scholarly journals The concentration and health risk of potentially toxic elements in black and green tea—both bagged and loose-leaf

2020 ◽  
Vol 12 (3) ◽  
pp. 140-150
Author(s):  
Ali Heshmati ◽  
Freshteh Mehri ◽  
Javad Karami-Momtaz ◽  
Amin Mousavi Khaneghah

The concentration of potentially toxic elements (PTEs), including lead (Pb), cadmium (Cd), arsenic (As), zinc (Zn), and copper (Cu), among 160 samples of black and green tea—both bagged and loose-leaf—in Iran was determined using a graphite furnace atomic absorption spectrophotometer (GF-AAS). Besides, the transfer rate of PTEs from made tea into tea infusion was investigated, and the related health risk for consumers was assessed. According to the results, the content of the PTEs is dependent on the type of tea (black or green), the place of cultivation (Iran or India), and the supplied form (both bagged and loose-leaf). The concentration of Pb, Cd, and As in green tea was significantly lower than black tea (P-value < 0.05). On the other hand, the contents of Zn and Cu in green tea were higher than the corresponding values for black tea. The mean concentration of Pb, As, and Zn in bagged tea samples was significantly higher than those of loose-leaf tea, while the Cd and As levels in Iranian tea samples were significantly lower than the Indian samples. Generally speaking, the mean concentration of Pb, Cd, As, Zn, and Cu were 0.59 ± 0.12, 0.12 ± 0.06, 0.16 ± 0.12, 14.23 ± 4.90, and 11.10 ± 2.49 mg kg?1, respectively. The mean transfer rates of Pb, Cd, As, Zn, and Cu were 7.78, 6.29, 9.27, 12.91, and 13.08%, respectively. The estimated daily intake (EDI) and noncarcinogenic quotient (target hazard quotient [THQ]) due to the ingestion of PTEs besides the carcinogenic risk of As and Cd were considered as acceptable.

2021 ◽  
Vol 11 (15) ◽  
pp. 7023
Author(s):  
Vannini Andrea ◽  
Martina Grattacaso ◽  
Giulia Canali ◽  
Francesco Nannoni ◽  
Luigi Antonello Di Lella ◽  
...  

The aim of this study was to provide, for the first time, data on the concentration of potentially toxic elements (PTEs) in soils and bulbs of elephant garlic (Allium ampeloprasum L.) cultivated in Valdichiana, a traditional agricultural area of Tuscany, Italy. Bulbs of elephant garlic and soil samples were collected in four cultivation fields and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to determine the concentrations of As, Cd, Co, Cr, Cu, Ni, Pb, Sb, Tl, U, V, Zn. The concentrations of these PTEs in bulbs and cultivation soils were used to calculate geochemical, ecological and health risk indices. The results of this study suggest that, although bulbs of elephant garlic from the Valdichiana area may present slightly high concentrations of Cd, Ni and Pb, the associated health risk based on the daily intake is absolutely negligible. Cultivation soils had somewhat high Cu concentrations probably due to the diffuse use of Cu-based products in agriculture, but showed overall a very low ecological risk.


2020 ◽  
pp. 371-376
Author(s):  
Monika Mania ◽  
Małgorzata Rebeniak ◽  
Oksana Orshulyak ◽  
Jacek Postupolski

Background. Cereal grains and their products are among the basic components of the diet all over the world. Their consumption varies depending on the dietary habits in each country. Apart from ingredients valuable from a health point of view, these products can also be a source of contaminants. The European Food Safety Authority (EFSA) included these foodstuffs in the group of main contributors to the dietary exposure to nickel by different groups of the population. Objective. The aim of the studies was to determine the nickel content in cereal grains and selected cereal products commercially available in Poland and to assess the exposure of consumers to nickel intake with these foodstuffs. Material and methods. A total of 56 samples of cereal grain and cereal products from trade were tested. Nickel content was determined after microwave mineralization of the samples by atomic absorption spectrometry with a graphite furnace atomization (GFAAS). The estimated exposure for the different groups of the population was assessed and compared with the Tolerable Daily Intake (TDI) value established by the European Food Safety Authority based on an updated risk assessment at 13 μg/kg body weight (b.w.) per day. Results. The mean (MB) and 95th percentile (MB) nickel content in investigated samples of cereal grains and their products were 0.66 mg/kg and 1.93 mg/kg. The mean content of Ni in the analyzed samples of grains was 1.16 mg/kg. Obtained results in this group of products ranged from 0.10 mg/kg for rye to 4.80 mg/kg for millet. In the group of grain products, the mean (MB) concentration of nickel was 0.61 mg/kg (95th percentile (MB) 1.84 mg/kg). The highest nickel level was determined in the samples of bran, groats, and flakes compared to other grain-based products. The highest content of Ni in the group of cereal products was found in the samples of roasted buckwheat 1.81 mg/kg and oat flakes 2.53 mg/kg. Significantly lower nickel content was observed in barley groats as well as for pasta and flour. The estimated average exposure of adults and children to nickel intake with grains and grain-based products ranged from 1.1% to 13.4% of TDI and it does not pose a health risk for consumers. Conclusions. Based on the obtained results, it was found that the nickel content in the tested samples of cereals and their products does not pose a health risk, even though the contamination of individual samples was significant.


Author(s):  
A. I. Yaradua ◽  
A. J. Alhassan ◽  
A. Nasir ◽  
K. I. Matazu ◽  
A. Usman ◽  
...  

This study was conducted to determine the heavy metals concentration in Hibiscus leaves cultivated in Katsina State Nigeria. The objectives were mainly to detect the presence of heavy metals in the cultivated Hibiscus leaves in the study area, compare the concentration of heavy metals in samples in relation to the permissible limits specified by WHO/FAO/USEPA Standards. Samples of cultivated Hibiscus leaves were collected in the year 2017 from the selected area.  Analysis for the concentration of these heavy metals; Cr, Cd, Fe, Ni, Mn, Pb and Zn was conducted by the use of AAS (by Atomic Absorption Spectrophotometry) method. The health risks to the local inhabitants from the consumption of the samples were evaluated based on the Target Hazard Quotient (THQ). The possibility of cancer risks for the adult and children population through intake of carcinogenic heavy metals in the samples was estimated using the Incremental Lifetime Cancer Risk (ILCR). Results from this study shows that with the exception of Pb with mean concentration of (0.508-0.978), the mean concentration (mg/kg) range values of Cr (0.135-0.261), Cd (0.042-0.051), Fe (0.684-0.978) and Zn (1.048-1.208) in the samples were generally lower than the USEPA, WHO/FAO maximum permissive limits. The results have indicated that the estimated daily intake (EDI) of the heavy metals were lower than the tolerable daily intake limit set by the USEPA in both samples and the health risk index (HRI) for all the heavy metals were <1. The target hazard quotient (THQ) for the samples for both the adult and children population was in the decreasing order of Zn>Pb>Fe>Cr>Cd. ILCR for Cd is below the threshold risk limit (>10−5) and ILCR for Pb reached the moderate risk limit (>10−3) in all the studied samples in adults, While in children ILCR for both Pb and Cd in samples from Dabai, Daura, Funtua, Matazu and Zango for all samples have reached the moderate risk limit (>10−3), while the ILCR for Pb in samples from Birchi, Dutsinma, Kafur, Katsina and Malunfashi were beyond the moderate risk level (>10−2). The sampling area trend of risk for developing cancer as a result of consuming the studied samples showed: Funtua > Daura > Dutsinma > Katsina > Malunfashi > Matazu > Zango > Ingawa > Kafur > Dabai > Birchi for both adult and children, cumulative cancer risk (∑ILCR) of all the studied Hibiscus samples have reached the moderate risk limit (>10−3) in adult. While in children with the exception of the sample from Birchi, Dabai and Kafur which are within the moderate cancer risk (>10−3) limit, all other samples were beyond the moderate cancer risk (>10−2) limit. The study suggests that consumption of the studied samples in Katsina state is of public health concern as they may contribute to the population cancer burden. 


2021 ◽  
Author(s):  
Hanbing Bao ◽  
Yan Song ◽  
Yujing Zhou ◽  
Haixia Sui ◽  
Ling Yong ◽  
...  

Abstract Background Rare earth element (REE) have been considered to have potential effects on human health. However, little is known about the health risk of REEs exposure among tea drinkers in China. Objectives To characterize the concentration of REEs in different categories of tea and assess the health risk of REEs of tea consumers in China. Methods 4326 tea samples(including oolong tea, dark tea, black tea, white tea, green tea and flowering tea from markets of 24 provinces, autonomous regions and municipalities in China, were analyzed for sixteen kinds of rare earth elements. Combining the REE concentration data with tea consumption data, derived from the China National Food Consumption Survey 2013–2014, the REE exposure level through tea for adults was estimated. Calculate the hazard quotient, and judge the health risk of the population based on the result value Results The average concentrations of rare earth elements in Oolong tea and black tea were the highest (1611.8µg/kg and 1435.2µg/kg), and in green tea and flower tea were the lowest (735.1µg/kg and 564.1µg/kg). The content values of light rare earth elements (LREEs) were dominant in 94.53% of tea samples, cerium (431.5µg/kg) was the most abundant, followed by lanthanum (267.3µg/kg). The average daily dose of REEs in tea intake for Chinese adults was 0.0328µg/kg BW. There are statistical differences in REEs exposure among different genders of tea drinkers(p < 0.001). The average daily intake of REEs in tea was highest in men aged 40–60 (mean: 0.0383µg/kg BW, P95: 0.1421µg/kg BW), but did not exceed the acceptable daily intake (51.5µg/kg BW). Conclusions Our study suggested the health risk of REEs exposure from tea is low in tea consumers in China.


2019 ◽  
Vol 83 (1) ◽  
pp. 101-107 ◽  
Author(s):  
ALI HESHMATI ◽  
FERESHTEH MEHRI ◽  
JAVAD KARAMI-MOMTAZ ◽  
AMIN MOUSAVI KHANEGHAH

ABSTRACT The concentration of cadmium (Cd) and lead (Pb) in vegetable (potatoes, onions, tomatoes, lettuce, leeks, and carrots) and cereal (wheat and rice) samples collected from Iran were investigated by a graphite furnace atomic absorption spectrophotometer. In addition, we determined the health risks due to exposure to Cd and Pb through vegetable and cereal consumption by computing the estimated daily intake, the target hazard quotient (THQ), the total THQ, and the margin of exposure. The mean concentrations of Pb in potato, onion, tomato, lettuce, leek, carrot, wheat, and rice samples were measured as 0.029 ± 0.011, 0.016 ± 0.012, 0.007 ± 0.005, 0.022 ± 0.020, 0.040 ± 0.048, 0.029 ± 0.025, 0.123 ± 0.120, and 0.097 ± 0.059 mg kg−1 wet weight, respectively, and all were below the maximum allowable concentrations set by the European Union. The mean concentrations of Cd in potatoes, onions, tomatoes, lettuce, leeks, carrots, wheat, and rice samples were measured as 0.022 ± 0.013, 0.011 ± 0.009, 0.003 ± 0.003, 0.007 ± 0.005, 0.015 ± 0.024, 0.013 ± 0.011, 0.046 ± 0.043, and 0.049 ± 0.04 mg kg−1 wet weight, respectively, and all were below the permissible levels established by the European Union. The corresponding values for the estimated daily intake of Cd were acceptable and lower than the provisional tolerable daily intake. The THQ and total THQ values of Cd through consumption of all vegetables and cereals were lower than 1. The margin of exposure values for Pb in samples were &gt;1, showing no significant human health risks for both potentially toxic elements. The findings of this study indicated there is no risk associated with exposure to Pb and Cd through the intake of selected vegetables and cereals in western Iran. HIGHLIGHTS


Foods ◽  
2019 ◽  
Vol 8 (8) ◽  
pp. 330 ◽  
Author(s):  
David Romero-Estévez ◽  
Gabriela S. Yánez-Jácome ◽  
Karina Simbaña-Farinango ◽  
Hugo Navarrete

In this study, cadmium (Cd), nickel (Ni), and lead (Pb) contents were analyzed in sixteen banana composite samples from different commercial establishments from eleven Ecuadorian production provinces using graphite furnace atomic absorption spectrophotometry. The concentrations (fresh weight) in the samples collected (9.3–47.3 μg·kg−1 for Cd, 16.1–105.6 μg·kg−1 for Ni, and 36.9–538.0 μg·kg−1 for Pb) were used to calculate the estimated daily intake (EDI), target hazard quotient (THQ), and target carcinogenic risk (CR) associated with dietary exposure to these potentially toxic metals. Cd and Ni results showed that every sample had EDIs lower than the oral reference dose and THQ values lower than 1, demonstrating that there was no non-carcinogenic risk related to the exposure to Cd and Ni. In the case of Pb, two EDIs results were higher than the reference dose, also their corresponding THQ values were higher than 1. The lead CR in all samples was less than 1 × 10−4, the upper limit used for acceptable cancer risk. Thus, there is no significant health risk to the consumer associated with bananas with contamination levels of Cd, Ni, but there is Pb risk for toddlers (12 kg of body weight) intake comparable to the one detected in the present study.


2020 ◽  
Vol 2020 ◽  
pp. 1-7
Author(s):  
K. Pakshir ◽  
Z. Mirshekari ◽  
H. Nouraei ◽  
Z. Zareshahrabadi ◽  
K. Zomorodian ◽  
...  

The fungal contamination and total aflatoxins (AF) and ochratoxin A (OTA) of tea samples were examined. A total of 60 tea samples were extracted and treated with immunoaffinity columns. The amount of AF and OTA were determined by using high-performance liquid chromatography (HPLC) with a fluorescence detector (FD). Tea samples were cultured and the fungi were identified. The results showed that 24 (40%) samples were contaminated with AFs and none of the tea samples were above the acceptable limit of AFs (≥10 μg/kg). All of the samples were contaminated with OTA where only 3 black tea samples (6.6%) and 1 green tea sample (6.7%) were detected to have more than the standard limits of toxin (10 μg·kg−1). The mean concentration of OTA in the black tea was higher than green tea. Aspergillus niger was the predominant fungi isolated from black and green tea samples. Considering the high contamination of mycotoxins in tea samples, regular monitoring in the tea process for improving quality is recommended.


Author(s):  
Patricia Rojas ◽  
Elizabeth Ruiz-Sánchez ◽  
Camilo Ríos ◽  
Ángel Ruiz-Chow ◽  
Aldo A. Reséndiz-Albor

The use of the medicinal plant Ginkgo biloba has increased worldwide. However, G. biloba is capable of assimilating both essential and toxic metals, and the ingestion of contaminated products can cause damage to health. The aim of this study was to investigate the safety of manganese (Mn), copper (Cu), lead (Pb), arsenic (As), and cadmium (Cd) in 26 items containing Ginkgo biloba (pharmaceutical herbal products, dietary supplements, and traditional herbal remedies) purchased in the metropolitan area of Mexico City. Metal analysis was performed using a graphite furnace atomic absorption spectrometer. All of the products were contaminated with Pb, 54% of them with As, and 81% with Cd. The lowest values of Pb, As, and Cd were detected in pharmaceutical herbal products > dietary supplements > traditional herbal remedies. The daily intake dose (DID) of pharmaceutical herbal products was within the established limits for the five metals. Dietary supplements and traditional herbal remedies exceeded the DID limits for Pb. The hazard quotients estimation and non-carcinogenic cumulative hazard estimation index for Mn, As, and Cd indicated no human health risk. Our results suggest that products containing G. biloba for sale in Mexico are not a health risk.


Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 613
Author(s):  
Samantha Jiménez-Oyola ◽  
Kenny Escobar Segovia ◽  
María-Jesús García-Martínez ◽  
Marcelo Ortega ◽  
David Bolonio ◽  
...  

Anthropogenic activities performed in the Ecuadorian Amazon have released potentially toxic elements (PTEs) into the rivers, causing severe environmental pollution and increasing the risk of exposure to the residents of the surrounding areas. This study aims to carry out a human health risk assessment using deterministic and probabilistic methods to estimate the hazard index (HI) and total cancer risk (TCR) related to multi-pathway human exposure to PTEs in polluted rivers. Concentrations of Al, Cd, Cr, Cu, Hg, Ni, Pb, and Zn in surface water and sediment samples from rivers on the Ecuadorian Amazon were considered to assess the potential adverse human health effects. As a result, deterministic and probabilistic estimations of cancer and non-cancer risk through exposure to surface waters and sediments were above the safety limit. A sensitivity analysis identified the concentration of PTEs and the exposure duration (ED) as the two most important variables for probabilistic health risk assessment. The highest risk for receptors was related to exposure to polluted sediments through incidental ingestion and dermal contact routes. According to the deterministic estimation, the human health risk through ingestion of water was above the threshold in specific locations. This study reveals the potential health risk to which the population is exposed. This information can be used as a baseline to develop public strategies to reduce anthropogenic pollution and exposure to PTEs in Ecuadorian Amazon rivers.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Hyeryeong Jeong ◽  
Jin Young Choi ◽  
Kongtae Ra

AbstractPotentially toxic elements (PTEs) were investigated in the different sizes of road deposited sediments (RDS) around the active smelting industry to understand their sources and to assess the pollution and ecological risk levels. The highest PTEs concentrations was shown near the raw materials import port and the smelting facilities. The fine particles of RDS showed extremely high PTEs concentrations. Zn has the highest mean concentration in the < 63 μm particle size of RDS, followed by Pb > Cu > As > Cr > Ni > Cd > Hg. The PTEs concentrations of this study were the highest values compared to the soils around the smelter and the RDS in urban and industrial areas in the world. This indicates that these PTEs pollution in RDS were mainly attributed to the transportation of raw materials for the smelting industry. According to nemerow pollution index calculation, RDS at all sampling sites with particles of less than 250 mm was seriously polluted with PTEs. The ecological risk was also found to be very high in all RDS fractions and highly toxic elements such as Cd, Pb and Hg pose extremely risk. Given the total amounts PTEs in the road surface, it is necessary to apply RDS removal management plan to reduce the PTEs pollution.


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