scholarly journals Interaction of Brilliant Blue dye solution with soil and its effect on mobility of compounds around the zones of preferenial flows at spruce stand

2017 ◽  
Vol 63 (2-3) ◽  
pp. 79-90 ◽  
Author(s):  
Juraj Bebej ◽  
Marián Homolák ◽  
Tomáš Orfánus

AbstractWe performed field experiment with 10 g l−1concentration of Brilliant Blue solutes in 100 l of water sprinkling on 1 × 1 m surface of the Dystric Cambisol. Consequently, four vertical profiles were exposed at experimental plot after 2 hours (CUT 2), 24 hours (CUT 24), 27 hours (CUT 27) and after 504 hours (CUT 504) in order to analyse spatiotemporal interactions among the BB solution (Na-salts), soil exchangeable complex and fine earth soil (%) samples extracted from both the high and low coloured zones located around the optically visualised macropore preferred flow (PF) zones. The concentration changes were quantifying via soil profiles not affected by BB (termed as REF) located in the close vicinity of experimental plot. Observed changes in pH (H2O), chemical composition of fineearth soil, as well as in concentration of Na+in soil exchangeable complex to suggest, the BB dye solution didn’t represent an inert tracer, but compounds strongly involved in reaction with surrounding soils. Recorded chemical trends seems to be the result both the competitive processes between the Na+ of BB dye solution and composition of surrounding soil exchangeable complex, as well and the spatial-temporal controlled mechanism of dye solution transfer in soil.

2013 ◽  
Vol 726-731 ◽  
pp. 2960-2963
Author(s):  
Ai Hui Liang ◽  
Dong Qin Han ◽  
Hui Yue Gan ◽  
Zhi Liang Jiang

In this paper, the effect of Fe3O4nanoparticle catalytic degradation brilliant blue X-BR dye was studied using spectrophotometric method. It was found that in the media of pH 0.65 HCl-NaAc buffer solution, 100 μmol/L H2O2, 0.7 g/L Fe3O4nanoparticle and the temperature 25°C, the degradation rate for reactive brilliant blue X-BR was over 93.5% in 20 min under the optimal conditions.


2016 ◽  
Vol 869 ◽  
pp. 765-767 ◽  
Author(s):  
Layane Rodrigues Almeida ◽  
João Sammy Nery Souza ◽  
Edson Cavalcanti Silva Filho ◽  
Josy Anteveli Osajima

The presence of organic pollutants, which cannot be eliminated by conventional processes of primary and secondary treatment, can be problematic. Photocatalytic processes offer an efficient breakdown of organic pollutants into non-toxic compounds such as CO2 and H2O. This paper proposes the use of the titanium dioxide embedded in palygorskite as a photoactive material in the degradation of cationic dye, Coomassie Brilliant Blue. The system was irradiated using UV light for a maximum time of 120 minutes. The concentration of the dye used was 1.0x10-4 mol L-1 in 0.5 g L-1 of the photoactive material. The kinetics of the system was monitored by UV-Vis spectrophotometry. In 120 minutes of radiation, the process of photocatalysis reduced the initial concentration of the Coomassie Brilliant Blue dye in half.


2015 ◽  
Vol 35 (1) ◽  
pp. 109-116 ◽  
Author(s):  
RONE B. DE OLIVEIRA ◽  
ULISSES R. ANTUNIASSI ◽  
MARCO A. GANDOLFO

This study defined the main adjuvant characteristics that may influence or help to understand drift formation process in the agricultural spraying. It was evaluated 33 aqueous solutions from combinations of various adjuvants and concentrations. Then, drifting was quantified by means of wind tunnel; and variables such as percentage of droplets smaller than 50 μm (V50), 100 μm (V100), diameter of mean volume (DMV), droplet diameter composing 10% of the sprayed volume (DV0.1), viscosity, density and surface tension. Assays were performed in triplicate, using Teejet XR8003 flat fan nozzles at 200 kPa (medium size droplets). Spray solutions were stained with Brilliant Blue Dye at 0.6% (m/ v). DMV, V100, viscosity cause most influence on drift hazardous. Adjuvant characteristics and respective methods of evaluation have applicability in drift risk by agricultural spray adjuvants.


PeerJ ◽  
2019 ◽  
Vol 7 ◽  
pp. e7880 ◽  
Author(s):  
Wenxiang Zhou ◽  
Guilin Han ◽  
Man Liu ◽  
Xiaoqiang Li

Soil carbon and nitrogen are essential factors for agricultural production and climate changes. A total of 106 soil samples from three agricultural lands (including two rice fields and one sugarcane field) and four non-agricultural lands (including two forest lands, one wasteland and one built-up land) in the Mun River Basin were collected to determine soil carbon, nitrogen, soil pH, soil particle sizes and explore the influence of pH and soil texture on soil C and N. The results show that total organic carbon (TOC) and nitrogen (TON) contents in topsoil (TOC: 2.78 ~ 18.83 g kg−1; TON: 0.48 ~ 2.05 g kg−1) are much higher than those in deep soil (TOC: 0.35 ~ 6.08 g kg−1; TON: <0.99 g kg−1). In topsoil, their contents of forest lands and croplands (TOC: average 15.37 g kg−1; TON: average 1.29 g kg−1) are higher than those of other land uses (TOC: average 5.28 g kg−1; TON: average 0.38 g kg−1). The pH values range from 4.2 to 6.1 in topsoil, and with increase in soil depth, they tend to increase and then decrease. Soil carbon, nitrogen and the C/N (TC/TN ratio) are negatively correlated with soil pH, demonstrating that relatively low pH benefits the accumulation of organic matter. Most soil samples are considered as sandy loam and silt loam from the percentages of clay, silt and sand. For soil profiles below 50 cm, the TOC and TON average contents of soil samples which contain more clay and silt are higher than those of other soil samples.


Author(s):  
Y. A. Unguwanrimi ◽  
A. M. Sada ◽  
G. N. Ugama ◽  
H. S. Garuba ◽  
A. Ugoani

Draft requirements of two animal – drawn (IAR) weeders operating on loam soil were determined in the study. The implements include a straddle row weeder and an emcot attached rotary weeder evaluated under the same soil conditions, using a pair of white Fulani breed of oxen. The animal draft requirement was first estimated from the animal ergonomics measurements. Using area of 0.054 hectare as experimental plot for each implement the draft requirement of each implement was investigated after taking soil samples for soil moisture content and bulk density determinations. The implements tested showed variation in their average draft requirement. The straddle row weeder had the highest value of 338.15 N respectively while the emcot attached rotary weeder had the lowest value of 188.12 N with 47.03%, respectively. The average soil moisture contents and bulk density were 13.0% and 1.46%/cm3, respectively.


2021 ◽  
Author(s):  
Calogero Schillaci ◽  
Sergio Saia ◽  
Aldo Lipani ◽  
Alessia Perego ◽  
Claudio Zaccone ◽  
...  

&lt;p&gt;Legacy data are frequently unique sources of data for the estimation of past soil properties. With the rising concerns about greenhouse gases (GHG) emission and soil degradation due to intensive agriculture and climate change effects, soil organic carbon (SOC) concentration might change heavily over time.&lt;/p&gt;&lt;p&gt;When SOC changes is estimated with legacy data, the use of soil samples collected in different plots (i.e., non-aligned data) may lead to biased results. The sampling schemes adopted to capture SOC variation usually involve the resampling of the original sample using a so called paired-site approach.&lt;/p&gt;&lt;p&gt;In the present work, a regional (Sicily, south of Italy) soil database, consisting of N=302 georeferenced soil samples from arable land collected in 1993 [1], was used to select coinciding sites to test a former temporal variation (1993-2008) obtained by a comparison of models built with data sampled in non-coinciding locations [2]. A specific sampling strategy was developed to spot SOC concentration changes from 1994 to 2017 in the same plots at the 0-30 cm soil depth and tested.&lt;/p&gt;&lt;p&gt;To spot SOC changes the minimum number of samples needed to have a reliable estimate of SOC variation after 23 years has been estimated. By applying an effect size based methodology, 30 out of 302 sites were resampled in 2017 to achieve a power of 80%, and an a=0.05.&lt;/p&gt;&lt;p&gt;After the collection of the 30 samples, SOC concentration in the newly collected samples was determined in lab using the same method&lt;/p&gt;&lt;p&gt;A Wilcoxon test applied to the variation of SOC from 1994 to 2017 suggested that there was not a statistical difference in SOC concentration after 23 years (Z = -0.556; 2-tailed asymptotic significance = 0.578). In particular, only 40% of resampled sites showed a higher (not always significant) SOC concentration than in 2017.&lt;/p&gt;&lt;p&gt;This finding contrasts with a previous SOC concentration increase that was found in 2008 (75.8% increase when estimated as differences of 2 models built with non-aligned data) [2], when compared to 1994 observed data (Z = -9.119; 2-tailed asymptotic significance &lt; 0.001).&lt;/p&gt;&lt;p&gt;Such a result implies that the use of legacy data to estimate SOC concentration changes need soil resampling in the same locations to overcome the stochastic model errors. Further experiment is needed to identify the percentage of the sites to resample in order to align two legacy datasets in the same area.&lt;/p&gt;&lt;p&gt;Bibliography&lt;/p&gt;&lt;p&gt;[1]Schillaci C, et al.,2019. A simple pipeline for the assessment of legacy soil datasets: An example and test with soil organic carbon from a highly variable area. CATENA.&lt;/p&gt;&lt;p&gt;[2]Schillaci C, et al., 2017. Spatio-temporal topsoil organic carbon mapping of a semi-arid Mediterranean region: The role of land use, soil texture, topographic indices and the influence of remote sensing data to modelling. Sci Total Environ.&amp;#160;&lt;/p&gt;


Forests ◽  
2020 ◽  
Vol 11 (5) ◽  
pp. 532 ◽  
Author(s):  
Wenxiang Zhou ◽  
Guilin Han ◽  
Man Liu ◽  
Jie Zeng ◽  
Bin Liang ◽  
...  

The profile distributions of soil organic carbon (SOC), soil organic nitrogen (SON), soil pH and soil texture were rarely investigated in the Lancangjiang River Basin. This study aims to present the vertical distributions of these soil properties and provide some insights about how they interact with each other in the two typical soil profiles. A total of 56 soil samples were collected from two soil profiles (LCJ S-1, LCJ S-2) in the Lancangjiang River Basin to analyze the profile distributions of SOC and SON and to determine the effects of soil pH and soil texture. Generally, the contents of SOC and SON decreased with increasing soil depth and SOC contents were higher than SON contents (average SOC vs. SON content: 3.87 g kg−1 vs. 1.92 g kg−1 in LCJ S-1 and 5.19 g kg−1 vs. 0.96 g kg−1 in LCJ S-2). Soil pH ranged from 4.50 to 5.74 in the two soil profiles and generally increased with increasing soil depth. According to the percentages of clay, silt, and sand, most soil samples can be categorized as silty loam. Soil pH values were negatively correlated with C/N ratios (r = −0.66, p < 0.01) and SOC contents (r = −0.52, p < 0.01). Clay contents were positively correlated with C/N ratios (r = 0.43, p < 0.05) and SOC contents (r = 0.42, p < 0.01). The results indicate that soil pH and clay are essential factors influencing the SOC spatial distributions in the two soil profiles.


2011 ◽  
Vol 474-476 ◽  
pp. 172-177 ◽  
Author(s):  
Jing Yong Liu ◽  
Xun An Ning

The soil samples in a profile were collected around the pyrite slag pile site near a sulfuric acid plant in Guangdong province and the contents of lead were investigated detail. At the same time, the mechanism of lead pollution was principium analyzed. The research found that the lead pollutants were mainly concentrated in soils surface layer about 0-10cm and shown characteristics of contents rapidly decreasing along the uprights. the main factors that affected the transference of lead from the slag to the soil were the filtering by acid rain and itself acidification of the slag. Iron oxide colloid and organic matter may have been responsible for the lead retention in soil.<b></b>


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