Allophanic soils are dark-colored young soils derived mainly from volcanic ash. These soils typically have a low bulk density (< 0.9 Mg/m3), a high water retention capacity (100% by weight at field capacity), and contain predominantly allophanes, imogolite, halloysite, and amorphous Al silicates in the clay fraction. These soils are found in small, restricted areas with volcanic activity. Worldwide, there are about 120 million ha of allophanic soils, which is about 1% of the Earth's ice-free land surface. In tropical regions, allophanic soils are among the most productive and intensively used agricultural soils. They occur in the Philippines, Indonesia, Papua New Guinea, the Caribbean and South Pacific islands, East Africa, Central America, and the Andean rim of South America. Allophanic soils are primarily Andisols and andic Inceptisols, Entisols, Mollisols, and Alfisols according to the Soil Taxonomy classification. Allophanic soils generally have a dark-colored surface soil, slippery or greasy consistency, a predominantly crumb and granular structure, and a low bulk density ranging from 0.3 to 0.8 Mg/m3. Although allophanic soils are apparently well-drained, they still have a very high water content many days after rain. When the soil is pressed between fingers, it gives a plastic, greasy, but non-sticky sensation of a silty or loamy texture. When dry, the soil loses its greasiness and becomes friable and powdery. The low bulk density of allophanic soils is closely related to the high soil porosity. For example, moderately weathered allophanic soils typically have a total porosity of 78%, with macro-, meso-, and micropores occupying 13%, 33%, and 32%, respectively. Water retained in the mesopores is readily available for plant uptake. Water retained in the micropores is held strongly by soil particles and is not readily available for plant use. The macropores provide soil aeration and facilitate water infiltration. The high water retention capacity is also associated with the high soil porosity. In allophanic soils formed under a humid climate, especially those containing large amounts of allophane, the moisture content at field capacity can be as high as 300%, calculated on a weight basis. Such extremely high values of water content seem misleading.
Testing of experimental samples of nanofibrillar cellulose in the production of lightweight coated paper
