Sensitive, Non-Intrusive, In Situ Measurements of Plasma Electric Fields

1983 ◽  
Vol 29 ◽  
Author(s):  
Richard A Gottscho ◽  
Cameron A. Moore ◽  
Glenn P. Davis
Keyword(s):  
Electric Fields ◽  
High Spatial Resolution ◽  
Band System ◽  
Absolute Measurement ◽  
Laser Induced Fluorescence ◽  
Rf Discharge ◽  
Electrode Surfaces ◽  
Charged Particle Transport ◽  
A New Technique

ABSTRACTWe report a new technique for the in situ, non-intrusive, and sensitive measurement of plasma electric fields with high spatial resolution. Fields as small as 40 V/cm can be characterized by spectrally resolving laser-induced fluorescence from Stark-mixed parity levels. The technique is demonstrated by exciting the A1 11−X 1Σ+ band system of BC1, produced in an rf discharge through BCI3. The characterization and absolute measurement of sheath fields, which have been elusive, are now possible. These fields are preeminent in governing charged particle transport to and between electrode surfaces and in maintaining the glow discharge.

Continuum Modeling of Charged Particle Transport: RF Breakdown and Discharges of SF6

1986 ◽  
Vol 68 ◽  
Author(s):  
Brian E. Thompson ◽  
Herbert H. Sawun ◽  
Aaron Owens
Keyword(s):  
Electric Fields ◽  
Electron Attachment ◽  
Negative Ions ◽  
Rate Coefficients ◽  
Rf Discharge ◽  
Continuity Equations ◽  
Positive Ions ◽  
Discharge Model ◽  
Rf Breakdown ◽  
Charged Particle Transport

AbstractContinuity equations for the concentration of electrons, positive ions, and negative ions were constructed and solved to predict rf breakdown voltages and the electrical properties of SF, discharges.These balances for the three types of charged species include terms for convection (electric field-driven fluxes), diffusion, and reactions (ionization, electron attachment, and negative-positive ion recombination).The mobilities, diffusivities, and reaction rate coefficients necessary for the rf discharge model are based on reported measurements and calculations of these parameters in dc electric fields.The electric fields developed in the rf discharge are calculated from Poisson's equation and applied voltage conditions.Predictions based on this model are compared with measured rf breakdown characteristics of SF6.

AC Electrophoresis, a New Technique for Deposition of Ceramic Nanoparticles; Introduction, Application and Mechanism

2012 ◽  
Vol 507 ◽  
pp. 41-45 ◽  
Author(s):  
Reza Riahifar ◽  
Babak Raissi ◽  
Ehsan Marzbanrad ◽  
Cyrus Zamani
Keyword(s):  
Electric Fields ◽  
Applied Field ◽  
Aqueous Suspension ◽  
Mutual Effect ◽  
Device Fabrication ◽  
Frequency Range ◽  
Ceramic Nanoparticles ◽  
Ac Electric Fields ◽  
A New Technique

Deposition of ceramic nanoparticles (dispersed in non-aqueous suspension) on in-plane electrodes and under the influence of AC electric fields in the frequency range of 0.01 Hz - 10 kHz is investigated. Analysis of the particle response to the applied field is a difficult task due to the mutual effect of electric and hydrodynamic forces which are present in the system. In this work, however, we show the possibility of dividing the frequency range into four domains with four distinct governing mechanisms. Possible mechanisms are suggested and dominant forces are determined for each domain. In situ optical microscopy observations are used for visualization of nanoparticles´ movement dispersed in liquid medium. These observations show that applying AC electrophoresis at frequencies below 10 kHz is an effective way for manipulating ceramic nanoparticles and device fabrication.

Quantitative In-Situ Measurement of Asperity Compression During Chemical Mechanical Planarization

2005 ◽  
Author(s):  
Caprice Gray ◽  
Daniel Apone ◽  
Chris Rogers ◽  
Vincent P. Manno ◽  
Chris Barns ◽  
...  
Keyword(s):  
Film Thickness ◽  
Spatial Resolution ◽  
High Spatial Resolution ◽  
Chemical Mechanical Planarization ◽  
Laser Induced Fluorescence ◽  
Calibration Factor ◽  
Dual Emission ◽  
Image Intensity ◽  
Slurry Layer

Modifications to the Dual Emission Laser Induced Fluorescence (DELIF) procedure used to collect images of the slurry layer between the polishing pad and wafer during Chemical Mechanical Planarization (CMP) have provided a means to attain instantaneous, high spatial resolution images of slurry film thickness. Presented here is a technique to determine the calibration factor that correlates image intensity to slurry film thickness. This presentation will discuss how to determine slurry layer shape near wafer features, pad roughness, and pad compressibility.

scholarly journals Tuning Single-Molecule Conductance by Controlled Electric Field-Induced trans-to-cis Isomerisation

2021 ◽  
Vol 11 (8) ◽  
pp. 3317
Author(s):  
C.S. Quintans ◽  
Denis Andrienko ◽  
Katrin F. Domke ◽  
Daniel Aravena ◽  
Sangho Koo ◽  
...  
Keyword(s):  
Electric Field ◽  
Electric Fields ◽  
Single Molecule ◽  
Quantum Interference ◽  
Single Molecule Level ◽  
Wet Chemical Synthesis ◽  
Single Molecule Junctions ◽  
Tunnelling Microscopy ◽  
The Difference

External electric fields (EEFs) have proven to be very efficient in catalysing chemical reactions, even those inaccessible via wet-chemical synthesis. At the single-molecule level, oriented EEFs have been successfully used to promote in situ single-molecule reactions in the absence of chemical catalysts. Here, we elucidate the effect of an EEFs on the structure and conductance of a molecular junction. Employing scanning tunnelling microscopy break junction (STM-BJ) experiments, we form and electrically characterize single-molecule junctions of two tetramethyl carotene isomers. Two discrete conductance signatures show up more prominently at low and high applied voltages which are univocally ascribed to the trans and cis isomers of the carotenoid, respectively. The difference in conductance between both cis-/trans- isomers is in concordance with previous predictions considering π-quantum interference due to the presence of a single gauche defect in the trans isomer. Electronic structure calculations suggest that the electric field polarizes the molecule and mixes the excited states. The mixed states have a (spectroscopically) allowed transition and, therefore, can both promote the cis-isomerization of the molecule and participate in electron transport. Our work opens new routes for the in situ control of isomerisation reactions in single-molecule contacts.

scholarly journals In-situ measurements of wave electric fields in the equatorial electrojet

1982 ◽  
Vol 9 (6) ◽  
pp. 688-691 ◽  
Author(s):  
R. F. Pfaff ◽  
M. C. Kelley ◽  
B. G. Fejer ◽  
N. C. Maynard ◽  
K. D. Baker
Keyword(s):  
Electric Fields ◽  
Equatorial Electrojet ◽  
In Situ Measurements

scholarly journals An in situ study of reconstructed gold electrode surfaces by second harmonic generation

1989 ◽  
Vol 163 (2-3) ◽  
pp. 123-128 ◽  
Author(s):  
A. Friedrich ◽  
B. Pettinger ◽  
D.M. Kolb ◽  
G. Lüpke ◽  
R. Steinhoff ◽  
...  
Keyword(s):  
Second Harmonic Generation ◽  
Harmonic Generation ◽  
Gold Electrode ◽  
Second Harmonic ◽  
Electrode Surfaces ◽  
In Situ Study

scholarly journals Voltammetry and molecular assembly of G-quadruplex DNAzyme on single-crystal Au(111)-electrode surfaces – hemin as an electrochemical intercalator

2016 ◽  
Vol 193 ◽  
pp. 99-112 ◽  
Author(s):  
Ling Zhang ◽  
Jens Ulstrup ◽  
Jingdong Zhang
Keyword(s):  
Single Crystal ◽  
Single Molecule ◽  
Electrode Surface ◽  
Molecular Assembly ◽  
Electrode Surfaces ◽  
Potential Control ◽  
G Quadruplex ◽  
Tunnelling Microscopy ◽  
Dna Quadruplexes

DNA quadruplexes (qs) are a class of “non-canonical” oligonucleotides (OGNs) composed of stacked guanine (G) quartets stabilized by specific cations. Metal porphyrins selectively bind to G-qs complexes to form what is known as DNAzyme, which can exhibit peroxidase and other catalytic activity similar to heme group metalloenzymes. In the present study we investigate the electrochemical properties and the structure of DNAzyme monolayers on single-crystal Au(111)-electrode surfaces using cyclic voltammetry and scanning tunnelling microscopy under electrochemical potential control (in situ STM). The target DNAzyme is formed from a single-strand OGN with 12 guanines and iron(iii) porphyrin IX (hemin), and assembles on Au(111) through a mercapto alkyl linker. The DNAzyme monolayers exhibit a strong pair of redox peaks at 0.0 V (NHE) at pH 7 in acetate buffer, shifted positively by about 50 mV compared to free hemin weakly physisorbed on the Au(111)-electrode surface. The voltammetric hemin signal of DNAzyme is enhanced 15 times compared with that of hemin adsorbed directly on the Au(111)-electrode surface. This is indicative of both the formation of a close to dense DNAzyme monolayer and that hemin is strongly bound to the immobilized 12G-qs in well-defined orientation favorable for interfacial ET with a rate constant of 6.0 ± 0.4 s−1. This is supported by in situ STM which discloses single-molecule G-quartet structures with a size of 1.6 ± 0.2 nm.

Fim/Iap/Tem Studies of Ion Implanted Nickel Emitters

1984 ◽  
Vol 41 ◽  
Author(s):  
S. D. Walck ◽  
J. J. Hren
Keyword(s):  
Electric Fields ◽  
Depth Profiling ◽  
Atom Probe ◽  
Hydrogen Trapping ◽  
Transmission Electron ◽  
Microscope Imaging ◽  
Important Field ◽  
High Electric Fields ◽  
Field Ion Microscope

AbstractAccurate depth profiling of implanted hydrogen and its isotopes in metals is extremely important. Field ion microscopy and atom-probe techniques provide the most accurate depth profiling analytical method of any available. In addition, they are extremely sensitive to hydrogen. This paper reports our early work on hydrogen trapping at defects in metals using the Field Ion Microscope/Imaging Atom Probe (FIM/IAP). Our results deal primarily with the control experiments required to overcome instrumental difficulties associated with in situ implantation and the influence of a high electric field. Transmission Electron Microscopy (TEM) has been used extensively to independently examine the influence of high electric fields on emitters.

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