scholarly journals Influence of Selected Coagulants of Indicator and Dioxin-Like PCB Removal from Drinking Water

2017 ◽  
Vol 24 (1) ◽  
pp. 41-51
Author(s):  
Agata Rosińska

Abstract The aim of the research was to compare selected coagulants efficiency in indicator and chosen dioxin-like PCB removal from surface water. As coagulants, there were used aluminium sulfate and 5 hydrolyzed polyaluminium chlorides, with trade names: PAX-XL1, PAX-XL10, PAX-XL19, PAX-XL60, PAX-XL69. For the research, surface water was used, collected from dam reservoir. The water composition was modified with standard mixtures PCB MIX24 and MIX13, in order to obtain concentration of each congener equal to 300 ng/dm3. The PCB MIX24 mixture was composed of indicator congeners solution: 28, 52, 101, 118, 138, 153, and 180, whereas the MIX13 mixture - solution of three dioxin-like PCB 77, PCB 126, and PCB 169. It was demonstrated that the application of aluminium sulfate allowed for reaching better effects for purifying water of PCB, than with the usage of pre-hydrolyzed salts, polyaluminium chlorides. Out of the studied coagulants, the best effects for indicator PCB removal were obtained with the application of aluminium sulfate, total PCB concentration was decreased by 65%. The highest efficiency for indicator congeners removal (90%) was obtained for PCB 138 and 153. After the application of hydrolyzed polyaluminium chlorides PAX-XL1, PAX-XL10 decrease in higher chlorinated PCB concentration was obtained, in the range of 23 to 74%. Selectivity of chosen PCB congener removal, depending on applied coagulant, was demonstrated; with the usage of aluminium sulfate, removal of heptachlorobiphenyl PCB 180 at the level of 34% was obtained, whereas with the application of PAX-XL1 and PAX-XL10 higher reduction efficiency for this congener was obtained, i.e. 83 and 74% respectively. For dioxin-like PCB, after application of aluminium sulfate, total concentration reduction by 74% was obtained, efficiency of this congeners removal amounted to from 54 (PCB 77) up to 72% (PCB 126), similar results were obtained after the usage of PAX-XL1. The lowest PCB removal from water rate was stated for coagulants PAX-XL60 and PAX-XL69.

2013 ◽  
Vol 10 (10) ◽  
pp. 6639-6655 ◽  
Author(s):  
M. F. G. Weinkauf ◽  
T. Moller ◽  
M. C. Koch ◽  
M. Kučera

Abstract. Planktonic Foraminifera are important marine calcifiers, and the ongoing change in the oceanic carbon system makes it essential to understand the influence of environmental factors on the biomineralization of their shells. The amount of calcite deposited by planktonic Foraminifera during calcification has been hypothesized to reflect a range of environmental factors. However, it has never been assessed whether their calcification only passively responds to the conditions of the ambient seawater or whether it reflects changes in resource allocation due to physiological stress. To disentangle these two end-member scenarios, an experiment is required where the two processes are separated. A natural analogue to such an experiment occurred during the deposition of the Mediterranean sapropels, where large changes in surface water composition and stratification at the onset of the sapropel deposition were decoupled from local extinctions of planktonic Foraminifera species. We took advantage of this natural experiment and investigated the reaction of calcification intensity, expressed as mean area density (MAD), of four species of planktonic Foraminifera to changing conditions during the onset of Sapropel S5 (126–121 ka) in a sediment core from the Levantine Basin. We observed a significant relationship between MAD and surface water properties, as reflected by stable isotopes in the calcite of Foraminifera shells, but we failed to observe any reaction of calcification intensity on ecological stress during times of decreasing abundance culminating in local extinction. The reaction of calcification intensity to surface water perturbation at the onset of the sapropel was observed only in surface-dwelling species, but all species calcified more strongly prior to the sapropel deposition and less strongly within the sapropel than at similar conditions during the present-day. These results indicate that the high-salinity environment of the glacial Mediterranean Sea prior to sapropel deposition induced a~more intense calcification, whereas the freshwater injection to the surface waters associated with sapropel deposition inhibited calcification. The results are robust to changes in carbonate preservation and collectively imply that changes in normalized shell weight in planktonic Foraminifera should reflect mainly abiotic forcing.


2020 ◽  
Vol 261 ◽  
pp. 114183 ◽  
Author(s):  
Jessie B. Hoffman ◽  
Michael C. Petriello ◽  
Andrew J. Morris ◽  
M. Abdul Mottaleb ◽  
Yipeng Sui ◽  
...  

Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 496
Author(s):  
Krystyna Koziol ◽  
Marek Ruman ◽  
Filip Pawlak ◽  
Stanisław Chmiel ◽  
Żaneta Polkowska

Surface catchments in Svalbard are sensitive to external pollution, and yet what is frequently considered external contamination may originate from local sources and natural processes. In this work, we analyze the chemical composition of surface waters in the catchments surrounding the Polish Polar Station in Svalbard, Hornsund fjord area. We have pooled unpublished and already published data describing surface water composition in 2010, related to its pH, electrical conductivity (EC), metals and metalloids, total organic carbon (TOC) and selected organic compound concentrations, including persistent organic pollutants (POPs) and surfactants. These data were statistically analyzed for spatial differences, using Kruskal–Wallis ANOVA and principal component analysis (PCA), with distance from the station in the PCA approximating local human activity impact. The geological composition of the substratum was found to be a strong determinant of metal and metalloid concentrations, sufficient to explain significant differences between the studied water bodies, except for the concentration of Cr. The past and present human activity in the area may have contributed also to some of the polycyclic aromatic hydrocarbons (PAHs), although only in the case of naphthalene can such an effect be confirmed by an inverse correlation with distance from the station. Other likely factors contributing to the chemical concentrations in the local waters are marine influence, long-range pollution transport and release from past deposition in the environment.


2017 ◽  
Vol 3 (4) ◽  
pp. 744-756 ◽  
Author(s):  
R. Floris ◽  
G. Moser ◽  
K. Nijmeijer ◽  
E. R. Cornelissen

To understand and mitigate the role of surface water composition and associated membrane fouling in the removal of nC60 nanoparticles by low-pressure membranes, experiments were carried out with microfiltration membranes using natural feed waters, mimicking separation in real industrial water treatment plants.


2014 ◽  
Vol 43 (2) ◽  
Author(s):  
Mariusz Kluska ◽  
Ewa Witkowska-Krajewska ◽  
Anna Marciniuk-Kluska

AbstractThe paper presents the results of research on the content of 16 PAH, selected anions and heavy metals in samples collected from Lake Oleckie Wielkie. The samples were collected at seven locations around the lake within about 15 m from the shore in November 2012. The highest total concentration of 16 PAH (68.58 μmol dm−3) was found in water sample no. 7, and the lowest in water samples no. 1, 4 and 5. The obtained results do not exceed the levels of standards accepted in Poland for the surface water. The analysis of collected water samples, performed with the isotachophoresis method, showed a low content (less than 4 mg dm−3) of the analyzed anions: nitrates(V), nitrates(III), chlorides, sulphates(VI), sulphates(IV), phosphates(V) and hydrocarbonates(IV), as well as a low content of the analyzed heavy metals.


2021 ◽  
Vol 896 (1) ◽  
pp. 012034
Author(s):  
B Syahputra ◽  
Nafiah

Abstract The Babon River in East Semarang has been polluted by heavy metals sourced from industrial waste. So that water pollution at the Babon River estuary does not spread, it is necessary to carry out water treatment. This research uses a glass aquarium reactor and utilizes yellow velvetleaf (limmoncharis Flava) and water spinach (Ipomoea aquatic fork) plants as a medium to reduce the concentration of copper ions (Cu2+) by using variations in detention time. The results and analysis showed that yellow velvetleaf and water spinach could reduce the concentration of copper ions (Cu2+) in estuary surface water within 1 hour, 2 hours, 3 hours, and 5 hours. After going through several stages of a simple drinking water pre-treatment process, the results showed that yellow velvetleaf plants could reduce the concentration of copper ions (Cu2+) in Babon river water samples, from an initial concentration of 0.055 mg/L to 0.020 mg/L, with the highest efficiency percentage reduction up to 61.5%. As for water spinach, the concentration of copper ions that can be reduced only reaches the lowest level of 0.047 mg/L, with the highest percentage reduction efficiency of only 9.6% after the same pre-treatment process.


Author(s):  
Ketevan Kupatadze

The article reviews the chemical composition of borehole and surface waters in three villages of one of the regions of Georgia - Kakheti, Gurjaani Municipality. The study was specifically focused on iodine content in waters. It turned out that certain amount of iodine really existed in borehole waters, which means that by everyday drinking of water, the human body gets maybe not the complete required amount of iodine, but at least some part of it. It was also discovered, that according to certain parameters, waters are clean, do not contain heavy metals and can be freely used for drinking and cooking. The chemical composition of the Alazani River was also examined according to all four seasons. This river is interesting because of being used for irrigation of vineyards and fruit gardens.


Water ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 2568
Author(s):  
Jong Kwon Im ◽  
Sujin Kim ◽  
Young Seuk Kim ◽  
Hye Ran Noh ◽  
Young-Min Lee ◽  
...  

Volatile organic compounds (VOCs) are ubiquitous pollutants in surface water, which is the main source of drinking water in South Korea. We investigated the behavior (concentration, distribution, and environmental risk) of eleven selected VOCs in the surface water of the Han River tributaries using purge-and-trap gas chromatography/mass spectrometry. The average concentration of VOCs was 0.29 ± 0.47 μg/L. Chloroform and trichloroethylene (TCE) were the major pollutants, accounting for approximately 64.2% and 25.6% of the total concentration, respectively, and showing that halocarbons accounted for 94%. Chloroform was positively correlated with TCE and xylenes, and TCE was positively correlated with tetrachloroethylene (PCE). No differences were observed in the temporal average concentrations of total VOCs, but the concentrations differed significantly among sub-watershed areas. The Imjin-Hantan River, Han River mainstream, and Anseong Stream watersheds had a high positive association with TCE, whereas the Bukhan and Namhan River watersheds had a strong positive link with chloroform. The contamination and detection frequency of VOCs were highest in industrial complexes, followed by urban and rural areas. Thus, point source pollution significantly contributed to VOC contamination of these tributaries. Risk quotients for most VOCs were <1, suggesting negligible risk. Considering the relatively high occurrence of VOCs and their potential ecological risks, continuous environmental monitoring and study of environmental impacts based on ecotoxicity studies of domestic aquatic species are warranted.


2009 ◽  
Vol 6 (5) ◽  
pp. 424 ◽  
Author(s):  
Ewen Silvester

Environmental context. Australian alpine peatlands are thought to have an important role in maintaining water quality in the associated headwater streams. This study has confirmed that these peatlands can significantly modify stream water through a range of mechanisms, including: nutrient uptake, salt sequestering, and the export of organic carbon. While the significance of this chemical regulation to down stream processes is yet to be fully understood, it is clear that these systems have considerable potential to modify water composition. Abstract. Heathy Spur 1 (HS-1) is an intact alpine peatland in the Bogong High Plains, Victoria, Australia, that serves as a reference system for understanding the impacts of historical land use practices (cattle grazing, water diversion) and wildfire. The major ion chemistry in the groundwater feed and drainage water at HS-1 was studied over seasonal timescales during ‘dry weather’ periods; conditions that allow a simple hydrological model to be used, where the groundwater is assumed to partition between evapotranspiration and stream discharge. With this model the acid neutralising capacity (ANC) of stream discharge can be understood in terms of evapotranspiration and proton uptake associated with nitrate and sulfate removal. Stream discharge ANC is strongly partitioned towards exported dissolved organic carbon, shifting the buffering intensity to lower pH compared to the groundwater. Given the extremely low alkalinity of the regional groundwater, these alpine peatlands likely have a critical role in increasing headwater stream buffering capacity.


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