Modeling the Kinetics of Saline Minerals Dissolution in Dombrovsky Quarry at the Kalush-Golinsky Potassium Salts Deposit

2020 ◽  
Vol 42 (4) ◽  
pp. 60-68
Author(s):  
Ya.O. MALKOVA ◽  
V.M. BOBKOV ◽  
V.V. DOLIN
Keyword(s):  
Chemical Composition ◽  
Diffusion Process ◽  
Atmospheric Precipitation ◽  
Point Of View ◽  
Concentration Difference ◽  
Hydrated Ions ◽  
Ore Body ◽  
Composition Formation ◽  
Host Rocks ◽  
Concentration Diffusion

The article deals with the peculiarities of the chemical composition formation of brines in the Dombrovsky quarry, primarily due to the dissolution of potash ore minerals and host rocks in water coming from the pebble horizon and atmospheric precipitation. The solubility of the ore body minerals has been studied, and it ranges from 333 to 502 g∙dm–3. The boundary conditions for the formation of a saturated salt solution were determined. The estimated concentration of saturated potash ore solution under normal conditions is 426 g∙dm–3. The mechanism of dissolution is considered from the standpoint of D.I. Mendeleev's chemical theory of solutions. The temporary dynamics of minerals dissolution of the ore body is studied experimentally. The parameters of kinetic-diffusion process are calculated. The rate of the dissolution process, which occurs in the kinetic region, significantly exceeds the rate of concentration diffusion of hydrated ions: from 5 to 400 times depending on the mineral composition of salts. Theoretically from the point of view of multistage process kinetics and experimentally in laboratory conditions it is proved that the process that determines the formation of the chemical composition of brines (the slowest stage) is the concentration diffusion of hydrated ions Na+, K+, Cl–. They enter the liquid phase due to the minerals dissolution of the ore body and host rocks of soil and sides of the quarry, in the direction of overcoming the concentration difference - from the lower layers of the brine to its surface. This conclusion is confirmed by the ratio of weight coefficients а1 and а2. The contribution of the process of the main minerals dissolution of the ore body to the chemical composition formation of the solution is significantly less than the concentration diffusion process.

scholarly journals Chemical Composition and Functional Properties of Dietary Fibre Concentrates from Winemaking By-Products: Skins, Stems and Lees

Foods ◽  
2021 ◽  
Vol 10 (7) ◽  
pp. 1510
Author(s):  
María Ángeles Rivas ◽  
Rocío Casquete ◽  
María de Guía Córdoba ◽  
Santiago Ruíz-Moyano ◽  
María José Benito ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Functional Properties ◽  
Dietary Fibre ◽  
Water Retention ◽  
Point Of View ◽  
Water Retention Capacity ◽  
Retention Capacity ◽  
Oil Retention ◽  
High Antioxidant Activity ◽  
By Products

The objective of this study was to evaluate, from a technological and nutritional point of view, the chemical composition and functional properties of the industrial winemaking by-products, namely skins, stems and lees. The chemical and physical characteristics, as well as the functional properties (fat and water retention and swelling capacity, antioxidant capacity, and their prebiotic effect), of the dietary fibre of these by-products were studied. The results showed that the skins, stems, and lees are rich in fibre, with the stem fibre containing the highest amounts of non-extractable polyphenols attached to polysaccharides with high antioxidant activity and prebiotic effect. Lee fibre had the highest water retention capacity and oil retention capacity. The results reveal that winemaking by-products could be used as a source of dietary fibre with functional characteristics for food applications.

YIELD, ECONOMICALLY VALUABLE INDICATORS AND CHEMICAL COMPOSITION OF BLUE HONEYSUCKLE UNDER CONDITIONS OF SAKHALIN TRADE-WIND LITTORAL CLIMATE

2021 ◽  
pp. 64-73
Author(s):  
V.N. Yefanov ◽  
◽  
E.V. Mitusova ◽  
Keyword(s):  
Chemical Composition ◽  
Point Of View ◽  
Trade Wind ◽  
Plant Industry ◽  
Monsoon Climate ◽  
Experimental Station ◽  
Vavilov Institute ◽  
Household Gardens ◽  
Blue Honeysuckle

The blue honeysuckle is the earliest ripening berry, which ripens 7–10 days earlier than the garden strawber-ries under the conditions of Sakhalin's climate. It is resistant to lower fungi and parasites and can be cultivat-ed without pesticides. Currently, many honeysuckle varieties with fruits of different morphologies and chemical composition have been bred. We analyzed values of economically valuable indicators and chemical composition in 14 varieties of honeysuckle, which grow in the monsoon climate of Sakhalin. To assess the most productive variety, the values of each character were presented as percentage of the maximum for each indicator. Knowing the total values of characters under investigation made it possible to choose the best va-rieties, from authors` point of view, to grow in the household gardens in the monsoon climate of Sakhalin: from the Pavlovsk Experimental Station of Vavilov Institute of Plant Industry – Leningradsky giant (506.4%), Berel (432.9%) and Viola (423.4%).

Application of papain enzyme in technology of meat products

2021 ◽  
Vol 12 (3) ◽  
Author(s):  
V. М. Israelian ◽  
◽  
N. V. Holembovska ◽  
N. M. Slobodyanyuk ◽  
◽  
...  
Keyword(s):  
Chemical Composition ◽  
Raw Materials ◽  
Meat Products ◽  
Chloride Concentration ◽  
Enzyme Concentration ◽  
Point Of View ◽  
Meat Production ◽  
High Catalytic Activity ◽  
Medium Temperature ◽  
Enzyme Preparations

Production of enzyme preparations occupies one of the leading places in modern biotechnology and belongs to the industries whose production is constantly growing and the field of application is expanding. Various enzyme preparations are widely used in the field of nutrition, this is due to their high catalytic activity, specificity of action, the ability to carry out biochemical reactions in mild conditions. Therefore, it is advisable to use enzymes for various industrial processes, both from an economic and technological point of view. The purpose of the work was to investigate the chemical composition and the activity of papain enzyme preparation with subsequent application in technology of meat production in order to increase the biological value and improve the functional and technological properties of the finished product. The analysis of literature sources and own research shows the prospects for research and the application of enzymes and enzyme preparations based on them in the food industry, as it improves the quality of finished products and the level of greening of production, more rational use of raw materials. As a result of a study of the chemical composition, it was found that the papain enzyme has a high protein content of 87.44%, due to which it has a broader effect on meat proteins. The dependence of papain activity on the pH of the medium, temperature, sodium chloride concentration, and enzyme concentration was studied. The results of the studies showed that the highest papain activity is in the range at pH 5.5–6.0. The enzyme has a maximum collagenase activity at pH 6.0 and at a temperature of 50–60 °C.

scholarly journals Overlay materials used for increasing lifetime of machine parts working under conditions of intensive abrasion

2013 ◽  
Vol 59 (No. 1) ◽  
pp. 16-22 ◽  
Author(s):  
M. Müller ◽  
P. Hrabě
Keyword(s):  
Wear Resistance ◽  
Chemical Composition ◽  
Abrasive Wear ◽  
Laboratory Experiments ◽  
Optical Emission Spectroscopy ◽  
Optical Emission ◽  
Point Of View ◽  
Laboratory Results ◽  
Machine Parts ◽  
Materials Used

We evaluated a degree of the machine part abrasive wear with secondary focus on their hardness. The paper states laboratory results of overlay systems from their wear resistance point of view. Laboratory experiments were carried out by two-body abrasion on bonded abrasive of a P120 granularity. The results proved an increased abrasive wear resistance of martensitic, ledeburitic and stellitic overlays against eleven different original products. The overlay UTP Ledurit 60 reached the optimum values. The GD-OES (Glow Discharge Optical Emission Spectroscopy) method proved the different chemical composition of the overlay from the stated chemical composition of the overlaying electrode.    

Sur la composition chimique moyenne des amphibolites

1953 ◽  
Vol S6-III (1-3) ◽  
pp. 153-173 ◽  
Author(s):  
Pierre Lapadu-Hargues
Keyword(s):  
Chemical Composition ◽  
Sedimentary Rocks ◽  
Point Of View ◽  
Igneous Rocks ◽  
Chemical Analyses ◽  
Average Chemical Composition ◽  
Composition Chimique

Abstract In a majority of cases, amphibolites derived from sedimentary rocks can be distinguished from those derived from dioritic or gabbroic igneous rocks on the basis of average chemical composition. From the purely chemical point of view, it is possible to consider that eclogites result from metamorphism of certain types of heteromorphic gabbros such as the ariegites,and ultimately give rise to amphibolitic rocks. Chemical analyses are included.

scholarly journals Chemical equilibrium of groundwater with minerals of the host rocks in Upper Jurassic sediments (Arctic regions of Western Siberia)

2019 ◽  
Vol 98 ◽  
pp. 01037 ◽  
Author(s):  
Dmitry A. Novikov
Keyword(s):  
Chemical Composition ◽  
Chemical Equilibrium ◽  
Western Siberia ◽  
Upper Jurassic ◽  
The Arctic ◽  
Geochemical Environment ◽  
Rock System ◽  
Arctic Regions ◽  
Host Rocks ◽  
Mineral Changes

The results of thermodynamic calculations for a water-rock system in the Upper Jurassic deposits of the Arctic regions of Western Siberia are presented. In the area under investigation the groundwaters have been identified with mineralization up to 63.3 g/L and various chemical composition and genesis. Despite the long interaction with the rock (150-160 ma) equilibrium with endogenous minerals (albite, microcline and anorthite) is practically not observed. At the same time, groundwaters are in equilibrium with clay minerals and micas, such as: Caand Na-montmorillonites, kaolinite, paragonite, margarite, illite, muscovite and Mg-chlorite. The establishment of a balance of groundwater with primary aluminosilicate minerals is also affected by interactions with carbonate minerals. The differences in composition of groundwater in equilibrium with certain aluminosilicates and carbonates indicate that the mineral changes are formed from a solution of a strictly defined chemical composition in an appropriate geochemical environment.

Corrigendum to “Impact of apatite chemical composition on (U-Th)/He thermochronometry: An atomistic point of view” [Geochim. Cosmochim. Acta 167 (2015) 162–176]

2016 ◽  
Vol 187 ◽  
pp. 375
Author(s):  
Duval Mbongo Djimbi ◽  
Cécile Gautheron ◽  
Jérôme Roques ◽  
Laurent Tassan-Got ◽  
Chloé Gerin ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Point Of View
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