Electric Transport Properties of a NiTi Shape Memory Alloy Under Applied Stress.

1991 ◽  
Vol 246 ◽  
Author(s):  
G. Airoldi ◽  
G. Riva ◽  
T. Ranucci ◽  
B. Vicentini
Keyword(s):  
Shape Memory ◽  
Applied Stress ◽  
Single Phase ◽  
Niti Alloy ◽  
Parent Phase ◽  
Physical Property ◽  
Niti Shape Memory Alloy ◽  
Hysteresis Cycle ◽  
Electric Transport ◽  
Deformation Processes

AbstractIt is well known that mechanical properties of Shape Memory Alloys are strongly dependent upon the test temperature (T) respect to transformation temperatures: the stress-strain curves however hinder the true deformation processes acting.Electrical resistance(ER), a physical property sensibly affected by electronic structure modifications, traditionally used to follow the growth of thermal martensite, is here investigated to follow the modifications of a NiTi alloy, in an initial single phase structure, under applied stress. ER measurements are here detected with the aim to distinguish different deformation processes at four test temperatures Ti (i=1,..,4): in martensitic phase,either at T1 <Mf or at T2<As within the hysteresis cycle; in parent phase, either at Af<T3 or at Ms<T4 within the hysteresis cycle, where T2 = T4. Results are examined in comparison with previous obtained data and discussed at the light of imprinted deformation.

scholarly journals Phase Field Study of the Microstructural Dynamic Evolution and Mechanical Response of NiTi Shape Memory Alloy under Mechanical Loading

Materials ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 183
Author(s):  
Shangbin Xi ◽  
Yu Su
Keyword(s):  
Shape Memory ◽  
Applied Stress ◽  
Phase Field ◽  
Mechanical Response ◽  
Niti Alloy ◽  
Dynamic Evolution ◽  
Niti Shape Memory Alloy ◽  
Free Energy Function ◽  
Potential Wells ◽  
Tension And Compression

For the purpose of investigating the microstructural evolution and the mechanical response under applied loads, a new phase field model based on the Ginzburg-Landau theory is developed by designing a free energy function with six potential wells that represent six martensite variants. Two-dimensional phase field simulations show that, in the process of a shape memory effect induced by temperature-stress, the reduction-disappearance of cubic austenite phase and nucleation-growth of monoclinic martensite multi-variants result in a poly-twined martensitic microstructure. The microstructure of martensitic de-twinning consists of different martensite multi-variants in the tension and compression, which reveals the microstructural asymmetry of nickel-titanium (NiTi) alloy in the tension and compression. Furthermore, in the process of super-elasticity induced by tensile or compressive stress, all martensite variants nucleate and expand as the applied stress gradually increases from zero. Whereas, when the applied stress reaches critical stress, only the martensite variants of applied stress-accommodating continue to expand and others fade gradually. Moreover, the twinned martensite microstructures formed in the tension and compression contain different martensite multi-variants. The study of the microstructural dynamic evolution in the phase transformation can provide a significant reference in improving properties of shape memory alloys that researchers have been exploring in recent years.

scholarly journals Structure Of TiN/Hydroxyapatite Multilayers Deposited On Surface Of NiTi Shape Memory Alloy

2015 ◽  
Vol 60 (3) ◽  
pp. 1777-1782 ◽  
Author(s):  
K. Dudek ◽  
T. Goryczka ◽  
T. Wierzchoń ◽  
J. Lelątko
Keyword(s):  
Glow Discharge ◽  
Titanium Nitride ◽  
Shape Memory ◽  
Niti Alloy ◽  
Parent Phase ◽  
Deposition Process ◽  
Nitride Layer ◽  
Niti Shape Memory Alloy ◽  
X Ray Diffraction ◽  
Protective Layers

Abstract In order to improve a corrosion resistance and biocompatibility of NiTi shape memory alloys, the surface of the NiTi alloy was covered by protective layers. The paper presents results of the layers composed of titanium nitride and hydroxyapatite (HAp). The TiN layers were deposited using the glow discharge technique and then the bioactive hydroxyapatite layer was formed from simulated body fluids solution. The results of the structure studies and microscopic observations confirmed that on the surface of the NiTi alloy a thin titanium nitride layer 35-50 nm thick (depending on the glow discharge technique parameters) was obtained. The structure of the deposited layers was studied by means of the X-ray diffraction technique. Also, mechanical parameters of obtained layers were characterized using nanoindentation. On the top of the titanium nitride, a layer consisted of hydroxyapatite and NaCl was formed. Applied parameters of deposition process did not lead to decomposition of the NiTi parent phase (B2) to the equilibrium ones.

scholarly journals Net-Shape NiTi Shape Memory Alloy by Spark Plasma Sintering Method

2021 ◽  
Vol 11 (4) ◽  
pp. 1802
Author(s):  
Sneha Samal ◽  
Orsolya Molnárová ◽  
Filip Průša ◽  
Jaromír Kopeček ◽  
Luděk Heller ◽  
...  
Keyword(s):  
Shape Memory ◽  
Shape Memory Effect ◽  
Spark Plasma Sintering ◽  
Memory Effect ◽  
Niti Alloy ◽  
Niti Shape Memory Alloy ◽  
Good Shape ◽  
Plasma Sintering ◽  
Shape Memory Effects ◽  
Spark Plasma

An analysis of the shape memory effect of a NiTi alloy by using the spark plasma sintering approach has been carried out. Spark plasma sintering of Ti50Ni50 powder (20–63 µm) at a temperature of 900 °C produced specimens showing good shape memory effects. However, the sample showed 2.5% porosity due to a load of 48 MPa. Furthermore, an apparent shape memory effect was recorded and the specimens were characterized by uniformity in chemical composition and shape memory alloys of NiTi showed significant austenite phases with a bending strain recovery of >2.5%.

scholarly journals Key Properties of a Bioactive Ag-SiO2/TiO2 Coating on NiTi Shape Memory Alloy as Necessary at the Development of a New Class of Biomedical Materials

2021 ◽  
Vol 22 (2) ◽  
pp. 507
Author(s):  
Mateusz Dulski ◽  
Robert Gawecki ◽  
Sławomir Sułowicz ◽  
Michal Cichomski ◽  
Alicja Kazek-Kęsik ◽  
...  
Keyword(s):  
Surface Roughness ◽  
Shape Memory Alloy ◽  
Shape Memory ◽  
Dermal Fibroblast ◽  
Niti Alloy ◽  
Bacterial Biofilm ◽  
Niti Shape Memory Alloy ◽  
Normal Human Dermal Fibroblast ◽  
Water Contact ◽  
Nano Coating

Recent years have seen the dynamic development of methods for functionalizing the surface of implants using biomaterials that can mimic the physical and mechanical nature of native tissue, prevent the formation of bacterial biofilm, promote osteoconduction, and have the ability to sustain cell proliferation. One of the concepts for achieving this goal, which is presented in this work, is to functionalize the surface of NiTi shape memory alloy by an atypical glass-like nanocomposite that consists of SiO2-TiO2 with silver nanoparticles. However, determining the potential medical uses of bio(nano)coating prepared in this way requires an analysis of its surface roughness, tribology, or wettability, especially in the context of the commonly used reference coat-forming hydroxyapatite (HAp). According to our results, the surface roughness ranged between (112 ± 3) nm (Ag-SiO2)—(141 ± 5) nm (HAp), the water contact angle was in the range (74.8 ± 1.6)° (Ag-SiO2)—(70.6 ± 1.2)° (HAp), while the surface free energy was in the range of 45.4 mJ/m2 (Ag-SiO2)—46.8 mJ/m2 (HAp). The adhesive force and friction coefficient were determined to be 1.04 (Ag-SiO2)—1.14 (HAp) and 0.247 ± 0.012 (Ag-SiO2) and 0.397 ± 0.034 (HAp), respectively. The chemical data showed that the release of the metal, mainly Ni from the covered NiTi substrate or Ag from Ag-SiO2 coating had a negligible effect. It was revealed that the NiTi alloy that was coated with Ag-SiO2 did not favor the formation of E. coli or S. aureus biofilm compared to the HAp-coated alloy. Moreover, both approaches to surface functionalization indicated good viability of the normal human dermal fibroblast and osteoblast cells and confirmed the high osteoconductive features of the biomaterial. The similarities of both types of coat-forming materials indicate an excellent potential of the silver-silica composite as a new material for the functionalization of the surface of a biomaterial and the development of a new type of functionalized implants.

EFFECTS OF PARTICLE SIZE AND SINTERING TEMPERATURE ON SUPERELASTICITY BEHAVIOR OF NiTi SHAPE MEMORY ALLOY USING NANOINDENTATION

2021 ◽  
pp. 2150024
Author(s):  
C. VELMURUGAN ◽  
V. SENTHILKUMAR
Keyword(s):  
Particle Size ◽  
Shape Memory Alloy ◽  
Shape Memory ◽  
Sintering Temperature ◽  
Niti Alloy ◽  
Indentation Load ◽  
Niti Shape Memory Alloy ◽  
Recovery Ratio ◽  
Work Recovery ◽  
Niti Sma

The present study investigates the superelasticity properties of spark plasma sintered (SPS) nickel titanium shape memory alloy (NiTi SMA) with the influence of sintering temperature and particle size. The nanoindentation is conducted on the surface of the NiTi SMA at various loads such as 100, 300 and 500[Formula: see text]mN. The nanoindentation technique determines the quantitative results of elasto-plastic properties such as depth recovery in the form of superelasticity, stiffness, hardness and work recovery ratio from load–depth ([Formula: see text]–[Formula: see text]) data during loading and unloading of the indenter. Experimental findings show that the depth and work recovery ratio increases with the decrease of indentation load and particle size. In contrast, increasing the sintering temperature exhibited a better depth and work recovery due to the removal of pores which could enhance the reverse transformation. The contact stiffness is influenced by [Formula: see text] which leads to attain a maximum stiffness at the highest load (500[Formula: see text]mN) and particle size (45[Formula: see text][Formula: see text]m) along with the lowest sintering temperature (700∘C). NiTi alloy exhibited a maximum hardness of 9.46[Formula: see text]GPa when subjected to indent at the lowest load and particle size sintered at 800∘C. The present study reveals a better superelastic behavior in NiTi SMA by reducing the particle size and indentation load associated with the enhancement of sintering temperature.

scholarly journals Influence of Batch Mass on Formation of NiTi Shape Memory Alloy Produced by High-Energy Ball Milling

Metals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1908
Author(s):  
Tomasz Goryczka ◽  
Piotr Salwa
Keyword(s):  
Ball Milling ◽  
Niti Alloy ◽  
Parent Phase ◽  
High Energy ◽  
High Energy Ball Milling ◽  
The Body ◽  
Niti Shape Memory Alloy ◽  
Scanning Calorimetry ◽  
Energy Ball ◽  
Grinding Time

A high-energy ball milling technique was used for production of the equiatomic NiTi alloy. The grinding batch was prepared in two quantities of 10 and 20 g. The alloy was produced using various grinding times. Scanning electron microscopy, X-ray diffraction, hardness measurement and differential scanning calorimetry were used for materials characterization at various milling stages. The produced alloy was studied by means of microstructure, chemical and phase composition, average grain and crystallite size, crystal lattice parameters and microstrains. Increasing the batch mass to 20 g and extending the grinding time to 140 h caused the increase in the average size of the agglomerates to 700 µm while the average crystallites size was reduced to a few nanometers. Microstrains were also reduced following elongation of milling time. Moreover, when the grinding time is extended, the amount of the monoclinic phase increases at the expense of the body-centered cubic one—precursors of crystalline, the B2 parent phase and the B19′ martensite. Crystallization takes place as a multistage process, however, at temperatures below 600 °C. After crystallization, the reversible martensitic transformation occurred with the highest enthalpy value—4 or 5 J/g after 120 and 140 h milling, respectively.

scholarly journals Biocompatibility of Nanoporous TiO2Coating on NiTi Alloy Prepared via Dealloying Method

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Jin Huang ◽  
Junqiang Wang ◽  
Xiangdong Su ◽  
Weichang Hao ◽  
Tianmin Wang ◽  
...  
Keyword(s):  
Low Temperature ◽  
Shape Memory ◽  
Biomedical Application ◽  
Niti Alloy ◽  
Treatment Method ◽  
Niti Shape Memory Alloy ◽  
Contact Method ◽  
Biological Compatibility ◽  
Before And After ◽  
Niti Shape Memory Alloys

This paper investigated the biocompatibility of nanoporous TiO2coating on NiTi shape-memory alloy (SMA) prepared via dealloying method. Our previous study shows that the dealloying treatment at low temperature leads to 130 nm Ni-free surface titania surface layer, which possesses good bioactivity because of the combination of hydroxyl (OH−) group in the process of dealloying treatment simultaneously. In this paper, the biological compatibility of NiTi alloy before and after dealloying treatment was evaluated and compared by direct contact method with dermal mesenchymal stem cells (DMSCs) by the isolated culture way. The interrelation between the biological compatibility and surface change of material after modification was systematically analyzed. As a consequence, the dealloying treatment method at low temperature could be of interest for biomedical application, as it can avoid sensitization and allergies and improve biocompatibility of NiTi shape-memory alloys. Thus it laid the foundation of the clinical trials for surface modification of NiTi memory alloy.

NiTi Shape Memory Alloy Used for Multiple-Resetting Actuator for Fire Protection

2017 ◽  
Vol 907 ◽  
pp. 8-13 ◽  
Author(s):  
Lucian Burlacu ◽  
Nicanor Cimpoeşu ◽  
Nicoleta Monica Lohan ◽  
Leandru Gheorghe Bujoreanu
Keyword(s):  
Thermal Analysis ◽  
Shape Memory Alloy ◽  
Shape Memory ◽  
Fire Protection ◽  
Room Temperature ◽  
Parent Phase ◽  
Niti Shape Memory Alloy ◽  
Scanning Calorimetry ◽  
Protection Systems ◽  
Executive Elements

The paper introduces the possibility to replace the “wet alloy”, used for sprinkler-triggering within automatic fire protection systems, with a shape memory alloy (SMA) type. The idea of the present application is based on the thermoelastic reversible martensitic transformation, governing SMA functioning, which has completely reversible character, and enables the occurrence of two-way shape memory effect (TWSME) after the application of a thermomechanical treatment called “training”. For this purpose a commercial NiTi rod, which was martensitic at room temperature, was subjected to thermal analysis tests, performed by differential scanning calorimetry (DSC) and dilatometry. Martensite (M) reversion to parent phase (A), during heating, was emphasized by an endothermic peak on the DSC thermogram and by a length shrinkage, on the dilatogram. The capacity to develop TWSME was revealed by the change in displacement-temperature variation, with increasing the number of training cycles. This stabilized fully reversible behavior recommends NiTi rods as executive elements of a new concept of resettable sprinkler for fire protection.

SHAPE MEMORY INVESTIGATION OF SMART CAMAR LOGO USING NITI ALLOY WIRE

2015 ◽  
Vol 76 (3) ◽  
Author(s):  
Muhammad Safwan Shuhaimi ◽  
Nubailah Abd. Hamid ◽  
Rosliza Razali ◽  
Muhammad Hussain Ismail
Keyword(s):  
Phase Transformation ◽  
Shape Memory ◽  
Shape Memory Effect ◽  
Memory Effect ◽  
Niti Alloy ◽  
Niti Shape Memory Alloy ◽  
Shape Effect ◽  
Niti Wire ◽  
The Wire ◽  
Reversible Phase

This project is investigates of NiTi shape memory alloy for simple smart application. The shape memory effect (SME) is attributed from the reversible phase transformation when subjected to stress and temperature. In this study, a small model of CAMAR logo was designed to mimic the shape memory effect. Three samples of wire were investigated; (i) Austenitic NiTi (ii) Martensitic NiTi and (iii) commercial plain carbon steel. The reversible austenite to martensite transformation of the NiTi wire was investigated by a differential scanning calorimetry (DSC) at temperatures ranging from -50 and 200oC. The wire was shaped into CAMAR logo using a mould and then heated at 500°C for 30 minutes in a high temperature furnace. To observe the shape effect recovery, the wire was straighten and reheated in warm water at different temperatures. Results showed that the austenitic wire exhibited complete shape memory recovery after heated at temperature approximately 35°C and  80°C. For the martensitic wire, complete recovery was only observed when the water temperature was ~ 80°C and no recovery was observed at ~30°C. This recovery effect was significantly influenced by the reversible phase transformation temperatures (PTTs) which attributed from the Austenite finish (Af) temperature.

Characterization of NiTi Shape Memory Alloy Sintered at Different Temperatures in Reducing Environment

2020 ◽  
Vol 1010 ◽  
pp. 632-637
Author(s):  
Hafizah Hanim Mohd Zaki ◽  
Nur Azemuzahir Mohd Sobri ◽  
Jamaluddin Abdullah ◽  
Norshahida Sariffudin ◽  
Farah Diana Mohd Daud
Keyword(s):  
Solid State ◽  
Shape Memory ◽  
Phase Formation ◽  
Single Phase ◽  
Reducing Agent ◽  
Niti Shape Memory Alloy ◽  
Transformation Behavior ◽  
Formidable Challenge ◽  
Different Temperatures ◽  
Reducing Environment

NiTi has received significant interest as medical implant materials due to its shape memory effect behavior apart from its good biocompatibility and mechanical properties. The formidable challenge of obtaining single phase NiTi from elemental powders via solid state is due to oxidation problem of elemental powders and the oxygen atoms dissolve in NiTi matrix as interstitial impurities forming stable oxygen-rich TiNiOx. This may deterioriate the shape memory behavior of NiTi. This research investigates the use of MgH2 in combination with CaH2 as in-situ reducing agent to eliminate oxidation of the specimen during sintering both at lower and higher sintering temperatures. Here, the effect of sintering temperature on phase formation and transformation behavior of NiTi in reducing environment was studied. The phase formation was characterized by using x-ray diffraction (XRD) where the morphology and elemental analysis were characterized by using the scanning electron microscope (SEM) equipped with EDS. The martensitic transformation behavior was analyzed using differential scanning calorimeter (DSC). The use of MgH2 and CaH2 as reducing agent has a significant influence on the phase formation of NiTi synthesized via solid state especially at 930 °C, where almost single phase NiTi was formed with good transformation behavior. This reducing agent creates a conducive environment for the production of single phase NiTi.

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