PEMBUATAN BIOETANOL DARI KULIT NANAS MELALUI HIDROLISIS DENGAN ASAM

EKUILIBIUM ◽  
2013 ◽  
Vol 12 (1) ◽  
Author(s):  
Ari Diana Susanti

<p>Abstract: Pineapple skin is an agricultural waste that has a carbohydrate content of about<br />10:54% and the skin of pineapple juice glucose levels by 17% so it can be utilized to ethanol.<br />Hydrolysis reaction is so slow that the reaction requires a catalyst. The catalyst used in this<br />study were hydrochloric acid (HCl). This study aims to Learn how to use the skin of pineapple<br />waste as alternative raw material manufacture bioethanol. The variables studied were the<br />concentration of hydrochloric acid, the hydrolysis and fermentation time. Sorghum starch<br />hydrolysis process using a three neck flask equipment, mercury stirrer, heating mantle, cooling<br />behind and a thermometer to measure temperature. Sampling for glucose analysis performed<br />when the temperature reaches 100 ºC every 45 minutes to obtain optimum glucose levels.<br />Glucose samples were analyzed by using the Lane-Eynon. Data analysis showed the longer the<br />higher the hydrolysis of the resulting glucose levels, but there are times when the glucose level<br />will drop over time for glucose resulting damage due to continuous heating. In the fermentation<br />process is carried out with fermentation time of 24 hours, 48jam, 72 hours, 96 hours, 120 hours<br />fiber. The most optimum bacterial activity is a long fermentation for 96 hours. Distillation process<br />carried out on the final results of ethanol fermentation and obtained the highest levels of<br />31.399%.<br />keyword : Pineapple skin, hydrolysis, fermentation, distillation, ethanol.</p>

EKUILIBIUM ◽  
2011 ◽  
Vol 10 (2) ◽  
Author(s):  
Ari Diana Susanti

<p><strong><em>Abstract: </em></strong><em>Pineapple skin is an agricultural waste that has a carbohydrate content of about 10:54% and the skin of pineapple juice glucose levels by 17% so it can be utilized to ethanol. Hydrolysis reaction is so slow that the reaction requires a catalyst. The catalyst used in this study were hydrochloric acid (HCl). This study aims to Learn how to use the skin of pineapple waste as alternative raw material manufacture bioethanol. The variables studied were the concentration of hydrochloric acid, the hydrolysis and fermentation time. Sorghum starch hydrolysis process using a three neck flask equipment, mercury stirrer, heating mantle, cooling behind and a thermometer to measure temperature. Sampling for glucose analysis performed when the temperature reaches 100<sup>o</sup>C every 45 minutes to obtain optimum glucose levels. Glucose samples were analyzed by using the Lane-Eynon. Data analysis showed the longer the higher the hydrolysis of the resulting glucose levels, but there are times when the glucose level will drop over time for glucose resulting damage due to continuous heating. In the fermentation process is carried out with fermentation time of 24 hours, 48 hours, 72 hours, 96 hours, 120 hours fiber. The most optimum bacterial activity is a long fermentation for 96 hours. Distillation process carried out on the final results of ethanol fermentation and obtained the highest levels of 31.399%.</em></p><p><strong><em> </em></strong><strong><em>Keywords</em></strong><em> : Pineapple skin, hydrolysis, fermentation, distillation, ethanol.</em></p><p> </p>


Jurnal Kimia ◽  
2016 ◽  
Author(s):  
Yohanes Armawan Sandi ◽  
Wiwik Susanah Rita ◽  
Yenni Ciawi

The aim of this research is to determine the effect of enzyme and acids concentration on the yield of glucose produced in the hydrolysis of Glacilaria sp. in the production of bioethanol. The concentrations of cellulase used were 200 units/mL, 400 units/mL, 600 units/mL, 800 units/mL and the concentration of sulphuric acid (H2SO4) and hydrochloric acid (HCl) used were 1%, 3%, 5%, 7% (w/v). The concentration of reduction sugar was determined using Anthrone and analyzed using UV-Vis spectrophotometry and the determination of ethanol concentration was carried out by using gas chromatography. The results showed that the contents of reducing sugar produced by sulphuric acid (H2SO4) hydrolysis were 26,19%; 36,69%; 41,40%; 45,0% (v/v), by hydrochloric acid (HCl) were 12,12%; 14,03%; 15,17%; 16,50% (v/v), and by cellulase enzyme were 46,15%; 46,73%; 47,68%; 48,25% (v/v). Optimum concentration of reducing sugar produced by hydrolysis using 800 units/mL cellulase was 48,25% (v/v). The optimum length of fermentation to produce bioethanol using Glacilaria sp. as raw material was 5 days. In the fermentation, inoculum with a concentrations of 5% and 10% (w/v) produced 0,85% and 1,51% (v/v) ethanol.


2016 ◽  
Vol 675-676 ◽  
pp. 31-34
Author(s):  
Achara Kleawkla ◽  
Pannarai Chuenkruth

Sugar is very important raw material of many industries such as food, beverage and renewable energy. In this research, pretreatment and hydrolysis of agricultural wastes to produce reducing sugars for an ethanol production were investigated. The rice stalk and corn stover from agricultural wastes were firstly pretreated with sodium hydroxide at 121 °C in different time as 20 30 and 40 minutes for removal of lignin. After that, the condition of hydrolysis using sulfuric acid of the pretreated rice stalk and corn stover was optimized. The optimum condition that obtained the highest reducing sugar content from rice stalk and corn stover of 76.12 and 136.25 mg/ml were using 1.0 % v/v sulfuric acid at temperature of 121 °C for a hydrolysis time of 40 minutes. This research made value adding in the industrial processing, decrease environmental problem and reduce global warming crisis by optimized utilization of agricultural waste.


2019 ◽  
Vol 15 (1) ◽  
pp. 84-95 ◽  
Author(s):  
Maktum Muharja ◽  
Nur Fadhilah ◽  
Tantular Nurtono ◽  
Arief Widjaja

Coconut husk (CCH) as an abundant agricultural waste in Indonesia has the potential to be utilized for sugar production, which is the intermediate product of biofuel. In this study, subcritical water (SCW) assisted by nitrogen (N2) was developed to enhance the enzymatic hydrolysis of CCH. SCW process was optimized by varying the operation condition: the pressure of 60-100 bar, the temperature of 150-190 °C, and the time of 20-60 min. The SCW-treated solid was subsequently hydrolyzed by utilizing a mixture of commercial cellulase and xylanase enzymes. The result shows that the optimum total sugar yield was obtained under the mild condition of SCW treatment, resulting in the sugar of 15.67 % and 10.31 % gained after SCW and enzymatic hydrolysis process, respectively. SEM and FTIR analysis of SCW-treated solid exhibited the deformation of lignin and solubilization of cellulose and hemicellulose, while XRD and TGA revealed an increase of the amount of crystalline part in the solid residue. The use of N2 in SCW treatment combined with enzymatic hydrolysis in this study suggested that the method can be considered economically for biofuel production from CCH waste in commercial scale. Copyright © 2020 BCREC Group. All rights reserved 


Author(s):  
Dwi Anna Anggorowati ◽  
Sriliani Sriliani ◽  
Anis Artiyani ◽  
Harimbi Setyawati ◽  
Kevin J

Coconut husk waste is waste that has not been used optimally, generally only as a craft material. Seeing the composition of coconut husk, it has the potential to be used as an alternative fuel, one of which is to produce bioethanol products. The purpose of this research was to utilize coconut husk waste as raw material for bioethanol production and to assess the effect of the number of enzymes and time of hydrolysis on the glucose levels produced. In this research, the authors focused on obtaining glucose levels from coconut husks by hydrolysis using cellulase enzymes with an activity of 700 EGU/g. The variations used in this research were the volume of cellulase enzymes (2, 3, 4, 5, 6) ml and the hydrolysis time (4, 8, 12) hours. After the coconut husk undergoes physical and chemical treatment using 10% NaOH, there is a decrease in lignin levels from 44% to 14% and there is an increase in cellulose levels from 24% to 38%, and the use of a cellulase enzyme volume of 2 ml with a hydrolysis time of 4 hours was more optimal with a glucose level of 0.32%.


2021 ◽  
Vol 14 (2) ◽  
pp. 43
Author(s):  
Putra Oktavianto ◽  
Risdiyana Setiawan ◽  
Ilhami Ariyanti ◽  
Muhammad Fadhil Jamil

BIOETHANOL PRODUCTION FROM COCONUT HUSK USING the WET GAMMA IRRADIATION METHOD. The use of coconut husk has only been used as a material for making handicrafts such as ropes, brooms, mats, and others or just burned. The combustion of coconut husk can cause air pollution. In fact, coconut husk can be used as a raw material for bioethanol production so that the beneficial value of coconut husk will also increase. One way of bioethanol production from coconut husk is by irradiating the coconut husk. The coconut husk irradiation technique to be carried out in this study is the wet irradiation technique. Wet irradiation is carried out to accelerate the process of bioethanol production because at the time of irradiation, cellulose has been hydrolyzed and glucose has been formed so that it is more efficient in time and use of the material so that the cellulose hydrolysis process is not necessary. The coconut husk samples were wet because they were mixed with 4% NaOH and were irradiated using a gamma irradiator from STTN-BATAN Yogyakarta with a dose of 30 kGy and 50 kGy and 0 kGy (or without irradiation). Then the sample is fermented with the fungus Saccharomyces Cerevisiae from tape yeast to form ethanol. Ethanol is purified and then analyzed for concentrations using pycnometric and refractometric methods. The result is that the highest ethanol content is without irradiation (0 kGy), this is due to the low dosage used. However, the main point in this wet method research is evidence of hydrolysis of cellulose by the formation of gluoxane after irradiated wet coconut husk, and with Fehling A and B analysis, brown deposits are seen proving that glucose has been formed.


EKUILIBIUM ◽  
2013 ◽  
Vol 12 (1) ◽  
Author(s):  
Enny Kriswiyanti

<p>Abstract : Sweet sorghum stem residues contains high enough cellulose (36.92%)so it can be<br />hydrolyzed to glucose. In this research, hydrolysis of cellulose is carried out using hydrochloric<br />acid catalyst. This research aims to determine the effect of acid catalyst concentration and<br />agitation speed on the resulting reduction of glucose levels and determine the reaction rate<br />constant of hydrolysis of sweet sorghum stem residues. The observed variables were the<br />concentration of hydrochloric acid catalyst (0.5 N, 1 N, 1.5 N, 2 N) and the agitation speed (150<br />rpm, 200 rpm, 250 rpm, 300 rpm). Glucose samples were analyzed by using the Lane-Eynon<br />method. Data analysis showed the higher concentration of hydrochloric acid (HCl) and the<br />agitation speed, the levels of reduced glucose that is formed is also higher. In this study by<br />assuming a first order reaction, the reaction rate constants obtained at variable concentrations of<br />hydrochloric acid catalyst ranged from 0.0010 to 0.0033 / minute and at agitation speeds variable<br />ranged from 0.0023 to 0.0030 / minute.<br />Keywords : sweet sorghum stem residues, hydrochloric acid, hydrolysis, cellulose</p>


WARTA AKAB ◽  
2021 ◽  
Vol 44 (2) ◽  
Author(s):  
Imas Solihat ◽  
Sri Redjeki Setyawati

The process of making bioethanol from Bintaro seeds (CERBERA manghas Lin.) has been carried out with a hydrolysis process through a sulfuric acid catalyst at a temperature of 60oC for 30 minutes and fermentation using yeast. Obtained glucose levels of 1.43% with 1.0 M sulfuric acid catalyst. For 30 minutes of hydrolysis time, a glucose level of 8.8% was obtained after the Bintaro seeds were fermented. Fermentation time for 5 days at a temperatur 100oC gives the ethanol content of 0.17%.


2021 ◽  
Author(s):  
Qurrotun Ayuni Khoirun Nisa ◽  
Vita Paramita

Abstract Due to pandemic, supply of alcohol as desinfectant really needed for nowadays. This research aims to determine the levels of bioethanol produced from banana rods by the hydrolysis process. The target to be achieved with the reactor design is to achieve high ethanol purity using a first order reaction kinetics approach. The study was carried out on various variables including fermentation time (6 - 30 hours), hydrolysis temperature (80 - 90 oC), and substrate enzyme ratio (1: 1 - 1: 3). While the parameters to be tested are glucose levels and bioethanol levels. The optimal effect of the variable on alcohol content is obtained when the alcohol content value is more than 17.2% with an enzyme ratio of 3 - 3.5 at a temperature of 94 - 96 oC for 35 - 40 hours. From the research, it was found that it is possible to enlarge the reactor up to 200 times by using a ratio to obtain the ideal stirred tank reactor dimensions with a conversion of 97.15%.


Author(s):  
Tiska Oktavianis ◽  
Sofiyanita Sofiyanita

Cocoa fruit skin is one of the agricultural wastes can be used as raw material for bioethanol production. Because the cocoa fruit waste containing 39.45% crude fiber and 3.92% glucose. The purpose of this study was to determine the level of optimization of yeast and fermentation time to produce maximum ethanol content. In this study the hydrolysis process cocoa leather is done using fungi Trichoderma viride and fermentation process using yeast Saccharomyses cerevisiae. While for bioethanol concentration measurements performed using vinometer. The results showed that bioethanol fermentation time for 1, 3, 5 and 7 days using yeast levels 2, 4, 6 and 8 grams produce maximum ethanol fermentation at 3 days and 6 grams yeast levels. Produced a maximum ethanol content of 12%.


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