A Comparison Of The Corrosion Behaviour Of Nanocrystalline And Normal Crystalline Nickel

1991 ◽  
Vol 238 ◽  
Author(s):  
R. Rofagha ◽  
R. Langer ◽  
A. M. El-Sherik ◽  
U. Erb ◽  
G. Palumbo ◽  
...  
Keyword(s):  
Grain Size ◽  
Grain Boundary ◽  
Corrosion Potential ◽  
Corrosion Behaviour ◽  
Corrosion Morphology ◽  
Free Corrosion Potential ◽  
Grain Sizes ◽  
Electrochemical Parameters ◽  
Passivation Current Density

ABSTRACTThe effect of grain size on the corrosion behaviour of nickel in 2N sulphuric acid is evaluated by potentiodynamic testing and characterization of the corrosion morphology for grain sizes ranging from 100μ to 32nm. The influence of the grain boundary component on key electrochemical parameters (free corrosion potential, passivation current density and potential, transpassive dissolution rate) is discussed.

Simulation of the interaction of plastic zone dislocations with the grain boundary at brittle-plastic transition temperatures in molybdenum

2021 ◽  
Vol 2021 (3) ◽  
pp. 77-85
Author(s):  
K. M. Borysovska ◽  
◽  
N. M. Marchenko ◽  
Yu. M. Podrezov ◽  
S. O. Firstov ◽  
...  
Keyword(s):  
Fracture Toughness ◽  
Grain Size ◽  
Grain Boundary ◽  
Plastic Zone ◽  
Grain Boundaries ◽  
Crack Tip ◽  
Dynamics Simulation ◽  
Density Of Dislocations ◽  
Grain Sizes ◽  
Pile Up

The (DD) method was used to model the formation of the plastic zone of the top of the cracks in polycrystalline molybdenum. Special attention was paid to take into account the interaction of dislocations in the plastic zone with grain boundaries. Structural sensitivity of fracture toughness was analyzed under brittle-ductile condition. Simulations were performed for a range of grain sizes from 400 to 100 μm, at which a sudden increase in fracture toughness with a decrease of grain size was experimentally shown. We calculated the value of K1c taking into account the shielding action of dislocations. The position of all dislocations in the plastic zone at fracture moment was calculated. Based on these data, we obtained the dependences of dislocation density on the distance from the crack tip thereby confirming significant influence of the grain boundaries on plastic zone formation. At large grain sizes, when the plastic zone does not touch the boundary, the distribution of dislocations remained unchanged. As grains reduce their size to size of the plastic zone, they start formating a dislocation pile – up near the boundaries. Dislocations on plastic zone move slightly toward the crack tip, but the density of dislocations in the middle of the grain remains unchanged, and fracture toughness remains almost unchanged. Further reduction of the grain size leads to the Frank-Reed source activation on the grain boundary Forming dislocation pile-up of the neighbor grains. Its stress concentration acts on dislocations of the first grain and causes redistribution of plastic zone dislocations. If the reduction in grain size is not enough to form a strong pile-up, density of dislocations on plastic zone increases slightly and crack resistance increases a few percent. Further reduction of grains promotes strong pile-up, dislocations move to crack tip, and its density on plastic zone increases. Crack is shielded and fracture toughness increases sharply. The calculation showed that the fracture toughness jump is observed at grain sizes of 100—150 μm, in good agreement with the experiment. Keywords: dislocation dynamics simulation, molybdenum, fracture toughness, grain size, plastic zone, brittle-ductile transition.

Deformation mechanisms in natural dolomite mylonites from a detachment system (Mt. Hymittos, Greece)

2021 ◽  
Author(s):  
Mark Coleman ◽  
Bernhard Grasemann ◽  
David Schneider ◽  
Konstantinos Soukis ◽  
Riccardo Graziani
Keyword(s):  
Grain Size ◽  
Grain Boundary ◽  
Boundary Migration ◽  
Size Reduction ◽  
Greenschist Facies ◽  
Normal Faults ◽  
Grain Boundary Migration ◽  
Grain Sizes ◽  
Subgrain Rotation ◽  
Middle Unit

<p>Microstructures may be used to determine the processes, conditions and kinematics under which deformation occurred. For a given set of these variables, different microstructures are observed in various materials due to the material’s physical properties. Dolomite is a major rock forming mineral, yet the mechanics of dolomite are understudied compared to other ubiquitous minerals such as quartz, feldspar, and calcite. Our new study uses petrographic, structural and electron back scatter diffraction analyses on a series of dolomitic and calcitic mylonites to document differences in deformation styles under similar metamorphic conditions. The Attic-Cycladic Crystalline Complex, Greece, comprises a series of core complexes wherein Miocene low-angle detachment systems offset and juxtapose a footwall of high-pressure metamorphosed rocks against a low-grade hanging wall. This recent tectonic history renders the region an excellent natural laboratory for studying the interplay of the processes that accommodate deformation. The bedrock of Mt. Hymittos, Attica, preserves a pair of ductile-then-brittle normal faults dividing a tripartite tectonostratigraphy. Field observations, mineral assemblages and observable microstructures suggests the tectonic packages decrease in metamorphic grade from upper greenschist facies (~470 °C at 0.8 GPa) in the stratigraphically lowest package to sub-greenschist facies in the stratigraphically highest package. Both low-angle normal faults exhibit cataclastic fault cores that grade into the schists and marbles of their respective hanging walls. The middle and lower tectonostratigraphic packages exhibit dolomitic and calcitic marbles that experienced similar geologic histories of subduction and exhumation. The mineralogically distinct units (calcite vs. dolomite) of the middle package deformed via different mechanisms under the same conditions within the same package and may be contrasted with mineralogically similar units that deformed under higher pressure and temperature conditions in the lower package. In the middle unit, dolomitic rocks are brittlely deformed. Middle unit calcitic marble are mylonitic to ultramylonitic with average grain sizes ranging from 30 to 8 μm. These mylonites evince grain-boundary migration and grain size reduction facilitated by subgrain rotation. Within the lower package, dolomitic and calcitic rocks are both mylonitic to ultramylonitic with grain sizes ranging from 28 to 5 μm and preserve clear crystallographic preferred orientation fabrics. Calcitic mylonites exhibit deformation microstructures similar to those of the middle unit. Distinctively, the dolomitic mylonites of the lower unit reveal ultramylonite bands cross-cutting and overprinting an older coarser mylonitic fabric. Correlated missorientation angles suggest these ultramylonites show evidence for grain size reduction accommodated by microfracturing and subgrain rotation. In other samples the dolomitic ultramylonite is the dominant fabric and is overprinting and causing boudinage of veins and relict coarse mylonite zones. Isolated interstitial calcite grains within dolomite ultramylonites are signatures of localized creep-cavitation processes. Following grain size reduction, grain boundary sliding dominantly accommodated further deformation in the ultramylonitic portions of the samples as indicated by randomly distributed correlated misorientation angles. This study finds that natural deformation of dolomitic rocks may occur by different mechanisms than those identified by published experiments; notably that grain-boundary migration and subgrain rotation may be active in dolomite at much lower temperatures than previously suggested.</p>

scholarly journals Characterization of glacial silt and clay using automated mineralogy

2019 ◽  
Vol 60 (80) ◽  
pp. 49-65
Author(s):  
Jeff W. Crompton ◽  
Gwenn E. Flowers ◽  
Brendan Dyck
Keyword(s):  
Grain Size ◽  
Size Composition ◽  
Rock Properties ◽  
Fine Grained ◽  
Rock Fragments ◽  
Grain Sizes ◽  
Automated Mineralogy ◽  
Log Normal ◽  
Discrete Populations

AbstractGlacial erosion produces vast quantities of fine-grained sediment that has a far-reaching impact on Earth surface processes. To gain a better understanding of the production of glacial silt and clay, we use automated mineralogy to quantify the microstructure and mineralogy of rock and sediment samples from 20 basins in the St. Elias Mountains, Yukon, Canada. Sediments were collected from proglacial streams, while rock samples were collected from ice marginal outcrops and fragmented using electrical pulse disaggregation. For both rock fragments and sediments, we observe a log-normal distribution of grain sizes and a sub-micrometer terminal grain size. We find that the abrasion of silt and clay results in both rounding and the exploitation of through-going fractures. The abundance of inter- versus intragranular fractures depends on mineralogy and size. Unlike the relatively larger grains, where crushing and abrasion are thought to exploit and produce discrete populations of grain sizes, the comminution of fines leads to a grain size, composition and rounding that is continuously distributed across size, and highly dependent on source-rock properties.

Thermal and mechanical characterization of polymer composites filled with dispersed zeolite and oil shale

2010 ◽  
Vol 45 (11) ◽  
pp. 1209-1216 ◽  
Author(s):  
A.M. Zihlif ◽  
Ziad Elimat ◽  
G. Ragosta
Keyword(s):  
Thermal Conductivity ◽  
Grain Size ◽  
Yield Stress ◽  
Oil Shale ◽  
Activation Volume ◽  
Filler Concentration ◽  
Grain Sizes ◽  
Eyring Theory ◽  
Zeolite Composite

The thermal, viscoelastic, mechanical behavior of polymers filled with dispersed zeolite and oil shale is studied as a function of temperature, grain size, and filler concentration. It was found that the thermal conductivity of epoxy—zeolite composite increases with different zeolite grain sizes and takes a higher value in case of the 63 μm grain size composite. The observed enhancement in the thermal conductivity of zeolite composites correlates well with that of the electrical conductivity. The thermodynamic results exhibit a slight increase in the glass transition temperature of the polystyrene/oil shale composites, and shift in the observed relaxation peaks with increasing the oil shale content. The plastic deformation of PS/oil shale composites shows that the elastic modulus increases and the compressive yield stress decreases with oil shale content. The Eyring theory of yielding could predict the dependence of the yield stress on the applied strain rate. The predicted activation volume and activation energy showed dependence on the oil shale grains sizes and content.

Analysis of Creep Deformation Due to Grain-Boundary Diffusion/Sliding

2007 ◽  
Vol 345-346 ◽  
pp. 565-568
Author(s):  
Byung Nam Kim ◽  
Keijiro Hiraga ◽  
Koji Morita ◽  
Hidehiro Yoshida
Keyword(s):  
Grain Size ◽  
Creep Rate ◽  
Grain Boundary ◽  
Boundary Diffusion ◽  
Effective Diffusion ◽  
High Viscosity ◽  
Grain Boundary Sliding ◽  
Grain Boundary Diffusion ◽  
Grain Sizes ◽  
Boundary Sliding

For steady-state deformation caused by grain-boundary diffusion and viscous grain-boundary sliding, the creep rate of regular polyhedral grains is analyzed by the energy-balance method. For the microstructure, the grain-grain interaction increases the degree of symmetry of diffusional field, resulting in a decrease of the effective diffusion distance. Meanwhile, the viscous grain-boundary sliding is found to decrease the creep rate. The present analysis reveals that the grain-size exponent is dependent on the grain size and the grain-boundary viscosity: the exponent becomes unity for small grain sizes and/or high viscosity, while it is three for large grain sizes and/or low viscosity.

scholarly journals Molecular Dynamics as a Means to Investigate Grain Size and Strain Rate Effect on Plastic Deformation of 316 L Nanocrystalline Stainless-Steel

Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3223 ◽  
Author(s):  
Abdelrahim Husain ◽  
Peiqing La ◽  
Yue Hongzheng ◽  
Sheng Jie
Keyword(s):  
Plastic Deformation ◽  
Grain Size ◽  
Stainless Steel ◽  
Grain Boundary ◽  
Strain Rate ◽  
Deformation Mechanism ◽  
Grain Boundary Sliding ◽  
Plastic Deformation Mechanism ◽  
Grain Sizes ◽  
Critical Grain Size

In the present study, molecular dynamics simulations were employed to investigate the effect of strain rate on the plastic deformation mechanism of nanocrystalline 316 L stainless-steel, wherein there was an average grain of 2.5–11.5 nm at room temperature. The results showed that the critical grain size was 7.7 nm. Below critical grain size, grain boundary activation was dominant (i.e., grain boundary sliding and grain rotation). Above critical grain size, dislocation activities were dominant. There was a slight effect that occurred during the plastic deformation mechanism transition from dislocation-based plasticity to grain boundaries, as a result of the stress rate on larger grain sizes. There was also a greater sensitive on the strain rate for smaller grain sizes than the larger grain sizes. We chose samples of 316 L nanocrystalline stainless-steel with mean grain sizes of 2.5, 4.1, and 9.9 nm. The values of strain rate sensitivity were 0.19, 0.22, and 0.14, respectively. These values indicated that small grain sizes in the plastic deformation mechanism, such as grain boundary sliding and grain boundary rotation, were sensitive to strain rates bigger than those of the larger grain sizes. We found that the stacking fault was formed by partial dislocation in all samples. These stacking faults were obstacles to partial dislocation emission in more sensitive stress rates. Additionally, the results showed that mechanical properties such as yield stress and flow stress increased by increasing the strain rate.

Influence of Grain Size and Grain Boundary of Workpiece on Micro EDM

2014 ◽  
Vol 941-944 ◽  
pp. 2116-2120 ◽  
Author(s):  
Qing Yu Liu ◽  
Qin He Zhang ◽  
Jian Hua Zhang ◽  
Min Zhang
Keyword(s):  
Grain Size ◽  
Grain Boundary ◽  
Micro Edm ◽  
Test Results ◽  
Machining Performance ◽  
Grain Sizes ◽  
Stainless Steel 304 ◽  
Micro Holes ◽  
The Difference ◽  
Micro Features

Micro EDM is used to machine micro features which are of the same size order as material microstructure of workpiece. Due to the difference of the thermal properties between the crystal grain and grain boundary, the machining performance of micro EDM varies with the crystal grain sizes of workpiece. This paper investigated on the influence of grain size and grain boundary on the machining performance of micro EDM. By drilling micro holes on two pieces of stainless steel 304 (SUS 304) which are different in grain sizes, test results revealed that the characteristics of micro EDM is influenced by grain sizes of workpiece materials significantly.

Effect of Addition of Al & Ca and Heat Treatment on the Cast Mg-6Zn Alloy

2013 ◽  
Vol 765 ◽  
pp. 33-37 ◽  
Author(s):  
S.S. Joshi ◽  
M.S. Mohan ◽  
S. Seshan ◽  
S. Kumar ◽  
S. Suwas
Keyword(s):  
Heat Treatment ◽  
Grain Size ◽  
Grain Boundary ◽  
Tensile Properties ◽  
Volume Fraction ◽  
Corrosion Behaviour ◽  
Boundary Phase ◽  
Al Content ◽  
Β Phase ◽  
The Matrix

In the present investigation, the effect of addition of Al and small amounts of Ca as well as the effect of heat treatment has been investigated on microstructure, tensile properties and corrosion behaviour of Mg-6Zn alloy produced by squeeze casting. The Mg-6Zn-1Al (ZA61) alloy consisted of α-Mg grains and MgZn (β) phase at the grain boundaries with a much higher strength and ductility than pure Mg. The addition of 0.1 and 0.5 wt% Ca to the ZA61 alloy refined the grain size and increased the volume fraction of the grain boundary phase but did not change the nature of the phase. Consequently, strength increased without much reduction in ductility. The increase in Al content of the alloy to 4 wt% (ZA64) changed the grain boundary phase to Al5Mg11Zn4 (Φ) phase, increased its volume fraction and refined the grain size as compared to ZA61 alloy. Consequently, strength increased with a reduction in ductility. On heat treatment of ZA61+0.5Ca and ZA64 alloys, the volume fraction of grain boundary phases decreased, fine precipitates were obtained in the matrix and the grain size increased. Thus, higher strength with a lower ductility was obtained on heat treatment but the ductility of both the alloys was still higher than that of pure Mg. Thus, 130 MPa 0.2%PS, 225 MPa UTS and 4.9% elongation to fracture could be obtained for the squeeze cast ZA64 alloy in the T6 condition, which are very good tensile properties for a cast Mg alloy. Increase in Al content and heat treatment reduced the corrosion resistance and addition of Ca improved it. The highest corrosion rate was observed to be 0.85 mm/year for the ZA64 alloy in the T6 condition.

Percolative composite model for prediction of the properties of nanocrystalline materials

1997 ◽  
Vol 12 (7) ◽  
pp. 1828-1836 ◽  
Author(s):  
Rachman Chaim
Keyword(s):  
Experimental Data ◽  
Grain Size ◽  
Grain Boundary ◽  
Nanocrystalline Materials ◽  
Composite Model ◽  
Grain Sizes ◽  
Percolation Thresholds ◽  
Definition Of ◽  
Critical Grain Size ◽  
Transport Type

A physical percolating composite model is presented for description of the changes in the transport-type properties with grain size in nanocrystalline materials. The model is based on hierarchial percolation through the different microstructural components such as grain boundaries, triple lines, and quadruple nodes at grain sizes when their respective percolation thresholds are reached. The model yields critical grain sizes at which the properties may change significantly. These grain sizes depend on the grain boundary thickness. Master curves were calculated for the elastic modulus and compared to the experimental data from the literature. Better fit was found with the experimental data in comparison to Hill's approximation model. The critical grain size at grain boundary percolation threshold is suggested as a criterion for definition of materials to exhibit nanocrystalline properties.

The Structure and Corrosion Process Characterization of Galvannealed and Galvanized Steel Sheets

2013 ◽  
Vol 834-836 ◽  
pp. 589-596
Author(s):  
She Ming Jiang ◽  
Da Wei Guo ◽  
Qi Fu Zhang
Keyword(s):  
Corrosion Potential ◽  
Corrosion Process ◽  
Galvanized Steel ◽  
Dissolution Process ◽  
Gamma Delta ◽  
Free Corrosion Potential ◽  
Steel Sheets ◽  
Delta Phase ◽  
Process Characterization

The dissolution process of galvannealed (GA) and galvanized (GI) coating was examined by correlating a chemical stripping test in 1MNaCl+0.01MH2SO4solution. The key time of dissolution process of coating was found via measuring the variation of free corrosion potential. Through coating metallographic observations at the key point, the dissolution process of coating can be clear. There are four Fe-Zn intermetallic phases in GA coating, namely gamma-1,gamma,delta and zeta phases, from the substrate. The compressed part of GA and GI coatings was the initial of corrosion process. The net crack will be emerging on the delta phase, which width graduallyincreasing until stripping. Pitting corrosion occurred on the GI coating in the solution containing Cl-ion, the area and depth of pit gradually increasing until stripping. The corrosion potential of Fe2Al5Znxinhibition layer is about-0.8VSCE.

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