CNT@PDMS/NW composite materials with superior electromagnetic shielding

Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Zi-Jing Zhou ◽  
Zhen-Xing Wang ◽  
Xiao-shuai Han ◽  
Jun-Wen Pu

Abstract Lightweight materials with high electrical conductivity and hydrophobic mechanical properties are ideal materials for electromagnetic interference (EMI) shielding. Herein, the conductive composites with great EMI shielding effectiveness (SE) were successfully obtained by introducing multi-walled carbon nanotube (CNT) and polydimethylsiloxane (PDMS) based on the original structure of natural wood (NW). CNT@PDMS/NW composites were prepared via vacuum-pulse impregnation method and characterized by Fourier transform infrared (FTIR), scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) patterns, hydrophobicity analysis, and EMI shielding performance. As demonstrated, CNT nanosheets were successfully inserted into wood matrices, and hydrogen bonding between CNT nanosheets and cellulose nanofibers induced the fabrication of CNT@PDMS/NW composites. CNT@PDMS/NW composites exhibited excellent EMI SE values of 25.2 dB at the X-band frequency.

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Zhenxing Wang ◽  
Xiaoshuai Han ◽  
Sijie Wang ◽  
Xuewen Han ◽  
Junwen Pu

AbstractWith the growing popularity in digital systems and electronic communication equipment, there is an urgent need to develop lightweight, green, and efficient electromagnetic interference (EMI) shielding materials to handle the increasingly serious problem of radiation pollution. Herein, Ti3C2Tx (MXene)/natural wood (NW) composites were prepared using a vacuum-pulse impregnation method and characterized by Fourier transform infrared (FTIR), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) patterns, X-ray photoelectron spectroscopy (XPS) analysis, and EMI shielding performance. As demonstrated, Ti3C2Tx nanosheets were successfully inserted into wood matrices, and hydrogen bonding between Ti3C2Tx nanosheets and cellulose nanofibers induced the fabrication of Ti3C2Tx/NW composites. Ti3C2Tx/NW composites exhibited excellent EMI shielding effectiveness (SE) values of 28.2 dB at the X-band frequency.


2015 ◽  
Vol 3 (4) ◽  
pp. 820-827 ◽  
Author(s):  
Hilal Ahmad Reshi ◽  
Avanish P. Singh ◽  
Shreeja Pillai ◽  
Rama Shankar Yadav ◽  
S. K. Dhawan ◽  
...  

EMI shielding effectiveness values of up to 19 dB are observed in LSMO nanomaterials.


2019 ◽  
Vol 956 ◽  
pp. 87-98 ◽  
Author(s):  
Wei Liu ◽  
Kun Jia ◽  
Jiang Jiang Ma ◽  
Dong Hong Wang ◽  
Jian Yu Gu ◽  
...  

A series of flexible graphene/carbon nanotubes (CNTs) hybrid papers were prepared by a facile impregnation method using cellulose papers as substrate. The impregnation cycles and sequence have a great impact on microstructure, electrical conductivity and electromagnetic interference (EMI) shielding performance of graphene/CNTs hybrid papers. The results showed that the surface of cellulose papers was covered by graphene and CNTs, forming continuous conductive networks. The graphene/CNTs hybrid papers achieved a thickness range of 174.7-253.2 μm and areal density range of 26-35.7 g/m2, which presented a larger advantage than traditional EMI shielding materials. The electrical conductivity was increased from 0.33 S/cm to 7.63 S/cm with the increase of impregnation cycles from 1 to 5. Furthermore, graphene/CNTs hybrid papers delivered a high EMI shielding effectiveness of 22-32 dB in the frequency of 30-1500MHz, which was superior to single graphene or CNTs papers. Moreover, the electrical conductivity and EMI shielding effectiveness of as-prepared graphene/CNTs hybrid papers presented little decline after even bending 100 times at an angle of 180° owing to their excellent flexibility. The graphene/CNTs hybrid papers possess a huge application potential in electromagnetic compatibility (EMC) of electronic device. Key words: graphene; carbon nanotubes; electromagnetic interference shielding; cellulose paper; dielectric polarization


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Rongliang Yang ◽  
Xuchun Gui ◽  
Li Yao ◽  
Qingmei Hu ◽  
Leilei Yang ◽  
...  

AbstractLightweight, flexibility, and low thickness are urgent requirements for next-generation high-performance electromagnetic interference (EMI) shielding materials for catering to the demand for smart and wearable electronic devices. Although several efforts have focused on constructing porous and flexible conductive films or aerogels, few studies have achieved a balance in terms of density, thickness, flexibility, and EMI shielding effectiveness (SE). Herein, an ultrathin, lightweight, and flexible carbon nanotube (CNT) buckypaper enhanced using MXenes (Ti3C2Tx) for high-performance EMI shielding is synthesized through a facile electrophoretic deposition process. The obtained Ti3C2Tx@CNT hybrid buckypaper exhibits an outstanding EMI SE of 60.5 dB in the X-band at 100 μm. The hybrid buckypaper with an MXene content of 49.4 wt% exhibits an EMI SE of 50.4 dB in the X-band with a thickness of only 15 μm, which is 105% higher than that of pristine CNT buckypaper. Furthermore, an average specific SE value of 5.7 × 104 dB cm2 g−1 is exhibited in the 5-μm hybrid buckypaper. Thus, this assembly process proves promising for the construction of ultrathin, flexible, and high-performance EMI shielding films for application in electronic devices and wireless communications.


2021 ◽  
Author(s):  
Siyi Yan ◽  
Peng Li ◽  
Zhongshi Ju ◽  
He Chen ◽  
Jiangang Ma

Abstract Silver nanowire (AgNW) networks are promising transparent conducting materials for electromagnetic interference (EMI) shielding and diverse optoelectronic devices. However, the poor contact between adjacent AgNWs leads to low electrical conductivity and weak mechanical stability of AgNW networks, which are limiting the practical application of these electronics. Here we report an efficient strategy to improve the overall performance of AgNW networks, in which the AgNW networks are sandwiched between two layers of graphene films. The graphene films improve the contact of overlapped AgNWs and bridge the discrete AgNWs, and thus increase the conductivity of graphene/AgNWs/graphene (GAG) films. Microwave permittivity measurements together with mechanism analyses reveal that the graphene films can enhance the EMI shielding effectiveness of AgNW networks through offering extra conduction loss, multiple dielectric polarization centers and multi-reflection processes. As a result, the GAG film with an average transmittance of 88% exhibits a sheet resistance lower than 15 Ω sq− 1 and an EMI shielding effectiveness of 31 dB (in the frequency range of 8.2‒12.4 GHz) after repeated stretching and release at a strain of 40%. Such a total performance is superior to that of most of as-reported transparent conductors. The GAG films therefore show application potential in the age of Internet of Things that electromagnetic radiation pollutions are everywhere.


2017 ◽  
Vol 5 (5) ◽  
pp. 1095-1105 ◽  
Author(s):  
Jun Li ◽  
Hu Liu ◽  
Jiang Guo ◽  
Zhen Hu ◽  
Zhijiang Wang ◽  
...  

Flexible lightweight conductive nanocomposites prepared by self-assembly of gold nanoparticles on charged polymer nanofibers show enhanced EMI shielding effectiveness and mechanical properties.


2021 ◽  
Vol 875 ◽  
pp. 160-167
Author(s):  
Muhammad Fayzan Shakir ◽  
Asra Tariq

Polymer nano composites based on poly vinyl chloride matrix were fabricated using polyaniline (PANI) and graphene nano platelets (GNP) as electrically conductive nano filler for the application of electromagnetic interference (EMI) shielding. DC conductivity was first evaluated by using cyclic voltammetry and found an increasing trend of electrical conductivity as PANI and GNP was added in PVC matrix that confirms the formation of electrically conductive network structure. Dielectric properties like dielectric constant, dielectric loss and AC conductivity were evaluated in frequency range of 100 Hz to 3 MHz that gives basic prediction for EMI shielding effectiveness. Vector Network Analyzer (VNA) was used to assess EMI shielding properties using coaxial cable method in 11GHz to 20GHz range and it was found that a maximum of 29 dB shielding was archived with the incorporation of 15 wt% of PANI in PVC. This value increased to 56 dB as 5 wt% GNP added in PVC/PANI 15 wt% blend. Interaction of matrix with filler, nature of filler and dispersion of filler in matrix are the key parameters for achieving high shielding effectiveness.


2022 ◽  
Author(s):  
Yongqin Hu ◽  
Chen Hou ◽  
Yuxia Shi ◽  
Jiamei Wu ◽  
Da Yang ◽  
...  

Abstract Electromagnetic pollution seriously affects the human reproductive system, cardiovascular system, people’s visual system, and so on. A novel versatile stretchable and biocompatible electromagnetic interference (EMI) shielding film has been developed, which could effectively attenuate electromagnetic radiation. The EMI shielding film was fabricated with a convenient solution casting and steam annealing with 2D MXene, iron oxide nanoparticles, and soluble polyurethane. The EMI shielding effectiveness is about 30.63 dB at 8.2 GHz, based on its discretized interfacial scattering and high energy conversion efficiency. Meanwhile, the excellent tensile elongation is 30.5%, because of the sliding migration and gradient structure of the nanomaterials doped in a polymer matrix. In addition, the film also demonstrated wonderful biocompatibility and did not cause erythema and discomfort even after being attached to the arm skin over 12 hours, which shows the great potential for attenuation of electromagnetic irradiation and protection of human health.


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