scholarly journals Improvement of water resistance and mechanical properties of fast-growing poplar with bio-based isobornyl methacrylate monomer

BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 2356-2370
Author(s):  
Ji Xu ◽  
Zhaolan Zhai ◽  
Xingyan Yan ◽  
Zhanqian Song ◽  
Shibing Shang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Water Resistance ◽  
In Situ Polymerization ◽  
Forest Tree ◽  
Ethanol Solution ◽  
Modulus Of Rupture ◽  
X Ray Diffraction ◽  
Simple Method ◽  
Fast Growing ◽  
Methacrylate Monomer

Fast-growing poplar has become an extensively planted fast-growing forest tree species because of its short plantation rotation, lightweight character, and strong adaptability. However, fast-growing poplar usually exhibits some disadvantageous properties, such as inferior mechanical properties, high hygroscopicity, and poor dimensional stability, which limits its applications to a great extent. Herein, a simple method for improving the water resistance and mechanical properties of fast-growing poplar wood using the biobased monomer isobornyl methacrylate (IBOMA) was investigated. Wood/PIBOMA composites were prepared by impregnating the wood matrix with IBOMA ethanol solution, and then the IBOMA in the wood matrix was heated to initiate in situ polymerization. Field emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD) were used to investigate the properties of fast-growing wood/PIBOMA composites. The results showed that the IBOMA successfully penetrated the wood structure and polymerized in the cell walls and cell lumens. Thereby, the water resistance and mechanical properties of the fast-growing poplar were effectively improved. In addition, the water uptake of the wood decreased from 168.3% to 35.8% after impregnation with the 90% IBOMA solution. The modulus of rupture (MOR), modulus of elasticity (MOE), and compression strength (CS) of the 90% wood/PIBOMA composites were increased by 82.7, 28.6, and 2.3%, respectively.

How Variability in OSB Mechanical Properties Affects Biological Durability Testing

Holzforschung ◽  
2003 ◽  
Vol 57 (1) ◽  
pp. 8-12
Author(s):  
S. F. Curling ◽  
J. E. Winandy ◽  
C. Carll ◽  
J. A. Micales ◽  
A. A. Tenwolde
Keyword(s):  
Mechanical Properties ◽  
Bending Strength ◽  
Particle Orientation ◽  
Modulus Of Rupture ◽  
Simple Method ◽  
Oriented Strandboard ◽  
Two Samples ◽  
Durability Testing ◽  
Biological Durability ◽  
Tensile Surface

Summary Loss in bending strength of wood has been shown to be a more sensitive measure of decay than is weight loss. Using modulus of rupture as the decay criterion is problematic for oriented strandboard (OSB) because of variation in mechanical properties due to particle orientation and size. Moreover, the small specimen size required for such tests increases the variance in mechanical properties. This study compared the variance in bending strength of ASTM D1037 standard-sized specimens and small specimens from two samples of commercial OSB. The small specimens were found to have a significantly higher level of variance in bending strength than the standard-sized specimens. A simple method of sorting the specimens based on strand orientation on the tensile surface significantly reduced the level of variance measured. The effects of differing levels of variance on the size, design and limitations of the experimental study are presented.

MECHANICAL PROPERTIES OF A POLYURETHANE/MONTMORILLONITE NANOCOMPOSITE FEATURING ORGANOMODIFICATION SYNTHESIZED VIA IN SITU POLYMERIZATION

2015 ◽  
Vol 88 (1) ◽  
pp. 138-146 ◽  
Author(s):  
Rouhollah Bagheri ◽  
Reza Darvishi
Keyword(s):  
Mechanical Properties ◽  
In Situ Polymerization ◽  
Xrd Analysis ◽  
Silicate Layer ◽  
X Ray Diffraction ◽  
X Ray ◽  
End Groups ◽  
Layer Sample ◽  
Silicate Layers

ABSTRACT In this study, polyurethane (PU)/organomodified montmorillonite (cloisite®30B) is synthesized via in situ polymerization by reaction of an ether-based prepolymer with the isocyanate end groups and adiamine chain extender (4, 4-methylene-bis(2-chloroaniline)) in the presence of different amounts of nanoparticles dispersed in the prepolymer matrix by an ultrasonic mixer for 1 h. The synthesized polymers are cast on a pretreated carbon steel sheet and cured at 120 °C in an oven. The PU and its composites have been characterized by using Fourier transform infrared spectroscopy, X-ray diffraction (XRD), and mechanical testing. The XRD analysis of the cured samples containing 1 to 3 wt% cloisite30B showed intercalation segments in the silicate layers and exfoliation for 0.5 wt% nanoparticles. The highest mechanical properties were obtained using the cured exfoliated silicate layer sample. A twofold increase in the ultimate tensile strength and a 2.3 times increase in the adhesion strength were found for 0.5 wt% organoclay/PU as compared with that of pure PU. In addition, the exfoliated structure sample exhibited a 16% reduction in abrasion compared with that of pure PU.

Design and Property Analysis of the Metal Mesh Reinforced LVL

2010 ◽  
Vol 113-116 ◽  
pp. 2145-2149
Author(s):  
Ying Cheng Hu ◽  
Jin Li ◽  
Fang Chao Cheng ◽  
Xu Jie Zhang
Keyword(s):  
Mechanical Properties ◽  
Modulus Of Elasticity ◽  
Modulus Of Rupture ◽  
Bending Test ◽  
Metal Mesh ◽  
Fast Growing ◽  
Laminated Veneer Lumber ◽  
Property Analysis ◽  
Wood Grain

This study mainly analyzed the factors that affected the mechanical properties of laminated veneer lumber（LVL）. To increase the mechanical properties, metal mesh was inserted into LVL that made of fast-growing timber. Effects of different factors were evaluated on the mechanical properties of LVL, several enhancement modes of metal mesh were designed to reinforce the LVL. Then, the mechanical properties (modulus of rupture and modulus of elasticity) of the LVL specimens were measured by static bending test. The results of different enhancement modes were analyzed and compared to investigate the effects of different factors. The position of metal mesh and the mesh number of metal mesh make significant effects on the MOE; the type of metal mesh and the angle of metal mesh-wood grain do not have any obvious effects on the MOE. The type of metal mesh and the position of metal mesh make significant effects on the MOR; the mesh number of metal mesh and the angle of metal mesh-wood grain do not have any obvious effects on the MOR.

Synthesis of Poly(Methyl Methacrylate) Reinforced by Graphene Nanoplates

2021 ◽  
Vol 897 ◽  
pp. 63-70
Author(s):  
Elif Kocacinar ◽  
Nilgun Baydogan
Keyword(s):  
Mechanical Properties ◽  
Methyl Methacrylate ◽  
In Situ Polymerization ◽  
Technical Problem ◽  
Test Method ◽  
X Ray Diffraction ◽  
Sem Images ◽  
Poly Methyl Methacrylate ◽  
Superior Mechanical Properties ◽  
Dispersion Problem

Graphene nanoplatelets (GNPs) was used as a nanofiller in Poly(methyl methacrylate) (PMMA) synthesized by the Atom Transfer Radical Polymerization (ATRP) method. The first step in the synthesis of the PMMA/GNPs was the dispersion of GNPs in the PMMA liquid monomers by combining the solutions so that GNPs had superior mechanical properties, thermal stability, and electrical conductivity also lower density of mass. Then the crosslinked PMMA/GNPs nanocomposite samples were synthesized by using the in-situ polymerization method. However, there was a challenging technical problem in the application of GNPs (at a large amount) in the polymer. For the purpose of benefiting from the advantageous properties of GNPs (especially in bulk quantities) at PMMA, the major problem at the synthesis of PMMA/GNPs nanocomposite was the GNPs dispersion in the polymer matrix. This research has focused on solving that dispersion problem with the aim of enhancing the mechanical properties of the nanocomposite by utilizing the ATRP method as the effective production technic. The structural characterization of PMMA/GNPs nanocomposite was performed for the examination of the integration of GNPs in PMMA. The surface morphology of the nanocomposite was analyzed using SEM images. X-Ray Diffraction (XRD) as a non-destructive test method was used to examine the changes in the crystalline properties of the nanocomposite structure with the rise of the GNPs amount in PMMA. The bonding interactions with each other were investigated by using Raman analysis.

Effect of Compression Ratio and Lay Angle of Metal Net on the Mechanical Properties of Metal Net-LVL Composite

2011 ◽  
Vol 418-420 ◽  
pp. 505-508
Author(s):  
Jin Li ◽  
Ying Cheng Hu
Keyword(s):  
Mechanical Properties ◽  
Shear Strength ◽  
Mechanical Strength ◽  
Compression Ratio ◽  
Modulus Of Elasticity ◽  
Modulus Of Rupture ◽  
Horizontal Shear ◽  
Fast Growing

In order to improve the mechanical strength of LVL, metal net was inserted into the LVL (metal net-LVL composite) made of fast-growing poplar. In this study, the effects of compression ratio and lay angle of metal net (which is lay angle for short in this paper) on the mechanical properties of the metal net-LVL composite was investigated in a comparative way. In order to find out the optimum compression ratio and lay angle, the modulus of rupture (MOR), modulus of elasticity (MOE) and horizontal shear strength of the metal net-LVL composite were tested. The results showed that the effects of the compression ratio on MOR, MOE and horizontal shear strength were significant, with increasing of compression ratio, the values of MOR and MOE showed an earlier raised and later decreased state, and had the maximum values at 31%. The effects of lay angle on MOR and MOE were significant, the values of MOR and MOE increased first and then decreased with lay angle increasing, and the maximum values were obtained at 20°, though there were no significant effects on horizontal shear strength, there were the maximum values at 20°. Therefore, when the compression ratio was 31% and the lay angle was 20°, the metal net-LVL composite could obtain the optimal overall mechanical properties.

Effects of Sodium Salt on Hot Mechanical Properties and Microstructure of MgO-Al-C Bricks

2013 ◽  
Vol 690-693 ◽  
pp. 662-665
Author(s):  
Jun Cong Wei ◽  
Xiu Mei Ji ◽  
Jian Kun Huang ◽  
Chun Hui Gao ◽  
Jun Bo Tu
Keyword(s):  
Mechanical Properties ◽  
Phase Composition ◽  
Electron Microscope ◽  
Silicon Powder ◽  
Modulus Of Rupture ◽  
Graphite Flake ◽  
X Ray Diffraction ◽  
X Ray ◽  
Al Powder ◽  
Scanning Electron

The effects of addition of silicon powder (1 wt. %) and Na2CO3 (converting to additional 0.5%, 1% Na2O) on the hot modulus of rupture (HMOR) of MgO-Al-C bricks were investigated. MgO-Al-C refractories were prepared by using fused magnesia and graphite flake as main starting materials, and Si, Na2CO3 or both as additives. Its phase composition and microstructure were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and EDS. The results showed that the HMOR of MgO-Al-C bricks increased slightly with addition of Si powder. However, the HMOR decreased when adding Na2CO3 and Si powder together. Moreover, the HMOR deduced with the increase of Na2CO3 content. The mechanism is that Al powder reacted to form fibrous Al4C3 and AlN, which could improve the HMOR. When silicon was added, β-SiC and M2S were formed, which could fill the passages and pores. So the densification and strength were improved. The addition of Na2CO3 could promote the oxidation of Al powder to form Al2O3, and inhibit the formation of Al4C3 and AlN. Hence the strength of MgO-Al-C deduced.

Evaluation of the Physical and Mechanical Properties of Ceramic Tiles Processed Using Steel Slag

2013 ◽  
Vol 856 ◽  
pp. 257-261
Author(s):  
Benneth C. Chukwudi ◽  
Boniface A. Okorie
Keyword(s):  
Mechanical Properties ◽  
Steel Slag ◽  
Physical And Mechanical Properties ◽  
Linear Shrinkage ◽  
Modulus Of Rupture ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Ceramic Tiles ◽  
Kaolinite Clay ◽  
Surface Appearance

This present study has evaluated the physical and mechanical properties of ceramic tiles processed from steel slag. The chemical compositions of both samples were conducted using atomic absorption spectrophotometer (AAS). Steel slag in the range of 0-100wt% was added to kaolinite clay. The blended samples were hydraulic pressed into rectangular moulds, oven dried and sintered within the temperature range of 1100°C - 1200°C. Surface appearance and colouration of sintered products were observed. Linear shrinkage, apparent porosity, water absorption, bulk density, apparent specific gravity and modulus of rupture of sintered samples were examined. Phases present were identified using X-ray diffraction (XRD), while microstructural examination was conducted using scanning electron microscopy (SEM). Phases like quartz, wollastonite, enstatite, were identified. SEM showed considerable degree of vetrification at both temperatures. Results obtained showed that samples containing 25-75wt% steel slag have very good usable ceramic tile properties.

Mechanical Properties of Wood-Polymer Composite Prepared by In-Situ Polymerization of Methyl Methacryalte and Styrene

2012 ◽  
Vol 166-169 ◽  
pp. 2938-2941 ◽  
Author(s):  
Yong Feng Li ◽  
Ding Wang Gong ◽  
Xiao Ying Dong ◽  
Zhen Bo Liu
Keyword(s):  
Mechanical Properties ◽  
Polymer Composite ◽  
In Situ Polymerization ◽  
Untreated Wood ◽  
Modulus Of Rupture ◽  
Test Results ◽  
Wood Polymer ◽  
Wood Based Composite ◽  
Wood Polymer Composite

Fast-growing poplar wood, Populus ussuriensis Kom, was used to prepare novel wood-polymer composite by the in-situ polymerization of methyl methacrylate (MMA) and styrene (St). SEM observation and FTIR analysis indicated that the resulted polymer well filled up wood cell lumen and physically reinforce wood matrix. The test results also proved that the mechanical properties of wood including modulus of rupture, modulus of elasticity, compression strength and hardness of were improved by 68.28%, 110.27%, 62.43%, 357% over those of Untreated Wood, respectively. Such wood-based composite could be potentially used as reinforced material in construction fields.

Fabrication of bionanocomposites reinforced with hemp nanocellulose and evaluation of their mechanical, thermal and dynamic mechanical properties

2021 ◽  
pp. 146442072110046
Author(s):  
SS Rana ◽  
MK Gupta
Keyword(s):  
Mechanical Properties ◽  
In Situ Polymerization ◽  
Loss Modulus ◽  
Dynamic Mechanical Properties ◽  
X Ray Diffraction ◽  
Dynamic Mechanical ◽  
Hemp Fibres ◽  
Polymerization Method

The present study aims to fabricate the epoxy-based bionanocomposites reinforced with hemp nanocellulose and the evaluation of their mechanical, thermal and dynamic mechanical properties. Nanocellulose from hemp fibres was isolated via the chemo-mechanical method and its bionanocomposites were prepared using the in situ polymerization method. Although many researchers have reported studies on the preparation and characterization of bionanocomposites however, studies on the mechanical, thermal, and dynamic mechanical properties of epoxy-based bionanocomposites reinforced with hemp nanocellulose are still unreported. The mechanical properties (i.e. tensile, flexural, hardness, and impact) and dynamic mechanical properties (i.e. glass transition temperature, damping behaviour, storage, and loss modulus) of the developed bionanocomposites were investigated. Further, the crystalline behaviour and thermal stability were also studied using the X-ray diffraction and thermogravimetric analysis techniques, respectively. The results revealed that an addition of nanocellulose considerably improved the mechanical, thermal, and viscoelastic properties of the bionanocomposites. As much as 52.17%, 48.17%, 89.08%, and 15.67% improvements in the tensile strength, flexural strength, impact strength, and hardness, respectively, for the 2 wt.% nanocellulose composites were found over the epoxy matrix.

Sign in / Sign up

Export Citation Format

Share Document