Experimental and Theoretical Study on the Structure of Nitramide H2NNO2
2002 ◽
Vol 57
(2)
◽
pp. 151-156
◽
Keyword(s):
X Ray
◽
Nitramide was investigated by multinuclear NMR spectroscopy, X-ray-diffraction and computational methods. The crystal structure analysis at various temperatures reveals a planar conformation of the molecule with a N-N bond length corresponding to a bond order between one and two. Hydrogen bonds connect the nitramide molecules side-on and end-on. This leads to the formation of layers in the crystal. Calculations were performed to explain the shorter N-N bond length in the crystal compared to the gas phase. The nitramide trimer is used as a model.
Keyword(s):
1998 ◽
Vol 54
(6)
◽
pp. 907-911
◽
2019 ◽
Vol 75
(5)
◽
pp. 504-507
◽
2003 ◽
Vol 42
(Part 1, No. 8)
◽
pp. 4943-4948
◽
2014 ◽
Vol 1004-1005
◽
pp. 542-545