scholarly journals Effects of igneous intrusions on source rock in the early diagenetic stage: A case study on Beipiao Formation in Jinyang Basin, Northeast China

2020 ◽  
Vol 12 (1) ◽  
pp. 990-1002
Author(s):  
Shouliang Sun ◽  
Tao Zhang ◽  
Yongfei Li ◽  
Shuwang Chen ◽  
Qiushi Sun

AbstractMesozoic intrusive bodies play an important role in the temperature history and hydrocarbon maturation of the Jinyang Basin in northeastern China. The Beipiao Formation, which is the main source rock in Jinyang Basin, was intruded by numerous igneous bodies and dykes in many areas. The effects of igneous intrusive bodies on thermal evolution and hydrocarbon generation and migration in the Beipiao Formation were investigated. A series of samples from the outcrop near the intrusive body were analyzed for vitrinite reflectance (R0%) and other organic geochemical parameters to evaluate the lateral extension of the thermal aureole. The R0 values of the samples increase from a background value of ∼0.9% at a distance above 200 m from the intrusive body to more than 2.0% at the vicinity of the contact zone. The width of the altered zone is equal to the thickness of the intrusive body outcropped in the field. Organic geochemical proxies also indicate the intrusive body plays a positive and beneficial role in the formation of regional oil and gas resources. Due to the influence of the anomalous heat from the intrusive body, the hydrocarbon conversion rate of the source rocks of the Beipiao Formation was significantly improved. The accumulation properties and the storage capacity of the shales also greatly improved due to the intrusive body as indicated by the free hydrocarbon migration in the shales. This new understanding not only provides a reliable scientific basis for the accurate assessment of oil and gas genesis and resources in the Jinyang Basin but also provides guidance and reference for oil and gas exploration in the similar type of basin.

Energies ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 650 ◽  
Author(s):  
Jinliang Zhang ◽  
Jiaqi Guo ◽  
Jinshui Liu ◽  
Wenlong Shen ◽  
Na Li ◽  
...  

The Lishui Sag is located in the southeastern part of the Taibei Depression, in the East China Sea basin, where the sag is the major hydrocarbon accumulation zone. A three dimensional modelling approach was used to estimate the mass of petroleum generation and accumulated during the evolution of the basin. Calibration of the model, based on measured maturity (vitrinite reflectance) and borehole temperatures, took into consideration two main periods of erosion events: a late Cretaceous to early Paleocene event, and an Oligocene erosion event. The maturation histories of the main source rock formations were reconstructed and show that the peak maturities have been reached in the west central part of the basin. Our study included source rock analysis, measurement of fluid inclusion homogenization temperatures, and basin history modelling to define the source rock properties, the thermal evolution and hydrocarbon generation history, and possible hydrocarbon accumulation processes in the Lishui Sag. The study found that the main hydrocarbon source for the Lishui Sag are argillaceous source rocks in the Yueguifeng Formation. The hydrocarbon generation period lasted from 58 Ma to 32 Ma. The first period of hydrocarbon accumulation lasted from 51.8 Ma to 32 Ma, and the second period lasted from 23 Ma to the present. The accumulation zones mainly located in the structural high and lithologic-fault screened reservoir filling with the hydrocarbon migrated from the deep sag in the south west direction.


2016 ◽  
Author(s):  
Samuel Salufu ◽  
Rita Onolemhemhen ◽  
Sunday Isehunwa

ABSTRACT This paper sought to use information from outcrop sections to characterize the source and reservoir rocks in a basin in order to give indication(s) for hydrocarbon generation potential in a basin in minimizing uncertainty and risk that are allied with exploration and field development of oil and gas, using subsurface data from well logs, well sections, seismic and core. The methods of study includes detailed geological, stratigraphical, geochemical, structural,, petro-graphical, and sedimentological studies of rock units from outcrop sections within two basins; Anambra Basin and Abakaliki Basin were used as case studies. Thirty eight samples of shale were collected from these Basins; geochemical analysis (rockeval) was performed on the samples to determine the total organic content (TOC) and to assess the oil generating window. The results were analyzed using Rock wares, Origin, and Surfer software in order to properly characterize the potential source rock(s) and reservoir rock(s) in the basins, and factor(s) that can favour hydrocarbon traps. The results of the geological, stratigraphical, sedimentological, geochemical, and structural, were used to developed a new model for hydrocarbon generation in the Basins. The result of the geochemical analysis of shale samples from the Anambra Basin shows that the TOC values are ≥ 1wt%, Tmax ≥ 431°C, Vitrinite reflectance values are ≥ 0.6%, and S1+S2 values are > 2.5mg/g for Mamu Formation while shale samples from other formations within Anambra Basin fall out of these ranges. The shale unit in the Mamu Formation is the major source rock for oil generation in the Anambra Basin while others have potential for gas generation with very little oil generation. The shale samples from Abakaliki Basin shows that S1+S2 values range from< 1 – 20mg/g, TOC values range from 0.31-4.55wt%, vitrinite reflectance ranges from 0.41-1.24% and Tmax ranges from423°C – 466°C. This result also shows that there is no source rock for oil generation in Abakaliki Basin; it is either gas or graphite. This observation indicates that all the source rocks within Abakaliki Basin have exceeded petroleum generating stage due to high geothermal heat resulting from deep depth or the shale units have not attained catagenesis stage as a result of S1+S2 values lesser than 2.5mg/g despite TOC values of ≥ 0.5wt% and vitrinite reflectance values of ≥ 0.6%. The novelty of this study is that the study has been able to show that here there is much more oil than the previous authors claimed, and the distribution of this oil and gas in the basins is controlled by two major factors; the pattern of distribution of the materials of the source rock prior to subsidence and during the subsidence period in the basin, and the pattern and the rate of tectonic activities, and heat flow in the basin. If these factors are known, it would help to reduce the uncertainties associated with exploration for oil and gas in the two basins.


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-18
Author(s):  
Chengfu Lyu ◽  
Xixin Wang ◽  
Xuesong Lu ◽  
Qianshan Zhou ◽  
Ying Zhang ◽  
...  

The Kuqa Basin is a typical foreland basin in northwest China, characterized by compressive foreland fold-and-thrust belts and a regionally distributed huge salt layer. A large number of overthrust faults, fault-related folds, and salt-related structures are formed on the thrust belt due to strong compression and structural deformation, causing difficulty in simulation of the basin. In this study, modeling of the thermal history of the complicated compressional structural profiles in the Kuqa foreland basin was successfully conducted based on the advanced “Block” function introduced by the IES PetroMod software and the latest geological interpretation results. In contrast to methods used in previous studies, our method comprehensively evaluates the influence of overthrusting, a large thick salt layer with low thermal conductivity, fast deposition, or denudation on the thermal evolution history. The results demonstrate that the hydrocarbon generation center of the Kuqa foreland basin is in the deep layers of the Kelasu thrust belt and not in the Baicheng Sag center, which is buried the deepest. A surprising result was drawn about the center of hydrocarbon generation in the Kuqa foreland basin, which, although not the deepest in Baicheng Sag, is the deepest part of the Kelasu thrust Belt. In terms of the maturity of the source rock, there are obvious temporal and spatial differences between the different structural belts in the Kuqa foreland basin, such as the early maturation of source rocks and the curbing of uplift and hydrocarbon generation in the piedmont zone. In the Kelasu thrust belt, the source rock made an early development into the low mature-mature stage and subsequently rapidly grew into a high-over mature stage. In contrast, the source rock was immature at an early stage and subsequently grew into a low mature-mature stage in the Baicheng Sag–South slope belt. The time sequence of the thermal evolution of source rocks and structural trap formation and their matching determines the different accumulation processes and oil and gas compositions in the different structural belts of the Kuqa foreland basin. The matching of the multistage tectonic activity and hydrocarbon generation determines the characteristics of the multistage oil and gas accumulation, with the late accumulation being dominant. The effective stacking of the gas generation center, subsalt structural traps, reservoir facies of fine quality, and huge, thick salt caprocks creates uniquely favorable geological conditions for gas enrichment in the Kelasu foreland thrust belt.


2021 ◽  
Vol 18 (2) ◽  
pp. 398-415
Author(s):  
He Bi ◽  
Peng Li ◽  
Yun Jiang ◽  
Jing-Jing Fan ◽  
Xiao-Yue Chen

AbstractThis study considers the Upper Cretaceous Qingshankou Formation, Yaojia Formation, and the first member of the Nenjiang Formation in the Western Slope of the northern Songliao Basin. Dark mudstone with high abundances of organic matter of Gulong and Qijia sags are considered to be significant source rocks in the study area. To evaluate their development characteristics, differences and effectiveness, geochemical parameters are analyzed. One-dimensional basin modeling and hydrocarbon evolution are also applied to discuss the effectiveness of source rocks. Through the biomarker characteristics, the source–source, oil–oil, and oil–source correlations are assessed and the sources of crude oils in different rock units are determined. Based on the results, Gulong and Qijia source rocks have different organic matter primarily detrived from mixed sources and plankton, respectively. Gulong source rock has higher thermal evolution degree than Qijia source rock. The biomarker parameters of the source rocks are compared with 31 crude oil samples. The studied crude oils can be divided into two groups. The oil–source correlations show that group I oils from Qing II–III, Yao I, and Yao II–III members were probably derived from Gulong source rock and that only group II oils from Nen I member were derived from Qijia source rock.


Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8317
Author(s):  
Qiang Cao ◽  
Jiaren Ye ◽  
Yongchao Lu ◽  
Yang Tian ◽  
Jinshui Liu ◽  
...  

Semi-open hydrous pyrolysis experiments on coal-measure source rocks in the Xihu Sag were conducted to investigate the carbon isotope evolution of kerogen, bitumen, generated expelled oil, and gases with increasing thermal maturity. Seven corresponding experiments were conducted at 335 °C, 360 °C, 400 °C, 455 °C, 480 °C, 525 °C, and 575 °C, while other experimental factors, such as the heating time and rate, lithostatic and hydrodynamic pressures, and columnar original samples were kept the same. The results show that the simulated temperatures were positive for the measured vitrinite reflectance (Ro), with a correlation coefficient (R2) of 0.9861. With increasing temperatures, lower maturity, maturity, higher maturity, and post-maturity stages occurred at simulated temperatures (Ts) of 335–360 °C, 360–400 °C, 400–480 °C, and 480–575 °C, respectively. The increasing gas hydrocarbons with increasing temperature reflected the higher gas potential. Moreover, the carbon isotopes of kerogen, bitumen, expelled oil, and gases were associated with increased temperatures; among gases, methane was the most sensitive to maturity. Ignoring the intermediate reaction process, the thermal evolution process can be summarized as kerogen0(original) + bitumen0(original)→kerogenr (residual kerogen) + expelled oil (generated) + bitumenn+r (generated + residual) + C2+(generated + residual) + CH4(generated). Among these, bitumen, expelled oil, and C2-5 acted as reactants and products, whereas kerogen and methane were the reactants and products, respectively. Furthermore, the order of the carbon isotopes during the thermal evolution process was identified as: δ13C1 < 13C2-5 < δ13Cexpelled oil < δ13Cbitumen < δ13Ckerogen. Thus, the reaction and production mechanisms of carbon isotopes can be obtained based on their changing degree and yields in kerogen, bitumen, expelled oil, and gases. Furthermore, combining the analysis of the geochemical characteristics of the Pinghu Formation coal–oil-type gas in actual strata with these pyrolysis experiments, it was identified that this area also had substantial development potential. Therefore, this study provides theoretical support and guidance for the formation mechanism and exploration of oil and gas based on changing carbon isotopes.


The Rock–Eval pyrolysis and LECO analysis for 9 shale and 12 coal samples, as well as, geostatistical analysis have been used to investigate source rock characteristics, correlation between the assessed parameters (QI, BI, S1, S2, S3, HI, S1 + S2, OI, PI, TOC) and the impact of changes in the Tmax on the assessed parameters in the Cretaceous Sokoto, Anambra Basins and Middle Benue Trough of northwestern, southeastern and northcentral Nigeria respectively. The geochemical results point that about 97% of the samples have TOC values greater than the minimum limit value (0.5 wt %) required to induce hydrocarbon generation from source rocks. Meanwhile, the Dukamaje and Taloka shales and Lafia/Obi coal are found to be fair to good source rock for oil generation with slightly higher thermal maturation. The source rocks are generally immature through sub-mature to marginal mature with respect to the oil and gas window, while the potential source rocks from the Anambra Basin are generally sub-mature grading to mature within the oil window. The analyzed data were approached statistically to find some relations such as factors, and clusters concerning the examination of the source rocks. These factors were categorized into type of organic matter and organic richness, thermal maturity and hydrocarbon potency. In addendum, cluster analysis separated the source rocks in the study area into two groups. The source rocks characterized by HI >240 (mg/g), TOC from 58.89 to 66.43 wt %, S1 from 2.01 to 2.54 (mg/g) and S2 from 148.94 to 162.52 (mg/g) indicating good to excellent source rocks with kerogen of type II and type III and are capable of generating oil and gas. Followed by the Source rocks characterized by HI <240 (mg/g), TOC from 0.94 to 36.12 wt%, S1 from 0.14 to 0.72 (mg/g) and S2 from 0.14 to 20.38 (mg/g) indicating poor to good source rocks with kerogen of type III and are capable of generating gas. Howeverr, Pearson’s correlation coefficient and linear regression analysis shows a significant positive correlation between TOC and S1, S2 and HI and no correlation between TOC and Tmax, highly negative correlation between TOC and OI and no correlation between Tmax and HI. Keywords- Cretaceous, Geochemical, Statistical, Cluster; Factor analyses.


2020 ◽  
Vol 17 (6) ◽  
pp. 1540-1555
Author(s):  
Jin-Jun Xu ◽  
Qiang Jin

AbstractNatural gas and condensate derived from Carboniferous-Permian (C-P) coaly source rocks discovered in the Dagang Oilfield in the Bohai Bay Basin (east China) have important implications for the potential exploration of C-P coaly source rocks. This study analyzed the secondary, tertiary, and dynamic characteristics of hydrocarbon generation in order to predict the hydrocarbon potentials of different exploration areas in the Dagang Oilfield. The results indicated that C-P oil and gas were generated from coaly source rocks by secondary or tertiary hydrocarbon generation and characterized by notably different hydrocarbon products and generation dynamics. Secondary hydrocarbon generation was completed when the maturity reached vitrinite reflectance (Ro) of 0.7%–0.9% before uplift prior to the Eocene. Tertiary hydrocarbon generation from the source rocks was limited in deep buried sags in the Oligocene, where the products consisted of light oil and gas. The activation energies for secondary and tertiary hydrocarbon generation were 260–280 kJ/mol and 300–330 kJ/mol, respectively, indicating that each instance of hydrocarbon generation required higher temperature or deeper burial than the previous instance. Locations with secondary or tertiary hydrocarbon generation from C-P coaly source rocks were interpreted as potential oil and gas exploration regions.


2020 ◽  
Vol 66 (4) ◽  
pp. 223-233
Author(s):  
O.A. Oluwajana ◽  
A.O. Opatola ◽  
O.B. Ogbe ◽  
T.D. Johnson

AbstractSubsurface information on source rock potential of the Eocene shale unit of the Abakaliki Fold Belt is limited and has not been widely discussed. The total organic carbon (TOC) content and results of rock-eval pyrolysis for nine shale samples, as well as the one-dimensional (1D) geochemical model, from an exploration well in the Abakaliki Fold Belt were used to evaluate the source rock potentials and timing of hydrocarbon generation of Lower Eocene source rocks. The TOC content values of all the samples exceeded the minimum threshold value of 0.5 wt.% required for potential source rocks. A pseudo-Van Krevelen plot for the shale samples indicated Type II–III organic matter capable of generating gaseous hydrocarbon at thermally mature subsurface levels. The 1D burial model suggests that the Eocene source rock is capable of generating oil and gas at the present time. The modelled transformation ratio trend indicates that a fair amount of hydrocarbon has been expelled from the source rocks. The results of this study indicate that the Eocene source units may have charged the overlying thin Eocene sand bodies of the Abakaliki Fold Belt.


Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 595
Author(s):  
Temitope Love Baiyegunhi ◽  
Kuiwu Liu ◽  
Oswald Gwavava ◽  
Nicola Wagner ◽  
Christopher Baiyegunhi

The southern Bredasdorp Basin, off the south coast of South Africa, is only partly understood in terms of its hydrocarbon potential when compared to the central and northern parts of the basin. Hydrocarbon potential assessments in this part of the basin have been limited, perhaps because the few drilled exploration wells were unproductive for hydrocarbons, yielding trivial oil and gas. The partial integration of data in the southern Bredasdorp Basin provides another reason for the unsuccessful oil and gas exploration. In this study, selected Cretaceous mudrocks and sandstones (wacke) from exploration wells E-AH1, E-AJ1, E-BA1, E-BB1 and E-D3 drilled in the southern part of the Bredasdorp Basin were examined to assess their total organic carbon (TOC), thermal maturity, organic matter type and hydrocarbon generation potential. The organic geochemical results show that these rocks have TOC contents ranging from 0.14 to 7.03 wt.%. The hydrogen index (HI), oxygen index (OI), and hydrocarbon index (S2/S3) values vary between 24–263 mg HC/g TOC, 4–78 mg CO2/g TOC, and 0.01–18 mgHC/mgCO2 TOC, respectively, indicating predominantly Type III and IV kerogen with a minor amount of mixed Type II/III kerogen. The mean vitrinite reflectance values vary from 0.60–1.20%, indicating that the samples are in the oil-generation window. The Tmax and PI values are consistent with the mean vitrinite reflectance values, indicating that the Bredasdorp source rocks have entered the oil window and are considered as effective source rocks in the Bredasdorp Basin. The hydrocarbon genetic potential (SP), normalized oil content (NOC) and production index (PI) values all indicate poor to fair hydrocarbon generative potential. Based on the geochemical data, it can be inferred that most of the mudrocks and sandstones (wackes) in the southern part of the Bredasdorp Basin have attained sufficient burial depth and thermal maturity for oil and gas generation potential.


2015 ◽  
Author(s):  
Jamal A. Madi ◽  
Elhadi M. Belhadj

Abstract Oman's petroleum systems are related to four known source rocks: the Precambrian-Lower Cambrian Huqf, the Lower Silurian Sahmah, the Late Jurassic Shuaiba-Tuwaiq and the Cretaceous Natih. The Huqf and the Natih have sourced almost all the discovered fields in the country. This study examines the shale-gas and shale-oil potential of the Lower Silurian Sahmah in the Omani side of the Rub al Khali basin along the Saudi border. The prospective area exceeds 12,000 square miles (31,300 km2). The Silurian hot shale at the base of the Sahmah shale is equivalent to the known world-class source rock, widespread throughout North Africa (Tannezouft) and the Arabian Peninsula (Sahmah/Qusaiba). Both thickness and thermal maturities increase northward toward Saudi Arabia, with an apparent depocentre extending southward into Oman Block 36 where the hot shale is up to 55 m thick and reached 1.4% vitrinite reflectance (in Burkanah-1 and ATA-1 wells). The present-day measured TOC and estimated from log signatures range from 0.8 to 9%. 1D thermal modeling and burial history of the Sahmah source rock in some wells indicate that, depending on the used kinetics, hydrocarbon generation/expulsion began from the Early Jurassic (ca 160 M.a.b.p) to Cretaceous. Shale oil/gas resource density estimates, particularly in countries and plays outside North America remain highly uncertain, due to the lack of geochemical data, the lack of history of shale oil/gas production, and the valuation method undertaken. Based on available geological and geochemical data, we applied both Jarvie (2007) and Talukdar (2010) methods for the resource estimation of: (1) the amount of hydrocarbon generated and expelled into conventional reservoirs and (2) the amount of hydrocarbon retained within the Silurian hot shale. Preliminary results show that the hydrocarbon potential is distributed equally between wet natural gas and oil within an area of 11,000 square mile. The Silurian Sahmah shale has generated and expelled (and/or partly lost) about 116.8 billion of oil and 275.6 TCF of gas. Likewise, our estimates indicate that 56 billion of oil and 273.4 TCF of gas are potentially retained within the Sahmah source rock, making this interval a future unconventional resource play. The average calculated retained oil and gas yields are estimated to be 6 MMbbl/mi2 (or 117 bbl oil/ac-ft) and 25.3 bcf/mi2 (or 403 mcf gas/ac-ft) respectively. To better compare our estimates with Advanced Resources International (EIA/ARI) studies on several Silurian shale plays, we also carried out estimates based on the volumetric method. The total oil in-place is 50.2 billion barrels, while the total gas in-place is 107.6 TCF. The average oil and gas yield is respectively 7 MMbbl/mi2 and 15.5 bcf/mi2. Our findings, in term of oil and gas concentration, are in line or often smaller than all the shale oil/gas plays assessed by EIA/ARI and others.


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