Influence of thermodynamic database on the modelisation of americium(III) speciation in a simulated biological medium

2005 ◽  
Vol 93 (11) ◽  
Author(s):  
Lionel Bion ◽  
Eric Ansoborlo ◽  
Valérie Moulin ◽  
Pascal Reiller ◽  
Richard Collins ◽  
...  

SummaryAn intercomparison exercise was led in order to study the impact of thermodynamic database (TDB) on the speciation of americium(III) in biochemical media.A first exercice was led, considering only the americium(III) species in solution. Even with different data sets, all the exercises are in relatively good agreement, concluding to successive complexation of the radioelement by phosphate (pH range from 0 to 3), citrate (pH range from 3 to 8) and hydroxo-carbonate (pH range from 8 to 14). Nevertheless, the speciation of americium differs for each pH range from one work to an other.These results are still observed when the speciation calculation includes the formation of solids. Nevertheless, some workers did not integrate in their data set the formation constant of Am(POThis work is a representative example of the impact of the thermodynamic data used in speciation exercises. Some exercices, using uncompleted TDB had wrong results and led to the conclusion of the necessity in the use of expertised and extended TDB.

2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Yahya Albalawi ◽  
Jim Buckley ◽  
Nikola S. Nikolov

AbstractThis paper presents a comprehensive evaluation of data pre-processing and word embedding techniques in the context of Arabic document classification in the domain of health-related communication on social media. We evaluate 26 text pre-processings applied to Arabic tweets within the process of training a classifier to identify health-related tweets. For this task we use the (traditional) machine learning classifiers KNN, SVM, Multinomial NB and Logistic Regression. Furthermore, we report experimental results with the deep learning architectures BLSTM and CNN for the same text classification problem. Since word embeddings are more typically used as the input layer in deep networks, in the deep learning experiments we evaluate several state-of-the-art pre-trained word embeddings with the same text pre-processing applied. To achieve these goals, we use two data sets: one for both training and testing, and another for testing the generality of our models only. Our results point to the conclusion that only four out of the 26 pre-processings improve the classification accuracy significantly. For the first data set of Arabic tweets, we found that Mazajak CBOW pre-trained word embeddings as the input to a BLSTM deep network led to the most accurate classifier with F1 score of 89.7%. For the second data set, Mazajak Skip-Gram pre-trained word embeddings as the input to BLSTM led to the most accurate model with F1 score of 75.2% and accuracy of 90.7% compared to F1 score of 90.8% achieved by Mazajak CBOW for the same architecture but with lower accuracy of 70.89%. Our results also show that the performance of the best of the traditional classifier we trained is comparable to the deep learning methods on the first dataset, but significantly worse on the second dataset.


2015 ◽  
Vol 8 (1) ◽  
pp. 421-434 ◽  
Author(s):  
M. P. Jensen ◽  
T. Toto ◽  
D. Troyan ◽  
P. E. Ciesielski ◽  
D. Holdridge ◽  
...  

Abstract. The Midlatitude Continental Convective Clouds Experiment (MC3E) took place during the spring of 2011 centered in north-central Oklahoma, USA. The main goal of this field campaign was to capture the dynamical and microphysical characteristics of precipitating convective systems in the US Central Plains. A major component of the campaign was a six-site radiosonde array designed to capture the large-scale variability of the atmospheric state with the intent of deriving model forcing data sets. Over the course of the 46-day MC3E campaign, a total of 1362 radiosondes were launched from the enhanced sonde network. This manuscript provides details on the instrumentation used as part of the sounding array, the data processing activities including quality checks and humidity bias corrections and an analysis of the impacts of bias correction and algorithm assumptions on the determination of convective levels and indices. It is found that corrections for known radiosonde humidity biases and assumptions regarding the characteristics of the surface convective parcel result in significant differences in the derived values of convective levels and indices in many soundings. In addition, the impact of including the humidity corrections and quality controls on the thermodynamic profiles that are used in the derivation of a large-scale model forcing data set are investigated. The results show a significant impact on the derived large-scale vertical velocity field illustrating the importance of addressing these humidity biases.


2021 ◽  
Author(s):  
David Cotton ◽  

<p><strong>Introduction</strong></p><p>HYDROCOASTAL is a two year project funded by ESA, with the objective to maximise exploitation of SAR and SARin altimeter measurements in the coastal zone and inland waters, by evaluating and implementing new approaches to process SAR and SARin data from CryoSat-2, and SAR altimeter data from Sentinel-3A and Sentinel-3B. Optical data from Sentinel-2 MSI and Sentinel-3 OLCI instruments will also be used in generating River Discharge products.</p><p>New SAR and SARin processing algorithms for the coastal zone and inland waters will be developed and implemented and evaluated through an initial Test Data Set for selected regions. From the results of this evaluation a processing scheme will be implemented to generate global coastal zone and river discharge data sets.</p><p>A series of case studies will assess these products in terms of their scientific impacts.</p><p>All the produced data sets will be available on request to external researchers, and full descriptions of the processing algorithms will be provided</p><p> </p><p><strong>Objectives</strong></p><p>The scientific objectives of HYDROCOASTAL are to enhance our understanding  of interactions between the inland water and coastal zone, between the coastal zone and the open ocean, and the small scale processes that govern these interactions. Also the project aims to improve our capability to characterize the variation at different time scales of inland water storage, exchanges with the ocean and the impact on regional sea-level changes</p><p>The technical objectives are to develop and evaluate  new SAR  and SARin altimetry processing techniques in support of the scientific objectives, including stack processing, and filtering, and retracking. Also an improved Wet Troposphere Correction will be developed and evaluated.</p><p><strong>Project  Outline</strong></p><p>There are four tasks to the project</p><ul><li>Scientific Review and Requirements Consolidation: Review the current state of the art in SAR and SARin altimeter data processing as applied to the coastal zone and to inland waters</li> <li>Implementation and Validation: New processing algorithms with be implemented to generate a Test Data sets, which will be validated against models, in-situ data, and other satellite data sets. Selected algorithms will then be used to generate global coastal zone and river discharge data sets</li> <li>Impacts Assessment: The impact of these global products will be assess in a series of Case Studies</li> <li>Outreach and Roadmap: Outreach material will be prepared and distributed to engage with the wider scientific community and provide recommendations for development of future missions and future research.</li> </ul><p> </p><p><strong>Presentation</strong></p><p>The presentation will provide an overview to the project, present the different SAR altimeter processing algorithms that are being evaluated in the first phase of the project, and early results from the evaluation of the initial test data set.</p><p> </p>


2009 ◽  
Vol 2 (1) ◽  
pp. 87-98 ◽  
Author(s):  
C. Lerot ◽  
M. Van Roozendael ◽  
J. van Geffen ◽  
J. van Gent ◽  
C. Fayt ◽  
...  

Abstract. Total O3 columns have been retrieved from six years of SCIAMACHY nadir UV radiance measurements using SDOAS, an adaptation of the GDOAS algorithm previously developed at BIRA-IASB for the GOME instrument. GDOAS and SDOAS have been implemented by the German Aerospace Center (DLR) in the version 4 of the GOME Data Processor (GDP) and in version 3 of the SCIAMACHY Ground Processor (SGP), respectively. The processors are being run at the DLR processing centre on behalf of the European Space Agency (ESA). We first focus on the description of the SDOAS algorithm with particular attention to the impact of uncertainties on the reference O3 absorption cross-sections. Second, the resulting SCIAMACHY total ozone data set is globally evaluated through large-scale comparisons with results from GOME and OMI as well as with ground-based correlative measurements. The various total ozone data sets are found to agree within 2% on average. However, a negative trend of 0.2–0.4%/year has been identified in the SCIAMACHY O3 columns; this probably originates from instrumental degradation effects that have not yet been fully characterized.


2014 ◽  
Vol 7 (4) ◽  
pp. 5087-5139 ◽  
Author(s):  
R. Pommrich ◽  
R. Müller ◽  
J.-U. Grooß ◽  
P. Konopka ◽  
F. Ploeger ◽  
...  

Abstract. Variations in the mixing ratio of trace gases of tropospheric origin entering the stratosphere in the tropics are of interest for assessing both troposphere to stratosphere transport fluxes in the tropics and the impact of these transport fluxes on the composition of the tropical lower stratosphere. Anomaly patterns of carbon monoxide (CO) and long-lived tracers in the lower tropical stratosphere allow conclusions about the rate and the variability of tropical upwelling to be drawn. Here, we present a simplified chemistry scheme for the Chemical Lagrangian Model of the Stratosphere (CLaMS) for the simulation, at comparatively low numerical cost, of CO, ozone, and long-lived trace substances (CH4, N2O, CCl3F (CFC-11), CCl2F2 (CFC-12), and CO2) in the lower tropical stratosphere. For the long-lived trace substances, the boundary conditions at the surface are prescribed based on ground-based measurements in the lowest model level. The boundary condition for CO in the free troposphere is deduced from MOPITT measurements (at ≈ 700–200 hPa). Due to the lack of a specific representation of mixing and convective uplift in the troposphere in this model version, enhanced CO values, in particular those resulting from convective outflow are underestimated. However, in the tropical tropopause layer and the lower tropical stratosphere, there is relatively good agreement of simulated CO with in-situ measurements (with the exception of the TROCCINOX campaign, where CO in the simulation is biased low ≈ 10–20 ppbv). Further, the model results are of sufficient quality to describe large scale anomaly patterns of CO in the lower stratosphere. In particular, the zonally averaged tropical CO anomaly patterns (the so called "tape recorder" patterns) simulated by this model version of CLaMS are in good agreement with observations. The simulations show a too rapid upwelling compared to observations as a consequence of the overestimated vertical velocities in the ERA-interim reanalysis data set. Moreover, the simulated tropical anomaly patterns of N2O are in good agreement with observations. In the simulations, anomaly patterns for CH4 and CFC-11 were found to be consistent with those of N2O; for all long-lived tracers, positive anomalies are simulated because of the enhanced tropical upwelling in the easterly phase of the quasi-biennial oscillation.


2021 ◽  
Author(s):  
Ahmed Attia ◽  
Matthew Lawrence

Abstract Distributed Fiber Optics (DFO) technology has been the new face for unconventional well diagnostics. This technology focuses on measuring Distributed Acoustic Sensing (DAS) and Distrusted Temperature Sensing (DTS) to give an in-depth understanding of well productivity pre and post stimulation. Many different completion design strategies, both on surface and downhole, are used to obtain the best fracture network outcome; however, with complex geological features, different fracture designs, and fracture driven interactions (FDIs) effecting nearby wells, it is difficult to grasp a full understanding on completion design performance for each well. Validating completion designs and improving on the learnings found in each data set should be the foundation in developing each field. Capturing a data set with strong evidence of what works and what doesn't, can help the operator make better engineering decisions to make more efficient wells as well as help gauge the spacing between each well. The focus of this paper will be on a few case studies in the Bakken which vividly show how infill wells greatly interfered with production output. A DFO deployed with a 0.6" OD, 23,000-foot-long carbon fiber rod to acquire DAS and DTS for post frac flow, completion, and interference evaluation. This paper will dive into the DFO measurements taken post frac to further explain what effects are seen on completion designs caused by interferences with infill wells; the learnings taken from the DFO post frac were applied to further escalate the understanding and awareness of how infill wells will preform on future pad sites. A showcase of three separate data sets from the Bakken will identify how effective DFO technology can be in evaluating and making informed decisions on future frac completions. In this paper we will also show and discuss how DFO can measure real time FDI events and what measures can be taken to lessen the impact on negative interference caused by infill wells.


2021 ◽  
Author(s):  
Gunta Kalvāne ◽  
Andis Kalvāns ◽  
Agrita Briede ◽  
Ilmārs Krampis ◽  
Dārta Kaupe ◽  
...  

<p>According to the Köppen climate classification, almost the entire area of Latvia belongs to the same climate type, Dfb, which is characterized by humid continental climates with warm (sometimes hot) summers and cold winters.  In the last decades whether conditions on the western coast of Latvia more characterized by temperate maritime climates. In this area there has been a transition (and still ongoing) to the climate type Cfb.</p><p>Temporal and spatial changes of temperature and precipitation regime have been examined in whole territory to identify the breaking point of climate type shifts. We used two type of climatological data sets: gridded daily temperature from the E-OBS data set version 21.0e (Cornes et al., 2018) and direct observations from meteorological stations (data source: Latvian Environment, Geology and Meteorology Centre). The temperature and precipitation regime have changed significantly in the last century - seasonal and regional differences can be observed in the territory of Latvia.</p><p>We have digitized and analysed more than 47 thousand phenological records, fixed by volunteers in period 1970-2018. Study has shown that significant seasonal changes have taken place across the Latvian landscape due to climate change (Kalvāne and Kalvāns, 2021). The largest changes have been recorded for the unfolding (BBCH11) and flowering (BBCH61) phase of plants – almost 90% of the data included in the database demonstrate a negative trend. The winter of 1988/1989 may be considered as breaking point, it has been common that many phases have begun sooner (particularly spring phases), while abiotic autumn phases have been characterized by late years.</p><p>Study gives an overview aboutclimate change (also climate type shift) impacts on ecosystems in Latvia, particularly to forest and semi-natural grasslands and temporal and spatial changes of vegetation structure and distribution areas.</p><p>This study was carried out within the framework of the Impact of Climate Change on Phytophenological Phases and Related Risks in the Baltic Region (No. 1.1.1.2/VIAA/2/18/265) ERDF project and the Climate change and sustainable use of natural resources institutional research grant of the University of Latvia (No. AAP2016/B041//ZD2016/AZ03).</p><p>Cornes, R. C., van der Schrier, G., van den Besselaar, E. J. M. and Jones, P. D.: An Ensemble Version of the E-OBS Temperature and Precipitation Data Sets, J. Geophys. Res. Atmos., 123(17), 9391–9409, doi:10.1029/2017JD028200, 2018.</p><p>Kalvāne, G. and Kalvāns, A.(2021): Phenological trends of multi-taxonomic groups in Latvia, 1970-2018, Int. J. Biometeorol., doi:https://doi.org/10.1007/s00484-020-02068-8, 2021.</p>


Big Data ◽  
2016 ◽  
pp. 261-287
Author(s):  
Keqin Wu ◽  
Song Zhang

While uncertainty in scientific data attracts an increasing research interest in the visualization community, two critical issues remain insufficiently studied: (1) visualizing the impact of the uncertainty of a data set on its features and (2) interactively exploring 3D or large 2D data sets with uncertainties. In this chapter, a suite of feature-based techniques is developed to address these issues. First, an interactive visualization tool for exploring scalar data with data-level, contour-level, and topology-level uncertainties is developed. Second, a framework of visualizing feature-level uncertainty is proposed to study the uncertain feature deviations in both scalar and vector data sets. With quantified representation and interactive capability, the proposed feature-based visualizations provide new insights into the uncertainties of both data and their features which otherwise would remain unknown with the visualization of only data uncertainties.


2017 ◽  
Vol 6 (3) ◽  
pp. 71 ◽  
Author(s):  
Claudio Parente ◽  
Massimiliano Pepe

The purpose of this paper is to investigate the impact of weights in pan-sharpening methods applied to satellite images. Indeed, different data sets of weights have been considered and compared in the IHS and Brovey methods. The first dataset contains the same weight for each band while the second takes in account the weighs obtained by spectral radiance response; these two data sets are most common in pan-sharpening application. The third data set is resulting by a new method. It consists to compute the inertial moment of first order of each band taking in account the spectral response. For testing the impact of the weights of the different data sets, WorlView-3 satellite images have been considered. In particular, two different scenes (the first in urban landscape, the latter in rural landscape) have been investigated. The quality of pan-sharpened images has been analysed by three different quality indexes: Root mean square error (RMSE), Relative average spectral error (RASE) and Erreur Relative Global Adimensionnelle de Synthèse (ERGAS).


Geophysics ◽  
1993 ◽  
Vol 58 (3) ◽  
pp. 408-418 ◽  
Author(s):  
L. R. Jannaud ◽  
P. M. Adler ◽  
C. G. Jacquin

A method developed for the determination of the characteristic lengths of an heterogeneous medium from the spectral analysis of codas is based on an extension of Aki’s theory to anisotropic elastic media. An equivalent Gaussian model is obtained and seems to be in good agreement with the two experimental data sets that illustrate the method. The first set was obtained in a laboratory experiment with an isotropic marble sample. This sample is characterized by a submillimetric length scale that can be directly observed on a thin section. The spectral analysis of codas and their inversion yields an equivalent correlation length that is in good agreement with the observed one. The second data set is obtained in a crosshole experiment at the usual scale of a seismic survey. The codas are recorded, analysed, and inverted. The analysis yields a vertical characteristic length for the studied subsurface that compares well with the characteristic length measured by seismic and stratigraphic logs.


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