Detailed Modeling of the Alkali/Surfactant/Polymer (ASP) Process by Coupling a Multipurpose Reservoir Simulator to the Chemistry Package PHREEQC

2012 ◽  
Vol 15 (04) ◽  
pp. 423-435 ◽  
Author(s):  
R.. Farajzadeh ◽  
T.. Matsuura ◽  
D.. van Batenburg ◽  
H.. Dijk
Keyword(s):  
Oil Recovery ◽  
Chemical Species ◽  
Chemical Processes ◽  
Flexible Tool ◽  
Flow Equations ◽  
Sector Model ◽  
Coupling Procedure ◽  
Reservoir Simulator ◽  
The Impact ◽  
Multipurpose Reservoir

Summary Accurate modeling of an ASP flood requires detailed representation of geochemistry and, if natural acids are present, the saponification process. Geochemistry and saponification affect the propagation of the injected chemicals and the amount of generated natural soaps. These in turn determine the chemical phase behavior and, hence, the effectiveness of the ASP process. In this paper, it is shown that by coupling a multipurpose reservoir simulator (MPRS) with PHREEQC (Parkhurst and Appelo 1999; Charlton and Parkhurst 2008), a robust and flexible tool is developed to model ASP floods. PHREEQC is used as the chemical-reaction engine, which determines the equilibrium state of the chemical processes modeled. The MPRS models the impact of the chemicals on the flow properties, solves the flow equations, and transports the chemicals. The validity of the approach is confirmed by benchmarking the results with the ASP module of the UTCHEM simulator (Delshad et al. 2000). Moreover, ASP corefloods have been matched with the new tool. The functionality of the model also has been tested on a 2D sector model. The advantages of using PHREEQC as the chemical engine include its rich database of chemical species and its flexibility in changing the chemical processes to be modeled. Therefore, the coupling procedure presented in this paper can also be extended to other chemical enhanced-oil-recovery (EOR) methods.

scholarly journals Evaluation of Polymer Flooding in a Highly Stratified Heterogeneous Reservoir. A Field Case Study

2020 ◽  
Vol 16 ◽  
Keyword(s):  
Oil Recovery ◽  
History Matching ◽  
Lower Layer ◽  
Polymer Flooding ◽  
Economic Life ◽  
Water Flooding ◽  
Base Case ◽  
Sweep Efficiency ◽  
Sector Model ◽  
Reservoir Simulator

Oil and gas companies are looking for proven hydrocarbon reserves from their mature drained reservoirs to extend the production and economic life of these fields. The chemical enhanced oil recovery (CEOR) is an attractive water-based EOR method for these mature fields. The polymer flooding (PF) is a widely applied process in reservoirs with low sweep efficiency after the water flooding (WF). The target Colombian field has one of the first polymer pilots in the region with positive results of oil recovery in “A” sands. Thus, the operator is interested in the expansion of PF for the same reservoir and even in deeper reservoir sands. This paper focuses in the evaluation of different scenarios of PF for the producer in layers A and B with a mechanistic simulation model, thus obtaining new recommendations for the recovery strategy in the field. A sector model was constructed from a full field model using a commercial reservoir simulator to the in-house chemical flooding reservoir simulator: UTCHEMRS. This sector model was also migrated to a second commercial simulator allowing a performance comparison for these three simulators. UTCHEMRS model results were compared with the commercial simulators through the history matching (HM) phase. The primary and waterflood history match was in agreement with the field data. Simulation results suggested that PF for the base case in “A” sands presented an incremental oil recovery of up to 12% additional to water flooding. Additionally, PF was extended to the lower layer “B” sand to investigate the potential of polymer injection. The PF injection in both reservoirs simultaneously loses sweep efficiency and decreases the oil recovery to about 3%. However, a hypothetical case of new infill producer wells with the objective of testing the individual reservoir performance has revealed that PF is having significant upside from B sands as well.

Recent Advances in Speciation Analyses of Tobacco and Other Important Economic Crops

2020 ◽  
Vol 17 ◽  
Author(s):  
Zhiping Jiang ◽  
Zhizhang Tian ◽  
Chuntao Zhang ◽  
Dengke Li ◽  
Ruoxin Wu ◽  
...  
Keyword(s):  
Method Comparison ◽  
Chemical Species ◽  
Complete Information ◽  
Speciation Analysis ◽  
Elemental Content ◽  
Specific Element ◽  
Balance Accuracy ◽  
Comprehensive Knowledge ◽  
Total Elemental Content ◽  
The Impact

Background: Speciation analysis is defined as the analytical activities of identifying and/or measuring the quantities of one or more individual chemical species in a sample. The knowledge of elemental species provides more complete information about mobility, bioavailability and the impact of elements on ecological systems or biological organisms. It is no longer sufficient to quantitate the total elemental content of samples to define toxicity or essentiality. Thus speciation analysis is of vital importance and generally offers a better understanding of a specific element. Discussion: Thorough speciation scheme consisting of sampling, sample preparation, species analysis and evaluation were described. Special emphasis is placed on recent speciation analysis approaches including both direct and coupling methods. A current summary of advantages and limitations of the various methods as well as an illustrative method comparison are presented. Certain elements and species of interest are briefly mentioned and practical examples of speciation applications in tobacco and other important economic crops are also discussed. Aim/Conclusion: This review aims to offer comprehensive knowledge about elemental speciation and provide readers with valuable information. Many strategies have been developed for the determination of multiple elemental species in tobacco and other important economic crops. Nevertheless, it is an eternal pursuit to establish speciation methods which can balance accuracy, agility as well as universality.

scholarly journals Experimental study of the supercritical CO 2 diffusion coefficient in porous media under reservoir conditions

2019 ◽  
Vol 6 (6) ◽  
pp. 181902 ◽  
Author(s):  
Junchen Lv ◽  
Yuan Chi ◽  
Changzhong Zhao ◽  
Yi Zhang ◽  
Hailin Mu
Keyword(s):  
Porous Media ◽  
Diffusion Coefficient ◽  
Oil Recovery ◽  
Carbon Capture ◽  
Carbon Capture And Storage ◽  
Elevated Pressure ◽  
Experimental Results ◽  
Saturated Porous Media ◽  
Reservoir Conditions ◽  
The Impact

Reliable measurement of the CO 2 diffusion coefficient in consolidated oil-saturated porous media is critical for the design and performance of CO 2 -enhanced oil recovery (EOR) and carbon capture and storage (CCS) projects. A thorough experimental investigation of the supercritical CO 2 diffusion in n -decane-saturated Berea cores with permeabilities of 50 and 100 mD was conducted in this study at elevated pressure (10–25 MPa) and temperature (333.15–373.15 K), which simulated actual reservoir conditions. The supercritical CO 2 diffusion coefficients in the Berea cores were calculated by a model appropriate for diffusion in porous media based on Fick's Law. The results show that the supercritical CO 2 diffusion coefficient increases as the pressure, temperature and permeability increase. The supercritical CO 2 diffusion coefficient first increases slowly at 10 MPa and then grows significantly with increasing pressure. The impact of the pressure decreases at elevated temperature. The effect of permeability remains steady despite the temperature change during the experiments. The effect of gas state and porous media on the supercritical CO 2 diffusion coefficient was further discussed by comparing the results of this study with previous study. Based on the experimental results, an empirical correlation for supercritical CO 2 diffusion coefficient in n -decane-saturated porous media was developed. The experimental results contribute to the study of supercritical CO 2 diffusion in compact porous media.

scholarly journals Shock interactions in inviscid air and $$\hbox {CO}_2$$–$$\hbox {N}_2$$ flows in thermochemical non-equilibrium

Shock Waves ◽  
2021 ◽  
Author(s):  
C. Garbacz ◽  
W. T. Maier ◽  
J. B. Scoggins ◽  
T. D. Economon ◽  
T. Magin ◽  
...  
Keyword(s):  
Chemical Species ◽  
High Energy ◽  
Ideal Gas ◽  
Shock Interaction ◽  
Interaction Patterns ◽  
Shock Interactions ◽  
Wave Interference ◽  
Type V ◽  
The Impact ◽  
Non Equilibrium

AbstractThe present study aims at providing insights into shock wave interference patterns in gas flows when a mixture different than air is considered. High-energy non-equilibrium flows of air and $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 over a double-wedge geometry are studied numerically. The impact of freestream temperature on the non-equilibrium shock interaction patterns is investigated by simulating two different sets of freestream conditions. To this purpose, the SU2 solver has been extended to account for the conservation of chemical species as well as multiple energies and coupled to the Mutation++ library (Multicomponent Thermodynamic And Transport properties for IONized gases in C++) that provides all the necessary thermochemical properties of the mixture and chemical species. An analysis of the shock interference patterns is presented with respect to the existing taxonomy of interactions. A comparison between calorically perfect ideal gas and non-equilibrium simulations confirms that non-equilibrium effects greatly influence the shock interaction patterns. When thermochemical relaxation is considered, a type VI interaction is obtained for the $$\hbox {CO}_2$$ CO 2 -dominated flow, for both freestream temperatures of 300 K and 1000 K; for air, a type V six-shock interaction and a type VI interaction are obtained, respectively. We conclude that the increase in freestream temperature has a large impact on the shock interaction pattern of the air flow, whereas for the $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 flow the pattern does not change.

Waterflooding in Carbonate Reservoirs: Does the Salinity Matter?

2014 ◽  
Vol 17 (03) ◽  
pp. 304-313 ◽  
Author(s):  
A.M.. M. Shehata ◽  
M.B.. B. Alotaibi ◽  
H.A.. A. Nasr-El-Din
Keyword(s):  
Oil Recovery ◽  
Sudden Change ◽  
Oil Production ◽  
Deionized Water ◽  
Production Performance ◽  
Shallow Aquifer ◽  
Secondary Recovery ◽  
Tertiary Recovery ◽  
The Impact ◽  
Indiana Limestone

Summary Waterflooding has been used for decades as a secondary oil-recovery mode to support oil-reservoir pressure and to drive oil into producing wells. Recently, the tuning of the salinity of the injected water in sandstone reservoirs was used to enhance oil recovery at different injection modes. Several possible low-salinity-waterflooding mechanisms in sandstone formations were studied. Also, modified seawater was tested in chalk reservoirs as a tertiary recovery mode and consequently reduced the residual oil saturation (ROS). In carbonate formations, the effect of the ionic strength of the injected brine on oil recovery has remained questionable. In this paper, coreflood studies were conducted on Indiana limestone rock samples at 195°F. The main objective of this study was to investigate the impact of the salinity of the injected brine on the oil recovery during secondary and tertiary recovery modes. Various brines were tested including deionized water, shallow-aquifer water, seawater, and as diluted seawater. Also, ions (Na+, Ca2+, Mg2+, and SO42−) were particularly excluded from seawater to determine their individual impact on fluid/rock interactions and hence on oil recovery. Oil recovery, pressure drop across the core, and core-effluent samples were analyzed for each coreflood experiment. The oil recovery using seawater, as in the secondary recovery mode, was, on the average, 50% of original oil in place (OOIP). A sudden change in the salinity of the injected brine from seawater in the secondary recovery mode to deionized water in the tertiary mode or vice versa had a significant effect on the oil-production performance. A solution of 20% diluted seawater did not reduce the ROS in the tertiary recovery mode after the injection of seawater as a secondary recovery mode for the Indiana limestone reservoir. On the other hand, 50% diluted seawater showed a slight change in the oil production after the injection of seawater and deionized water slugs. The Ca2+, Mg2+, and SO42− ions play a key role in oil mobilization in limestone rocks. Changing the ion composition of the injected brine between the different slugs of secondary and tertiary recovery modes showed a measurable increase in the oil production.

Advanced Multi-Disciplinary Simulation Workflow for Well Placement, Hydraulic Fracturing and Production Optimization Applied to the Diyab Unconventional Play in Onshore UAE

2021 ◽  
Author(s):  
Hamid Pourpak ◽  
Samuel Taubert ◽  
Marios Theodorakopoulos ◽  
Arnaud Lefebvre-Prudencio ◽  
Chay Pointer ◽  
...  
Keyword(s):  
Hydraulic Fracturing ◽  
United Arab Emirates ◽  
Reservoir Characterization ◽  
Horizontal Wells ◽  
Production Optimization ◽  
Production Performance ◽  
Well Placement ◽  
Fully Integrated ◽  
Sector Model ◽  
The Impact

Abstract The Diyab play is an emerging unconventional play in the Middle East. Up to date, reservoir characterization assessments have proved adequate productivity of the play in the United Arab Emirates (UAE). In this paper, an advanced simulation and modeling workflow is presented, which was applied on selected wells located on an appraisal area, by integrating geological, geomechanical, and hydraulic fracturing data. Results will be used to optimize future well landing points, well spacing and completion designs, allowing to enhance the Stimulated Rock Volume (SRV) and its consequent production. A 3D static model was built, by propagating across the appraisal area, all subsurface static properties from core-calibrated petrophysical and geomechanical logs which originate from vertical pilot wells. In addition, a Discrete Fracture Network (DFN) derived from numerous image logs was imported in the model. Afterwards, completion data from one multi-stage hydraulically fracked horizontal well was integrated into the sector model. Simulations of hydraulic fracturing were performed and the sector model was calibrated to the real hydraulic fracturing data. Different scenarios for the fracture height were tested considering uncertainties related to the fracture barriers. This has allowed for a better understanding of the fracture propagation and SRV creation in the reservoir at the main target. In the last step, production resulting from the SRV was simulated and calibrated to the field data. In the end, the calibrated parameters were applied to the newly drilled nearby horizontal wells in the same area, while they were hydraulically fractured with different completion designs and the simulated SRVs of the new wells were then compared with the one calculated on the previous well. Applying a fully-integrated geology, geomechanics, completion and production workflow has helped us to understand the impact of geology, natural fractures, rock mechanical properties and stress regimes in the SRV geometry for the unconventional Diyab play. This work also highlights the importance of data acquisition, reservoir characterization and of SRV simulation calibration processes. This fully integrated workflow will allow for an optimized completion strategy, well landing and spacing for the future horizontal wells. A fully multi-disciplinary simulation workflow was applied to the Diyab unconventional play in onshore UAE. This workflow illustrated the most important parameters impacting the SRV creation and production in the Diyab formation for he studied area. Multiple simulation scenarios and calibration runs showed how sensitive the SRV can be to different parameters and how well placement and fracture jobs can be possibly improved to enhance the SRV creation and ultimately the production performance.

Nonlinear mixed convective Williamson nanofluid flow with the suspension of gyrotactic microorganisms

2021 ◽  
pp. 2150145
Author(s):  
Shuang-Shuang Zhou ◽  
M. Ijaz Khan ◽  
Sumaira Qayyum ◽  
B. C. Prasannakumara ◽  
R. Naveen Kumar ◽  
...  
Keyword(s):  
Heat Source ◽  
Lewis Number ◽  
Solution Procedure ◽  
Energy Concentration ◽  
Gyrotactic Microorganisms ◽  
Dimensionless Parameters ◽  
Flow Equations ◽  
Fluid Parameter ◽  
Source Sink ◽  
The Impact

This investigation aims to present the thermally developed bioconvection flow of Williamson nanoliquid over an inclined stretching cylinder in presence of linear mixed convection and nonuniform heat source/sink. The activation energy and suspension of gyrotactic microorganisms are accounted with applications of bioconvection phenomenon. Appropriate nondimensional variables are opted to attain the dimensionless form of flow equations. The resulting momentum, energy, concentration and motile density equations are abridged to highly coupled and nonlinear in nature. The numerical treatment is followed for the solution procedure by employing the shooting method. The influence of some relevant dimensionless parameters is discoursed graphically along with physical justifications. Moreover, the impact of several dimensionless parameters on skin friction and Nusselt number is obtained and listed in tables. It is observed that the velocity of fluid shows a decreasing variation for Williamson fluid parameter. The change in unsteadiness parameter and heat source parameter enhanced the nanofluid temperature. The motile microorganisms profile declines with bioconvection constant and bio-convection Lewis number.

Modeling to support physicochemical enhancement techniques

2021 ◽  
pp. 79-90
Author(s):  
Т. A. Pospelova
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Oil And Gas ◽  
Chemical Modeling ◽  
Comparative Structure ◽  
Water Cut ◽  
Physical And Chemical ◽  
Oil And Gas Companies ◽  
The Impact ◽  
Selection Of

The article discusses ways to increase the oil recovery factor in already developed fields, special attention is paid to the methods of enhanced oil recovery. The comparative structure of oil production in Russia in the medium term is given. The experience of oil and gas companies in the application of enhanced oil recovery in the fields is analyzed and the dynamics of the growth in the use of various enhanced oil recovery in Russia is estimated. With an increase in the number of operations in the fields, the requirements for the selection of candidates inevitably increase, therefore, the work focuses on hydrodynamic modeling of physical and chemical modeling, highlights the features and disadvantages of existing simulators. The main dependences for adequate modeling during polymer flooding are given. The calculation with different concentration of polymer solution is presented, which significantly affects the water cut and further reduction of operating costs for the preparation of the produced fluid. The possibility of creating a specialized hydrodynamic simulator for low-volume chemical enhanced oil recovery is considered, since mainly simulators are applicable for chemical waterflooding and the impact is on the formation as a whole.

The Impact of Ionic Liquid and Nanoparticles on Stabilizing Foam for Enhanced Oil Recovery

2018 ◽  
Vol 3 (44) ◽  
pp. 12461-12468
Author(s):  
Lei Jiang ◽  
Jingtao Sun ◽  
Jiqian Wang ◽  
Qi Xue ◽  
Songyan Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
The Impact
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