Prediction of Silicide Formation Sequence from the Principle of the Largest Free Energy Degradation Rate

1993 ◽  
Vol 311 ◽  
Author(s):  
Lin Zhang ◽  
Douglas G. Ivey
Keyword(s):  
Free Energy ◽  
Kinetic Model ◽  
Degradation Rate ◽  
Diffusion Flux ◽  
Experimental Results ◽  
Silicide Formation ◽  
Change Rate ◽  
Energy Degradation ◽  
Generalized Kinetic Model ◽  
Good Agreement

ABSTRACTRecently, a generalized kinetic model for silicide formation has been developed and a principle of the largest free energy degradation rate (largest FEDR) has been proposed. Free energy change rate as a function of diffusion flux has been derived from the kinetic model so that the principle can be justified not only for first phase formation but also for the subsequent processes. Silicide formation sequence predictions, from the model and the FEDR principle, for 15 metal-Si systems have shown very good agreement with the experimental results reported in the literature. In this paper, a brief introduction to the model and the principle is given, followed by examples of the predictions for several metal-Si systems and comparison with experimental results.

A New Kinetic Model for The Nucleation and Growth of Self-Interstitial Clusters in Silicon

2001 ◽  
Vol 669 ◽  
Author(s):  
Christophe J. Ortiz ◽  
Daniel Mathiot
Keyword(s):  
Kinetic Model ◽  
Inverse Modeling ◽  
Nucleation And Growth ◽  
Experimental Results ◽  
Physical Parameters ◽  
Formation Energies ◽  
Good Agreement

ABSTRACTA model for nucleation and growth of {311} defects is proposed on the basis of thermodynamic and kinetic considerations. Simulated results are discussed and compared to experimental results found in the literature. According to our model it is found that formation energies of self-interstitial clusters depends on the local interstitial supersaturation. Physical parameters extracted from experimental results by inverse modeling are in good agreement with recent values published in the literature.

The Coarsening of Dendrite Arm Spacing during Solidification of Al-Cu-Mn Alloy

2011 ◽  
Vol 239-242 ◽  
pp. 2029-2033 ◽  
Author(s):  
Zhi He
Keyword(s):  
Boundary Layer ◽  
Diffusion Flux ◽  
Experimental Results ◽  
Simplified Model ◽  
Back Diffusion ◽  
Secondary Dendrite Arm Spacing ◽  
Dendrite Arm Spacing ◽  
Solute Boundary Layer ◽  
Good Agreement

A secondary dendrite arm spacing coarsening model for multi-component alloy is proposed, where the back diffusion flux in solid is simplified by introducing the parameter of solute boundary layer,δi. The simplified model was applied to the predication of the secondary arm spacing of directional solidified Al-Cu-Mn alloy. The good agreement between the experimental results and the calculated lines shows that this simplified model is satisfactory for the prediction of dendrite arm coarsening during solidification in multi-component alloys.

Inducing Frictional Force to Enhance the Transient Response in Beams

2019 ◽  
Vol 22 (2) ◽  
pp. 88-93
Author(s):  
Hamed Khanger Mina ◽  
Waleed K. Al-Ashtrai
Keyword(s):  
Numerical Analysis ◽  
Transient Response ◽  
Frictional Force ◽  
Damping Ratio ◽  
Experimental Results ◽  
Damping Capacity ◽  
Tightening Force ◽  
Contact Areas ◽  
Good Agreement ◽  
Ansys Workbench

This paper studies the effect of contact areas on the transient response of mechanical structures. Precisely, it investigates replacing the ordinary beam of a structure by two beams of half the thickness, which are joined by bolts. The response of these beams is controlled by adjusting the tightening of the connecting bolts and hence changing the magnitude of the induced frictional force between the two beams which affect the beams damping capacity. A cantilever of two beams joined together by bolts has been investigated numerically and experimentally. The numerical analysis was performed using ANSYS-Workbench version 17.2. A good agreement between the numerical and experimental results has been obtained. In general, results showed that the two beams vibrate independently when the bolts were loosed and the structure stiffness is about 20 N/m and the damping ratio is about 0.008. With increasing the bolts tightening, the stiffness and the damping ratio of the structure were also increased till they reach their maximum values when the tightening force equals to 8330 N, where the structure now has stiffness equals to 88 N/m and the damping ratio is about 0.062. Beyond this force value, increasing the bolts tightening has no effect on stiffness of the structure while the damping ratio is decreased until it returned to 0.008 when the bolts tightening becomes immense and the beams behave as one beam of double thickness.

Nitrate and chloride formation in chloramination

1994 ◽  
Vol 30 (9) ◽  
pp. 101-110
Author(s):  
V. Diyamandoglu
Keyword(s):  
Kinetic Model ◽  
Analytical Method ◽  
Kinetic Data ◽  
Experimental Results ◽  
Mass Balances ◽  
Time Profiles ◽  
Slow Decay ◽  
Concentration Time ◽  
End Products ◽  
Chlorine Residuals

The formation of nitrate and chloride as end-products of chloramination (combined chlorination) was investigated at pH ranging between 6.9 and 9.6 at 25°C. The experimental results comprised concentration-time profiles of combined chlorine residuals along with nitrate and chloride. Nitrite, if present, was always below the detectibility limit of the analytical method used (25 ppb). Mass balances on chlorine species depicted that chloride formed during the slow decay of combined chlorine residuals does not account for all the chlorine lost. This substantiates the formation of other reaction end-products which are yet to be identified. A kinetic model for chloramination is proposed based on the kinetic data obtained in this study.

Diffusion model for deposition of epitaxial GaAs layers prepared by the MOCVD method

1991 ◽  
Vol 56 (10) ◽  
pp. 2020-2029
Author(s):  
Jindřich Leitner ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma ◽  
Rudolf Hladina
Keyword(s):  
Experimental Data ◽  
Growth Rate ◽  
Kinetic Model ◽  
Gas Phase ◽  
Substrate Surface ◽  
Deposition Process ◽  
Hydrogen Atmosphere ◽  
Epitaxial Gaas ◽  
Kinetics Of ◽  
Good Agreement

The authors proposed and treated quantitatively a kinetic model for deposition of epitaxial GaAs layers prepared by reaction of trimethylgallium with arsine in hydrogen atmosphere. The transport of gallium to the surface of the substrate is considered as the controlling process. The influence of the rate of chemical reactions in the gas phase and on the substrate surface on the kinetics of the deposition process is neglected. The calculated dependence of the growth rate of the layers on the conditions of the deposition is in a good agreement with experimental data in the temperature range from 600 to 800°C.

PHOTOINDUCED NONLINEAR OCTUPOLAR POLARIZATION: TRANSIENT AND PERMANENT REGIMES

1996 ◽  
Vol 05 (04) ◽  
pp. 653-670 ◽  
Author(s):  
CÉLINE FIORINI ◽  
JEAN-MICHEL NUNZI ◽  
FABRICE CHARRA ◽  
IFOR D.W. SAMUEL ◽  
JOSEPH ZYSS
Keyword(s):  
Theoretical Analysis ◽  
Second Harmonic ◽  
Experimental Results ◽  
Polar Field ◽  
Rotational Spectrum ◽  
Dual Frequency ◽  
One Dimensional ◽  
Ethyl Violet ◽  
Disperse Red 1 ◽  
Good Agreement

An original poling method using purely optical means and based on a dual-frequency interference process is presented. We show that the coherent superposition of two beams at fundamental and second-harmonic frequencies results in a polar field with an irreducible rotational spectrum containing both a vector and an octupolar component. This enables the method to be applied even to molecules without a permanent dipole such as octupolar molecules. After a theoretical analysis of the process, we describe different experiments aiming at light-induced noncentrosymmetry performed respectively on one-dimensional Disperse Red 1 and octupolar Ethyl Violet molecules. Macroscopic octupolar patterning of the induced order is demonstrated in both transient and permanent regimes. Experimental results show good agreement with theory.

scholarly journals Comparison of Experimental and Numerical Transient Drop Deformation during Transition through Orifices in High-Pressure Homogenizers

2021 ◽  
Vol 5 (3) ◽  
pp. 32
Author(s):  
Benedikt Mutsch ◽  
Peter Walzel ◽  
Christian J. Kähler
Keyword(s):  
High Pressure ◽  
Visual Analysis ◽  
Imaging Technique ◽  
Extensional Flow ◽  
Droplet Breakup ◽  
Experimental Results ◽  
Drop Deformation ◽  
Droplet Deformation ◽  
Shadow Imaging ◽  
Good Agreement

The droplet deformation in dispersing units of high-pressure homogenizers (HPH) is examined experimentally and numerically. Due to the small size of common homogenizer nozzles, the visual analysis of the transient droplet generation is usually not possible. Therefore, a scaled setup was used. The droplet deformation was determined quantitatively by using a shadow imaging technique. It is shown that the influence of transient stresses on the droplets caused by laminar extensional flow upstream the orifice is highly relevant for the droplet breakup behind the nozzle. Classical approaches based on an equilibrium assumption on the other side are not adequate to explain the observed droplet distributions. Based on the experimental results, a relationship from the literature with numerical simulations adopting different models are used to determine the transient droplet deformation during transition through orifices. It is shown that numerical and experimental results are in fairly good agreement at limited settings. It can be concluded that a scaled apparatus is well suited to estimate the transient droplet formation up to the outlet of the orifice.

Simulation of Sphere’s Motion Induced by Shock Waves

2012 ◽  
Vol 134 (10) ◽  
Author(s):  
Dan Igra ◽  
Ozer Igra ◽  
Lazhar Houas ◽  
Georges Jourdan
Keyword(s):  
Shock Waves ◽  
Drag Coefficient ◽  
Drag Force ◽  
Stationary Flow ◽  
Experimental Results ◽  
Experimental Findings ◽  
Sphere Drag ◽  
Simulation Scheme ◽  
Good Agreement

Simulations of experimental results appearing in Jourdan et al. (2007, “Drag Coefficient of a Sphere in a Non-Stationary Flow: New Results,”Proc. R. Soc. London, Ser. A, 463, pp. 3323–3345) regarding acceleration of a sphere by the postshock flow were conducted in order to find the contribution of the various parameters affecting the sphere drag force. Based on the good agreement found between present simulations and experimental findings, it is concluded that the proposed simulation scheme could safely be used for evaluating the sphere’s motion in the postshock flow.

Viscoelastic Deformation of PC/ABS Alloy

2007 ◽  
Vol 353-358 ◽  
pp. 1229-1232
Author(s):  
Z.N. Yin ◽  
L.F. Fan ◽  
Tie Jun Wang
Keyword(s):  
Dynamic Mechanical Analysis ◽  
Relaxation Modulus ◽  
Mechanical Analysis ◽  
Experimental Results ◽  
Viscoelastic Deformation ◽  
Dynamic Mechanical ◽  
Storage And Loss Moduli ◽  
Static Relaxation ◽  
Comparison Of The Results ◽  
Good Agreement

Dynamic Mechanical Analysis (DMA) and static relaxation tests are carried out to study the viscoelastic deformation of PC/ABS alloy with blending ratio of PC to ABS being 50/50. A modified approach is developed to calculate the relaxation modulus of PC/ABS alloy from the DMA experimental results of storage and loss moduli. Comparison of the results obtained from DMA and static relaxation tests is presented and good agreement is found.

Influence of the Morphology on the Optical Properties of Nanocermet Films: A Renormalization Approach

1990 ◽  
Vol 195 ◽  
Author(s):  
S. Berthier ◽  
K. Driss-Khodja
Keyword(s):  
Optical Properties ◽  
Critical Exponents ◽  
Inhomogeneous Media ◽  
Experimental Results ◽  
Percolation Transition ◽  
Position Space ◽  
Renormalization Approach ◽  
2D And 3D ◽  
Good Agreement ◽  
Effective Medium Models

ABSTRACTIn order to take into account the actual morphology of the inhomogeneous media, we have developed, effective medium models based on a 2D and 3D position space renormalization /1,2/. These models predict the dipolar resonance and the percolation transition with critical exponents in good agreement with theoretical values and fairly reproduce most of the experimental results, whatever the concentration is. Further more, this allows a valuable comparison of the predictions of our models when applied on different lattices like real digitized TEM of cermet films or randomly occupied lattices.

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