GHANDOUR ◽  
WATARU MAEJIMA ◽  
JOHN S. ARMSTRONG-ALTRIN ◽  
ABDEL-MONEM T. ABDEL-HAMEED
Keyword(s):  
Tectonic Setting ◽  
Source Area ◽  
Xrd Analysis ◽  
Climatic Conditions ◽  
Source Rocks ◽  
Northern Margin ◽  
Rock Fragments ◽  
Geochemical Parameters ◽  
Clastic Sediments ◽  
Chemical Index

AbstractCombined petrographic and geochemical methods are utilized to investigate the provenance, tectonic setting, palaeo-weathering and climatic conditions of the Cambrian Araba clastic sediments of NE Egypt. The ~ 60 m thick Araba Formation consists predominantly of sandstone and mudstone interbedded with conglomerate. Petrographically the Araba sandstones are mostly sub-mature and classified as subarkoses with an average framework composition of Q80F14L6. The framework components are dominated by monocrystalline quartz with subordinate K-feldspar, together with volcanic and granitic rock fragments. XRD analysis demonstrated that clay minerals comprise mixed-layer illite/smectite (I/S), illite and smectite, with minor kaolinite. Diagenetic features of the sandstone include mechanical infiltration of clay, mechanical and chemical compaction, cementation, dissolution and replacement of feldspars by carbonate cements and clays. The modal composition and geochemical parameters (e.g. Cr/V, Y/Ni, Th/Co and Cr/Th ratios) of the sandstones and mudstones indicate that they were derived from felsic source rocks, probably from the crystalline basement of the northern fringe of the Arabian–Nubian Shield. The study reveals a collisional tectonic setting for the sediments of the Araba Formation. Palaeo-weathering indices such as the chemical index of alteration (CIA), chemical index of weathering (CIW) and plagioclase index of alteration (PIA) of the clastic sediments suggest that the source area was moderately chemically weathered. On the northern margin of Gondwana, early Palaeozoic weathering occurred under fluctuating climatic conditions.

scholarly journals Geochemistry of Recent Brahmaputra River Sediments: Provenance, Tectonics, Source Area Weathering and Depositional Environment

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 813
Author(s):  
Md Aminur Rahman ◽  
Sudeb Chandra Das ◽  
Mark I. Pownceby ◽  
James Tardio ◽  
Md Sha Alam ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Element ◽  
Chemical Weathering ◽  
Earth Element ◽  
Tectonic Setting ◽  
River Sediments ◽  
Source Area ◽  
Source Rocks ◽  
Heavy Minerals ◽  
Brahmaputra River

Sediments from stable sand bars along a 40 km section of the Brahmaputra River in northern Bangladesh were analyzed for their major, trace and rare earth element contents to determine their provenance, compositional maturity, source area weathering and tectonic setting. Geochemically, the sediments were classified as litharenites and the Index of Compositional Variability (ICV) varied between 1.4 and 2.0, indicating low compositional and mineralogical maturity. A high mean SiO2 concentration (72.9 wt.%) and low Al2O3 (11.1 wt.%) were consistent with a low abundance of shale and clay components. The depletion of the oxide components Na2O, CaO and K2O relative to average upper crustal compositions (UCC) reflected loss of feldspar during chemical weathering in the source region. Average TiO2 values for most samples were higher than average crustal levels, consistent with the northern section of the Brahmaputra River being a potential resource for valuable Fe-Ti oxide heavy minerals. Major and trace element ratios indicated the sediments represented erosional products from typical felsic upper continental crustal materials with contamination (30%–40%) from more intermediate/mafic compositions. The rare earth element patterns showed negative Eu anomalies (0.57–0.71), indicating they were derived mainly from fractionated felsic rocks. Resemblance of the sediment compositions to mean compositions from Higher Himalaya crystalline rocks pointed to these being potential source rocks but with components from a mafic source also present. Major element chemistries and low to intermediate weathering indices for all sediments indicated a lack of substantial chemical weathering. Evidence from tectonic discrimination diagrams suggested the Brahmaputra River sediments were derived from rock types that formed in a transitional tectonic setting ranging from an ancient passive margin to an active continental margin. Deposition occurred under cool to semi-arid climatic conditions in an oxic environment.

scholarly journals Source Area Weathering, Paleo-Environment and Paleo-Climatic Conditions of Soils from Bitumen Rich Ode Irele Area of Ondo State, Nigeria

2019 ◽  
Vol 4 (3) ◽  
pp. 59-67
Author(s):  
Romanus Ayoola Obasi ◽  
Henry Y. Madukwe ◽  
Temitope Olaosun
Keyword(s):  
Clay Minerals ◽  
Inductively Coupled Plasma ◽  
Saline Water ◽  
Source Area ◽  
Climatic Conditions ◽  
Source Rocks ◽  
Inductively Coupled ◽  
Anoxic Environments ◽  
Chemical Index ◽  
Ondo State

The study is aimed at determining the source-weathering, paleo-redox and paleoclimatic conditions of soil from Ode Irele area of Ondo State, Nigeria. X-Ray Fluorescence (XRF) and the Laser Ablation Inductively Coupled Plasma-Mass Spectrometry ICP-MS) analyses wereusd to determine the major, trace and rare earth element compositios used for the study. The Chemical index of alteration (CIA), Chemical index of weathering (CIW), Plagioclase index of alteration (PIA), Mineralogical index of alteration (MIA), Th/U nd a plot of CIA against Al2O3 as well as the A-CN-K Ternary diagram suggest a high degree of weathering of the source rocks. The positive correlation between Al2O3 with TiO2, K2O, Fe2O3 and MgO implies that they occur in clay minerals formed from weathering. The average K2O/Al2O3 ratios of the investigated samples is ≈0.006, which suggests prevalence of clay minerals relative to other minerals. Low U/Th ratio ranging between 0.14 and 0.50 (average 0.18) relative to PAAS (0.21) and UCC (0.26) suggests deposition under oxic conditions. V/Vi + Ni ratios indicate suboxic to anoxic environment of deposition. However, plots of V/V+ Ni vs Ni/Co and V/Cr vs Ni/Co indicate oxic, dysoxic and suboxic to anoxic environments all suggesting deposition under oxic and suboxic conditions. The Ode Irele sediments was deposited in low saline water with a strong continental rather than marine influence in an arid and semi-arid climatic condition; the low average ratio of P2O5/Al2O3 (0.014) is in unison with freshwater environments.

scholarly journals Anti-Microbial, Anti-Oxidant, and α-Amylase Inhibitory Activity of Traditionally-Used Medicinal Herbs: A Comparative Analyses of Pharmacology, and Phytoconstituents of Regional Halophytic Plants’ Diaspora

Molecules ◽  
2020 ◽  
Vol 25 (22) ◽  
pp. 5457
Author(s):  
Mohsen Al-Omar ◽  
Hamdoon Mohammed ◽  
Salman Mohammed ◽  
Essam Abd-Elmoniem ◽  
Yasser Kandil ◽  
...  
Keyword(s):  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Inhibition Zone ◽  
Climatic Conditions ◽  
Inductively Coupled ◽  
Long Time ◽  
Iron And Zinc ◽  
Anti Oxidant ◽  
Halophytic Plants

Halophytes are the category of plants growing under harsh conditions of super-salinity, and are wide-spread in the coastal Mediterranean climatic conditions and desert oasis. They are adept at surviving through maintaining excessive production of enzymatic, and non-enzymatic secondary metabolites, especially phenolics and flavonoids that primarily work as anti-oxidants and phytoalexins. Five major halophyte species growing in the kingdom’s Qassim’s high-salted desert regions were investigated for confirming their traditionally used biological activity of sugar-control and anti-infectious properties. In this context, the comparative presence of phenolics, and flavonoids together with anti-microbial, anti-oxidants, and the anti-diabetic potentials of the plants’ extracts were investigated through the α-amylase inhibition method. The highest concentrations of phenolics and flavonoids were detected in Salsola imbricata (360 mg/g of the extract as Gallic-Acid-Equivalents/GAE, and 70.5 mg/g of the extract as Rutin-Equivalents/RE). In contrast, the lowest concentrations of phenolics and flavonoids were detected in Salsola cyclophylla (126.6 mg/g GAE, and 20.5 mg/g RE). The halophytes were found rich in trace elements, a factor for water-retention in high-salinity plants, wherein iron and zinc elements were found comparatively in higher concentrations in Aeluropus lagopoides (4113 µg/kg, and 40.1 µg/kg, respectively), while the copper was detected in higher concentration (11.1 µg/kg) in S. imbricata, analyzed through Inductively Coupled Plasma Optical Emission Spectrometric (ICP-OES) analysis. The anti-oxidant potentials and α-amylase enzyme inhibition-based anti-diabetic activity of S. imbricata was significantly higher than the other halophytes under study, wherein S. cyclophylla exhibited the lowest level of α-amylase inhibition. The maximum DPPH radicals’ (52.47 mg/mL), and α-amylase inhibitions (IC50 22.98 µg/mL) were detected in A.lagopoides. The anti-microbial activity against the Methicillin-Resistant Staphylococcus aureus was strongly exhibited by Zygophyllum simplex (33 mm Inhibition Zone-Diameter, 50 µg/mL Minimum-Inhibitory-Concentration), while Escherichia coli, Enterococcus faecalis, and Candida albicans growths were moderately inhibited by Tamarix aphylla. The current findings exhibited significant differences among the locally distributed halophytic plants species with regards to their bioactivity levels, anti-oxidant potentials, and the presence of trace elements. The ongoing data corroborated the plants’ traditional uses in infections and diabetic conditions. The enhanced local distribution of the plants’ diaspora and higher density of occurrence of these plants species in this region, in comparison to their normal climatic condition’s counterparts, seemed to be affected by humans’ use of the species as part of the traditional and alternative medicine over a period of long time.

scholarly journals Efflorescent Sulfate Crystallization on Fractured and Polished Colloform Pyrite Surfaces: A Migration Pathway of Trace Elements

Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 12
Author(s):  
Dimitrina Dimitrova ◽  
Vassilka Mladenova ◽  
Lutz Hecht
Keyword(s):  
Electron Microscopy ◽  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Microprobe Analysis ◽  
Electron Microprobe Analysis ◽  
X Ray ◽  
Inductively Coupled ◽  
Migration Pathway ◽  
Plasma Mass Spectrometry ◽  
Scanning Electron

The colloform pyrite variety incorporates many trace elements that are released in the environment during rapid oxidation. Colloform pyrite from the Chiprovtsi silver–lead deposit in Bulgaria and its oxidation efflorescent products were studied using X-ray diffractometry, scanning electron microscopy, electron microprobe analysis, and laser ablation inductively coupled plasma mass spectrometry. Pyrite is enriched with (in ppm): Co (0.1–964), Ni (1.8–3858), Cu (2.9–3188), Zn (3.1–77), Ag (1.2–1771), As (8179–52,787), Se (2.7–21.7), Sb (48–17792), Hg (4–2854), Tl (1.7–2336), Pb (13–7072), and Au (0.07–2.77). Gypsum, anhydrite, szomolnokite, halotrichite, römerite, copiapite, aluminocopiapite, magnesiocopiapite, coquimbite, aluminocoquimbite, voltaite, and ammoniomagnesiovoltaite were identified in the efflorescent sulfate assemblage. Sulfate minerals contain not only inherited elements from pyrite (Cr, Fe, Co, Ni, Cu, Zn, Ag, In, As, Sb, Hg, Tl, and Pb), but also newly introduced elements (Na, Mg, Al, Si, P, K, Ca, Sc, Ti, V, Mn, Ga, Rb, Sr, Y, Zr, Sn, Cs, Ba, REE, U, and Th). Voltaite group minerals, copiapite, magnesiocopiapite, and römerite incorporate most of the trace elements, especially the most hazardous As, Sb, Hg, and Tl. Colloform pyrite occurrence in the Chiprovtsi deposit is limited. Its association with marbles would further restrict the oxidation and release of hazardous elements into the environment.

Origin, weathering, and geochemical composition of loess in southwestern Hungary

2008 ◽  
Vol 69 (03) ◽  
pp. 421-437 ◽  
Author(s):  
Gábor Újvári ◽  
Andrea Varga ◽  
Zsuzsanna Balogh-Brunstad
Keyword(s):  
Source Area ◽  
Transport Processes ◽  
Heavy Minerals ◽  
Dust Particles ◽  
Chemical Compositions ◽  
Moderate Degree ◽  
Geochemical Composition ◽  
Geochemical Parameters ◽  
Chemical Index Of Alteration ◽  
Active Tectonism

Loess geochemistry generally reflects paleo-weathering conditions and it can be used to determine the average composition of the upper continental crust (UCC). In this study, major and trace element concentrations were analyzed on loess samples from southwestern Hungary to determine the factors influencing their chemical compositions and to propose new average loess compositions. All studied loess samples had nearly uniform chemical composition, suggesting similar alteration history of these deposits. Chemical Index of Alteration values (58–69) suggested a weak to moderate degree of weathering in a felsic source area. Typical non-steady state weathering conditions were shown on the Al2O3–CaO+Na2O–K2O patterns, indicating active tectonism of the Alpine–Carpathian system during the Pleistocene. Whole-rock element budgets were controlled by heavy minerals derived from a felsic magmatic or reworked sedimentary provenance. Geochemical parameters indicated that dust particles must have been recycled and well homogenized during fluvial and eolian transport processes.

Geochemical and mineralogical characteristics of beach sand sediments in southwestern Black Sea: An approach to heavy mineral placers

2020 ◽  
Author(s):  
Hatice Nur Bayram ◽  
Asli Nur Uslu ◽  
Ali Erdem Bakkalbasi ◽  
Demet Kiran Yildirim ◽  
Zeynep Doner ◽  
...  
Keyword(s):  
Black Sea ◽  
Heavy Mineral ◽  
Source Rocks ◽  
Heavy Minerals ◽  
Beach Sand ◽  
Minor Amount ◽  
X Ray ◽  
Mineralogical Characteristics ◽  
Beach Sands ◽  
Sand Sediments

<p><strong>Geochemical and mineralogical characteristics of beach sand sediments in southwestern Black Sea: An approach to heavy mineral placers  </strong></p><p><strong> </strong><strong>Hatice Nur Bayram (1*), Aslı Nur Uslu (1), Ali Erdem Bakkalbaşı (1), Demet Kiran Yildirim (1), </strong><strong>Zeynep Doner (1), Ali Tugcan Unluer (1)</strong></p><p><strong> </strong>(1) Istanbul Technical University, Faculty of Mines, Department of Geological Engineering, Istanbul, Turkey (*[email protected])</p><p><strong>Abstract: </strong><strong> </strong></p><p>Coastal or beach placer deposits are enrichments of heavy minerals with significant metal content that have been mechanically formed. This work studies the geochemical and mineralogical characteristics of beach sand sediments of southwestern Black Sea, Turkey which cover approximately 20 km<sup>2</sup> area. The study area has 4 main geological units: Upper Cretaceous moderately-K kalkalkaline Istanbul volcanics, Oligocene Danismen Formation which is dominated by flood plain, marshy and lake environments, Upper Miocene-Pliocene Belgrad Formation which is dominated by terrestrial deposits, mostly gravel, sand and clay dominated and Quaternary formations which include sandy beaches, sand dunes and river alluvials.</p><p>A total of 8 beach sand samples were analyzed by X-ray Diffraction (XRD) and X-ray Fluorecance (XRF). Mineralogical compositions are mainly dominated by quartz, siderite, albite, calcite and minor amount of magnetite. Siderite-rich beach sands are observed in western part of the study area and mostly derived from Danismen Formation. Fe<sub>2</sub>O<sub>3</sub> contents of this area are determined up to 40%.  On the other hand, in eastern part of the study area REE-Th-U content of beach sands are relatively higher than source rocks which is defined as a high-Al moderately-K kalkalkaline felsic rocks. The highest HFSE concentration were determined in -250+125µm fraction which consists of 16.5% of eastern beach sand. In this fraction LREE-Zr-U content rise drastically. It can be considered that REE-LREE contents is related with monazite minerals and U contents is related with zircon minerals, considering the monazite and zircon minerals are resistant to weathering and likely to occur in the orthomagmatic phase in the source volcanics.</p><p><strong>Key words</strong>: Beach sand sediments; REE-Th-U; heavy minerals; southwestern of Black Sea; Turkey</p>

Lithofacies and fluvial–lacustrine environments of the Palaeogene Sevkhuul and Ergil members (Ergiliin Zoo Formation, South Gobi, Mongolia)

2006 ◽  
Vol 143 (2) ◽  
pp. 165-179 ◽  
Author(s):  
H. G. DILL ◽  
S. KHISHIGSUREN ◽  
J. BULGAMAA ◽  
KH. BOLORMA ◽  
F. MELCHER
Keyword(s):  
Source Area ◽  
Field Work ◽  
Late Eocene ◽  
Climatic Conditions ◽  
Heavy Minerals ◽  
Gobi Desert ◽  
Carbonate Minerals ◽  
Delta Front ◽  
Delta Plain ◽  
Sheet Silicates

The clastic sequence of the Ergiliin Zoo Formation stretches along the Mongolian–Chinese border in the southern Gobi Desert, Mongolia. Its members (Sevkhuul, Ergil) exposed in the Erdene Sum region are well known for their vertebrate remains of Late Eocene and Oligocene age. Based upon field work, the continental red beds were subdivided into four units described as (I) prodelta/mud-sand flat, (II) delta front, (III) delta plain and (IV) calcretes. All sub-environments are in a fluvial–lacustrine setting. Electronmicroprobe analysis, in addition to conventional thin-section examination, was applied to shed some light on the complex mineral association made up of light minerals (quartz, plagioclase, ternary feldspar, orthoclase, smectite, illite, rare palygorskite), heavy minerals (almandine–pyrope solid solution series, zoisite–epidote s.s.s.) and abundant goethite and carbonate minerals (calcite, dolomite). Igneous rocks being exposed in the source area have contributed to the formation of carbonate minerals and Mg-bearing sheet silicates during diagenesis. Higher up on the delta plain transitional between distal alluvial and deltaic deposits, fluids emerged from the distal alluvial–fluvial deposits and formed calcareous duricrusts. Drawing conclusions from the rock colour, the mineral assemblage and the palaeoecological data, the climatic conditions may be described as alternating wet and dry seasons, closely resembling those conditions of a modern savannah.

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