Application of modified starch in high-temperature-resistant colloidal gas aphron (CGA) drilling fluids

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Wenxi Zhu ◽  
Xiuhua Zheng
Keyword(s):  
High Temperature ◽  
High Temperatures ◽  
High Performance ◽  
Oil And Gas ◽  
Elevated Temperatures ◽  
Drilling Fluid ◽  
Drilling Fluids ◽  
Modified Starch ◽  
Gas Reservoirs ◽  
Building Capability

Abstract Colloidal gas aphrons (CGA) are finding increasing application in depleted oil and gas reservoirs because of their distinctive characteristics. To overcome the limitations of its application in high-temperature drilling, a modified starch foams stabilizer WST with a temperature resistance of 160 °C was synthesized via radical polymerization. The chemical structure of WST was characterized by Fourier infrared spectroscopy and results showed that all three monomers acrylamide, 2-acrylamido-2-methyl-1-propane sulfonic acid, and N-vinylpyrrolidone have been grafted onto starch efficiently. Based on the microscopic observations, highly stable aphrons have been successfully generated in the WST-based CGA drilling fluids within 160 °C, and most aphrons lie in the range of 10–150 μm. WST can provide higher viscosity at high temperatures compared to xanthan gum, which helps to extend foam life and stability by enhancing the film strength and slowing down the gravity drainage. Results show that WST-CGA aged at elevated temperatures (120–160 °C) is a high-performance drilling fluid with excellent shear-thinning behavior, cutting carrying capacity, and filtration control ability. The significant improvement of filtration control and well-building capability at high temperatures is an important advantage of WST-CGA, which can be attributed to the enhancement of mud cake quality by WST.

Well Clean-Up Using a Combined Thermochemical/Chelating Agent Fluids

2019 ◽  
Vol 141 (10) ◽  
Author(s):  
Mohamed Mahmoud
Keyword(s):  
High Temperature ◽  
Filter Cake ◽  
Oil And Gas ◽  
Drilling Fluid ◽  
Chelating Agent ◽  
Drilling Fluids ◽  
Gas Wells ◽  
Oil And Gas Wells ◽  
Different Types ◽  
Cake Removal

The well clean-up process involves the removal of impermeable filter cake from the formation face. This process is essential to allow the formation fluids to flow from the reservoir to the wellbore. Different types of drilling fluids such as oil- and water-based drilling fluids are used to drill oil and gas wells. These drilling fluids are weighted with different weighting materials such as bentonite, calcium carbonate, and barite. The filter cake that forms on the formation face consists mainly of the drilling fluid weighting materials (around 90%), and the rest is other additives such as polymers or oil in the case of oil-base drilling fluids. The process of filter cake removal is very complicated because it involves more than one stage due to the compatibility issues of the fluids used to remove the filter cake. Different formulations were used to remove different types of filter cake, but the problem with these methods is the removal efficiency or the compatibility. In this paper, a new method was developed to remove different types of filter cakes and to clean-up oil and gas wells after drilling operations. Thermochemical fluids that consist of two inert salts when mixed together will generate very high pressure and high temperature in addition to hot water and hot nitrogen. These fluids are sodium nitrate and ammonium chloride. The filter cake was formed using barite and calcite water- and oil-based drilling fluids at high pressure and high temperature. The removal process started by injecting 500 ml of the two salts and left for different time periods from 6 to 24 h. The results of this study showed that the newly developed method of thermochemical removed the filter cake after 6 h with a removal efficiency of 89 wt% for the barite filter cake in the water-based drilling fluid. The mechanisms of removal using the combined solution of thermochemical fluid and ethylenediamine tetra-acetic acid (EDTA) chelating agent were explained by the generation of a strong pressure pulse that disturbed the filter cake and the generation of the high temperature that enhanced the barite dissolution and polymer degradation. This solution for filter cake removal works for reservoir temperatures greater than 100 °C.

Elevated-Temperature and -Pressure Tribology of Drilling Fluids Used in Oil and Gas Extended-Reach-Drilling Applications

SPE Journal ◽  
2018 ◽  
Vol 23 (06) ◽  
pp. 2339-2350 ◽  
Author(s):  
Pixiang Lan ◽  
Kyriaki Polychronopoulou ◽  
Larry L. Iaccino ◽  
Xiaoying Bao ◽  
Andreas A. Polycarpou
Keyword(s):  
Elevated Temperature ◽  
Photoelectron Spectroscopy ◽  
Oil And Gas ◽  
Elevated Temperatures ◽  
Drilling Fluid ◽  
Cost Effective ◽  
Chamber Pressure ◽  
Drilling Fluids ◽  
Slight Reduction ◽  
Extended Reach Drilling

Summary Extended-reach-drilling (ERD) wells are expensive and challenging; however, in special situations, compared with conventional drilling, ERD wells are more environmentally friendly and cost-effective. Application of drilling fluids with good lubrication for ERD is one of the most important methods to facilitate longer total depth (TD) of the wells. To better simulate the elevated-temperature environment in the borehole, this study proposes a method to perform tribological studies of drilling fluids at temperatures higher than 100°C by conducting experiments in a high-chamber-pressure environment, which can suppress the evaporation of the drilling fluid at high temperatures. Two lubricant additives were studied, and the results showed that, for the drilling fluid at elevated temperatures, a prototype additive (Additive A) reduced the coefficient of friction (COF) significantly by 44.8%, whereas a commercial additive (Additive B) caused only a slight reduction of the COF by 4%. After the tribological experiments, the wear mechanisms of the additives and abrasive particles were investigated with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS).

scholarly journals The application of MWCNT to enhance the rheological behavior of drilling fluids at high temperature

2017 ◽  
Vol 12 (3) ◽  
Author(s):  
Abdul Razak Ismail ◽  
W. R. W Sulaiman ◽  
M. Z. Jaafar ◽  
A. Aftab ◽  
A. A. Razi ◽  
...  
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Rheological Behavior ◽  
Oil And Gas ◽  
Drilling Fluid ◽  
Gel Strength ◽  
Drilling Fluids ◽  
Deep Wells ◽  
Multi Walled Carbon Nanotube ◽  
Filtrate Loss

Drilling fluid is the key component to drill oil and gas wells. The rheological behavior of drilling fluid will be affected when drilling deep wells especially at high temperature and high pressure reservoir. This research was conducted to study the effect of the nanoparticles over the rheological properties of the drilling fluid when aging at high temperature condition. Several drilling fluids were prepared using synthetic based fluids (Sarapar and Saraline) to study the effect of multi-walled carbon nanotube (MWCNT) at different concentrations. The rheological properties of drilling fluid were analyzed after aging at 250 °F and 350 °F for 16 hours. The results revealed that the addition of MWCNT improved the 10-sec gel strength by 33% and filtrate loss volume was reduced to 10% after aging at 250°F in Saraline drilling fluid. Moreover, the plastic viscosity of Saraline and Sarapar drilling fluid after addition of MWCNT was enhanced by 6% and 27% at 350 °F. Filtrate loss volume of Sarapar drilling fluid was reduced by 19 % after aging at 250 °F for 16 hours. The overall results showed that the addition of MWCNT into the drilling fluid have slightly improved the rheological properties of drilling fluids under high temperature conditions.

scholarly journals Study on the Rheological Properties of Ultra-High Temperature CGA Drilling Fluids

2021 ◽  
Author(s):  
Wenxi Zhu ◽  
Xiuhua Zheng
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
High Temperatures ◽  
Drilling Fluid ◽  
Drilling Fluids ◽  
Underbalanced Drilling ◽  
Deep Wells ◽  
Colloidal Gas Aphron ◽  
Oil Gas ◽  
Ultra High Temperature

Colloidal gas aphron (CGA) drilling fluids are a kind of environmentally-friendly underbalanced drilling technique, which has attracted more attention in depleted reservoirs and other low-pressure areas. With the shortage of global oil/gas resources, drilling has gradually shifted to high-temperature and deep wells. Hence, a study on the ultra-high temperature rheology properties of CGA fluids is lacking and urgently needed. In this study, a novel CGA drilling fluid system was prepared by modified starch and amino acid surfactant, and rheological properties after 120-300°C aged was investigate. Results show that: (1) Herschel-Bulkley model is the preferred model to predict CGA drilling fluid at ultra-high temperatures; (2) It was proved that CGA drilling fluid is a high-quality drilling fluid with extremely high value of LSRV and shear thinning property within 280°C. Compared to the traditional XG-based CGA drilling fluid, the improvement of LSRV at ultra-high temperatures is a significant advantage of EST-based CGA drilling fluid which is conducive to carrying cuttings and sealing formation pores.

First Use of Novel High Temperature Water-Based Reservoir Drilling Fluid to Access Depleted Deepwater Reserves

2021 ◽  
Author(s):  
Alexandra Clare Morrison ◽  
Conan King ◽  
Kevin Rodrigue
Keyword(s):  
High Temperature ◽  
Elevated Temperatures ◽  
Drilling Fluid ◽  
Synthetic Polymer ◽  
Wellbore Stability ◽  
Soluble Solids ◽  
Fluid Loss ◽  
Drilling Fluids ◽  
Flow Loop ◽  
Loss Control

Abstract A combination of divalent base brine and high wellbore temperature presents significant challenges for high density aqueous reservoir drilling fluids. Such systems traditionally use biopolymers as viscosifiers; however, they are subject to degradation at elevated temperatures. Non-aqueous drilling fluids are thermally stable but complete removal of the filtercake is challenging and this can lead to formation damage. This paper describes the qualification and first deepwater drilling application of a unique aqueous reservoir drilling fluid at temperatures above 320°F. A high-temperature divalent brine-based reservoir drilling fluid (HT-RDF) and a solids-free screen running fluid (SF-SRF) were designed, both utilizing the same novel synthetic polymer technology. Calcium bromide brine was selected for use to minimize the total amount of acid-soluble solids in the drilling fluid. A comprehensive qualification was undertaken examining parameters such as rheology performance across a range of temperatures, long-term stability, fluid loss under expected and stress conditions (16 hours at 356°F), production screen test (PST), and various fluid-fluid compatibility tests. Return permeability tests were conducted on the final formulations to validate their suitability for use. The synthetic polymer technology provided excellent rheology, suspension, and fluid loss control in the fluid systems designed in the laboratory. To prepare for field execution multiple yard mixes were performed to verify the laboratory results on a larger scale. Additionally, a flow loop system was utilized to evaluate fluid performance under simulated downhole temperature and pressure conditions before field deployment. The final high temperature drilling fluid as designed provided rheological properties that met the necessary equivalent circulating density (ECD) requirements while drilling the reservoir. The fluid loss remained extremely stable and there were no downhole losses despite the depleted nature of the wellbore. Production screens were run straight to total depth (TD) with no wellbore stability issues after a three-day logging campaign. High temperature aqueous reservoir drilling fluids have historically been limited by the lack of suitable viscosifiers and fluid loss control additives. This paper outlines the design, mixing and logistical considerations and field execution of a novel polymer-based reservoir drilling fluid.

scholarly journals Application of Thermal Resistant Gemini Surfactants in Highly Thixotropic Water-in-oil Drilling Fluid System

2019 ◽  
Vol 17 (1) ◽  
pp. 1435-1441
Author(s):  
Yonggui Liu ◽  
Yang Zhang ◽  
Jing Yan ◽  
Tao Song ◽  
Yongjun Xu
Keyword(s):  
Gemini Surfactants ◽  
Drilling Fluid ◽  
Drilling Fluids ◽  
Excellent Thermal Stability ◽  
Oil Drilling ◽  
Low Viscosity ◽  
Emulsion Drops ◽  
Oil Emulsions ◽  
Building Capability ◽  
Liquid Precipitation

AbstractTraditional water-in-oil drilling fluids are limited by their shear thinning behavior. In this article, we propose the synthesis of a thermal resistant quaternary ammonium salt gemini surfactant DQGE-I. This surfactant was synthesized using monomers such as N,N-dimethyl-1,3-propanediamine, organic acids and epichlorohydrin, as well as blocking groups such as N-vinylpyrrolidone (NVP). The prepared surfactant exhibited various advantages over traditional surfactants, including excellent thermal stability, good emulsifying and wetting capability. The use of these surfactants was shown to improve the compactness of emulsifier molecules at the oil/water interface, as well as the overall emulsificaiton effect. Laboratory studies revealed that water-in-oil emulsions prepared using DQGE-I showed high emulsion breaking voltage, low liquid precipitation and small and uniformly distributed emulsion drops. Highly thixotropic water-in-oil drilling fluids based on DQGE-I showed low viscosity, high shear rate and thermal tolerance up to 260oC. Additionally, the proposed fluid was applied in 16 wells (including WS1-H2, GS3 and XS1-H8) in the Daqing Oilfield. Testing showed that DQGE-1 exhibited excellent rheological behavior and wall-building capability. The emulsion breaking voltage exceeded 1500 V, and the yield point/ plastic viscosity ratio exceeded 0.4. The use of this surfactant can help to solve problems such as high formation temperature and poor well wall stability.

Low ECD High Performance Invert Emulsion Drilling Fluids: Lab Development and Field Deployment

2021 ◽  
Author(s):  
Vikrant Wagle ◽  
Abdullah Yami ◽  
Michael Onoriode ◽  
Jacques Butcher ◽  
Nivika Gupta
Keyword(s):  
High Performance ◽  
Filter Cake ◽  
Drilling Fluid ◽  
Field Performance ◽  
Superior Performance ◽  
Core Material ◽  
Drilling Fluids ◽  
Invert Emulsion ◽  
Field Deployment ◽  
Permeability Studies

Abstract The present paper describes the results of the formulation of an acid-soluble low ECD organoclay-free invert emulsion drilling fluid formulated with acid soluble manganese tetroxide and a specially designed bridging package. The paper also presents a short summary of field applications to date. The novel, non-damaging fluid has superior rheology resulting in lower ECD, excellent suspension properties for effective hole cleaning and barite-sag resistance while also reducing the risk of stuck pipe in high over balance applications. 95pcf high performance invert emulsion fluid (HPIEF) was formulated using an engineered bridging package comprising of acid-soluble bridging agents and an acid-soluble weighting agent viz. manganese tetroxide. The paper describes the filtration and rheological properties of the HPIEF after hot rolling at 300oF. Different tests such as contamination testing, sag-factor analysis, high temperature-high pressure rheology measurements and filter-cake breaking studies at 300oF were performed on the HPIEF. The 95pcf fluid was also subjected to particle plugging experiments to determine the invasion characteristics and the non-damaging nature of the fluids. The 95pcf HPIEF exhibited optimal filtration properties at high overbalance conditions. The low PV values and rheological profile support low ECDs while drilling. The static aging tests performed on the 95pcf HPIEF resulted in a sag factor of less than 0.53, qualifying the inherent stability for expected downhole conditions. The HPIEF demonstrated resilience to contamination testing with negligible change in properties. Filter-cake breaking experiments performed using a specially designed breaker fluid system gave high filter-cake breaking efficiency. Return permeability studies were performed with the HPIEF against synthetic core material, results of which confirmed the non-damaging design of the fluid. The paper thus demonstrates the superior performance of the HPIEF in achieving the desired lab and field performance.

ENVIRONMENTAL DRILLING SOLUTIONS ON THE POLYMERIC BASIS

2020 ◽  
Author(s):  
E.A. Flik ◽  
◽  
Y.E. Kolodyazhnaya
Keyword(s):  
Oil And Gas ◽  
Drilling Fluid ◽  
Oil And Gas Industry ◽  
Environmental Safety ◽  
Drilling Fluids ◽  
Gas Industry ◽  
Fluid Systems ◽  
Water Based

The article assesses the environmental safety of drilling fluids that are currently widely used in the oil and gas industry. It shows active development of water-based drilling fluid systems using xanthan biopolymer.

scholarly journals Experimental Investigation of the Rheological Behavior of an Oil-Based Drilling Fluid with Rheology Modifier and Oil Wetter Additives

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4877
Author(s):  
Mobeen Murtaza ◽  
Sulaiman A. Alarifi ◽  
Muhammad Shahzad Kamal ◽  
Sagheer A. Onaizi ◽  
Mohammed Al-Ajmi ◽  
...  
Keyword(s):  
High Temperature ◽  
Zeta Potential ◽  
Hot Rolling ◽  
Emulsion Stability ◽  
Drilling Fluid ◽  
Temperature Tolerance ◽  
Fluid Loss ◽  
Drilling Fluids ◽  
Before And After ◽  
Rheology Modifier

Drilling issues such as shale hydration, high-temperature tolerance, torque and drag are often resolved by applying an appropriate drilling fluid formulation. Oil-based drilling fluid (OBDF) formulations are usually composed of emulsifiers, lime, brine, viscosifier, fluid loss controller and weighting agent. These additives sometimes outperform in extended exposure to high pressure high temperature (HPHT) conditions encountered in deep wells, resulting in weighting material segregation, high fluid loss, poor rheology and poor emulsion stability. In this study, two additives, oil wetter and rheology modifier were incorporated into the OBDF and their performance was investigated by conducting rheology, fluid loss, zeta potential and emulsion stability tests before and after hot rolling at 16 h and 32 h. Extending the hot rolling period beyond what is commonly used in this type of experiment is necessary to ensure the fluid’s stability. It was found that HPHT hot rolling affected the properties of drilling fluids by decreasing the rheology parameters and emulsion stability with the increase in the hot rolling time to 32 h. Also, the fluid loss additive’s performance degraded as rolling temperature and time increased. Adding oil wetter and rheology modifier additives resulted in a slight loss of rheological profile after 32 h and maintained flat rheology profile. The emulsion stability was slightly decreased and stayed close to the recommended value (400 V). The fluid loss was controlled by optimizing the concentration of fluid loss additive and oil wetter. The presence of oil wetter improved the carrying capacity of drilling fluids and prevented the barite sag problem. The zeta potential test confirmed that the oil wetter converted the surface of barite from water to oil and improved its dispersion in the oil.

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