scholarly journals Heavy metals and their bioavailability from soils in the long-term polluted Central Spiš region of SR

2009 ◽  
Vol 55 (No. 4) ◽  
pp. 167-172 ◽  
Author(s):  
P. Takáč ◽  
T. Szabová ◽  
Ľ. Kozáková ◽  
M. Benková
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Statistical Processing ◽  
Soil Samples ◽  
Acidic Ph ◽  
Mobile Form ◽  
Lead And Zinc ◽  
Mobile Forms ◽  
Metal Contents

The heavy metal contents and their bioavailability were monitored in soils of Central Spiš region of SR. This area belongs to long term contaminated and hygienically loaded areas. Soil contamination by heavy metals is caused especially by ore mining, processing and treatment. Soil samples from the Central Spiš contained higher proportions of mobile forms which corresponded to the following sequence Pb > Zn > Cu, while for mobilizable forms the sequence of investigated metals was as follows: Cu > Zn > Pb. Soil pH is one of the parameters that affect significantly the share of bioavailable forms of metals. Higher proportions of mobile fractions of metals were detected in samples taken from soils with acidic pH. Statistical processing confirmed a relationship between the percentage share of lead and zinc in the mobile form and the level of pH/KCl, which was significant for Zn: <I>r</I> = –0.53. The relationships for lead and copper were insignificant.

Analysis on Pb, Cd, Cr, As, Mn Emission and Control Technology of Typical Industries

2012 ◽  
Vol 610-613 ◽  
pp. 1176-1187 ◽  
Author(s):  
Tao Yue ◽  
Fan Wang ◽  
Bin Jie Han ◽  
Peng Lai Zuo ◽  
Fan Zhang
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Flue Gas ◽  
Power Plants ◽  
Raw Materials ◽  
Control Technology ◽  
Generator System ◽  
Lead And Zinc ◽  
Metal Contents ◽  
Industrial Boilers

The heavy metals including Pb, Cd, Cr, As and Mn emission characteristics of coal-fired power plant boilers, industrial boilers, lead and zinc smelters, cement kilns, and steel industries were studied in this paper. The removing effects of heavy metals by pollution control technology were analyzed. ICP-AES method was used to measure the contents of heavy metals in solid samples. In addition, M-29, the U.S. EPA isokinetic sampling method was used to sample heavy metals in the flue gas, and the sampled heavy metals were tested by ICP-AES-hydride generator system. For coal-fired boilers, heavy metal contents in descending order were Mn, Pb and Cd in the tested coal. The heavy metals’ emission concentrations of coal-fired industrial boilers were much higher than the heavy metals’ emission concentrations of power plants. For the lead and zinc smelters, Pb and its compounds in flue gas after cleaning can meet the emission standards. The heavy metal contents in the cement raw materials in descending order were Pb, Cr and Cd. For the sintering mixture, the heavy metal contents in descending order were Pb, Cr and Cd as well. The removal effects of heavy metals by existing pollutant control technologies in the various typical industries were also tested and analyzed in the paper. The research did in the paper made a scientific basis for controlling heavy metal emissions from typical industries.

scholarly journals Heavy Metal Residues in Soil and Accumulation in Maize at Long-Term Wastewater Irrigation Area in Tongliao, China

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Yintao Lu ◽  
Hong Yao ◽  
Dan Shan ◽  
Yichen Jiang ◽  
Shichao Zhang ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Growth Cycle ◽  
Wastewater Irrigation ◽  
Pollution Level ◽  
Irrigated Area ◽  
Metal Contents ◽  
Maize Roots ◽  
Translocation Factors

Soil and plant samples were collected from Tongliao, China, during the maize growth cycle between May and October 2010. Heavy metals, such as Cr, Pb, Ni, and Zn, were analyzed. The concentrations of Cr, Pb, Ni, and Zn in the wastewater-irrigated area were higher than those in the topsoil from the groundwater-irrigated area. The concentrations of metals in the maize increased as follows: Pb < Ni < Zn < Cr. In addition, Cr, Pb, and Ni mainly accumulated in the maize roots, and Zn mainly accumulated in the maize fruit. The results of translocation factors (TF) and bioconcentration factors (BCF) of maize for heavy metals revealed that maize is an excluder plant and a potential accumulator plant and can serve as an ideal slope remediation plant. In addition, the increasing heavy metal contents in soils that have been polluted by wastewater irrigation must result in the accumulation of Cr, Pb, Ni, and Zn in maize. Thus, the pollution level can be decreased by harvesting and disposing of and recovering the plant material.

scholarly journals Biosolids and heavy metals in soils

2003 ◽  
Vol 60 (4) ◽  
pp. 793-806 ◽  
Author(s):  
Maria Lucia Azevedo Silveira ◽  
Luís Reynaldo Ferracciú Alleoni ◽  
Luiz Roberto Guimarães Guilherme
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Concentration ◽  
Treatment Method ◽  
Soil Fertilization ◽  
Free Ions ◽  
Metal Contents ◽  
Agricultural Areas ◽  
Inorganic Ligands

The application of sewage sludge or biosolids on soils has been widespread in agricultural areas. However, depending on their characteristics, they may cause increase in heavy metal concentration of treated soils. In general, domestic biosolids have lower heavy metal contents than industrial ones. Origin and treatment method of biosolids may markedly influence their characteristics. The legislation that controls the levels of heavy metal contents in biosolids and the maximum concentrations in soils is still controversial. In the long-term, heavy metal behavior after the and of biosolid application is still unknown. In soils, heavy metals may be adsorbed via specific or non-specific adsorption reactions. Iron oxides and organic matter are the most important soil constituents retaining heavy metals. The pH, CEC and the presence of competing ions also affect heavy metal adsorption and speciation in soils. In solution, heavy metals can be present either as free-ions or complexed with organic and inorganic ligands. Generally, free-ions are more relevant in environmental pollution studies since they are readily bioavailable. Some computer models can estimate heavy metal activity in solution and their ionic speciation. Thermodynamic data (thermodynamic stability constant), total metal and ligand concentrations are used by the GEOCHEM-PC program. This program allows studying heavy metal behavior in solution and the effect of changes in the conditions, such as pH and ionic strength and the application of organic and inorganic ligands caused by soil fertilization.

scholarly journals Monitoring of heavy metal contamination of soil and plants (for example, Potentilla tanacetifolia Willd. ex Schlecht.) of natural ecosystems in Chita urban areas

2018 ◽  
Vol 7 (1) ◽  
pp. 110-115
Author(s):  
Galina Yurievna Samoilenko ◽  
Evgeniy Aleksandrovich Bondarevich ◽  
Natalia Nikolaevna Kotsyurzhinskaya ◽  
Igor Anatolyevich Boriskin
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Urban Areas ◽  
Heavy Metal Contamination ◽  
Soil Samples ◽  
Natural Ecosystems ◽  
High Concentration ◽  
Mobile Forms ◽  
Zinc Cadmium ◽  
Cadmium Lead

The paper presents data on the content of gross and mobile forms of zinc, cadmium, lead and copper in the soils of Chita and its surroundings. The paper contains a comparative analysis of the accumulation (Kn) and movement (KP) coefficients of these microelements in organs ( Potentilla tanacetifolia Willd. ex Schlecht.), relative to their gross content and mobile forms in soils. The authors have revealed that soil samples of the studied sites contain unequal gross amount of heavy metals. In some points (6 and 3) the content of cadmium and zinc exceeded the Mac, that is why such soils have been attributed to heavily polluted. The index of biological activity on mobile forms of heavy metals in all sites significantly exceeded the same index on gross forms. It was found that Potentilla tanacetifolia are accumulators of heavy metal ions. Aboveground bodies accumulate and absorb cadmium and copper especially intensively, thus the content of mobile forms of these metals in the soil is insignificant. Excessive adsorption of trace elements in the phytomass of plants can be connected with surface contamination. According to the content of zinc and lead, the accumulation values in the organs of P. tanacetifolia were characterized by small coefficient values, against the background of their high concentration in the soil.

scholarly journals Determination of Molybdenum Contents and Relation of Some Heavy Metals in the Soil of Meadow-Pasture Terraces Between Kırıkhan-Reyhanlı

2019 ◽  
Vol 7 (1) ◽  
pp. 13 ◽  
Author(s):  
Mehmet Yalçın ◽  
Kerim Mesut Çimrin
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Pollution ◽  
Soil Samples ◽  
Molybdenum Content ◽  
Limit Values ◽  
Significant Relationships ◽  
Metal Contents ◽  
Different Depths

This study was aimed to determine the molybdenum content of meadow - pasture soil between Kırıkhan and Reyhanlı in Hatay province and to determine the relations of the molybdenum content with some heavy metals in the soil. For this purpose, two different depths (0-20 and 20-40 cm) representing grassland pasture lands and 80 soil samples from 40 different points were taken. Cadmium (Cd), Cobalt (Co), Nickel (Ni), Lead (Pb), Copper (Cu), Iron (Fe), and Molybdenum (Mo) contents were determined in the soil samples. The contents of the available Cd, Co, Pb, Cu, Fe, Ni and Mo of the soil were determined by reading the 0.005 M DTPA + 0.01 M CaCl2 + 0.1 M TEA extracts in the ICP instrument. The results of the research shows that the Cd contents of the soils are between 0.01-0.32 ppm; Co contents are from 0.01 to 4.97 ppm; Ni contents 0.00 to 20.00 ppm; Pb contents 3.00-67.00 ppm; Cu contents 0.26-7.48 ppm; The Fe contents are between 4.00 and 61.00 and the Mo contents are between 0.001 and 0.064 ppm. It was determined that there are significant positive relationships between Co, Ni, Pb, Cu and Fe contents of Mo in the soil. It was also determined that there are significant positive significant relationships between Cd and Co; Co with Ni, Pb, Fe and Pb and Cu, Fe and Cu and Fe. No heavy metal pollution was found when the heavy metal contents of the regional soils were compared with the limit values.

scholarly journals Heavy metal contents in Latosols cultivated with vegetable crops1

2016 ◽  
Vol 46 (4) ◽  
pp. 391-400 ◽  
Author(s):  
Laércio Santos Silva ◽  
◽  
Izabel Cristina de Luna Galindo ◽  
Clístenes Williams Araújo do Nascimento ◽  
Romário Pimenta Gomes ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Principal Component Analysis ◽  
Agricultural Practices ◽  
Principal Component ◽  
Soil Samples ◽  
Vegetable Crops ◽  
Chemical Analyses ◽  
Analysis Techniques ◽  
Metal Contents

ABSTRACT Heavy metals are naturally found in soils, but their levels may increase as a result of anthropogenic actions. This study aimed at determining the concentrations of Cd, Cu, Mn, Ni, Pb and Zn in Yellow Latosol from vegetable crops areas, as well as the influence of the cultivation and position in the landscape on the accumulation of these elements. Soil samples were collected from five farming areas and four areas with natural vegetation, which served as a reference. Soil was collected along the planting rows from three transect positions (upper, middle and lower sections of the slope), as well as from the upper portion of forest areas, at three depths (0.0-0.10 m, 0.10-0.30 m and 0.30-0.60 m). The results from the chemical analyses indicated that Cd, Cu, Mn, Pb and Zn levels in the soil increased as a result of cultivation. Only Cd and Cu concentrations were above the quality reference values for the Pernambuco State. The multivariate analysis techniques used were efficient at separating the environments and at differentiating the origin of the metals. Soils from forest areas were clearly separated from croplands, demonstrating the effect of agricultural practices on the metal contents in the soils. The principal component analysis indicated a predominantly anthropogenic origin (phosphate fertilizing) for Cd, in more superficial soil samples.

scholarly journals A proposed method for the assessment of the interactive heavy metal accumulation in soils

2015 ◽  
Vol 17 (4) ◽  
pp. 835-846 ◽  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Quantitative Assessment ◽  
Metal Accumulation ◽  
Surface Soil ◽  
Heavy Metal Accumulation ◽  
Soil Samples ◽  
Plant Nutrients ◽  
Heavy Metals In Soils

<p>A method is proposed for the assessment of the interactive accumulation of heavy metals in soils. Sixty surface soil samples were collected from fifteen sites, at a depth of 0-30cm, evenly distributed, within the 30,700ha comprising the study area.</p> <p>It was found that at least&nbsp; some of these metals were significantly contributed to soil, i.e. Mn 9.53, Fe 8.06, Zn 0.86, Pb 0.29, Cd 0.033, Co 0.112 and Ni 0.125 kg/ha, respectively.</p> <p>Similarly considerable levels of plant nutrients were accumulated in the studied soil such as P<sub>2</sub>O<sub>5</sub> 8.6, or 3.75 kg P/ha, K<sub>2</sub>O 52.92 or 43.94 kg K/ha, and Ca 78.98 kg/ha. As expected, the heavy metals accumulated in lower concentrations than those of plant nutrients and in non toxic levels. Nevertheless, the toxicity of these metals must be considered in relation to long term accumulation.</p> <div> <p>It was shown that the proposed method, based on the quantification of the elemental interactions contribution in heavy metals, could be used as a tool for the quantitative assessment of their accumulation and for the prediction of the &laquo;silent&nbsp; pollution&raquo; that gradually occurs in soils with these metals.</p> </div> <p>&nbsp;</p>

scholarly journals Assessment of Concentrations of Heavy Metals in Soils around ESPRO Asphalt Production and Quarry Site, Wasinmi, Osun State Southwest Nigeria

2019 ◽  
pp. 1-10
Author(s):  
O. O. Alabi ◽  
S. O. Sedara ◽  
S. Y. Awowole
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Groundwater Exploration ◽  
Soil Samples ◽  
Asphalt Production ◽  
Mean Values ◽  
Low Concentrations ◽  
Metal Contents ◽  
Southwest Nigeria ◽  
Mean Concentration

This work examined the concentration of heavy metals in soil samples around ESPRO Asphalt Production and Quarry Site located in Wasinmi, Irewole Local Government Area, Osun State. A total of nine (9) soil samples were collected from three points with distances of 0, 1 and 2 km from the quarry site. Atomic Absorption Spectroscopy (AAS) was used to determine the concentrations of heavy metals in the soil samples. The results revealed that the mean values metal contents in the soil samples analyzed were in the order Fe>Zn>Cu>Cr>Mn>Pb>Cd. The concentration of the heavy metals in the soil samples were found to decrease as the soil depths increased from 0-25 cm and also as the spatial distances of the sampled locations increased from the quarry plant. The study also showed that low concentrations of Lead (Pb) had a mean concentration value of 0.87 ppm and Cadmium (Cd) with a mean concentration value of 0.29 ppm. It was also observed that Iron (Fe) had the highest mean concentration value of 148.8 ppm. The study concluded that quarrying activities raised the soil heavy metal contents up to the range of about 2 km away from the quarry site. This can be attributed to the number of years of mining and excavation activities in the study area and accumulation of the heavy metal concentrations over time and this could be dangerous to the site environments, especially for farming and groundwater exploration activities in the area.

scholarly journals Chemical Properties of Heavy Metal-Contaminated Soils from a Korean Military Shooting Range: Evaluation of Pb Sources Using Pb Isotope Ratios

2021 ◽  
Vol 11 (15) ◽  
pp. 7099
Author(s):  
Inkyeong Moon ◽  
Honghyun Kim ◽  
Sangjo Jeong ◽  
Hyungjin Choi ◽  
Jungtae Park ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Contaminated Soils ◽  
Management Strategies ◽  
Chemical Properties ◽  
Heavy Metal Concentration ◽  
Soil Samples ◽  
Shooting Range ◽  
Geochemical Properties ◽  
Mineral Phases

In this study, the geochemical properties of heavy metal-contaminated soils from a Korean military shooting range were analyzed. The chemical behavior of heavy metals was determined by analyzing the soil pH, heavy metal concentration, mineral composition, and Pb isotopes. In total, 24 soil samples were collected from a Korean military shooting range. The soil samples consist of quartz, albite, microcline, muscovite/illite, kaolinite, chlorite, and calcite. Lead minerals, such as hydrocerussite and anglesite, which are indicative of a transformation into secondary mineral phases, were not observed. All soils were strongly contaminated with Pb with minor concentrations of Cu, Ni, Cd, and Zn. Arsenic was rarely detected. The obtained results are indicated that the soils from the shooting range are contaminated with heavy metals and have evidences of different degree of anthropogenic Pb sources. This study is crucial for the evaluation of heavy metal-contaminated soils in shooting ranges and their environmental effect as well as for the establishment of management strategies for the mitigation of environmental risks.

scholarly journals Heavy-Metal Contents and the Impact of Roasting on Polyphenols, Caffeine, and Acrylamide in Specialty Coffee Beans

Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1310
Author(s):  
Matúš Várady ◽  
Sylwester Ślusarczyk ◽  
Jana Boržíkova ◽  
Katarína Hanková ◽  
Michaela Vieriková ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Dry Matter ◽  
Green Beans ◽  
Caffeoylquinic Acids ◽  
Coffee Beans ◽  
Metal Contents ◽  
Specialty Coffee ◽  
Quantitative Analyses ◽  
The Impact

The aim of this study was to determine the effect of roasting on the contents of polyphenols (PPH), acrylamide (AA), and caffeine (CAF) and to analyze heavy metals in specialty coffee beans from Colombia (COL) and Nicaragua (NIC). Samples of NIC were naturally processed and COL was fermented anaerobically. Green beans from COL (COL-GR) and NIC (NIC-GR) were roasted at two levels, light roasting (COL-LIGHT and NIC-LIGHT) and darker roasting (COL-DARK and NIC-DARK), at final temperatures of 210 °C (10 min) and 215 °C (12 min), respectively. Quantitative analyses of PPH identified caffeoylquinic acids (CQA), feruloylquinic acids, and dicaffeoylquinic acids. Isomer 5-CQA was present at the highest levels and reached 60.8 and 57.7% in COL-GR and NIC-GR, 23.4 and 29.3% in COL-LIGHT and NIC-LIGHT, and 18 and 24.2% in COL-DARK and NIC-DARK, respectively, of the total PPH. The total PPH contents were highest in COL-GR (59.76 mg/g dry matter, DM). Roasting affected the contents of PPH, CAF, and AA (p < 0.001, p < 0.011 and p < 0.001, respectively). Nickel and cadmium contents were significantly higher in the COL-GR than in the NIC-GR beans. Darker roasting decreased AA content, but light roasting maintained similar amounts of CAF and total PPH.

Sign in / Sign up

Export Citation Format

Share Document