scholarly journals Hydroxypropyl methylcellulose nanocomposites containing nano fibrillated cellulose (NFC) from Agave americana L. for food packaging applications

BioResources ◽  
2021 ◽  
Vol 16 (4) ◽  
pp. 8125-8151
Author(s):  
Paladugu Krishnadev ◽  
Kizhaeral S. Subramanian ◽  
Arunachalam Lakshmanan ◽  
Shunmugam Ganapathy ◽  
Kalimuthu Raja ◽  
...  

Hydroxypropylmethylcellulose (HPMC) is popularly known as a hydrocolloid for potential use as a biopolymer film. The films of HPMC exhibit brittleness, lacking flexibility, but they can provide a gas barrier. With the aim of improving the HPMC film properties, nanofibrillated cellulose (NFC) from the succulent plant Agave americana L was incorporated as reinforcement material using the solution casting method. The films were prepared with three different amounts of NFC with glycerol as a plasticizer. The incorporation of the NFC into the nanocomposite films showed a 1,000-fold reduction in the gas permeability. However, significant improvements in the tensile strength (TS), the elongation at break (EAB), and Young’s modulus (YM) were only observed with 1% NFC. A higher moisture content (24.5%) and a higher solubility (59.5%) were observed in the HPMC/NFC-1 film, which also exhibited the best biodegradability loss of the films that were observed with a 92.8% degradation rate in 15 d of soil burial studies. Therefore, the results evidence that the HPMC/NFC films might be potentially suitable as food wrap packaging on perishable produce of fruits and vegetables to maintain their quality attributes and prolong the storage life.

2021 ◽  
Author(s):  
Yamanappagouda Amaregouda ◽  
Kantharaju Kamanna ◽  
Tilak Gasti ◽  
Vijay Kumbar

Abstract Herein, we described novel biogenic preparation of the CuO nanorods and its surface modification with L-alanine amino acid accelerated by microwave irradiation. The effect of surface functionalized CuO nanorods on the polyvinyl alcohol/carboxymethyl cellulose film physico-mechanical properties were investigated through various characterization techniques. The tensile strength was improved from 28.58 ± 0.73 MPa to 43.40 ± 0.93 MPa, UV shielding ability and barrier to the water vapors were highly enhanced when PVA/CMC matrices filled with 8 wt% of CuO-L-alanine. In addition, the prepared films exhibited acceptable overall migration limit and readily undergoes soil burial degradation. Nevertheless, CuO-L-alanine incorporated films showed potent antioxidant activity against DPPH radicals and had high antibacterial activity against Staphylococcus aureus and Escherichia coli, and antifungal activity against Candida albicans and Candida tropicalis. Furthermore, the nanocomposite films showed negligible cytotoxic effect on HEK293 and Caco-2 cell lines. In these contexts, the developed nanocomposite films can be implementing as an active food packaging material.


Foods ◽  
2020 ◽  
Vol 9 (9) ◽  
pp. 1143 ◽  
Author(s):  
Santosh Kumar ◽  
Abhinab Mudai ◽  
Barnali Roy ◽  
Indra Bhusan Basumatary ◽  
Avik Mukherjee ◽  
...  

In the context of emerging global concerns with synthetic plastic packaging, alternative natural biodegradable packaging materials are gaining increasing attention for food packaging applications. In this study, chitosan and gelatin nanocomposite hybrid films containing green synthesized zinc oxide (ZnO) nanoparticles (NPs) were developed and microstructural properties were studied. Antimicrobial activity of the developed films was evaluated using both Gram negative (Escherichia coli) and Gram positive bacteria (Staphylococcus aureus). Green synthesis protocol was used for the precipitation of ZnO NPs using fruit extract of Cassia fistula. The as-synthesized polyhedral ZnO NPs were in the range of 20–40 nm (average size ≈29 nm). Reinforcement with ZnO NPs in the hybrid films lead to improved thermal stability, elongation-at-break (EAB), and compactness properties. The developed films with 2% and 4% ZnO NPs showed a smooth, compact, and heterogeneous surface morphology compared to the control (chitosan-gelatin hybrid) films. Disc diffusion assays showed that the nanocomposite film had significant antimicrobial activity against E. coli. The developed hybrid nanocomposite films have potential to be developed as biodegradable alternative for postharvest packaging of fresh fruits and vegetables.


2021 ◽  
Vol 55 (5-6) ◽  
pp. 649-658
Author(s):  
SALAH A. A. MOHAMED ◽  
AHMED SALAMA ◽  
MOHAMED EL-SAKHAWY ◽  
ABDELMAGEED M. OTHMAN

There is a growing demand to develop biodegradable composite films, with enhanced water resistance, antimicrobial activity, high mechanical properties and low oxygen permeability. In the present study, chitosan/hydroxypropyl methylcellulose (HPMC) films reinforced with cellulose nanocrystal (CNC) and containing menthol oil were prepared for food packaging applications. Menthol oil was selected due to its antibacterial properties, as well as relatively low cost and wide availability. CNC was prepared from bagasse via acid degradation. The bio-composites were prepared through a simple and versatile solution mixing and casting method. The morphology, chemical composition, water absorption, mechanical properties and antibacterial activity of the films were investigated. FTIR spectra were used to evaluate the film structure in terms of the interactions between components. Data showed that the addition of CNC improved the mechanical properties of the formed films and the menthol oil enhanced their antibacterial properties. HPMC and HPMC/CNC reduced the water absorption of the pure chitosan membrane from 70% to 22% and 9-11% by weight, respectively, which makes these constituents a good alternative for producing packaging.


Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3543
Author(s):  
Wei Zhou ◽  
Jiawei Fang ◽  
Shuwei Tang ◽  
Zhengguo Wu ◽  
Xiaoying Wang

Cushioning and antibacterial packaging are the requirements of the storage and transportation of fruits and vegetables, which are essential for reducing the irreversible quality loss during the process. Herein, the composite of carboxymethyl nanocellulose, glycerin, and acrylamide derivatives acted as the shell and chitosan/AgNPs were immobilized in the core by using coaxial 3D-printing technology. Thus, the 3D-printed cushioning–antibacterial dual-function packaging aerogel with a shell–core structure (CNGA/C–AgNPs) was obtained. The CNGA/C–AgNPs packaging aerogel had good cushioning and resilience performance, and the average compression resilience rate was more than 90%. Although AgNPs was slowly released, CNGA/C–AgNPs packaging aerogel had an obvious antibacterial effect on E. coli and S. aureus. Moreover, the CNGA/C–AgNPs packaging aerogel was biodegradable. Due to the customization capabilities of 3D-printing technology, the prepared packaging aerogel can be adapted to more application scenarios by accurately designing and regulating the microstructure of aerogels, which provides a new idea for the development of food intelligent packaging.


Author(s):  
Elumalai Kowsalya ◽  
Kithiyon MosaChristas ◽  
Pannerselvam Balashanmugam ◽  
Veerasamy Manivasagan ◽  
Thiyagarajan Devasena ◽  
...  

2018 ◽  
Vol 9 (4) ◽  
pp. 60 ◽  
Author(s):  
Giuseppe Cavallaro ◽  
Giuseppe Lazzara ◽  
Lorenzo Lisuzzo ◽  
Stefana Milioto ◽  
Filippo Parisi

We investigated the efficacy of several nanoclays (halloysite, sepiolite and laponite) as nanofillers for Mater-Bi, which is a commercial bioplastic extensively used within food packaging applications. The preparation of Mater-Bi/nanoclay nanocomposite films was easily achieved by means of the solvent casting method from dichloroethane. The prepared bio-nanocomposites were characterized by dynamic mechanical analysis (DMA) in order to explore the effect of the addition of the nanoclays on the mechanical behavior of the Mater-Bi-based films. Tensile tests found that filling Mater-Bi with halloysite induced the most significant improvement of the mechanical performances under traction force, while DMA measurements under the oscillatory regime showed that the polymer glass transition was not affected by the addition of the nanoclay. The tensile properties of the Mater-Bi/halloysite nanotube (HNT) films were competitive compared to those of traditional petroleum plastics in terms of the elastic modulus and stress at the breaking point. Both the mechanical response to the temperature and the tensile properties make the bio-nanocomposites appropriate for food packaging and smart coating purposes. Here, we report a preliminary study of the development of sustainable hybrid materials that could be employed in numerous industrial and technological applications within materials science and pharmaceutics.


2013 ◽  
Vol 829 ◽  
pp. 534-538 ◽  
Author(s):  
Alireza Shakeri ◽  
Sattar Radmanesh

Cellulose nanofibrils ( NF ) have several advantages such as biodegradability and safety toward human health. Zein is a biodegradable polymer with potential use in food packaging applications. It appears that polymer nanocomposites are one of the most promising applications of zein films. Cellulose NF were prepared from starting material Microcrystalline cellulose (MCC) by an application of a high-pressure homogenizer at 20,000 psi and treatment consisting of 15 passes. Methods such as atomic force microscopy were used for confirmation of nanoscale size production of cellulose. The average diameter 45 nm were observed. Zeincellulose NF nanocomposite films were prepared by casting ethanol suspensions of Zein with different amounts of cellulose NF in the 0% to 5%wt. The nanocomposites were characterized by using Fourier transform infrared spectroscopy ( FTIR ), Atomic force microscopy ( AFM ) and X-ray diffraction ( XRD ) analysis. From the FTIR spectra the various groups present in the Zein blend were monitored. The homogeneity, morphology and crystallinity of the blends were ascertained from the AFM and XRD data, respectively. The thermal resistant of the zein nanocomposite films improved as the nanocellulose content increased. These obtained materials are transparent, flexible and present significantly better physical properties than the corresponding unfilled Zein films.


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