scholarly journals Nagra/PSI Chemical Thermodynamic Data Base 01/01

2002 ◽  
Vol 90 (9-11) ◽  
Author(s):  
W. Hummel ◽  
U. Berner ◽  
E. Curti ◽  
F. J. Pearson ◽  
T. Thoenen

SummaryThe Nagra/PSI Chemical Thermodynamic Data Base has been updated to support performance assessments of the planned Swiss repositories for radioactive waste. The update from version 05/92 to 01/01 involved major revisions for most of the actinides and fission products. Altogether, more than 70% of the database contents have been revised. Data for U, Np, Pu, Am and Tc recommended by the NEA TDB project were considered in the update. Thermodynamic data for Th, Sn, Eu, Pd, Al, and solubility and metal complexation of sulphides and silicates were extensively reviewed. Data for Zr, Ni and Se were examined less rigorously as these elements are currently being reviewed in phase II of the NEA TDB project. Our experiences from this two year team effort can be summarised as follows. Detailed in-house reviews and critical appraisal of NEA recommendations greatly improved the chemical consistency and quality of the selected data. On the other hand, we could discern major gaps in the data, especially missing carbonate complexes. In some systems,

1990 ◽  
Vol 212 ◽  
Author(s):  
Hans Wanner

ABSTRACTThe geochemical modelling in support of the performance assessment of radioactive waste disposal systems calls for a large number of chemical thermodynamic data. For realistic modelling it is essential that the data used are fully consistent. The verification of consistency of existing data bases is complicated by the fact that it requires the knowledge of a considerable amount of primary information to ensure:1.Consistency with the fundamental laws of thermodynamics2.Consistency within a chemical model3.Consistency with auxiliary data4.Consistency in the data correction proceduresThis paper includes selected examples for each of the four items to visualize the problems. It should be noted that there are numerous other systems that could serve as examples as well, and the range of cases reported here is far from being exhaustive.Realistic geochemical modelling depends not only on the quality of the data base, but also on the quality of the chemical model used. For the establishment of a chemical model, additional information is needed that is not contained in thermodynamic data bases.


2004 ◽  
Vol 236 (1) ◽  
pp. 561-577 ◽  
Author(s):  
Tres Thoenen ◽  
Urs Berner ◽  
Enzo Curti ◽  
Wolfgang Hummel ◽  
F. J. Pearson

2021 ◽  
Vol 11 (16) ◽  
pp. 7269
Author(s):  
Jun-Yeop Lee ◽  
Sang June Park ◽  
Seokyoung Ahn

A RESRAD-OFFISTE computational code for the safety assessment model of a radioactive waste repository was utilized to evaluate the influence of the updated OECD/NEA thermodynamic database on the safety assessment model in terms of exposure dose. The solubility data as the input parameter for the RESRAD-OFFSITE code obtained with two different sets of chemical thermodynamic databases such as JAEA-TDB and amended JAEA-TDB reflecting the updates of the OECD/NEA thermodynamic database were calculated and compared with each other. As a result, almost identical exposure doses were obtained due to the remarkable similarity between the solubility data of various radionuclides for both chemical thermodynamic databases. In contrast, dramatic changes in exposure dose were observed with varying distribution coefficients. Thermodynamic calculations indicated that the aqueous species distribution can be significantly changed by the selection of a chemical thermodynamic database and thus the relevant distribution coefficient can also be influenced as a consequence. Accordingly, the result obtained in the present work indicated that (i) the impact of the updated chemical thermodynamic data was somewhat minor from the viewpoint of the solubility and (ii) the distribution coefficient, which can be sensitively influenced by the predominant chemical species, produced a remarkable change in the exposure dose. This work provided an insight into the precise exposure dose calculation in terms of the reliable estimation of the distribution coefficient by means of a surface complexation model, which can predict the distribution coefficient as a function of groundwater composition coupled with a chemical speciation calculation based on up to date chemical thermodynamic data.


1985 ◽  
Vol 50 ◽  
Author(s):  
A. B. Muller ◽  
B. Fritz ◽  
A. Wyman ◽  
M. Snellman

AbstractThe OECD Nuclear Energy Agency is coordinating the development of a critically reviewed CODATA compatible chemical thermodynamic data base for ten radioelements important to various areas of nuclear technologies. Such a data base in itself is insufficient for modeling the speciation and solubility behaviour of radioelements in natural rock/water systems. Data must also be available for describing the rock phases present, which determine to a large extent the physico-chemical environment. Since a number of NEA Member countries are contemplating nuclear waste disposal in granitic environments, a data base for seventy-three minerals associated with granite is presented here, as a complement to the data base work on radioelements.


1999 ◽  
Vol 556 ◽  
Author(s):  
A. T. Emrén ◽  
Randy Arthur ◽  
Pierre D. Glynn ◽  
Jude McMurry

AbstractFour researchers were asked to provide independent modeled estimates of the solubility of a radionuclide solid phase, specifically Pu(OH)4, under five specified sets of conditions. The objectives of the study were to assess the variability in the results obtained and to determine the primary causes for this variability.In the exercise, modelers were supplied with the composition, pH and redox properties of the water and with a description of the mineralogy of the surrounding fracture system A standard thermodynamic data base was provided to all modelers. Each modeler was encouraged to use other data bases in addition to the standard data base and to try different approaches to solving the problem.In all, about fifty approaches were used, some of which included a large number of solubility calculations. For each of the five test cases, the calculated solubilities from different approaches covered several orders of magnitude. The variability resulting firom the use of different thermodynamic data bases was in most cases, far smaller than that resulting from the use of different approaches to solving the problem.


Author(s):  
K. T. Tokuyasu

During the past investigations of immunoferritin localization of intracellular antigens in ultrathin frozen sections, we found that the degree of negative staining required to delineate u1trastructural details was often too dense for the recognition of ferritin particles. The quality of positive staining of ultrathin frozen sections, on the other hand, has generally been far inferior to that attainable in conventional plastic embedded sections, particularly in the definition of membranes. As we discussed before, a main cause of this difficulty seemed to be the vulnerability of frozen sections to the damaging effects of air-water surface tension at the time of drying of the sections.Indeed, we found that the quality of positive staining is greatly improved when positively stained frozen sections are protected against the effects of surface tension by embedding them in thin layers of mechanically stable materials at the time of drying (unpublished).


CCIT Journal ◽  
2014 ◽  
Vol 7 (3) ◽  
pp. 335-354
Author(s):  
Untung Rahardja ◽  
Muhamad Yusup ◽  
Ana Nurmaliana

The accuracy and reliability is the quality of the information. The more accurate and reliable, the more information it’s good quality. Similarly, a survey, the better the survey, the more accurate the information provided. Implementation of student satisfaction measurement to the process of teaching and learning activities on the quality of the implementation of important lectures in order to get feedback on the assessed variables and for future repair. Likewise in Higher Education Prog has undertaken the process of measuring student satisfaction through a distributed questioner finally disemester each class lecture. However, the deployment process questioner is identified there are 7 (seven) problems. However, the problem can be resolved by the 3 (three) ways of solving problems one of which is a system of iLearning Survey (Isur), that is by providing an online survey to students that can be accessed anywhere and anytime. In the implementation shown a prototype of Isur itself. It can be concluded that the contribution Isur system can maximize the decision taken by the Higher Education Prog. By using this Isur system with questions and evaluation forms are submitted and given to the students and the other colleges. To assess the extent to which the campus has grown and how faculty performance in teaching students class, and can be used as a media Isur valid information for an assessment of activities throughout college.


2017 ◽  
Vol 4 (1) ◽  
pp. 189-215
Author(s):  
Yoiz Shofwa Shafrani

Perkembangan dunia perbankan syariah tidak lepas dari peran para nasabah yang memberikan kepercayaan terhadap pihak perbankan untuk penyimpanan asset keuangannya. Faktanya banyak kelompok nasabah yang memutuskan untuk menjadi nasabah di perbankan syariah karena faktor religiusitasnya. Faktor lain yang dapat ikut mempengaruhi keputusan nasabah adalah kualitas produk. Di mana kualitas produk merupakan karakteristik yang melekat dari suatu produk. Kemungkinan yang terjadi bahwa kebanyakan nasabah pada perbankan syariah juga masih merupakan nasabah perbankan konvensional.Tujuan yang ingin dicapai dalam penelitian ini adalah untuk mengetahui pengaruh kualitas produk dan tingkat religiusitas nasabah terhadap keputusan nasabah untuk menyimpan dananya atau tidak di BSM Cabang Purwokerto. Alat analisis yang digunakan adalah analisis regresi linier berganda, dengan jumlah sampel 100 nasabah. Diperoleh hasil Y = 5,046 + 0,101X1 + 0,218X2. Berdasarkan uji F yang sudah dilakukan maka dapat diketahui bahwa variabel kualitas produk dan religiusitas secara bersama – sama berpengaruh terhadap keputusan nasabah untuk menyimpan dananya di BSM Cabang Purwokerto. Berdasarkan uji t yang sudah dilakukan dapat diketahui bahwa secara partial baik variabel kualitas produk maupun variabel religiusitas berpengaruh terhadap keputusan nasabah untuk menyimpan dananya di BSM Cabang Purwokerto. The progress of the Islamic bank cannot be separated from the role of its customers who give trust to the bank to deposit their financial assets. It is a fact many groups of customers decide to be the customers of the Islamic bank because of their religiosity. The other influences factor of a customer’s decision is the quality of the product. The aim of this research was to determine the effect of product quality and level of customers’ religiosity towards customers’ decision whether to keep their funds in Syariah Mandiri Bank, Branch of Purwokerto, or not. The analytical tool used was multiple linear regression analysis, with a sample of 100 customers. The results indicate Y = 5,046 + 0,101X1 + 0,218X2. Based on F, it can be seen that both variables of product quality and religiosity simultanously affect the customers’ decision to keep theirfunds in BSM Branch of Purwokerto. Based on t test, it can be seen that independently, either variable of product quality or variables of religiosityinfluences the customers’ decision to keep their funds in BSM Branch of Purwokerto.


2020 ◽  
Vol 7 (1) ◽  
pp. 99
Author(s):  
Yong Adilah Shamsul Harumain ◽  
Nur Farhana Azmi ◽  
Suhaini Yusoff

Transit stations are generally well known as nodes of spaces where percentage of people walking are relatively high. The issue is do more planning is actually given to create walkability. Creating walking led transit stations involves planning of walking distance, providing facilities like pathways, toilets, seating and lighting. On the other hand, creating walking led transit station for women uncover a new epitome. Walking becomes one of the most important forms of mobility for women in developing countries nowadays. Encouraging women to use public transportation is not just about another effort to promote the use of public transportation but also another great endeavour to reduce numbers of traffic on the road. This also means, creating an effort to control accidents rate, reducing carbon emission, improving health and eventually, developing the quality of life. Hence, in this paper, we sought first to find out the factors that motivate women to walk at transit stations in Malaysia. A questionnaire survey with 562 female user of Light Railway Transit (LRT) was conducted at LRT stations along Kelana Jaya Line. Both built and non-built environment characteristics, particularly distance, safety and facilities were found as factors that are consistently associated with women walkability. With these findings, the paper highlights the criteria  which are needed to create and make betterment of transit stations not just for women but also for walkability in general.


Sign in / Sign up

Export Citation Format

Share Document