Properties of wood-plastic composites (WPCs) reinforced with extracted and delignified wood flour

Holzforschung ◽  
2014 ◽  
Vol 68 (8) ◽  
pp. 933-940 ◽  
Author(s):  
Yao Chen ◽  
Nicole M. Stark ◽  
Mandla A. Tshabalala ◽  
Jianmin Gao ◽  
Yongming Fan

Abstract The water sorption and mechanical properties of wood-plastic composites (WPCs) made of extracted and delignified wood flour (WF) has been investigated. WF was prepared by extraction with the solvent systems toluene/ethanol (TE), acetone/water (AW), and hot water (HW), and its delignification was conducted by means of sodium chlorite/acetic acid (AA) solution. A 24 full-factorial experimental design was employed to determine the effects of treatments and treatment combinations. WPCs were prepared with high-density polyethylene (HDPE) and treated WF was prepared by means of extrusion followed by injection molding, and the water absorption characteristics and mechanical properties of the products were evaluated. WPCs produced with extracted WF had lower water absorption rates and better mechanical properties than those made of untreated WF. WPCs containing delignified WF had higher water absorption rates and improved mechanical performance compared with those made of untreated WF.

2011 ◽  
Vol 393-395 ◽  
pp. 76-79 ◽  
Author(s):  
Hai Bing Huang ◽  
Hu Hu Du ◽  
Wei Hong Wang ◽  
Hai Gang Wang

In this article, wood-plastic composites(WPCs) were manufactured with wood flour(80~120mesh、40~80mesh、20~40mesh、10~20mesh) combing with high density polyethylene(HDPE). Effects of the size of wood flour on mechanical properies and density of composites were investigated. Results showed that particle size of wood flour had an important effect on properitiesof WPCs. Change of mesh number had a outstanding effect on flexural modulus, tensile modulus and impact strength, howere, little effect on flexural strength and tensile strength. When mesh number of wood flour changed from 80~120mesh to 10~20mesh,flexural modulus and tensile modulus were respectively enhanced by 42.4% and 28.4%, respectively, and impact strength was decreased by 35.5%.Size of wood flour basically had no effect on density of composite within 10~120mesh. The use of wood flour or fiber as fillers and reinforcements in thermoplastics has been gaining acceptance in commodity plastics applications in the past few years. WPCs are currently experiencing a dramatic increase in use. Most of them are used to produce window/door profiles,decking,railing,ang siding. Wood thermoplastic composites are manufactured by dispering wood fiber or wood flour(WF) into molten plastics to form composite materials by processing techniques such as extrusion,themoforming, and compression or injection molding[1]. WPCs have such advantages[2]:(1)With wood as filler can improve heat resistance and strength of plastic, and wood has a low cost, comparing with inorganic filler, wood has a low density. Wood as strengthen material has a great potential in improving tensile strength and flexural modulus[3];(2) For composite of same volume, composites with wood as filler have a little abrasion for equipment and can be regenerated;(3)They have a low water absorption and low hygroscopic property, They are not in need of protective waterproof paint, at the same time, composite can be dyed and painted for them own needs;(4)They are superior to wood in resistantnce to crack、leaf mold and termite aspects, composites are the same biodegradation as wood;(5)They can be processed or connected like wood;(6)They can be processed into a lots of complicated shape product by means of extrusion or molding and so on, meanwhile, they have high-efficiency raw material conversion and itself recycle utilization[4]. While there are many sucesses to report in WPCs, there are still some issues that need to be addressed before this technology will reach its full potential. This technology involves two different types of materials: one hygroscopic(biomass) and one hydrophobic(plastic), so there are issues of phase separation and compatibilization[5]. In this paper, Effects of the size of wood powder on mechanical properties of WPCs were studied.


BioResources ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 789-804
Author(s):  
Qiang Jin ◽  
Lin Zhu ◽  
Jiedeerbieke Madiniyeti ◽  
Chunxia He ◽  
Li Li

Hydration-active steel slag and slag micropowder were used as inorganic fillers with silane coupling agent (KH550) to prepare wheat straw/polyvinyl chloride wood-plastic composites (WPCs) by extrusion molding. A 35-day immersion and a pre-immersion test were carried out to analyze the influence of steel slag and slag micropowder on the physical and mechanical properties of the WPCs under wet conditions. Results showed the following: (1) KH-550 exhibited a good surface modification effect on the activated steel slag and slag micropowder, (2) an increase in the activated steel slag and slag micropowder content could effectively reduce the percent water absorption of the WPCs by 20% to 25% and the expansion by 20% to 24%, respectively, compared with the control group, but had a limited effect on the tensile strength retention, and (3) pre-immersion could effectively induce the synergistic reinforcement effect of the active fillers, resulting in reaching the saturated water absorption within 20 days. The water absorption and tensile strength were respectively 18% to 25% lower and 1.5% to 3% higher than those of the composites without pre-immersion. The results of this study could provide experimental data and theoretical references for the influence of hydration-active inorganic fillers on WPC properties.


2019 ◽  
Vol 36 (1) ◽  
pp. 31-46 ◽  
Author(s):  
Haoqun Hong ◽  
Quannan Guo ◽  
Haiyan Zhang ◽  
Hui He

The article presents the preparation of a high-performance wood–plastic composites with improved interfacial interactions by adding ternary-monomer graft copolymers as the interfacial modifiers and by braising wood flour (WF) and investigates their effects on the rheological properties of recycled polyethylene (rPE)/WF composites. The processing properties, capillary rheological properties, dynamical rheological properties, and mechanical properties were investigated. Results show that graft copolymer of polyethylene is effective in improving the interfacial interactions of rPE/WF composites, dramatically changing the rheological and mechanical properties. The braising of WF enlarges the gaps of cells and promotes the infiltration of rPE into the gaps, as promoting the increasing in mechanical properties of rPE/WF composites and significantly changing the rheological properties of the composites.


Holzforschung ◽  
2013 ◽  
Vol 67 (2) ◽  
pp. 193-200 ◽  
Author(s):  
Manuel Raul Pelaez-Samaniego ◽  
Vikram Yadama ◽  
Eini Lowell ◽  
Thomas E. Amidon ◽  
Timothy L. Chaffee

Abstract Undebarked ponderosa pine chips were treated by hot water extraction to modify the chemical composition. In the treated pine (TP), the mass was reduced by approximately 20%, and the extract was composed mainly of degradation products of hemicelluloses. Wood flour produced from TP and unextracted chips (untreated pine, UP) was blended with high-density polyethylene (HDPE) and polypropylene (PP) and was extruded into wood plastic composites (WPCs). Formulations for WPCs consisted of 58% pine, 32% plastic, and 10% other additives. WPC based on HDPE+TP and PP+TP absorbed 46–45% less water than did WPC based on HDPE+UP and PP+UP, respectively. Thickness swelling was reduced by 45–59%, respectively, after 2520 h of immersion. The diffusion constant decreased by approximately 36%. Evaluation of mechanical properties in flexure and tension mode indicated improvements in TP-WPC properties, although the data were not statistically significant in all cases. Results showed that debarking of ponderosa pine is not required for WPC production.


2010 ◽  
Vol 150-151 ◽  
pp. 358-361
Author(s):  
Wen Lei ◽  
Hong Ming Ma ◽  
Yi Xu

In order to improve the flame retardancy of wood-plastic composites,a new sandwiched composite is introduced in this paper with basic magnesium sulfated whisker(MOS) filled high density polyethylene(HDPE) as skin and wood flour filled HDPE as core.The oxygen index of the skin and the mechanical properties of the whole sandwiched composite are investigated. The results show that, the flame retardancy of the skin will be improved siginicantly when much MOS is used,and the skin containing 40wt% MOS has an oxygen index of 25.6%,in addition,the sandwiched composite in which both the mass contents of MOS in the skin and wood flour in the core are 40% has better mechanical properties than the traditional wood plastic composite(WPC) without any skin,and the sandwiched WPC is more fatigue-resistant.


2018 ◽  
Vol 26 (1) ◽  
pp. 45-58 ◽  
Author(s):  
Chin-Hsing Chen ◽  
Chin-Lung Chiang ◽  
Wei-Jen Chen ◽  
Ming-Yuan Shen

Wood–plastic composites (WPCs) are a promising environmentally friendly material refers to composite that contain plant powders or fibers as reinforcement and plastic matrix. In this study, an epoxy resin and Methyl metharylate-Butadiene-Styrene Copolymer (MBS) were used as a compatibilizer and toughener and were filled into recycled polyethylene terephthalate (PET) and recycled polyamide 6 (PA6) blends (PET/PA6) and filled with wood flour to prepare the WPCs. The mechanical properties of the WPCs, including the tensile, flexural, and impact properties, with different mixing ratio polymer blends of PET to PA6 (E60/A40, E50/A50, and E40/A60) were investigated under different environmental aging conditions. The experimental results showed that different environmental conditions, such as temperature and humidity, markedly changed the mechanical properties of the WPCs with different mixing ratio polymer blends. In addition, the mechanisms responsible for the interface of the WPCs were identified by studying the fracture surfaces with field emission scanning electron microscopy.


2007 ◽  
Vol 15 (5) ◽  
pp. 365-370 ◽  
Author(s):  
L.M. Matuana ◽  
S. Cam ◽  
K.B. Yuhasz ◽  
Q.J. Armstrong

This study examined both the use of acrylonitrile-butadiene-styrene (ABS) as a plastic matrix for wood-plastic composites (WPCs) and the effect of impact modification on the mechanical properties of ABS/wood-flour composites. Blends of ABS filled with wood flour (both pine and maple) were processed into profile shape using a conical twin-screw extruder and the mechanical properties of the resulting composites were characterised and compared to WPCs made with polyolefins (HDPE and PP) and rigid PVC matrices. Generally, WPCs made with ABS matrix outperformed their polyolefin counterparts in both flexural strength and modulus, whereas ABS-based composites had inferior strength but greater modulus than those made with rigid PVC. The impact strength of ABS/wood-flour composites was below that of wood plastic composites made with polyolefins. However, impact modification with acrylonitrile-butadiene-styrene terpolymers had some effect in toughening of the ABS/wood-flour composites.


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