INVESTIGATION OF POSSIBILITY TO PRODUCE HIGH-STRENGTH BORON ALUMINUM SHEETS WITHOUT HOMOGENIZATION AND QUENCHING OPERATIONS

Author(s):  
K. Yu. Chervyakova ◽  
N. A. Belov ◽  
M. E. Samoshina ◽  
A. A. Yakovlev

Al–Cu–Mn (Zr) alloys feature high strength and processability without any thermal treatment operations. Al–2%Cu–1,5%Mn–2%B and Al–2%Cu–1,5%Mn–0,4%Zr–2%B alloys were obtained in order to investigate the possibility of producing a aluminum boroncontaining alloy in the form of high-strength sheet rolled stock without thermal treatment. Melting was performed in the RELTEK induction furnace with intense melt stirring to eliminate sedimentation of boride refractory particles. Melting temperature was 950– 1000 °С. Melt was poured into 40×120×200 mm graphite casting molds. Calculation methods (Thermo-Calc) were used to demonstrate that manganese forms complex borides with aluminum and zirconium at a melting temperature while there is enough manganese in liquid and there is practically no zirconium left. Experimental methods (electronic scanning microscopy and electron microprobe analysis) proved the formation of the complex AlB2Mn2 boride, however, manganese remained in a solid solution is enough to form the Al20Cu2Mn3 phase particles in the amount up to 7 wt.%. In the alloy with zirconium, boron stimulates primary Al3Zr crystal separation and, therefore, zirconium content left in the aluminum solid solution is not sufficient for hardening. It is shown that it is possible to produce thin-rolled steel with a thickness of less than 0,3 mm with uniformly distributed clusters of the boride phase with a particle size of less than 10 μm. A high level of strength up to 543 MPa is reached without the use of hardening and aging due to the precipitation of Al20Cu2Mn3 phase dispersions during hot deformation (t =450 °C).

2009 ◽  
Vol 633-634 ◽  
pp. 707-715 ◽  
Author(s):  
Julia Lyubimova ◽  
Jens Freudenberger ◽  
Alexandere Gaganov ◽  
Hansjörg Klauss ◽  
Ludwig Schultz

Recovery, recrystallisation and grain growth processes as well as the formation of a solid solution and the phase separation of a homogeneous material into a heterogeneous one are observed for Cu-Ag-Zr alloys heat-treated at different temperatures by means of mechanical, electrical and microstructural analyses. Heat treatments are shown to be an effective tool to enhance the strain to failure. If applied between several deformation steps the heat treatment causes an increase of both strain and strength limits.


2021 ◽  
Vol 72 ◽  
pp. 104-113
Author(s):  
Rui Jiang ◽  
Shengnan Qian ◽  
Chuang Dong ◽  
Ying Qin ◽  
Yujuan Wu ◽  
...  

Author(s):  
D.M. Vanderwalker

Aluminum-lithium alloys have a low density and high strength to weight ratio. They are being developed for the aerospace industry.The high strength of Al-Li can be attributed to precipitation hardening. Unfortunately when aged, Al-Li aquires a low ductility and fracture toughness. The precipitate in Al-Li is part of a sequence SSSS → Al3Li → AlLi A description of the phases may be found in reference 1 . This paper is primarily concerned with the Al3Li phase. The addition of Zr to Al-Li is being explored to find the optimum in properties. Zirconium improves fracture toughness and inhibits recrystallization. This study is a comparision between two Al-Li-Zr alloys differing in Zr concentration.Al-2.99Li-0.17Zr(alloy A) and Al-2.99Li-0.67Zr (alloy B) were solutionized for one hour at 500oc followed by a water quench. The specimens were then aged at 150°C for 16 or 40 hours. The foils were punched into 3mm discs. The specimens were electropolished with a 1/3 nitric acid 2/3 methanol solution. The transmission electron microscopy was conducted on the JEM 200CX microscope.


Alloy Digest ◽  
1994 ◽  
Vol 43 (11) ◽  

Abstract CARLSON ALLOYS C600 AND C600 ESR have excellent mechanical properties from sub-zero to elevated temperatures with excellent resistance to oxidation at high temperatures. It is a solid-solution alloy that can be hardened only by cold working. High strength at temperature is combined with good workability. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as forming, heat treating, and machining. Filing Code: Ni-470. Producer or source: G.O. Carlson Inc.


Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Irati Zurutuza ◽  
Nerea Isasti ◽  
Eric Detemple ◽  
Volker Schwinn ◽  
Hardy Mohrbacher ◽  
...  

The synergetic effect on hardenability by combining boron with other microalloying elements (such as Nb, Mo and Nb + Mo) is widely known for high-strength medium carbon steels produced by direct quenching and subsequent tempering treatment. The improvement of mechanical properties could be reached through optimization of different mechanisms, such as solid solution hardening, unit size refinement, strain hardening, fine precipitation hardening and the effect of carbon in solid solution. The current study proposes a procedure for evaluating the contribution of different microstructural aspects on Charpy impact toughness. First, the effect that austenite conditioning has on low-temperature transformation unit sizes and microstructural homogeneity was analysed for the different microalloying element combinations. A detailed crystallographic characterization of the tempered martensite was carried out using electron backscattered diffraction (EBSD) in order to quantify the effect of unit size refinement and dislocation density. The impact of heterogeneity and presence of carbides was also evaluated. The existing equations for impact transition temperature (ITT50%) predictions were extended from ferrite-pearlite and bainitic microstructures to tempered martensite microstructures. The results show that microstructural refinement is most beneficial to strength and toughness while unit size heterogeneity has a particularly negative effect on ductile-to-brittle transition behaviour. By properly balancing alloy concept and processing, steel having a yield strength above 900 MPa and low impact transition temperature could be obtained by direct quenching and tempering.


Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1473
Author(s):  
Hao Wang ◽  
Yanping Bao ◽  
Chengyi Duan ◽  
Lu Lu ◽  
Yan Liu ◽  
...  

The influence of rare earth Ce on the deep stamping property of high-strength interstitial-free (IF) steel containing phosphorus was analyzed. After adding 120 kg ferrocerium alloy (Ce content is 10%) in the steel, the inclusion statistics and the two-dimensional morphology of the samples in the direction of 1/4 thickness of slab and each rolling process were observed and compared by scanning electron microscope (SEM). After the samples in each rolling process were treated by acid leaching, the three-dimensional morphology and components of the second phase precipitates were observed by SEM and energy dispersive spectrometer (EDS). The microstructure of the sample was observed by optical microscope, and the grain size was compared. Meanwhile, the content and strength of the favorable texture were analyzed by X-ray diffraction (XRD). Finally, the mechanical properties of the product were analyzed. The results showed that: (1) The combination of rare earth Ce with activity O and S in steel had lower Gibbs free energy, and it was easy to generate CeAlO3, Ce2O2S, and Ce2O3. The inclusions size was obviously reduced, but the number of inclusions was increased after adding rare earth. The morphology of inclusions changed from chain and strip to spherical. The size of rare earth inclusions was mostly about 2–5 μm, distributed and dispersed, and their elastic modulus was close to that of steel matrix, which was conducive to improving the structure continuity of steel. (2) The rare earth compound had a high melting point. As a heterogeneous nucleation point, the nucleation rate was increased and the solidification structure was refined. The grade of grain size of products was increased by 1.5 grades, which is helpful to improve the strength and plasticity of metal. (3) Rare earth Ce can inhibit the segregation of P element at the grain boundary and the precipitation of Fe(Nb+Ti)P phase. It can effectively increase the solid solution amount of P element in steel, improve the solid solution strengthening effect of P element in high-strength IF steel, and obtain a large proportion of {111} favorable texture, which is conducive to improving the stamping formability index r90 value.


2010 ◽  
Vol 667-669 ◽  
pp. 925-930
Author(s):  
S.V. Krymskiy ◽  
Elena Avtokratova ◽  
M.V. Markushev ◽  
Maxim Yu. Murashkin ◽  
O.S. Sitdikov

The effects of severe plastic deformation (SPD) by isothermal rolling at the temperature of liquid nitrogen combined with prior- and post-SPD heat treatment, on microstructure and hardness of Al-4.4%Cu-1.4%Mg-0.7%Mn (D16) alloy were investigated. It was found no nanostructuring even after straining to 75%. Сryodeformation leads to microshear banding and processing the high-density dislocation substructures with a cell size of ~ 100-200 nm. Such a structure remains almost stable under 1 hr annealing up to 200oC and with further temperature increase initially transforms to bimodal with a small fraction of nanograins and then to uniform coarse grained one. It is found the change in the alloy post–SPD aging response leading to more active decomposition of the preliminary supersaturated aluminum solid solution, and to the alloy extra hardening under aging with shorter times and at lower temperatures compared to T6 temper.


2004 ◽  
Vol 851 ◽  
Author(s):  
Dmitri V. Louzguine-Luzgin ◽  
Larissa V. Louzguina-Luzgina ◽  
Hidemi Kato ◽  
Akihisa Inoue

ABSTRACTThe high-strength and ductile hypo-, hyper- and eutectic Ti-Fe alloys were formed in the shape of the arc-melted ingots with the dimensions of about 25–40 mm in diameter and 10–15 mm in height. The structure of the samples consists of cubic Pm 3 m TiFe and BCC Im 3 m β-Ti supersaturated solid solution phase. The arc-melted hypereutectic Ti65Fe35 alloy has a dispersed structure consisting of the primary TiFe phase and submicron-size eutectic structure. This alloy exhibits excellent mechanical properties: a Young's modulus of 149 GPa, a high mechanical fracture strength of 2.2 GPa, a 0.2 % yield strength of 1.8 GPa and 6.7 % ductility. The hard round-shaped intermetallic TiFe phase and the supersaturated β-Ti solid solution result in a high strength of the Ti65Fe35 alloy which in addition has much higher ductility compared to that of the nanostructured or glassy alloys. The reasons for the high ductility of the hypereutectic alloy are discussed.


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