Modification of biaxially oriented polypropylene films using dicyclopentadiene based hydrogenated hydrocarbon resin

2015 ◽  
Vol 35 (9) ◽  
pp. 859-866 ◽  
Author(s):  
Won-Suk Kong ◽  
Tae-Jun Ju ◽  
Jun-Hyo Park ◽  
Jae-Wook Lee ◽  
Ho Gyu Yoon
Keyword(s):  
Mechanical Properties ◽  
Oxygen Permeability ◽  
Amorphous Structure ◽  
High Glass Transition Temperature ◽  
Scanning Calorimetry ◽  
Film Properties ◽  
X Ray ◽  
Biaxially Oriented Polypropylene ◽  
Oriented Polypropylene ◽  
Polypropylene Films

Abstract The morphologies, crystalline structures, and thermal and rheological behaviors of isotactic polypropylene (iPP) blended with dicyclopentadiene based hydrogenated hydrocarbon resin (HCR) were investigated using scanning electron microscopy (SEM), wide-angle X-ray diffractometry, and differential scanning calorimetry in detail. Furthermore, the transparency, mechanical properties, and water vapor and oxygen permeability of biaxially oriented polypropylene films, fabricated from these iPP/HCR blends using a biaxial drawing machine, were examined. It was found that crystallinity varies with the HCR content of the iPP/HCR blend. In addition, amorphous HCR with its high glass transition temperature (Tg) upon blending with iPP’s amorphous structure affords improvements in various film properties, such as mechanical properties, transparency, and gas permeabilities.

Oxygen permeability of biaxially oriented polypropylene films

2008 ◽  
Vol 48 (4) ◽  
pp. 642-648 ◽  
Author(s):  
Y.J. Lin ◽  
P. Dias ◽  
H.Y. Chen ◽  
S. Chum ◽  
A. Hiltner ◽  
...  
Keyword(s):  
Oxygen Permeability ◽  
Biaxially Oriented Polypropylene ◽  
Oriented Polypropylene ◽  
Polypropylene Films

scholarly journals Effects of Sintering Temperature on Densification, Microstructure and Mechanical Properties of Al-Based Alloy by High-Velocity Compaction

Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 218
Author(s):  
Xianjie Yuan ◽  
Xuanhui Qu ◽  
Haiqing Yin ◽  
Zaiqiang Feng ◽  
Mingqi Tang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Velocity ◽  
Sintered Density ◽  
Sintering Temperature ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Transmission Electron ◽  
High Velocity Compaction ◽  
Sintered Temperature

This present work investigates the effects of sintering temperature on densification, mechanical properties and microstructure of Al-based alloy pressed by high-velocity compaction. The green samples were heated under the flow of high pure (99.99 wt%) N2. The heating rate was 4 °C/min before 315 °C. For reducing the residual stress, the samples were isothermally held for one h. Then, the specimens were respectively heated at the rate of 10 °C/min to the temperature between 540 °C and 700 °C, held for one h, and then furnace-cooled to the room temperature. Results indicate that when the sintered temperature was 640 °C, both the sintered density and mechanical properties was optimum. Differential Scanning Calorimetry, X-ray diffraction of sintered samples, Scanning Electron Microscopy, Energy Dispersive Spectroscopy, and Transmission Electron Microscope were used to analyse the microstructure and phases.

Research on compatibility and surface of high impact bio-based polyamide

2021 ◽  
pp. 095400832110055
Author(s):  
Yang Wang ◽  
Yuhui Zhang ◽  
Yuhan Xu ◽  
Xiucai Liu ◽  
Weihong Guo
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Crystallization Behavior ◽  
High Impact ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

The super-tough bio-based nylon was prepared by melt extrusion. In order to improve the compatibility between bio-based nylon and elastomer, the elastomer POE was grafted with maleic anhydride. Scanning Electron Microscopy (SEM) and Thermogravimetric Analysis (TGA) were used to study the compatibility and micro-distribution between super-tough bio-based nylon and toughened elastomers. The results of mechanical strength experiments show that the 20% content of POE-g-MAH has the best toughening effect. After toughening, the toughness of the super-tough nylon was significantly improved. The notched impact strength was 88 kJ/m2 increasing by 1700%, which was in line with the industrial super-tough nylon. X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) were used to study the crystallization behavior of bio-based PA56, and the effect of bio-based PA56 with high crystallinity on mechanical properties was analyzed from the microstructure.

scholarly journals Simultaneous Enhancement of Strength and Toughness of PLA Induced by Miscibility Variation with PVA

Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1178 ◽  
Author(s):  
Yanping Liu ◽  
Hanghang Wei ◽  
Zhen Wang ◽  
Qian Li ◽  
Nan Tian
Keyword(s):  
Mechanical Properties ◽  
High Performance ◽  
Fracture Strain ◽  
Electrospun Fiber ◽  
Structural Evolution ◽  
Amorphous Structure ◽  
Poly Lactic Acid ◽  
Poly Vinyl Alcohol ◽  
Scanning Calorimetry ◽  
Strength And Toughness

The mechanical properties of poly (lactic acid) (PLA) nanofibers with 0%, 5%, 10%, and 20% (w/w) poly (vinyl alcohol) (PVA) were investigated at the macro- and microscale. The macro-mechanical properties for the fiber membrane revealed that both the modulus and fracture strain could be improved by 100% and 70%, respectively, with a PVA content of 5%. The variation in modulus and fracture strain versus the diameter of a single electrospun fiber presented two opposite trends, while simultaneous enhancement was observed when the content of PVA was 5% and 10%. With a diameter of 1 μm, the strength and toughness of the L95V5 and L90V10 fibers were enhanced to over 3 and 2 times that of pure PLA, respectively. The structural evolution of electrospun nanofiber was analyzed by differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR). Although PLA and PVA were still miscible in the concentration range used, the latter could crystallize independently after electrospinning. According to the crystallization behavior of the nanofibers, a double network formed by PLA and PVA—one microcrystal/ordered structure and one amorphous structure—is proposed to contribute to the simultaneous enhancement of strength and toughness, which provides a promising method for preparing biodegradable material with high performance.

The Structure and Mechanical Properties of Plastically Consolidated Al-Ni Alloy

2016 ◽  
Vol 682 ◽  
pp. 245-251 ◽  
Author(s):  
Grzegorz Włoch ◽  
Tomasz Skrzekut ◽  
Jakub Sobota ◽  
Antoni Woźnicki ◽  
Justyna Cisoń
Keyword(s):  
Mechanical Properties ◽  
Vickers Hardness ◽  
Tensile Tests ◽  
Mechanical Analysis ◽  
Intermetallic Phases ◽  
Scanning Calorimetry ◽  
Porosity Formation ◽  
X Ray ◽  
Ni Alloy ◽  
Thermal Stability Of

Mixed and preliminarily consolidated powders of aluminium and nickel (90 mass % Al and 10 mass % Ni) were hot extruded. As results the rod, 8 mm in diameter, was obtained. As-extruded material was subjected to the microstructural investigations using scanning electron microscopy (SEM/EDS) and X-ray analysis (XRD). The differential scanning calorimetry (DSC) and thermo-mechanical analysis (TMA) were also performed. The mechanical properties of as extruded material were determined by the tensile test and Vickers hardness measurements. In order to evaluate the thermal stability of PM alloy, samples were annealed at the temperature of 475 and 550 °C. After annealing Vickers hardness measurements and tensile tests were carried out. The plastic consolidation of powders during extrusion was found to be very effective, because no pores or voids were observed in the examined material. The detailed microstructural investigations and XRD analyses did not reveal the presence of the intermetallic phases in the as-extruded material. During annealing, the Al3Ni intermetallic compound was formed as the result of chemical reaction between the alloy components. The hardness of the alloy after annealing at the temperature of 475°C was found to be comparable to the hardness in as-extruded state. Annealing of the material at the temperature of 550°C results in hardness decreasing by about 50%, as the consequence of porosity formation and Al3Ni cracking.

Effects of Cooling Rate and Sn Addition on the Microstructure of Ti-Nb-Sn Alloys

2011 ◽  
Vol 172-174 ◽  
pp. 190-195 ◽  
Author(s):  
Giorgia T. Aleixo ◽  
Eder S.N. Lopes ◽  
Rodrigo Contieri ◽  
Alessandra Cremasco ◽  
Conrado Ramos Moreira Afonso ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cooling Rate ◽  
Melting Furnace ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Β Phase ◽  
Arc Melting ◽  
Ti Alloys ◽  
Ω Phase

Ti-based alloys present unique properties and hence, are employed in several industrial segments. Among Ti alloys, β type alloys form one of the most versatile classes of materials in relation to processing, microstructure and mechanical properties. It is well known that heat treatment of Ti alloys plays an important role in determining their microstructure and mechanical behavior. The aim of this work is to analyze microstructure and phases formed during cooling of β Ti-Nb-Sn alloy through different cooling rates. Initially, samples of Ti-Nb-Sn system were prepared through arc melting furnace. After, they were subjected to continuous cooling experiments to evaluate conditions for obtaining metastable phases. Microstructure analysis, differential scanning calorimetry and X-ray diffraction were performed in order to evaluate phase transformations. Depending on the cooling rate and composition, α” martensite, ω phase and β phase were obtained. Elastic modulus has been found to decrease as the amount of Sn was increased.

scholarly journals Preparation of Reswellable Amorphous Porous Celluloses through Hydrogelation from Ionic Liquid Solutions

Materials ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3249 ◽  
Author(s):  
Satoshi Idenoue ◽  
Yoshitaka Oga ◽  
Daichi Hashimoto ◽  
Kazuya Yamamoto ◽  
Jun-ichi Kadokawa
Keyword(s):  
Mechanical Properties ◽  
Ionic Liquid ◽  
Amorphous Structure ◽  
X Ray Diffraction ◽  
Electron Microscopic ◽  
X Ray ◽  
Liquid Solutions ◽  
Scanning Electron Microscopic ◽  
Porous Morphology ◽  
Scanning Electron

In this study, we have performed the preparation of reswellable amorphous porous celluloses through regeneration from hydrogels. The cellulose hydrogels were first prepared from solutions with an ionic liquid, 1-butyl-3-methylimidazolium chloride (BMIMCl), in different concentrations. Lyophilization of the hydrogels efficiently produced the regenerated celluloses. The powder X-ray diffraction and scanning electron microscopic measurements of the products suggest an amorphous structure and porous morphology, respectively. Furthermore, the pore sizes of the regenerated celluloses, or in turn, the network sizes of cellulose chains in the hydrogels, were dependent on the concentrations of the initially prepared solutions with BMIMCl, which also affected the tensile mechanical properties. It was suggested that the dissolution states of the cellulose chains in the solutions were different, in accordance with the concentrations, which representatively dominated the pore and network sizes of the above materials. When the porous celluloses were immersed in water, reswelling was observed to regenerate the hydrogels.

Structure and properties of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)/poly(L-lactic acid) quasi core/sheath melt-electrospun microfibers

2018 ◽  
Vol 89 (9) ◽  
pp. 1770-1781 ◽  
Author(s):  
Huaizhong Xu ◽  
Benedict Bauer ◽  
Masaki Yamamoto ◽  
Hideki Yamane
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Tensile Tests ◽  
Processing Parameters ◽  
Structure And Properties ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Diffraction Patterns

A facile route was proposed to fabricate core–sheath microfibers, and the relationships among processing parameters, crystalline structures and the mechanical properties were investigated. The compression molded poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH)/poly(L-lactic acid) (PLLA) strip enhanced the spinnability of PHBH and the mechanical properties of PLLA as well. The core–sheath ratio of the fibers was determined by the prefab strip, while the PLLA sheath component did not completely cover the PHBH core component due to the weak interfacial tension between the melts of PHBH and PLLA. A rotational target was applied to collect aligned fibers, which were further drawn in a water bath. The tensile strength and the modulus of as-spun and drawn fibers increased with increasing the take-up velocities. When the take-up velocity was above 500 m/min, the jet became unstable and started to break up at the tip of the Taylor cone, decreasing the mechanical properties of the fibers. The drawing process facilitated the crystallization of PLLA and PHBH, and the tensile strength and the modulus increased linearly with the increasing the draw ratio. The crystal information displayed from wide-angle X-ray diffraction patterns and differential scanning calorimetry heating curves supported the results of the tensile tests.

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