Sorption and transport of Mn2+ in soil amended with alkali modified pomelo biochar

Author(s):  
Qiang An ◽  
Sheng Zhu ◽  
Zheng Li ◽  
Shu-man Deng ◽  
Bin Zhao ◽  
...  

Abstract Owing to its effectiveness and environment-friendly, biochar has been used for adsorbing and immobilizing pollutants in soil in recent years of studies, which is also suitable for manganese pollution in soil caused by manganese mining and processing activities. In this research, alkali modified pomelo biochar (MBC) was regarded as a soil amendment, the improvement of soil physicochemical properties as well as Mn 2+ sorption and transport in soil by modifying with MBC were investigated. In incubation experiment, 0-10% (w/w) MBC addition amount significantly improved the physicochemical properties of soil. Due to the amelioration of soil physicochemical properties along with the oxygen-containing functional groups and the developed pore structure of MBC itself, the adsorption capacity of MBC modification soil towards Mn 2+ (q e ) was enhanced in batch adsorption experiment, and q e increased by 10-108% when MBC ratio grew from 0 to 10% at 300 mg·L -1 Mn 2+ solution. In column migration experiment, the Mn 2+ retention rate climbed by 13-106% from 0 to 10% MBC addition proportion when adopted the MBC filling way that placed MBC on the soil upper layer , and the reinforced restriction on Mn 2+ transport in soil amended with MBC might ascribe to the enhanced q e as well as the reduced saturated hydraulic conductivity. These results proved that MBC effectively augmented adsorption ability and suppressed transport of Mn 2+ in soil, which could provide an available mind on prevention and remediation of soil Mn contamination.

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2617
Author(s):  
Alicja Szatanik-Kloc ◽  
Justyna Szerement ◽  
Agnieszka Adamczuk ◽  
Grzegorz Józefaciuk

Thousands of tons of zeolitic materials are used yearly as soil conditioners and components of slow-release fertilizers. A positive influence of application of zeolites on plant growth has been frequently observed. Because zeolites have extremely large cation exchange capacity, surface area, porosity and water holding capacity, a paradigm has aroused that increasing plant growth is caused by a long-lasting improvement of soil physicochemical properties by zeolites. In the first year of our field experiment performed on a poor soil with zeolite rates from 1 to 8 t/ha and N fertilization, an increase in spring wheat yield was observed. Any effect on soil cation exchange capacity (CEC), surface area (S), pH-dependent surface charge (Qv), mesoporosity, water holding capacity and plant available water (PAW) was noted. This positive effect of zeolite on plants could be due to extra nutrients supplied by the mineral (primarily potassium—1 ton of the studied zeolite contained around 15 kg of exchangeable potassium). In the second year of the experiment (NPK treatment on previously zeolitized soil), the zeolite presence did not impact plant yield. No long-term effect of the zeolite on plants was observed in the third year after soil zeolitization, when, as in the first year, only N fertilization was applied. That there were no significant changes in the above-mentioned physicochemical properties of the field soil after the addition of zeolite was most likely due to high dilution of the mineral in the soil (8 t/ha zeolite is only ~0.35% of the soil mass in the root zone). To determine how much zeolite is needed to improve soil physicochemical properties, much higher zeolite rates than those applied in the field were studied in the laboratory. The latter studies showed that CEC and S increased proportionally to the zeolite percentage in the soil. The Qv of the zeolite was lower than that of the soil, so a decrease in soil variable charge was observed due to zeolite addition. Surprisingly, a slight increase in PAW, even at the largest zeolite dose (from 9.5% for the control soil to 13% for a mixture of 40 g zeolite and 100 g soil), was observed. It resulted from small alterations of the soil macrostructure: although the input of small zeolite pores was seen in pore size distributions, the larger pores responsible for the storage of PAW were almost not affected by the zeolite addition.


CATENA ◽  
2021 ◽  
Vol 202 ◽  
pp. 105284
Author(s):  
Yafu Zhang ◽  
Jinman Wang ◽  
Yu Feng

Agronomy ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1529
Author(s):  
Ahmad Numery Ashfaqul Haque ◽  
Md. Kamal Uddin ◽  
Muhammad Firdaus Sulaiman ◽  
Adibah Mohd Amin ◽  
Mahmud Hossain ◽  
...  

A pot experiment was executed to investigate the impact of biochar and compost with water-saving irrigation on the rice yield, water use efficiency, and physicochemical properties of soil. Two irrigation regimes—namely alternate wetting and drying (AWD) and continuous flooding (CF)—and four types of organic amendments (OA)—namely rice husk biochar (RHB), oil palm empty fruit bunch biochar (EFBB), compost and a control—were applied to evaluate their effects. Under the AWD irrigation regime, the maximum grain was produced by RHB (241.12 g), whereas under the same organic amendments, both AWD and CF produced a similar grain yield. Under the same organic amendment, a significantly higher water use efficiency (WUE) was observed from the AWD irrigation with RHB (6.30 g L−1) and EFBB (5.80 g L−1). Within the same irrigation regime, soil pH, cation exchange capacity, total carbon, total nitrogen and available phosphorus were enhanced due to the incorporation of biochar and compost, while higher soil exchangeable potassium was observed under CF irrigation for all treatments. RHB and EFBB significantly reduced the soil bulk density (up to 20.70%) and increased porosity (up to 16.70%) under both irrigation regimes. The results imply that the use of biochar with AWD irrigation could enhance the nutrient uptake and physicochemical properties of soil and allow rice to produce a greater yield with less water consumption.


2020 ◽  
Vol 112 (5) ◽  
pp. 4358-4372
Author(s):  
Meiqi Chen ◽  
Jisheng Xu ◽  
Zengqiang Li ◽  
Bingzi Zhao ◽  
Jiabao Zhang

2008 ◽  
Vol 396-398 ◽  
pp. 65-68
Author(s):  
Elena Mavropoulos ◽  
Nilce C.C. da Rocha ◽  
Andrea Machado Costa ◽  
Maria Helena M. Rocha-Leão ◽  
Alexandre Mello ◽  
...  

In this study, the insulin adsorption ability by synthetic hydroxyapatite was investigated. Hydroxyapatite before thermal treatment and heated at 900°C and 1100°C were incubated in a solution containing 32 mg insulin/gHA. Adsorption and desorption experiments were carried out at 37°C under constant and slowly stirring. From FTIR results it was observed that insulin was tightly attached to HA surface after 96 hours adsorption experiment. Thermal pre-treatment on HA samples had no effect on insulin adsorption. However, protein desorption was more pronounced on samples not submitted to thermal treatment.


2021 ◽  
Vol 10 (1) ◽  
pp. 3492-3500
Author(s):  
Vipin Y. Borole ◽  
◽  
Sonali B. Kulkarni ◽  

Soil properties may be varied by spatially and temporally with different agricultural practices. An accurate and reliable soil properties assessment is challenging issue in soil analysis. The soil properties assessment is very important for understanding the soil properties, nutrient management, influence of fertilizers and relation between soil properties which are affecting the plant growth. Conventional laboratory methods used to analyses soil properties are generally impractical because they are time-consuming, expensive and sometimes imprecise. On other hand, Visible and infrared spectroscopy can effectively characterize soil. Spectroscopic measurements are rapid, precise and inexpensive. Soil spectroscopy has shown to be a fast, cost-effective, environmentally friendly, non-destructive, reproducible and repeatable analytical technique. In the present research, we use spectroscopy techniques for soil properties analysis. The spectra of agglomerated farming soils were acquired by the ASD Field spec 4 spectroradiometer. Different fertilizers treatment applied soil samples are collected in pre monsoon and post monsoon season for 2 year (4 season) for banana and cotton crops in the form of DS-I and DS-II respectively. The soil spectra of VNIR region were preprocessed to get pure spectra. Then process the acquired spectral data by statistical methods for quantitative analysis of soil properties. The detected soil properties were carbon, Nitrogen, soil organic matter, pH, phosphorus, potassium, moisture sand, silt and clay. Soil pH is most important chemical properties that describe the relative acidity or alkalinity of the soil. It directly effect on plant growth and other soil properties. The relationship between pH properties on soil physical and chemical parameters and their influence were analyses by using linear regression model and show the performance of regression model with R2 and RMSE. Keywords soil; physicochemical properties; spectroscopy; pH


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