scholarly journals Drying kinetics of blackberry leaves

Author(s):  
Elton A. S. Martins ◽  
André L. D. Goneli ◽  
Alexandre A. Goncalves ◽  
Cesar P. Hartmann Filho ◽  
Valdiney C. Siqueira ◽  
...  

ABSTRACT Blackberry leaves have some pharmacological properties and one of the most widespread and studied uses is to relieve symptoms of the climacteric and other symptoms during the premenstrual period. Thus, drying becomes important for the conservation and storage of the product until its use or processing. The present study aimed to evaluate the drying kinetics of blackberry leaves, as well as to determine the effective diffusion coefficient and the activation energy during the drying process. Blackberry leaves were dried in an experimental fixed-bed dryer under four controlled temperature conditions (40, 50, 60 and 70 °C) and two drying air speeds (0.4 and 0.8 m s-1). With the experimental data of moisture ratio, eight mathematical models were fitted to represent the process of thin-layer drying of agricultural products. Based on the obtained results, it was found that the Midilli model represented best the phenomenon of drying of blackberry leaves. The increase in temperature and air speed reduced the drying time of blackberry leaves and increased the values of the effective diffusion coefficient. This relation can be described by the Arrhenius equation, which has an activation energy for the liquid diffusion during drying of 65.94 and 66.08 kJ mol-1, for drying air speeds of 0.4 and 0.8 m s-1, respectively.

Author(s):  
Elton A. S. Martins ◽  
André L. D. Goneli ◽  
Alexandre A. Gonçalves ◽  
Valdiney C. Siqueira ◽  
Claúdia A. L. Cardoso ◽  
...  

ABSTRACT Solanum paniculatum L. (jurubeba) is among the numerous medicinal plants used by the Brazilian population, and the use of its leaves is quite popular, in the form of tea, as a remedy against hangovers after excessive consumption of alcohol and food, besides being used in the form of ointments as healing agent and also in the treatment of liver and digestive problems. Leaves of medicinal plants usually have a high moisture content, requiring its reduction by drying, so that the product can be stored safely until its processing. The objective of this study was to evaluate the drying kinetics of jurubeba leaves and to determine the effective diffusion coefficient and activation energy during drying. Jurubeba leaves were dried at different air temperatures (30, 40, 50, 60 and 70 °C) and speed (0.4 and 0.8 m s-1). The Midilli model satisfactorily fitted to the observed data of drying of jurubeba leaves for all air conditions. Increasing the drying air temperature and speed reduced the drying time and increased the effective diffusion coefficient. For the air temperature range from 40 to 70 °C, as the drying air speed increases, the activation energy for the drying of the jurubeba leaves is reduced.


2019 ◽  
Vol 11 (8) ◽  
pp. 225
Author(s):  
Wellytton Darci Quequeto ◽  
Valdiney Cambuy Siqueira ◽  
Geraldo Acácio Mabasso ◽  
Eder Pedroza Isquierdo ◽  
Rafael Araujo Leite ◽  
...  

As well as most agricultural products, some medicinal plants need to go through a drying process to ensure quality maintenance, however each product behaves differently. Therefore, the present study aimed to evaluate the drying kinetics of spiked pepper (Piper aduncum L.) leaves and determine their thermodynamic properties at different drying temperatures in laboratory scale. Leaves with initial moisture content of 78% w.b. (wet basis) were subjected to drying at temperatures of 40, 50, 60 and 70 ºC and air speed of 0.85 m s-1 in an experimental fixed bed dryer. The drying kinetics of the leaves was described by statistical fitting of mathematical models and determination of effective diffusion coefficient and activation energy. Enthalpy, entropy and Gibbs free energy were also evaluated for all drying conditions. It was concluded that, among the models evaluated, only Midilli and Valcam can be used to represent the drying of Piper aduncum leaves; the first for the two highest temperatures (60 and 70 ºC) and the second for 40 and 50 ºC. The activation energy was approximately 55.64 kJ mol-1, and the effective diffusion coefficient increase with the elevation of temperature. The same occurs with the values of Gibbs free energy, whereas the specific enthalpy and entropy decrease.


2019 ◽  
Vol 11 (5) ◽  
pp. 250 ◽  
Author(s):  
Wellytton Darci Quequeto ◽  
Osvaldo Resende ◽  
Patrícia Cardoso Silva ◽  
Fábio Adriano Santos e Silva ◽  
Lígia Campos de Moura Silva

Noni seeds have been used for years as an important medicinal source, with wide use in the pharmaceutical and food industry. Drying is a fundamental process in the post-harvest stages, where it enables the safe storage of the product. Therefore, the present study aimed to fit different mathematical models to experimental data of drying kinetics of noni seeds, determine the effective diffusion coefficient and obtain the activation energy for the process during drying under different conditions of air temperature. The experiment used noni seeds with initial moisture content of 0.46 (decimal, d.b.) and dehydrated up to equilibrium moisture content. Drying was conducted under different controlled conditions of temperature, 40; 50; 60; 70 and 80 ºC and relative humidity, 24.4; 16.0; 9.9; 5.7 and 3.3%, respectively. Eleven mathematical models were fitted to the experimental data. The parameters to evaluate the fitting of the mathematical models were mean relative error (P), mean estimated error (SE), coefficient of determination (R2), Chi-square test (c2), Akaike Information Criterion (AIC) and Schwarz’s Bayesian Information Criterion (BIC). Considering the fitting criteria, the model Two Terms was selected to describe the drying kinetics of noni seeds. Effective diffusion coefficient ranged from 8.70 to 23.71 × 10-10 m2 s-1 and its relationship with drying temperature can be described by the Arrhenius equation. The activation energy for noni seeds drying was 24.20 kJ mol-1 for the studied temperature range.


Author(s):  
Rafaiane M. Guimarães ◽  
Daniel E. C. de Oliveira ◽  
Osvaldo Resende ◽  
Jhessika de S. Silva ◽  
Thaisa A. M. de Rezende ◽  
...  

ABSTRACT ‘Okara’ is the insoluble part obtained after the aqueous extraction of soybeans, generated in large quantities as a by-product of the ‘tofu’ industry or soybean water-soluble extract. This work aimed to study ‘okara’ convective drying kinetics, determine the effective diffusion coefficient, and obtain activation energy and thermodynamic properties under different drying conditions. The by-product ‘okara’ was obtained from the processing of BRS 257 soybean water-soluble extract, homogenized and dried in a forced-air oven at temperatures of 40, 50, 60 and 70 °C until constant weight. Among the analysed models, Wang & Singh was selected to represent the drying phenomenon. Effective diffusion coefficient increased with the temperature rise, and the activation energy for the net diffusion in the drying was 28.15 kJ mol-1. Enthalpy and Gibbs free energy increased with the elevation of drying temperature.


2021 ◽  
Vol 43 ◽  
pp. e50301
Author(s):  
Luciana Alves da Silva Tavone ◽  
Kauyse Matos Nascimento ◽  
Yasmin Jaqueline Fachina ◽  
Grasiele Scaramal Madrona ◽  
Rita de Cássia Bergamasco ◽  
...  

Muntingia calabura fruits are rich in bioactive compounds such as antioxidants, and the consumption of these compounds is associated with cancer prevention and aging. In this study, mathematical models were used to fit the experimental data of the Muntingia calabura peel drying kinetics, and the effective diffusion coefficient, activation energy and thermodynamic properties of the process were determined. Then, the effect of the drying temperature on the antioxidant activity and phenolic compounds of fruit peels was examined using conventional extraction and ultrasonication. Among the analyzed models, the logarithmic model was selected to represent the drying phenomenon of the calabura peel kinetics. The effective diffusion coefficient decreased by 74% as the temperature increased from 40 to 60°C, and the activation energy for liquid diffusion during drying was 23.96 kJ mol-1. The enthalpy and entropy decreased with increasing temperature, while the Gibbs free energy increased by 5% for each 10°C increase in temperature. Regarding the content of phenolic compounds and the antioxidant activity of the calabura peel, it was observed that an increase in the drying temperature had a positive effect on the conservation of the bioactive compounds, making it possible to conclude that drying at 60°C and ultrasound extraction are the most suitable approach to conduct the process.


2020 ◽  
Vol 44 ◽  
Author(s):  
Valdiney Cambuy Siqueira ◽  
Rafael Araújo Leite ◽  
Geraldo Acácio Mabasso ◽  
Elton Aparecido Siqueira Martins ◽  
Wellytton Darci Quequeto ◽  
...  

ABSTRACT Buckwheat has become important in the food sector as its flour does not contain gluten. Since buckwheat is a relatively new crop in the agricultural environment, there is little information available regarding its processing. Drying is one of the most important post-harvest stages of buckwheat. The aim of the present study was to describe the drying process of buckwheat grains. Buckwheat grains with a moisture content of 0.41 ± 0.01 (dry basis, d.b.) were harvested, followed by drying in an experimental dryer at the temperatures of 40, 50, 60, 70, and 80 °C, at an air speed of 0.8 m s-1. The drying rate was determined, and the mathematical models generally employed to describe the drying process of several agricultural products were fitted to the experimentally obtained data. Model selection was based on the Gauss-Newton non-linear regression method and was complemented by Akaike Information Criterion and Schwarz’s Bayesian Information Criterion. It was concluded that the drying rate increased with an increase in temperature and decreased with an increase in drying time. It is recommended to use the Midilli model to represent the drying kinetics of buckwheat grains at the temperatures of 40, 60, and 70 °C, while the Approximation of diffusion model is recommended for the temperatures of 50 and 80 °C. The magnitudes of effective diffusion coefficients ranged from 1.8990 × 10-11 m2 s-1 to 17.8831 × 10-11 m2 s-1. The activation energy required to initiate the drying process was determined to be 49.75 kJ mol-1.


Processes ◽  
2019 ◽  
Vol 7 (1) ◽  
pp. 21 ◽  
Author(s):  
Thi Van Linh Nguyen ◽  
My Duyen Nguyen ◽  
Duy Chinh Nguyen ◽  
Long Giang Bach ◽  
Tri Duc Lam

Lemongrass is a plant that contains aromatic compounds (myrcene and limonene), powerful deodorants, and antimicrobial compounds (citral and geraniol). Identifying a suitable drying model for the material is crucial for establishing an initial step for the development of dried products. Convection drying is a commonly used drying method that could extend the shelf life of the product. In this study, a suitable kinetic model for the drying process was determined by fitting moisture data corresponding to four different temperature levels: 50, 55, 60 and 65 °C. In addition, the effect of drying temperature on the moisture removal rate, the effective diffusion coefficient and activation energy were also estimated. The results showed that time for moisture removal increases proportionally with the air-drying temperature, and that the Weibull model is the most suitable model for describing the drying process. The effective diffusion coefficient ranges from 7.64 × 10−11 m2/s to 1.48 × 10−10 m2/s and the activation energy was 38.34 kJ/mol. The activation energy for lemongrass evaporation is relatively high, suggesting that more energy is needed to separate moisture from the material by drying.


Author(s):  
Thaís A. de S. Smaniotto ◽  
Osvaldo Resende ◽  
Kelly A. de Sousa ◽  
Daniel E. C. de Oliveira ◽  
Rafael C. Campos

ABSTRACT The objectives of this study were to fit different mathematical models to experimental data of drying of sunflower grains, determine and evaluate the effective diffusion coefficient and obtain the activation energy for the process during the drying under various conditions of air. The sunflower grains were collected with an initial moisture content of 0.5267 dry basis (d.b.) and dried in an oven with forced air ventilation under five temperature conditions: 35, 50, 65, 80 and 95 °C, until reaching the moisture content of 0.0934 ± 0.0061 (d.b.). Among the analyzed models, Wang and Singh showed the best fit to describe the drying phenomenon. The effective diffusion coefficient of sunflower grains increased with the increment in air temperature and has activation energy for liquid diffusion in the sunflower drying of 29.55 kJ mol-1.


Author(s):  
Elisabete P. de Sousa ◽  
Rossana M. F. de Figueirêdo ◽  
Josivanda P. Gomes ◽  
Alexandre J. de M. Queiroz ◽  
Deise S. de Castro ◽  
...  

ABSTRACT The aim of this work was to study the drying kinetics of pequi pulp by convective drying at different conditions of temperature (50, 60, 70 and 80 °C) and thickness (0.5, 1.0 and 1.5 cm) at the air speed of 1.0 m s-1, with no addition of adjuvant. The experimental data of pequi pulp drying kinetics were used to plot drying curves and fitted to the models: Midilli, Page, Henderson & Pabis and Newton. Effective diffusivity was calculated using the Fick’s diffusion model for a flat plate. It was found that, with increasing thickness, the drying time increased and, with increasing temperature, the drying time was reduced. The Midilli model showed the best fit to the experimental data of pequi pulp drying at all temperatures and thicknesses, presenting higher coefficients of determination (R2), indicating that this model satisfactorily represents the pequi pulp drying phenomenon. There was a trend of increase in the effective diffusivity with the increase in pulp layer thickness and temperature.


Author(s):  
Monica Premi ◽  
Harish Sharma ◽  
Ashutosh Upadhyay

Abstract The present study examines the effect of air velocity on drying kinetics of the drumstick leaves in a forced convective dryer. The drumstick leaves were dried in the temperature range of 50–800 C, at different air velocity (Dv) of 0.5 and 1.3 m/s. The results indicated that drying temperature and air velocity are the factors in controlling the drying rate. Experimental data obtained for the samples for color, drying rate and drying time proved that air velocity of 1.3 m/s yielded the product superior in terms of both quality and energy efficiency as compared to the samples at 0.5 m/s. Activation energy for drumstick leaves dried with air velocity, 0.5 and 1.3 m/s was 12.50 and 32.74 kJ/mol respectively. The activation energy relates similarly with the effective moisture diffusivity which also increased with increase in air velocity and temperature.


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