scholarly journals Spatial distribution and risk assessment of heavy metals in bottom sediments of two small dam reservoirs (south-east Poland)

2015 ◽  
Vol 41 (4) ◽  
pp. 67-80 ◽  
Author(s):  
Halina Smal ◽  
Sławomir Ligęza ◽  
Anna Wójcikowska-Kapusta ◽  
Stanisław Baran ◽  
Danuta Urban ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Metal Concentration ◽  
Bottom Sediments ◽  
Contaminated Sediments ◽  
Skewed Distribution ◽  
Geochemical Background ◽  
Dam Reservoirs ◽  
Significant Difference ◽  
Dredging Operation

Abstract Sediments of two dam reservoirs in SE Poland, Zalew Zemborzycki (ZZ) and Brody Iłżeckie (BI) were studied. The sediments from both reservoirs were sampled in the transects perpendicular to the shoreline, at the river inflow and the frontal dam. The total concentration of Mn, Zn, Pb, Cd, Cu, Cr and Ni was determined by ICP-EAS method after the sample digestion in the mixture of concentrated HNO3 and HClO4 acids. The statistical analyses: value intervals, mean values, variation coefficient, the median and the skewed distribution were performed. To estimate differences between the means for transects, Tukey’s test was applied with least significant difference (LSD) determination. The maps of the metal spatial distribution were drawn and sediment quality according to the geochemical and ecotoxicological criteria evaluated. Differences between the reservoirs in terms of heavy metals concentration in bottom sediments, and regularities in their spatial distribution were found. In the ZZ sediments the concentration was at the level of geochemical background (Zn, Cr), slightly (Cd, Cu, Ni) or moderately (Pb) contaminated sediments. The metal concentration in the sediments of the BI was up to eight times higher as compared to the ZZ. Moreover, sediments from the BI reservoir showed a greater variability of metal concentration than those from ZZ, which resulted from the dredging operation performed in the part of the reservoir. Metal concentration in sediments of the dredged part was ca. 2–5 times lower than in the undredged one, which indicates that after the dredging operation, accumulation of these metals was slight. The concentrations of Zn, Pb and Cd from the undredged part of BI were at the level of contaminated sediments and exceeded the probable effects level (PEL). In the ZZ, the greatest accumulation of metals occurred in the upper part of the reservoir and at the frontal dam, and the lowest in the middle part of the reservoir. In BI, the lower outflow of water in this reservoir caused a lower metal concentration in the sediments at the frontal dam, as compared with the other sediments in the undredged part of the reservoir. The results indicate that in small and shallow reservoirs, areas of accumulation of heavy metals depend on such factors as a parent river current, reservoir depth, water waving, reservoir shape (narrowing, coves/bays), and type of water outflow.

scholarly journals Influence of Bottom Sediments Physicochemical Characteristics on Distribution of Microelements in the Crimean Shelf Water Areas

2020 ◽  
Author(s):  
E. A. Kotelyanets ◽  
K. I. Gurov ◽  
◽  
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Spatial Distribution ◽  
Organic Carbon ◽  
Bottom Sediments ◽  
Clay Fraction ◽  
Zinc Content ◽  
Physicochemical Characteristics ◽  
Water Area ◽  
Pollution Level

The paper presents the results of studies of the Kalamitsky Bay bottom sediments pollution level with microelements and heavy metals (Pb, Zn, Cu, Ni, Co, Cr, V, As, Sr, Ti, Fe, Mn) in comparison with the content of these microelements and heavy metals in the Balaklava Bay sediments. The paper analyzes data obtained during expeditions on the R/V Professor Vodyanitsky in the Kalamitsky Gulf in August 2011 (seaward part) and on the R/V Rioni in September 2012 (coastal area) as well as in the Balaklava Bay in October 2018. Content of microelements and heavy metals in bottom sediments of the studied water areas was determined by the X-ray fluorescence method using Spectroscan MAX-G device. For the water area of the Kalamitsky Gulf, the features of the studied trace element spatial distribution are considered, groups of trace elements with different spatial distribution patterns are identified. The correlation analysis determined influence of physicochemical characteristics of the sediments on distribution and accumulation of trace elements. In the water area of the Kalamitsky Gulf, a statistically significant correlation was observed of nickel, iron and zinc content with the clay fraction; dependance of increased concentrations of zinc, nickel and chrome on the content of organic carbon and predominance of lead in highcarbonate sediments. For the Balaklava Bay, the maximum positive values of correlations with the pelitic-silty fraction were noted for iron, manganese, vanadium and chrome; organic carbon correlates with chrome, iron, nickel and copper, whereas carbonates correlate with strontium. Similar patterns were observed earlier in the Sevastopol region bays, Feodosiya Gulf and Kerch Strait.

scholarly journals Heavy metals contamination of the sediments of the south-eastern Baltic Sea: the impact of economic development

Baltica ◽  
2019 ◽  
Vol 32 (1) ◽  
pp. 51-62
Author(s):  
Alexander Krek ◽  
Aleksandr Danchenkov ◽  
Marina Ulyanova ◽  
Darya Ryabchuk
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Baltic Sea ◽  
Metal Concentration ◽  
Bottom Sediments ◽  
Heavy Metal Concentration ◽  
South Eastern ◽  
Heavy Metals Contamination ◽  
The Impact ◽  
Eastern Baltic

The scope of the study was to assess the impact of potential sources of Cu, Zn, Co, Ni, and Cr on bottom sediments of the Russian sector of the south-eastern Baltic Sea. A total of 68 samples were taken and analyzed for grain-size (laser diffraction and sieve method) and heavy metal concentration (atomic absorption spectroscopy method). To avoid the influence of the sorption capacity of the fine-grained sediments to accumulate the pollutants, the normalization of the heavy metal concentration to Fe was applied. The environmental indices (contamination factor and modified degree of contamination) were calculated. The research has shown the contribution of oil platform, pipelines, ports and wastewater treatment facilities on the geochemical composition of bottom sediments. The authors have identified the level of heavy metals contamination of the middle parts of the Curonian and Vistula spits as a result of alongshore transport of pollutants.

scholarly journals ANALYSIS AND ASSESSMENT OF HEAVY METALS CONCENTRATIONS IN NEMUNAS RIVER BOTTOM SEDIMENTS AT ALYTUS CITY TERRITORY

2015 ◽  
Vol 23 (2) ◽  
pp. 147-154 ◽  
Author(s):  
Vaidotas VALSKYS ◽  
Roberta VALSKIENĖ ◽  
Gytautas IGNATAVIČIUS
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Bottom Sediments ◽  
Anthropogenic Impact ◽  
River Sediments ◽  
Left Bank ◽  
River Ecosystem ◽  
X Ray ◽  
Left And Right ◽  
River Bottom

Concentrations and spatial distribution of heavy metals on the left and right banks of the river Nemunas bottom sediments are analyzed in this article. The research methodology of X-ray fluorescence spectrometry for bottom sediments and operating principles of XL2 spectrometer used for analysis are overviewed. The results of analysis are presented and compared with LAND 20-2005 requirements as well as studies that were carried out previously. The influence of Alytus city for Nemunas river sediments quality is assessed. Dischargers formed additional samples which were taken and included to the list of ordinary samples. The trend of heavy metals (Cd, Cu, Cr) concentrations showed the growth of pollution downstream the urban area. The estimated Zd (total pollution) values clearly indicated higher contamination by heavy metals on the left bank of Nemunas River. Extensive surveys of river sediments allow assessing the extent of anthropogenic impact, which can be harmful to the river ecosystem and human health.

scholarly journals Differentiation of the concentration of heavy metals and persistent organic pollutants in lake sediments depending on the catchment management (Lake Gopło case study)

2015 ◽  
Vol 8 (1) ◽  
pp. 71-80 ◽  
Author(s):  
Włodzimierz Juśkiewicz ◽  
Włodzimierz Marszelewski ◽  
Wojciech Tylmann
Keyword(s):  
Heavy Metals ◽  
Human Impact ◽  
Organic Pollutants ◽  
Bottom Sediments ◽  
Persistent Organic Pollutants ◽  
Industrial Pollution ◽  
Catchment Management ◽  
Geochemical Background ◽  
Degree Of Contamination ◽  
The Impact

Abstract This paper presents the results of the study on the concentration of heavy metals and persistent organic pollutants (POPs), including PAHs and PCBs, in the bottom sediments of Lake Gopło. This lake is significantly elongated (about 25 km); its longitudinal profile is diversified, and there are deeps and thresholds impeding the flow of water. The shoreline is varied, which is characteristic of tunnel valley lakes. The catchment has a typical agricultural character with a point arrangement of industrial centres. The analysis of the diversity of the concentration of heavy metals and POPs was based on 37 samples from two representative cores: one collected in the northern part of the lake, the catchment of which shows an industrial character, and the second one in the southern part where the catchment is agricultural in character. In the sediments, the content of the following heavy metals was analysed: Cu, Pb, Cd, Zn, Ni, Cr, Hg and As, as well as PAHs and PCBs. The sediment age was determined by the 210Pb dating method. In order to assess the contamination level of the bottom sediments with heavy metals, the contamination factor (CF) and degree of contamination (DC) were calculated. Moreover, the impact of the changes in the catchment’s land use over the past 100 years was determined. The results showed that the sediments from the industrial part of the lake significantly exceed the geochemical background for both the heavy metals from the group identified as industrial pollution and from the group of agricultural pollutants. The southern core shows only a slight increase in the amount of pollution from the agricultural group, lack of industrial pollution and a low degree of contamination. A slight increase in persistent organic pollutants is also recorded, without any apparent effect on the state of the deposited sediment. The 210PB dating enabled the main stages of human impact to be determined: the pre-industrial revolution, from the beginning of industrialisation to the 1950s, intensive human impact from the 1960s to the 1980s, and a gradual decrease in the human impact starting from the 1990s. In addition, attention was paid to the changing sedimentation rate.

scholarly journals Leaves and roots of Typha latifolia L. and Iris pseudacorus L. as bioindicators of contamination of bottom sediments by heavy metals

2016 ◽  
Vol 16 (2) ◽  
pp. 77-83 ◽  
Author(s):  
Agnieszka Parzych ◽  
Małgorzata Cymer ◽  
Kamila Macheta
Keyword(s):  
Heavy Metals ◽  
Bottom Sediments ◽  
Typha Latifolia ◽  
Absorption Spectrometry ◽  
Anthropogenic Factors ◽  
Geochemical Background ◽  
Iris Pseudacorus ◽  
Nickel Iron ◽  
Leaves And Roots ◽  
Iron And Manganese

Abstract The paper concerns the bioaccumulation of zinc, nickel, iron and manganese in leaves and roots of selected macrophytes from the Krzynia Reservoir (northern Poland). The research was conducted within the area of 10 stations situated in the littoral zone of the reservoir. Samples of surface waters, bottom sediments and plants were taken in summer. Heavy metal content was determined by the atomic absorption spectrometry method (ASA). The concentration of heavy metals in the waters of Krzynia Reservoir was low and noinfluence of anthropogenic factors was found. Concentration of heavy metals in the examined bottom sediments was low and remained within the limits of the geochemical background for Zn and Fe. In the case of Ni and Mn it sporadically exceeded the level of the geochemical background. The tested plants mainly accumulated heavy metals in roots, with the exception of nickel which appeared in larger quantities in leaves. The relationships among the content of the determined elements in the organs of macrophytes was identical for the tested species and could be arranged into the following sequences: Mn>Fe>Ni>Zn in leaves and Fe>Mn>Zn>Ni in roots. Statistically significant differences were found in the content of Mn in leaves and Zn and Fe in the roots of Typha latifolia L. and Iris pseudacorus L. By accumulating substantial quantities of heavy metals in their organs, macrophytes constitute an effective protective barrier for the waters and bottom sediments.

scholarly journals MODERN CONTAMINATION OF BOTTOM SEDIMENTS AND ECOLOGICAL STATE OF MACROZOOBENTHOS IN THE COASTAL ZONE AT VLADIVOSTOK (PETER THE GREAT BAY, JAPAN SEA)

2019 ◽  
Vol 196 ◽  
pp. 155-181
Author(s):  
A. V. Moshchenko ◽  
T. A. Belan ◽  
B. M. Borisov ◽  
T. S. Lishavskaya ◽  
A. V. Sevastianov
Keyword(s):  
Heavy Metals ◽  
Bottom Sediments ◽  
Peter The Great Bay ◽  
Ecological Status ◽  
Geochemical Background ◽  
Chemical Contamination ◽  
Safe Level ◽  
Peter The Great ◽  
Golden Horn ◽  
Great Bay

Contamination of bottom sediments in Peter the Great Bay is spatially variable, but for majority of stations it exceeds the natural geochemical background and «safe» level with at least one pollutant, mainly with hydrocarbons, pesticides, cadmium and mercury. The main sources of contaminants are the waste discharge of Vladivostok and other cities (oil products, pesticides, phenols, heavy metals: Cd, Cu, Hg, Pb, Zn) and rivers fall into the northern parts of Amur and Ussuri Bays (Co, Mn, Ni, Fe). The Golden Horn Bay and the Bosphorus East Strait are the most polluted areas, where concentrations of both heavy metals and hydrocarbons exceed the natural background and «safe» level considerably. The Amur Bay has moderate contamination, and the Ussuri Bay is contaminated slightly. Recently the chemical contamination and eutrophication are the main factors that determine the ecological status of bottom populations, though the former one is valid locally, in the most contaminated areas only.

scholarly journals Heavy Metals in Bottom Sediments of Reservoirs in the Lowland Area of Western Poland: Concentrations, Distribution, Sources and Ecological Risk

Water ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 56 ◽  
Author(s):  
Mariusz Sojka ◽  
Joanna Jaskuła ◽  
Marcin Siepak
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Ecological Risk ◽  
Bottom Sediments ◽  
Sampling Site ◽  
Point Sources ◽  
Lowland Area ◽  
The Mean ◽  
The Impact ◽  
Geogenic Sources

The paper presents the results of a study of heavy metals (HMs) concentrations in six retention reservoirs located in the lowland area of western Poland. The objectives of this study were to analyze the Cd, Cr, Cu, Ni, Pb and Zn concentrations, assess contamination and ecological risk, analyze the spatial variability of HM concentrations and identify potential sources and factors determining the concentration and spatial distribution. The bottom sediment pollution by HMs was assessed on the basis of the index of geo-accumulation (Igeo), enrichment factor (EF), pollution load index (PLI) and metal pollution index (MPI). To assess the ecological risk associated with multiple HMs, the mean probable effect concentration (PEC) quotient (Qm-PEC) and the toxic risk index (TRI) were used. In order to determine the similarities and differences between sampling sites in regard to the HM concentration, cluster analysis (CA) was applied. Principal component analysis (PCA) was performed to assess the impact of grain size, total organic matter (TOM) content and sampling site location on HM spatial distribution. Additionally, PCA was used to assess the impact of catchment, reservoir characteristics and hydrological conditions. The values of Igeo, EF, MPI and PLI show that Cd, Cr, Cu, Ni and Pb mainly originate from geogenic sources. In contrast, Zn concentrations come from point sources related to agriculture. The mean PEC quotient (Qm-PEC) and TRI value show that the greatest ecological risk occurred at the inlet to the reservoir and near the dam. The analysis showed that the HMs concentration depends on silt and sand content. However, the Pb, Cu, Cd and Zn concentrations are associated with TOM as well. The relationship between individual HMs and silt was stronger than with TOM. The PCA results indicate that HMs with the exception of Zn originate from geogenic sources—weathering of rock material. However, the Ni concentration may additionally depend on road traffic. The results show that a reservoir with more frequent water exchange has higher HMs concentrations, whereas the Zn concentration in bottom sediments is associated with agricultural point sources.

scholarly journals Characterizing Khetri copper mine environment using geospatial tools

2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Anita Punia ◽  
Pawan Kumar Joshi ◽  
Neelam Siva Siddaiah
Keyword(s):  
Heavy Metals ◽  
Remote Sensing ◽  
Spatial Distribution ◽  
Metal Concentration ◽  
Landscape Pattern ◽  
Spectral Response ◽  
Geochemical Data ◽  
Pollution Indices ◽  
Lulc Change ◽  
Copper Mine

AbstractMines result in land use and land cover (LULC) change due to degradation of natural resources and establishment of new infrastructure for ore extraction and beneficiation. The present study was carried out to, with objectives, (1) characterize LULC change (from 1975 to 2017) in Khetri copper mine region, (2) spatial distribution of pollution indices and (3) spectral response of elemental concentration of soil and groundwater using Landstat and ASTER satellite data. The study was designed to fulfil the objectives and for the same NDVI values were calculated for LULC classification and generated maps were analyzed for landscape pattern. Spatial distribution of pollution indices calculated using geochemical data of soil and groundwater was plotted to understand the impact of contamination on landscape pattern. The correlation of spectral response of Landstat bands with heavy metals concentration was plotted to assess their possible use in quantification of heavy metals. Results show constant increase in settlements, mines and open area while vegetation cover has decreased. Landscape and class level metrics (number of patch, patch density, aggregation index and landscape shape index) indicate increase in the fragmentation of landscape in recent years. Shannon’s Evenness Index indicates increase in uniformity in landscape and it is attributed to loss of vegetation and agriculture patches. Pollution indices, Pollution Load Index for soil is high near the overburden materials and Index of Environmental Risk (IER) and Contamination Index for ground water is high near abandoned mines. Spectral bands 5 and 6 (SWIR 1) show significant negative correlation, and 9 (Cirrus) shows significant positive correlation with metal concentration in soil and water suggesting the possible use of remote sensing in assessment of metal concentration at ground level. Thus, it can be concluded that mines significantly influence the landscape pattern and remote sensing could be used for the assessment and predication of heavy metal contamination at broader scale in a cost-effective way.

scholarly journals FEATURES OF HEAVY METALS DISTRIBUTION IN BOTTOM SEDIMENTS OF THE RIVERS OF UKRAINE

2018 ◽  
pp. 28-32
Author(s):  
N. G. Lyuta
Keyword(s):  
Heavy Metals ◽  
Chemical Composition ◽  
Bottom Sediments ◽  
Chemical Elements ◽  
River Basins ◽  
Water Bodies ◽  
Geochemical Background ◽  
Metallogenic Province ◽  
Catchment Areas ◽  
Background Content

The chemical composition of bottom sediments is an important indicator of the ecological state of both water systems and watershed areas, since contaminated bottom sediments are a potential source of secondary pollution of aquatic systems. The analysis of recent publications shows that great attention has been paid to the chemical composition of bottom sediments, however, as a rule, these studies are of a local nature, that is, they cover very small areas. This often raises the issue of criteria for assessing the ecological and geochemical status of bottom sediments, since a small number of samples does not allow correctly determining the local geochemical background. In addition, generally accepted norms, for example, the maximum allowable concentrations, do not exist for bottom sediments. In these conditions, data on regional geochemical backgrounds of pollutants are needed. The need for the implementation of the Water Framework Directive in Ukraine, which requires the introduction of water management basin-based, necessitates the determination of the geochemical characteristics of bottom sediments within the river basin territories. To study the distribution of heavy metals and determine their regional backgrounds in the bottom sediments, a database of environmental and geochemical information was used in the GIS, one of the blocks of which is information on the content of chemical elements and compounds in the bottom sediments of watercourses and water bodies of Ukraine, and the electronic map of river basins of Ukraine. Based on the analysis in the GIS of information on the chemical composition of the bottom sediments of the rivers of Ukraine (about 8,1 thousand samples), regional geochemical background of lead, zinc, copper, chromium, nickel and cobalt have been determined. The main regularities of distribution of chemical elements in bottom sediments in the territory of Ukraine are established. For the chemical elements in question, a gradual increase in their content in soils from north to south, that is, from the river basins of the Polissya zone to the basins of the Steppe landscape-climatic zone, is consistent with the geochemical features of the soil cover of the catchment areas. The increased background content of chemical elements in bottom sediments often spatially coincides with the spread of soil differences in the catchment areas, which also have a high content of these elements. The maximum background content of most heavy metals in bottom sediments is naturally clearly recorded within the Carpathian-Crimean metallogenic province. Thus, despite the long and intensive technogenic impact on the surface water bodies of Ukraine, it is necessary to note the priority of natural factors in the formation of the chemical composition of bottom sediments, at least for the heavy metals considered above.

scholarly journals Concentration of Heavy Metals in Vegetables Cultivated around Dumpsites in Jimeta and Ngurore Areas, Adamawa State, Nigeria

2020 ◽  
Vol 24 (6) ◽  
pp. 1035-1040
Author(s):  
D.C. Sakiyo ◽  
G. Chessed ◽  
J. Eli ◽  
Y.J. Usongo
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Atomic Absorption ◽  
Metal Concentration ◽  
Lactuca Sativa ◽  
Concentration Level ◽  
Spinacia Oleracea ◽  
Limit Of Detection ◽  
Atomic Absorption Spectrophotometer ◽  
Significant Difference

The study analyses the health risk assessment of the concentration of Iron, Lead, Copper, Chromium, and Cadmium heavy metals in vegetables grown near dumpsites of Jimeta and Ngurore areas of Adamawa State, Nigeria. Vegetables mainly Spinach (Spinacia oleracea) and lettuce (Lactuca sativa) were collected in triplicates and analyzed using Atomic Absorption Spectrophotometer Buck 210VGP (AAS). The result revealed that heavy metals detected in spinach at Jimeta dumpsite decreased in the following order: Fe (3.7 mg/kg) > Pb (0.18 mg/kg) > Cu (0.12 mg/kg) > Cr (0.07 mg/kg) > Cd (below limit of detection), compared to the metal concentration in spinach at Ngorure dumpsite with lower concentration of heavy metal which decreased in the order of: Fe (2.5 mg/kg) > Pb (0.16 mg/kg) > Cu (0.14 mg/kg) > Cr (0.02 mg/kg) > Cd (below limit of detection). Other result for Spinach in Jimeta decreased in the order Fe (3.31mg/kg) > Pb (0.2mg/kg) > Cu (0.11mg/kg) > Cr (0.05mg/kg) > Cd (ND) beyond the limit of detection while Lettuce decreased in the order Fe (22.54mg/kg) > Cu (0.31mg/kg) > Pb (0.12mg/kg) > Cr (0.07mg/kg) > Cd (ND) beyond the limit of detection. Fe is the most abundant element in the vegetables with a mean value of 21 mg/kg followed by Pb (0.177 mg/kg). The analyses of paired T-test for vegetables in Ngurore and Jimeta at 0.05 level of significant confirmed that Cu and Cr showed no statistically significant difference in their concentration level while Fe and Pb confirmed that there was statistically significant difference in their concentration level. However, the detection of heavy metals in these vegetables calls for close environmental monitoring and adequate public awareness. This is necessary to discourage further pollution which could lead to high metal concentration and metal poisoning in vegetables and invariably humans that consume them. Keywords: Spinacia oleracea, Lactuca sativa, Heavy metal, Atomic Absorption Spectrophotometer

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