scholarly journals DISTRIBUTION, MATERIAL AND CHEMICAL COMPOSITION OF SEDIMENTARY MATTER OF RAINFALL ON THE TERRITORY OF THE KALININGRAD REGION RF

Author(s):  
V.Yu. Topchaya ◽  
E.I. Kotova ◽  
D.P. Starodymova ◽  
V.A. Chechko

Author(s):  
Yu.A. Spirin ◽  
S.I. Zotov ◽  
V.S. Taran ◽  
Yu.V. Koroleva

The aim of the work is to research the chemical composition of surface watercourses in the Slavsky district of the Kaliningrad region in the winter hydrological season, and to compare the results with the data previously obtained by the authors for the autumn hydrological season and partly for the summer hydrological season. Watercourses and monitoring points for research have been identified: r. Zlaya, r. Shluzovaya, r. Nemoninka and r. Osa. In the winter season, water samples were taken, hydrometric characteristics were measured, and primary hydrochemical indicators were determined. On the basis of the obtained hydrochemical data, integral indicators were calculated to assess the quality of water, using combined lists of maximum permissible concentrations of pollutants. When monitoring hydrochemical indicators, it was revealed that the studied watercourses are, to one degree or another, subject to pollution. The water quality class in them varies from "moderately polluted" to "extremely dirty". When comparing the seasons, a tendency was revealed to improve the quality of water, which is associated with the water content of rivers, as well as with the cycles of natural and anthropogenic activity. The work has theoretical and practical significance. The data can participate in the planning of rational use of natural resources and the selection of measures to improve the geoecological state of the river network of the Slavsky region. The research can serve as a supplement to the formation of the general geoecological picture of the Kaliningrad region.



Author(s):  
К. Н. Скворцов ◽  
О. С. Румянцева ◽  
Д. А. Ханин

В статье рассмотрен химический состав и техника нанесения красной эмали гривны, производной от типа Хавор, происходящей из могильника Калиново самбийско-натангийской культуры (Калининградская обл.). Гривна датирована второй половиной I - второй третью II в. н. э. Установлено, что эмаль была изготовлена по «кельтскому» рецепту с высоким содержанием меди и свинца. Однако если состав в данном случае является скорее хронологическим, чем культурноопределяющим признаком, то его сочетание с техникой нанесения эмали (в прорезные углубления-насечки) заставляет искать прототипы данного украшения среди образцов кельтского эмальерного ремесла. Данные о хронологии и технологической традиции, в которой изготовлена гривна, полученные на основании стилистического анализа и состава эмали, хорошо согласуются с результатами комплекса исследований, посвященных данной находке. The article considers the chemical composition and technique of applying the red enamel on the torque derived from the Havor type, originating from the cemetery of Kalinovo of Sambian-Natangian culture (Kaliningrad region). The torque dates back to the second half of I - second third of II c. AD. The enamel was produced using «Celtic» recipe with high copper and lead content. The composition of the enamel in this case is rather chronological than a culturally determining indication. However, its combination with the technique of enamelling (in the slotted recessing notches) gives grounds to search for the prototypes of this decoration among the samples of the Celtic enamel craft. The data on the chronology and technological tradition in which the torque was made, obtained on the basis of stylistic analysis and data on the enamel composition, well agree with the results of a comprehensive studies of this find.



Author(s):  
Yulia Koroleva ◽  
Vladimir Revunkov

Epiphytic lichens are well-known indicators of air contamination. The chemical composition of lichens is affected by the concentration of pollutants in the environment. Usually, researchers assess long-term variations in trace elements or other pollutants in the study area or identify the spatial features of air contamination. The aim of this study is to create a database of trace element concentrations in the samples of the epiphytic lichen Hypogymnia physodes growing in the Kaliningrad region. The database can be used as a ‘reference point’ for monitoring studies. Another objective is to identify the spatial patterns of iron, manganese, nickel, cadmium, silver, lead, strontium, rubidium, and calcium in the Kaliningrad region. The samples of wild lichens were collected from pine and birch trees 1.2-1.8 m from the bases of the threes, using a regular grid, in August 2010. One-two-year-old thalli were used in the chemical analysis. The metals Ag, Cd, Cu, Pb, Ni, Fe, Mn, and Zn were determined by AAS (Mn, Fe by flame AAS and the others by ETA-AAS) and the elements Sr, Rb, and Ca by X-ray fluorescence. The concentration of metals in the western coastal area (the Sambian or Kaliningrad Peninsula) is higher than it is in the central and eastern parts of the region. Principal component factor analysis was carried out to detect and characterise different pollution sources and to identify the most polluted areas. The factors of metal emission were described. The authors examined the features of the spatial distribution of trace elements. Prevailing winds are form south-west. Therefore, the highest concentrations of trace elements were found on the Sambian peninsula and on the coasts of the Vistula and Curonian Lagoons. The high concentrations of trace elements in the samples of the lichen H.physodes, which were observed in the coastal part of the region, are associated with human impact and subsequent pollution. The chemical composition of lichens on the Sambian peninsula may have developed under the impact of both local pollution sources – vehicles, thermal energy facilities, and ports – and such factors as transboundary traffic and sea spray.



2021 ◽  
pp. 135-142
Author(s):  
Svetlana Viktorovna Agafonova ◽  
Artem Igorevich Rykov

The aim of the work was to study the chemical composition of seeds of plants Lupinus albus L., Lupinus angustifolius L., growing in the Kaliningrad region. Lupin is a promising crop due to the high content of biologically valuable protein in its seeds, as well as minerals, unsaturated fatty acids, water - and fat-soluble biologically active substances. The paper considers the amino acid, mineral, and fatty acid composition of seeds, presents data on the content of water-soluble vitamins in them, and shows the component composition of chloroform extracts of seeds. The total number of amino acids (47.72±0.37 and 38.655±0.32%, respectively) was found in the seeds of narrow-leaved and white lupine, and a high content of glutamic acid and asparagine was found. The macronutrient composition, which is dominated by potassium, phosphorus and calcium, was studied. Among the microelements of seeds, manganese, iron, zinc and silicon predominate. A particularly high content of manganese in white lupin seeds (192.14±1.67 mg per 100 g) was noted. Analysis of the fatty acid composition of lupin seed oils showed a high degree of unsaturation with a high content of oleic and linoleic acids. Both types of lupine contain thiamine, pyridoxine, and niacin, while white lupine seeds also contain Pantothenic and folic acids. Сhromatography-mass spectrometry analysis of the fraction isolated by chloroform from lupine seeds showed the presence of substances of the terpenes class (farnesene, neofitadiene, γ-tocopherol) and steriodic alcohols (campesterol, β-sitosterol).



1962 ◽  
Vol 14 ◽  
pp. 149-155 ◽  
Author(s):  
E. L. Ruskol

The difference between average densities of the Moon and Earth was interpreted in the preceding report by Professor H. Urey as indicating a difference in their chemical composition. Therefore, Urey assumes the Moon's formation to have taken place far away from the Earth, under conditions differing substantially from the conditions of Earth's formation. In such a case, the Earth should have captured the Moon. As is admitted by Professor Urey himself, such a capture is a very improbable event. In addition, an assumption that the “lunar” dimensions were representative of protoplanetary bodies in the entire solar system encounters great difficulties.



1976 ◽  
Vol 32 ◽  
pp. 343-349
Author(s):  
Yu.V. Glagolevsky ◽  
K.I. Kozlova ◽  
V.S. Lebedev ◽  
N.S. Polosukhina

SummaryThe magnetic variable star 21 Per has been studied from 4 and 8 Å/mm spectra obtained with the 2.6 - meter reflector of the Crimean Astrophysical Observatory. Spectral line intensities (Wλ) and radial velocities (Vr) have been measured.



Author(s):  
J.R. Mcintosh

The mitotic apparatus is a structure of obvious biological and medical interest, but it has proved to be a difficult cellular machine to understand. The chemical composition of the spindle is only slightly elucidated, largely because of the difficulties in preparing useful isolates of the structure. Chemical studies of the mitotic spindle have been reviewed elsewhere (Mcintosh, 1977), and will not be discussed further here. One would think that structural studies on the mitotic apparatus (MA) in situ would be straightforward, but even with this approach there is some disagreement in the results obtained with various methods and by different investigators. In this paper I will review briefly the approaches which have been used in structural studies of the MA, pointing out the strengths and problems of each approach. I will summarize the principal findings of the different methods, and identify what seem to be fruitful avenues for further work.



Author(s):  
E. A. Elfont ◽  
R. B. Tobin ◽  
D. G. Colton ◽  
M. A. Mehlman

Summary5,-5'-diphenyl-2-thiohydantoin (DPTH) is an effective inhibitor of thyroxine (T4) stimulation of α-glycerophosphate dehydrogenase in rat liver mitochondria. Because this finding indicated a possible tool for future study of the mode of action of thyroxine, the ultrastructural and biochemical effects of DPTH and/or thyroxine on rat liver mere investigated.Rats were fed either standard or DPTH (0.06%) diet for 30 days before T4 (250 ug/kg/day) was injected. Injection of T4 occurred daily for 10 days prior to sacrifice. After removal of the liver and kidneys, part of the tissue was frozen at -50°C for later biocheailcal analyses, while the rest was prefixed in buffered 3.5X glutaraldehyde (390 mOs) and post-fixed in buffered 1Z OsO4 (376 mOs). Tissues were embedded in Araldlte 502 and the sections examined in a Zeiss EM 9S.Hepatocytes from hyperthyroid rats (Fig. 2) demonstrated enlarged and more numerous mitochondria than those of controls (Fig. 1). Glycogen was almost totally absent from the cytoplasm of the T4-treated rats.



Author(s):  
William J. Baxter

In this form of electron microscopy, photoelectrons emitted from a metal by ultraviolet radiation are accelerated and imaged onto a fluorescent screen by conventional electron optics. image contrast is determined by spatial variations in the intensity of the photoemission. The dominant source of contrast is due to changes in the photoelectric work function, between surfaces of different crystalline orientation, or different chemical composition. Topographical variations produce a relatively weak contrast due to shadowing and edge effects.Since the photoelectrons originate from the surface layers (e.g. ∼5-10 nm for metals), photoelectron microscopy is surface sensitive. Thus to see the microstructure of a metal the thin layer (∼3 nm) of surface oxide must be removed, either by ion bombardment or by thermal decomposition in the vacuum of the microscope.



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