Thermal Properties of Cu-Hf-Ti Metallic Glass Compositions

2012 ◽  
Vol 1485 ◽  
pp. 155-160 ◽  
Author(s):  
I. A. Figueroa

ABSTRACTThe glass transition temperature Tg, crystallization temperature Tx, solidus temperature Tm, and liquidus temperature Tl, of a number of ternary Cu-Hf-Ti glassy alloys in the composition range of 51< Cu <67, 5 < Hf < 40 and 5 < Ti <40 (at.%) are reported and discussed. It is found that increasing the Ti:Hf ratio results in a rapid decreasing of Tg and Tx. This behavior is related to the fact that the melting point and cohesive energy for Ti are substantially lower than for Hf. The solidus temperature Tm, remains relatively constant on a wide range of compositions. The liquidus temperatures data suggest a ternary eutectic within the compositional field encompassed by the Cu55Hf20Ti25, Cu59Hf21Ti20, Cu60Hf20Ti20 and Cu55Hf21Ti24 alloys, with a liquidus temperature, Tl, of ∼1170 K; this is supported by the DTA traces, which show a single melting peak. Based on the DTA analysis, the experimentally calculated liquidus projection for the ternary Cu-Hf-Ti alloy system is also reported.

2004 ◽  
Vol 19 (8) ◽  
pp. 2221-2225 ◽  
Author(s):  
J.Y. Lee ◽  
D.H. Bae ◽  
J.K. Lee ◽  
D.H. Kim

In this study, the effect of addition of Nb on glass formation in Ni–Ti–Zr–Si–Sn alloys has been studied. The composition range for bulk glass formation with Dmax > 2 mm (Dmax, maximum diameter for glass formation by injection cast method) becomes wider when compared with the non-Nb–containing alloy. The ΔTx (= Tx – Tg; Tx, crystallization onset temperature; Tg, glass transition temperature), Trg (= Tg/Tl; Tl, liquidus temperature) and γ [= Tx/(Tl + Tg)] values for the alloys Dmax > 2 mm are in the range of 40–59, 0.638–0.651, and 0.410–0.419, respectively. The compositions of the alloys (Dmax > 2 mm) are closer to pseudo-eutectic composition than that of the alloy without Nb, showing an improved glass forming ability. The critical cooling rate for glass formation (Dmax = 5 mm) is estimated to be order of approximately 40 K/s.


2012 ◽  
Vol 706-709 ◽  
pp. 2424-2427
Author(s):  
Hai Jun Su ◽  
Jun Zhang ◽  
Wei Guo ◽  
Jian Zheng Yu ◽  
Lin Liu ◽  
...  

The well-aligned growth structures which derive from directional solidification of ceramic eutectics are of great interests due to their potential use in electronic devices and as structural materials at high temperatures. Because of the complexity of the component system and very high melting points, the solidification behavior on the oxide ceramic eutectic is still unclear up to date. In the presented paper, the Al2O3-Y2O3-ZrO2ternary eutectic ceramic is remelted by a DTA apparatus. The maximal heating temperature is 1950 °C. The melting and solidification behavior are investigated by the DTA analysis. The solidification microstructure is investigated by scanning electron microscopy (SEM), energy disperse spectroscopy (EDS) and X-ray diffraction (XRD). The results show that solidus temperature and the liquidus temperature are 1738.4 °C and 1750.1 °C, respectively. The formation path of eutectic phase is discussed. The microstructure of as-solidified eutectic ceramic shows a divorced ternary eutectic structure consisting of Al2O3, YAG and ZrO2phases with a random distribution. Furthermore, the microstructural comparison with directionally solidified ternary eutectic ceramic is presented and discussed.


2006 ◽  
Vol 21 (1) ◽  
pp. 234-241 ◽  
Author(s):  
W. Zhang ◽  
A. Inoue

The addition of Ag to Cu–Zr alloys is very effective for the increase in the stability of supercooled liquid as well as the glass-forming ability (GFA). The large supercooled liquid region (ΔTx) exceeding 60 K in Cu–Zr–Ag ternary system was obtained in a wide range of 25–55 at.% Cu, 40–65 at.% Zr, and 5–25 at.% Ag. The best GFA was obtained around Cu45Zr45Ag10, and glassy alloy rods with diameters up to 6.0 mm were formed by copper mold casting. The bulk glassy alloys exhibit good mechanical properties, i.e., compressive fracture strength of 1780–1940 MPa, Young's modulus of 106–112 GPa, compressive plastic elongation of 0.2–2.9%, and Vickers hardness of 534–599. The finding of the new Cu–Zr–Ag ternary glassy alloy system with high GFA and good mechanical properties is important for development and scientific studies of bulk glassy alloys.


Author(s):  
N. S. Aryaeva ◽  
E. V. Koptev-Dvornikov ◽  
D. A. Bychkov

A system of equations of thermobarometer for magnetite-silicate melt equilibrium was obtained by method of multidimensional statistics of 93 experimental data of a magnetite solubility in basaltic melts. Equations reproduce experimental data in a wide range of basalt compositions, temperatures and pressures with small errors. Verification of thermobarometers showed the maximum error in liquidus temperature reproducing does not exceed ±7 °C. The level of cumulative magnetite appearance in the vertical structure of Tsypringa, Kivakka, Burakovsky intrusions predicted with errors from ±10 to ±50 m.


2021 ◽  
Author(s):  
Max Olsen ◽  
Ragni Hatlebakk ◽  
Chris Holcroft ◽  
Arne Stavland ◽  
Nils Harald Giske ◽  
...  

Abstract Scope Controlled dissolution glasses form a permanent consolidating mineral matrix inside formations with either permeable or impermeable properties. The unique solution has a low injection viscosity and can be easily injected into a wide range of formations. The application method is simple and does not require multiple fluids or pre- and post-flushing. This paper focuses on the benefits of controlled dissolution glasses and potential applications in the oil and gas industry. Methods, Procedures, Process Controlled dissolution glasses have been researched extensively by Glass Technology Services (GTS) since 1999 for the biomedical industry, nuclear waste storage industry, and defense and aerospace industries. GTS together with operators have been performing research and development for the oil industry over the last 10 years. The research investigated different glass compositions to determine their injectability and change in formation properties post-treatment. Sandstone, chalk, and shale formations were used in the testing. Flow testing using a Hoek cell and a core flood apparatus was used to determine the post-treatment permeability. For post-treatment strength measurement, Brazilian tensile strength tests and modified cone penetration tests were used to determine tensile strength and shear strength respectively. The testing evaluated different mixing fluids, such as water and different brines, compatibility, corrosion testing, and concentrations. Results, Observations, Conclusions The testing identified different glass compositions and concentrations that are suitable for different applications and formations. Certain glass compositions increase tensile strength significantly while also maintaining the permeability in the formation. Other glass compositions have similar tensile strength increase, but result in an impermeable seal. The liquid glass solutions react with the formation to form a mineral precipitation inside the formation. The reaction with the formation occurs quickly at downhole conditions, within hours of placement. The glass can be mixed with water and variety of brines to form a stable solution across a range of densities. The testing and results to date have laid the foundation for use in a variety of consolidation and P&A applications in oil and gas wells. Testing is ongoing for a chalk and sandstone consolidation solution and for a sealing solution. Novel/Additive Information These novel glass solutions can solve many of the production and instability challenges that plague weak formations. The glasses can be injected into very low permeability formation to either seal or consolidate.


2007 ◽  
Vol 22 (2) ◽  
pp. 471-477 ◽  
Author(s):  
Dong Ho Kim ◽  
Jin Man Park ◽  
Do Hyang Kim ◽  
Won Tae Kim

The effects of niobium (Nb) addition on the glass-forming ability (GFA), crystallization behavior, and compressive mechanical property of iron (Fe)–boron (B)–yttrium (Y) alloys have been investigated. Among the (Fe71.2B24Y4.8)100−xNbx (x = 0, 2, 4, 6, 8) alloys investigated, (Fe71.2B24Y4.8)96Nb4 exhibits the highest GFA, enabling the formation of glassy rods with a maximum diameter of 7 mm, which is the largest among quaternary Fe-based alloys. The comparison of the crystallization behavior of the alloys shows that the formation of metastable Fe23B6 phase during crystallization in the (Fe71.2B24Y4.8)96Nb4 alloy can suppress the formation of other stable crystalline phases such as α-Fe, enhancing the stability of the glass phase. The present results show that the attainment of a significantly high GFA is possible even in a quaternary Fe-based alloy system by properly tailoring the competing crystalline phase by the modification of liquid chemistry.


Author(s):  
Martin Löbel ◽  
Thomas Lindner ◽  
Maximilian Grimm ◽  
Lisa-Marie Rymer ◽  
Thomas Lampke

AbstractHigh-entropy alloys (HEAs) have shown a wide range of promising structural and functional properties. By the application of coating technology, an economical exploitation can be achieved. The high wear and corrosion resistance of HEAs make them particularly interesting for the application as protective coatings. Especially for alloys with a high chromium content, a high corrosion resistance has been revealed. For the current investigations, the equimolar HEA CrFeCoNi with a single-phase face centered cubic structure is considered as a base alloy system. To increase the corrosion resistance as well as the hardness and strength, the influence of the alloying elements aluminum and molybdenum is analyzed. For the current investigations, the high kinetic process high-velocity oxygen fuel thermal spraying (HVOF) has been considered to produce coatings with a low porosity and oxide content. Feedstock is produced by inert gas atomization. The influence of the alloy composition on the microstructure, phase formation and resulting property profile is studied in detail. A detailed analysis of the corrosion resistance and underlying mechanisms is conducted. The pitting and passivation behavior are investigated by potentiodynamic polarization measurements in NaCl and H2SO4 electrolyte. A distinct improvement of the corrosion resistance can be achieved for the alloy Al0.3CrFeCoNiMo0.2.


Author(s):  
E. V. Koptev-Dvornikov ◽  
D. A. Bychkov

A system of equations of the liquidus thermobarometer of olivine — silicate melt was obtained by processing the sample of 772 experimental equilibria of olivines with basic melts using methods of multidimensional statistics. Equations reproduce with small error experimental data in a wide range of basite compositions (from komatiites to dacites), temperatures from 1040 to 1500 ᵒС, pressures from 1 bar up to 30 kbar. Thermobarometer testing demonstrated that the deviations of the calculated liquidus temperature from the experimental one in most of the temperature range do not exceed ±3 ᵒC.


2020 ◽  
Vol 51 (12) ◽  
pp. 6658-6669
Author(s):  
Bo Hu ◽  
Dejiang Li ◽  
Jingya Wang ◽  
Zixin Li ◽  
Xueyang Wang ◽  
...  

2016 ◽  
Vol 30 (03) ◽  
pp. 1550261 ◽  
Author(s):  
Roberto N. Duarte ◽  
Jonas D. Faria ◽  
Crystopher Brito ◽  
Nathalia C. Veríssimo ◽  
Noé Cheung ◽  
...  

The dependence of tensile properties on the length scale of the dendritic morphology of Al–Cu, Al–Ag and Al–Ag–Cu alloys is experimentally investigated. These alloys were directionally solidified (DS) under a wide range of cooling rates [Formula: see text], permitting extensive microstructural scales to be examined. Experimental growth laws are proposed relating the primary dendritic arm spacing, [Formula: see text] to [Formula: see text] and tensile properties to [Formula: see text]. It is shown that the most significant effect of the scale of [Formula: see text] on the tensile properties is that of the ternary alloy, which is attributed to the more homogeneous distribution of the eutectic mixture for smaller [Formula: see text] and by the combined reinforcement roles of the intermetallics present in the ternary eutectic: Al2Cu and nonequilibrium Ag3Al.


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