Flame retardant high-power Li-S flexible batteries enabled by bio-macromolecular binder integrating conformal fractions

Polymer binders for sulfur cathodes play a very critical role as they prerequisites for an in-situ immobilization against polysulfide shuttle and volume change, while ensuring good adhesion within active materials for ion conduction along with robust mechanical and chemical stability. Here, we demonstrate anionic surface charge facilitated bio-polymer binder for sulfur cathodes enabling excellent performance and fire safety improvement. The aqueous-processable tragacanth gum-based binder is adjusted to house high sulfur loading over 12 mg cm−2 without compromising the sulfur utility and reversibility, imparting high accessibility for Li-ions to sulfur particles about 80%. The intrinsic rod and sphere-like saccharidic conformal fraction’s multifunctional polar units act as active channels to reach the sulfur particles. As a result, the binder entraps polysulfides with 46% improvement and restrains the volume changes within 16 % even at 4 C. Moreover, the flexible Li-S battery delivers a stack gravimetric energy density of 243 Wh kg–1, demonstrating high reactivity of sulfur along with good shape conformality, which would open an avenue for the potential development of the compact and flexible high-power device.

Effect of foliar spray of micronutrients and hormones on cauliflower (Brassica oleracea var. botrytis L.)

In order to achieve optimal plant growth and production, essential nutrients must be readily available in adequate quantities and in a balanced proportion to give a good yield, especially cauliflower which has health benefits that may not be found in many other plants. For this purpose, this experiment was carried out during the seasons 2020-2021 in the on station of Bangladesh Agricultural Research Institute, Khulna under Smallholder Agricultural competitiveness project. Although the treatments showed a positive effect on yield, quality and economics but, T1 revealed most significant influence on all parameters under study as compared to T0 (control). For micronutrients and hormone, T1 treatment produced the highest curd yield (29.99 t ha-1) and the lowest (17.04 t ha-1) was control from the varietal effect the highest curd yield was (35.14 t ha-1) from V4 (It Amazuku 33) and the lowest was (16.21 t ha-1) from V5 (BARI Fulcopi-1). In case of combined effect, the highest curd yield (45.16 t ha-1) was obtained from T1V4 and the lowest curd yield (10.27 t ha-1) from T0V1. Therefore, it can be suggested that the highest curd yield and good shape cauliflower curd can be obtained application of Zn 8.83 kg/ha, B 3.5 kg/ha, Ma 8.43 kg/ha and Flora (Hormone) 2 ml/1 L of water. Therefore, foliar application of micronutrients and hormone is suitable way to feed the cauliflower crop to enhance the marketable yield and quality.

Freeform 3D Bioprinting Involving Ink Gelation by Cascade Reaction of Oxidase and Peroxidase: A Feasibility Study Using Hyaluronic Acid-Based Ink

Freeform bioprinting, realized by extruding ink-containing cells into supporting materials to provide physical support during printing, has fostered significant advances toward the fabrication of cell-laden soft hydrogel constructs with desired spatial control. For further advancement of freeform bioprinting, we aimed to propose a method in which the ink embedded in supporting materials gelate through a cytocompatible and rapid cascade reaction between oxidase and peroxidase. To demonstrate the feasibility of the proposed method, we extruded ink containing choline, horseradish peroxidase (HRP), and a hyaluronic acid derivative, cross-linkable by HRP-catalyzed reaction, into a supporting material containing choline oxidase and successfully obtained three-dimensional hyaluronic acid-based hydrogel constructs with good shape fidelity to blueprints. Cytocompatibility of the bioprinting method was confirmed by the comparable growth of mouse fibroblast cells, released from the printed hydrogels through degradation on cell culture dishes, with those not exposed to the printing process, and considering more than 85% viability of the enclosed cells during 10 days of culture. Owing to the presence of derivatives of the various biocompatible polymers that are cross-linkable through HRP-mediated cross-linking, our results demonstrate that the novel 3D bioprinting method has great potential in tissue engineering applications.

Thermoplastic Mandrel for Manufacturing Composite Components with Complex Structure

This study was to solve the mandrel demolding problem after curing the composite component with complex structure. In this paper, a reusable thermoplastic mandrel with heating softening characteristics was developed by resin transfer molding (RTM). The glass transition temperature (Tg), surface roughness, and reusability of the mandrel, as well as the shape, surface roughness, thickness uniformity, and internal quality of the formed structure, were tested. The result showed that the Tg of the mandrel was between 80 and 90 °C and the surface roughness was less than Ra 0.5 μm. Additionally, the mandrel can be recycled and can still maintain a good shape after 20 times of deformation. By using this method, the demolding process can be realized by heating and softening the mandrel. The profile error of the formed structure was within 0.5 mm, the surface roughness was less than Ra 0.5 μm, the thickness error was within 0.2 mm, and the average porosity of the upper and lower halves of composite parts was 0.72% and 0.61%. All those data showed that the formed part was in good shape and of good quality. The thermoplastic mandrel can solve the demolding problem of composite materials with complex shapes.

RANCANG BANGUN PROTOTYPE HYDRO TURBINE JENIS CROSS-FLOW UNTUK PERKOTAAN

The problem of fossil fuel crisis, both petroleum and coal, and the phenomenon of climatechange due to global warming, trigger the use of renewable energy that can overcome these problems.Cross-flow water turbine is one of the machine that can be used to produce small scale electric energy insmall scope. This turbine can be used in urban areas to assist industrial activities and their usefulness indaily life. The use of the right materials and strong construction can produce a good shape so that thiswater turbine is not only make efficient energy but also efficient and ergonomic in its use. This study isconducted theoretically to a cross-flow turbine which assumed to operate at 10m water height with 1.4L/s, outer diameter 150mm and 75mm thickness. The turbine consist of 15 blades with angle of attack ofthe blades is 30o. The results show that the turbine generate 119 Watt

Wearable Device Based on IoT in the Healthcare System for Disease Detection and Symptom Recognition

Humans in good shape face many challenges in their lives, such as food habits and climate change. The result must be aware of the health situation to survive. Lack of accurate patient information, preventive errors, data risks, overdiagnosis, and delayed implementation are challenges that health support services face. Wearable sensors that connect extensive data, data mining analysis for healthcare, and the Internet of things (IoT) have been proposed to solve this problem. This research, Disease Prediction and Symptom Recognition Model using IoT (DDSR-IoT) framework, is proposed for reasoning with regression rules to gather patient information. The Boltzmann network to train Artificial Intelligence (AI) feedback is introduced in the end. As a result, the broad interaction analysis of genomes is used to predict conditions. If those infections have affected people, emails are sent to warn them and provide them with prescriptions and medical advice. In the recommended approach, the experimental study resulted in an enhanced forecast rate of 97.4 percent and a precision of 97.42 percent.

Parliamentary Representation in Modern Britain: Past, Present, and Future

A series of recent books all attest to a revival of interest in the theory and practice of parliamentary representation in the modern era as a scholarly discipline. This review surveys eight different aspects of that history since the early nineteenth century: the spatial dimension of the Palace of Westminster; the comparative framework offered by the history of parliaments in Europe; ideas of parliamentary representation; the history of parliamentary procedure; women in parliament; the House of Lords; the history of corruption; and the Brexit crisis. Insights and perspectives are drawn from recent historical research as well as from political science and intellectual history. The review concludes by observing that the history of parliamentary representation in the modern era is in good shape. Some older interpretive paradigms still lurk, especially an obsession with ‘democratization’. However, more is now known about individual MPs and constituencies than ever before. The digitization of the records of parliament is expediting the kind of longitudinal analysis which was impossible back in the 1960s and 1970s. And the intellectual history and public policy literature around the idea of representation is enjoying a renaissance.

3D Printed Chitosan-Pectin Hydrogels: From Rheological Characterization to Scaffold Development and Assessment

Chitosan-pectin hydrogels were prepared, and their rheological properties were assessed in order to select the best system to develop scaffolds by 3D printing. Hydrogels showed a weak gel behavior with shear thinning flow properties, caused by the physical interactions formed between both polysaccharides, as observed by FTIR analysis. Since systems with high concentration of pectin showed aggregations, the system composed of 2 wt% chitosan and 2 wt% pectin (CHI2PEC2) was selected for 3D printing. 3D printed scaffolds showed good shape accuracy, and SEM and XRD analyses revealed a homogeneous and amorphous structure. Moreover, scaffolds were stable and kept their shape and size after a cycle of compression sweeps. Their integrity was also maintained after immersion in PBS at 37 °C, showing a high swelling capacity, suitable for exudate absorption in wound healing applications.

Body-Temperature Programmable Soft-Shape Memory Hybrid Sponges for Comfort Fitting

Porous shape memory hybrids are fabricated with different matrix (silicone) hardness and different inclusion (polycaprolactone, PCL) ratios. They are characterized to obtain their mechanical response to cyclic loads (with/without pre-straining/programming) and their shape memory performances after body-temperature programming are investigated. These materials are lightweight due to their porous structures. Wetted hydrogels used in the fabrication process for creating pores are reusable and hence this process is eco-friendly. These porous shape memory hybrids exhibit the good shape memory effect of around 90% with higher inclusion (PCL) ratios, which is better than the solid versions reported in the literature. Hence, it is concluded that these materials have great potential to be used in, for instance, insoles and soles for comfort fitting, as demonstrated.

Valorization of Recycled Tire Rubber for 3D Printing of ABS- and TPO-Based Composites

Vulcanized and devulcanized ground tire rubber microparticles have been used as a minor phase in acrylonitrile butadiene styrene copolymer (ABS) and thermoplastic polyolefins (TPO) for the development of materials with desired functionalities by 3D printing. These polymers have been selected because they (i) present part of the plastic waste generated by the automotive industry and (ii) have totally different properties (ABS for its stiffness and robustness and TPO for its softness and ductility). The study aims to improve the circular economy of the automotive industry by proposing a promising route for recycling the generated tire rubber waste. In this respect, emergent technology for plastic processing such as 3D printing is used, as part of the additive manufacturing technologies for the prolongated end of life of recycled plastics originated from automotive waste such as ABS and TPO. The obtained results revealed that (i) the composites are suitable for successful filament production with desired composition and diameter required for successful 3D printing by fused deposition modeling, and that (ii) the optimization of the composition of the blends allows the production of materials with interesting mechanical performances. Indeed, some of the investigated ABS-recycled rubber tire blends exhibit high impact properties as TPO-based composites do, which in addition exhibits elongation at break higher than 500% and good compression properties, accompanied with good shape recovery ratio after compression.