scholarly journals Study on microcrystalline cellulose/chitosan blend foam gel material

2020 ◽  
Vol 27 (1) ◽  
pp. 424-432
Author(s):  
Hongkai Zhao ◽  
Kehan Zhang ◽  
Shoupeng Rui ◽  
Peipei Zhao
Keyword(s):  
Microcrystalline Cellulose ◽  
Raw Materials ◽  
Pore Space ◽  
Sodium Dodecyl ◽  
Cost Effective ◽  
High Water ◽  
Aldehyde Group ◽  
Sem Analysis ◽  
Present Contribution ◽  
Bet Analysis

AbstractIn the present contribution, an environmental-friendly and cost-effective adsorbent was reported for soil treatment and desertification control. A novel foam gel material was synthesized here by the physical foaming in the absence of catalyst. By adopting modified microcrystalline cellulose and chitosan as raw materials and sodium dodecyl sulfonate (SDS) as foaming agent, a microcrystalline cellulose/chitosan blend foam gel was synthesized. It is expected to replace polymers derived from petroleum for agricultural applications. In addition, a systematical study was conducted on the adsorbability, water holding capacity and re-expansion performance of foam gel in deionized water and brine under different SDS concentrations (2%–5%) as well as adsorption time. To be specific, the adsorption capacity of foam gel was up to 105g/g in distilled water and 54g/g in brine, indicating a high water absorption performance. As revealed from the results of Fourier transform infrared spectroscopy (FTIR) analysis, both the amino group of chitosan and the aldehyde group modified by cellulose were involved. According to the results of Scanning electron microscope (SEM) analysis, the foam gel was found to exhibit an interconnected pore network with uniform pore space. As suggested by Bet analysis, the macroporous structure was formed in the sample, and the pore size ranged from 0 to 170nm. The mentioned findings demonstrated that the foam gel material of this study refers to a potential environmental absorbent to improve soil and desert environments. It can act as a powerful alternative to conventional petroleum derived polymers.

scholarly journals De-Inking of ONP Paper by using Different Surfactants: in Dissolved Air Flotation Process

2020 ◽  
Vol 8 (5) ◽  
pp. 4609-4613
Keyword(s):  
Optical Properties ◽  
Raw Materials ◽  
Sodium Dodecyl ◽  
Sodium Dodecyl Benzene Sulfonate ◽  
Cost Effective ◽  
Strength Properties ◽  
Dissolved Air Flotation ◽  
Flotation Process ◽  
Physical Strength ◽  
Paper Product

Meeting the demand of paper and paper product requirement and at the same time decreasing the availability of fibrous raw materials, keeping an eye on cost effectiveness is challenging. Thus, recycling of paper is an alternative. Corrugated box, old newspapers and office waste papers are the sources of raw materials for paper and paper product industries. Deinking is an important step for recycling of old waste writing, printing and newsprint papers. The efficiency of ink separation in the process of waste paper recycling depends on the ink properties, kind of the additives, surfactants used, age of waste papers, the printing techniques and printing conditions. In general, deinking process consumes a large amount of chemicals which makes this method expensive, pollution intensive and even quality is compromised. In this study the effectiveness of surfactants like benzene dodecyl sulphonate, lauryl benzene sulphonate and sodium carbonate for cost effective deinking process by optimizing the chemical doses has been studied. The physical strength and optical properties of the paper after deinking was also explored. The surfactant better for both physical strength properties and optical properties of paper is identified to be the sodium dodecyl benzene sulfonate.

scholarly journals GAS CONCRETE FOR CONSTRUCTION OBJECTS OF TRANSPORT INFRASTRUCTURE

2018 ◽  
Vol 15 (5) ◽  
pp. 774-786
Author(s):  
E. V. Fomina ◽  
V. S. Lesovik ◽  
I. V. Lashina
Keyword(s):  
Pore Structure ◽  
Raw Materials ◽  
Construction Material ◽  
Calculated Data ◽  
Sem Analysis ◽  
Transport Infrastructure ◽  
Sound Insulation ◽  
Vapor Permeability ◽  
Main Task ◽  
Bet Analysis

Introduction.Construction objects of transport infrastructure have different influence and service conditions. An actual technical task is the design of optimal microclimate for human operation in workshops and office buildings. Therefore, such conditions can be achieved by using of construction material with high parameters of heat- and sound-insulation such as a gas concrete. The main task of the research is the improvement of heat- and sound-insulation in the gas concrete.Materials and methods.The evaluation of the gas concrete efficiency is based on the research of such parameters as heat- and sound-insulation. The analysis of the material at macro- and micro-level is performed with SEM-analysis and BET-analysis. In addition, the complex of experimental and calculated data of physical and chemical characteristics for gas concrete is carried out.Results.As a result, the usage of amorphous alum inosilicate raw materials in gas concrete allows variation of parameters to effect on pore structure such as homogeneous pore distribution in bulk, thickness and density of interpore partition, pore shape and pore size. The reduction of aerated concrete density by 22.5 % leads to reducing of heat conductivity by 19.26 %. The formation of cellular structure with mainly closed pores allows reducing of sorption humidity and vapor permeability of material under different environmental humidity.Differently-sized pores in the gas concrete and predominantly small pores with size of 0.3-0.9 mm as well as with size up to 94,6 nm leads to increasing isolation index of airborne sound due to increasing of absorption of acoustic wave in frequency range of 125-4000 Hz. Complexly, it provides high sound-insolating parameters of wall envelopes.Discussion and conclusions.Monitoring of heat- and sound-insolation of the gas concrete due to optimization of pore structure allows formation of energy effective composites able to protect humans from unfavorable environment in the transport enterprises.

scholarly journals End-of-Life Alternatives of Glass Reinforced Polyester Boat Hulls Compared by LCA

2018 ◽  
Vol 27 (4) ◽  
pp. 096369351802700 ◽  
Author(s):  
Mehmet Önal ◽  
Gökdeniz Neşer
Keyword(s):  
End Of Life ◽  
Environmental Impacts ◽  
Raw Materials ◽  
Weight Ratio ◽  
Cost Effective ◽  
Raw Material ◽  
Photochemical Oxidation ◽  
Human Toxicity ◽  
Vacuum Infusion ◽  
Infusion Method

Glass reinforced polyester (GRP), as a thermoset polymer composites, dominates boat building industry with its several advantages such as high strength/weight ratio, cohesiveness, good resistance to environment. However, proper recovering and recycling of GRP boats is became a current environmental requirement that should be met by the related industry. In this study, to propose in a cost effective and environmentally friendly way, Life Cycle Assessment (LCA) has been carried out for six scenarios include two moulding methods (namely Hand Lay-up Method, HLM and Vacuum Infusion Method, VIM) and three End-of-Life (EoL) alternatives(namely Extruding, Incineration and Landfill) for a recreational boat's GRP hulls. A case study from raw materials purchasing phase to disposal/recycling stages has been established taking 11 m length GRP boat hull as the functional unit. Analysis show that in the production phase, the impacts are mainly due to the use of energy (electricity), transport and raw material manufacture. Largest differences between the methods considered (HLM and VIM) can be observed in the factors of marine aquatic ecotoxicity and eutrophication while the closest ones are abiotic depletion, ozon layer depletion and photochemical oxidation. The environmental impact of VIM is much higher than HLM due to its higher energy consumption while vacuum infusion method has lower risk than hand lay-up method in terms of occupational health by using less raw material (resin) in a closed mold. In the comparison of the three EoL techniques, the mechanical way of recycling (granule extruding) shows better environmental impacts except terrestrial ecotoxicity, photochemical oxidation and acidification. Among the EoL alternatives, landfill has the highest environmental impacts except ‘global warming potential’ and ‘human toxicity’ which are the highest in extrusion. The main cause of the impacts of landfill is the transportation needs between the EoL boats and the licenced landfill site. Although it has the higher impact on human toxicity, incineration is the second cleaner alternative of EoL techniques considered in this study. In fact that the similar trend has been observed both in production and EoL phases of the boat. It is obvious that using much more renewable energy mix and greener transportation alternative can reduce the overall impact of the all phases considerably.

PU composites based on different types of textile fibers

2021 ◽  
pp. 002199832110316
Author(s):  
Nuno Gama ◽  
B Godinho ◽  
Ana Barros-Timmons ◽  
Artur Ferreira
Keyword(s):  
Thermal Conductivity ◽  
Raw Materials ◽  
Natural Fibers ◽  
Tensile Modulus ◽  
High Water ◽  
Textile Fibers ◽  
Synthetic Fibers ◽  
Hydrophilic Nature ◽  
Different Types ◽  
Recycled Composites

In this study polyurethane (PU) residues were mixed with residues of textile fibers (cotton, wool and synthetic fibers up to 70 wt/wt) to produce 100% recycled composites. In addition, the effect of the type of fiber on the performance of the ensuing composites was evaluated. The presence of fibers showed similar effect on the density, reducing the density in the 5.5-9.0% range. In a similar manner, the addition of fillers decreased their thermal conductivity. The 70 wt/wt wool composite presented 38.1% lower thermal conductivity when compared to the neat matrix, a reduction that was similar for the other type of fibers. Moreover, the presence of fillers yields stiffer materials, especially in the case of the Wool based composites, which with 70 wt/wt of filler content increased the tensile modulus of the ensuing material 3.4 times. This was attributed to the aspect ratio and stiffness of this type of fiber. Finally, the high-water absorption and lower thermal stability observed, especially in the case of the natural fibers, was associated with the hydrophilic nature of fibers and porosity of composites. Overall, the results suggest that these textile-based composites are suitable for construction and automotive applications, with the advantage of being produced from 100% recycled raw-materials, without compromised performance.

scholarly journals Mineralogical and Microstructure Analysis for Characterization and Provenance of Ceramic Artifacts from Late Helladic Kastrouli Settlement, Delphi (Central Greece)

Geosciences ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 36
Author(s):  
Vayia Xanthopoulou ◽  
Ioannis Iliopoulos ◽  
Ioannis Liritzis
Keyword(s):  
Raw Materials ◽  
Analytical Techniques ◽  
Sem Analysis ◽  
Petrographic Analysis ◽  
Ceramic Assemblage ◽  
Thin Sections ◽  
Central Greece ◽  
High Calcium ◽  
Local Geology

The present study deals with the characterization of a ceramic assemblage from the Late Mycenaean (Late Helladic III) settlement of Kastrouli, at Desfina near Delphi, Central Greece using various analytical techniques. Kastrouli is located in a strategic position supervising the Mesokampos plateau and the entire peninsula and is related to other nearby coeval settlements. In total 40 ceramic sherds and 8 clay raw materials were analyzed through mineralogical, petrographic and microstructural techniques. Experimental briquettes (DS) made from clayey raw materials collected in the vicinity of Kastrouli, were fired under temperatures (900 and 1050 °C) in oxidizing conditions for comparison with the ancient ceramics. The petrographic analysis performed on thin sections prepared from the sherds has permitted the identification of six main fabric groups and a couple of loners. The aplastic inclusions recognized in all fabric groups but one confirmed the local provenance since they are related to the local geology. Fresh fractures of representative sherds were further examined under a scanning electron microscope (SEM/EDS) helping us to classify them into calcareous (CaO > 6%) and non-calcareous (CaO < 6%) samples (low and high calcium was noted in earlier pXRF data). Here, the ceramic sherds with broad calcium separation are explored on a one-to-one comparison on the basis of detailed mineralogical microstructure. Moreover, their microstructure was studied, aiming to estimate their vitrification stage. The mineralogy of all studied samples was determined by means of X-ray powder diffraction (XRPD), permitting us to test the validity of the firing temperatures revealed by the SEM analysis. The results obtained through the various analytical techniques employed are jointly assessed in order to reveal potters’ technological choices.

scholarly journals Alkali-Activated Zeolite 4A Granules—Characterization and Suitability Assessment for the Application of Adsorption

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 360
Author(s):  
Pauls P. Argalis ◽  
Laura Vitola ◽  
Diana Bajare ◽  
Kristine Vegere
Keyword(s):  
Compressive Strength ◽  
Raw Materials ◽  
Physical And Mechanical Properties ◽  
Morphological Properties ◽  
Solid Ratio ◽  
Suitability Assessment ◽  
Bet Analysis ◽  
Zeolite 4A ◽  
Compressive Strength Test ◽  
Alkali Activated

A major problem in the field of adsorbents is that binders (kaolin clay, bentonite) introduced to bind zeolites and ensure the needed mechanical strength, are not able to sorb gases like CO2 and N2, and decrease the overall adsorption capacity. To solve this problem, one of the pathways is to introduce a binder able to sorb such gases. Thus, in this study, the physical and mechanical properties of a novel binder based on metakaolin and its composite with zeolite 4A in the granular form were studied. Metakaolin was used as a precursor for alkali-activated binder, which was synthesized using an 8M NaOH activation solution. Raw materials were characterized using granulometry, X-ray diffraction (XRD), and differential thermal analysis (DTA); and final products were characterized using density measurements, a compressive strength test, XRD, Brunauer–Emmett–Teller (BET) analysis, and scanning electron microscopy (SEM). Alkali-activated metakaolin was found to be efficient as a binding material when data for morphological properties were analyzed. A relationship was observed—by increasing the liquid-to-solid ratio (L/S), compressive strength decreased. Zeolite granule attrition was higher than expected: 2.42% and 4.55% for ZG-0.8, 3.64% and 5.76% for ZG-1.0, and 2.73% and 4.85% for ZG-1.2, measured at 4 and 5 atmospheres, respectively.

scholarly journals The mineralogic and isotopic fingerprint of equatorial carbonates: Kepulauan Seribu, Indonesia

2021 ◽  
Author(s):  
Dwi Amanda Utami ◽  
Lars Reuning ◽  
Maximillian Hallenberger ◽  
Sri Yudawati Cahyarini
Keyword(s):  
River Runoff ◽  
Patch Reef ◽  
High Water ◽  
Sem Analysis ◽  
Shallow Waters ◽  
Carbonate System ◽  
Riverine Water ◽  
High Turbidity ◽  
Java Sea ◽  
River Catchments

AbstractKepulauan Seribu is an isolated patch reef complex situated in the Java Sea (Indonesia) and is a typical example for a humid, equatorial carbonate system. We investigate the mineralogical and isotopic fingerprint of Panggang, one of the reef platforms of Kepulauan Seribu, to evaluate differences to other carbonate systems, using isotope in combination with XRD and SEM analysis. A characteristic property of shallow water (< 20 m) sediments from Kepulauan Seribu is their increased LMC content (~ 10%) derived from some genera of rotaliid foraminifers and bivalves. The relative abundance of these faunal elements in shallow waters might be related to at least temporary turbid conditions caused by sediment-laden river runoff. This influence is also evidenced by the presence of low amounts of siliciclastic minerals below the regional wave base. Kepulauan Seribu carbonates are characterized by very low δ13C and δ18O values. This is related to the isotopically depleted riverine input. The δ13CDIC in riverine water is reduced by the contribution of 12C from riverside mangroves. Deep atmospheric convection and intensive rains contribute 18O-depleted freshwater in the river catchments, finally reducing salinity in the Java Sea. The depleted δ13C signature in carbonates is further enhanced by the lack of green algae and inorganic carbonates and abundance of coral debris. Low δ18O values in carbonates are favored by the high water temperatures in the equatorial setting. Since equatorial carbonates in SE Asia, including the Java Sea, are typically influenced by high turbidity and/or river runoff, the observed distinctively low isotope values likely are characteristic for equatorial carbonate systems in the region.

Graphene Oxide as a Substrate for Biosensors: Synthesis and Characterization

2021 ◽  
Vol 324 ◽  
pp. 87-93
Author(s):  
Mohamed Adel ◽  
Abdel Hady A. Abdel-Wahab ◽  
Ahmed Abdel-Mawgood ◽  
Ahmed Osman Egiza
Keyword(s):  
Raman Spectroscopy ◽  
Graphene Oxide ◽  
Acidic Solution ◽  
Cost Effective ◽  
Sem Analysis ◽  
Visible Spectroscopy ◽  
Sem Images ◽  
Hummers Method ◽  
Uv Visible ◽  
Modified Hummers Method

Graphene oxide (GO) is an oxidized nanosheets of graphite with a 2D planar structure. GO could be readily complexed with bio-entities as it possesses many oxygen-containing functionalities on its surface. The preparation process is fast, easy, and cost-effective. It was prepared using modified Hummers’ method in acidic solution as a primary solvent and potassium permanganate as an oxidizing agent. Afterwards, it was successfully characterized by FTIR, UV-visible spectroscopy, as well as XRD and Raman spectroscopy, and finally, SEM analysis. It was observed that the formed GO is mainly composed of carbon and oxygen elements rich in oxygen functional groups. Furthermore, the existence of (001) plane in XRD interprets the complete oxidation of graphite with d-spacing 9 Å. Moreover, Raman spectroscopy displayed the sp3 carbon hybridization, besides, the ID/IG ratio is found to be 0.84, which confirms the disorder between graphene oxide layers. The SEM images also pointed out that graphene oxide sheets were regularly stacked together as flake-like structures. Accordingly, the richness of oxygen-containing functionalities was confirmed. Hence, it is appropriate to be used as a base transducer for biosensing applications.

Highly efficient photo-degradation of cetirizine antihistamine with TiO2-SiO2 photocatalyst under ultraviolet irradiation

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sonam Rani ◽  
Alok Garg ◽  
Neetu Singh
Keyword(s):  
Particle Size ◽  
Photocatalytic Activity ◽  
Terephthalic Acid ◽  
Cost Effective ◽  
Oh Radicals ◽  
Large Specific Surface Area ◽  
Photo Degradation ◽  
Macroscopic Structure ◽  
Bet Analysis ◽  
Positive Effect

Abstract Photocatalysis is an extraordinary and vastly researched topic; there is a need to find new ways to support producing composite materials that are cost-effective, efficient and have a low environmental impact. The investigation was undertaken on syn TiO2 by depositing it on silica. The results elucidate the positive effect on photocatalysis activity and the macroscopic structure on which the TiO2 is formed. For the analysis of photocatalyst, various characterisation measurements were undertaken, such as XRD, FTIR, DRS, FESEM, TEM, RS, and BET. The accumulated TiO2 onto the surface of SiO2 stabilised its transformation of the phase from anatase to rutile, resulting in decreased particle size and enhancing its photocatalytic activity under UV irradiation. The concentration of OH• radicals was determined using terephthalic acid as a probe molecule to determine its role in the photocatalytic degradation of antihistamine. The results of BET analysis showed that the syn TiO2-SiO2 sample has a large specific surface area of 192.6 m2 g−1. Maximum degradation of cetirizine (about 97%) was achieved with 80% TiO2-20% SiO2 (TS-4). Recyclability test confirmed that 80% TiO2-20% SiO2 sample was stable up to six cycles.

Mature Field Economic Rejuvenation with Infill and Re-Entry Multilateral Well Creation Techniques

2021 ◽  
Author(s):  
Benjamin Butler ◽  
Justin Roberts ◽  
Matthew Kelsey ◽  
Steffen Van Der Veen
Keyword(s):  
Case Studies ◽  
Field Performance ◽  
Cost Effective ◽  
High Water ◽  
Additional Time ◽  
Flow Management ◽  
Performance Improvements ◽  
Mature Field ◽  
Water Cut ◽  
Time Required

Abstract Multilateral wells have been proven over decades and have developed into a reliable and cost effective approach to mature field rejuvenation and extended commercial viability. This paper will discuss case studies demonstrating a number of techniques used to create infill multilateral wells in existing fields with a high level of reliability and repeatability. Techniques reviewed will cover cutting and pulling production casing to drill and case a new mainbore versus sidetracking and adding laterals to an existing mainbore. Discussion will also cover completion designs that tie new laterals into existing production casing providing significantly greater reservoir contact. Temporary isolation of high water-cut laterals brought into production later in the well's life through bespoke completion designs will also be discussed. Case studies will include discussion of workover operations, isolation methods, and lateral creation systems. Where available, resulting field performance improvements will also be discussed. In Norway, slot recoveries are commonly performed by cutting and pulling the 10-3/4" casing, redrilling a new mainbore, and running new casing. This enables junction placement closer to unswept zones and easier lateral drilling to targets. It does have drawbacks, however, related to the additional time required to pull the subsea xmas tree and challenges associated with pulling casing. In 2019, Norway successfully completed a 10-3/4" retrofit installation, whereas a sidetrack was made from the 10-3/4" and an 8-5/8" expandable liner was run down into the reservoir pay zone where two new laterals were created. The 8-5/8" liner saved time otherwise spent having to drill the section down to the payzone from the laterals. These wells have a TAML Level 5 isolated junction, Autonomous Inflow Control Devices (AICDs) in each lateral, and an intelligent completion interface across the junction, enabling active flow management and monitoring of both branches. In Asia, infill laterals were added to existing wellbores by sidetracking 9-5/8" casing and tying production back to the original mainbore. These dual laterals were completed with intelligent completions to enable lateral flow management and monitoring of both laterals. In Australia, dual laterals were created in a similar fashion; laterals are added to existing wells; however, a novel approach was used to manage water from existing lower mainbore laterals whereby they are shut in at completion and opened later when the new lateral is watered out. The older lateral now produces at lower water cut given the time allowed for water coning in the lateral to relax. Using this practice, production is alternated back and forth between the two laterals. In the Middle East, an older well has been converted from TAML Level 4 to Level 5 in order to prevent detected gas migrating into the mainbore at the junction. This conversion of a cemented junction well has enabled production to resume on this well. The well was converted to incorporate an intelligent completion to enable flow control of each lateral. This paper intends to provide insights into the various mature field re-entry methods for multilateral well construction, and a review of the current technology capabilities and well designs through the review of multiple case histories.

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