Effect of Alteration on the Geochemistry and Mechanical Properties of Granite from Pingjiang, Hunan Province, China
Abstract The effect of alteration on the geochemistry and mechanical properties of granite from Pingjiang, Hunan Province, China was investigated. Six weathered and 14 hydrothermally altered samples in three footrills (PD2, PD3, and PD4) were collected for mechanical tests and major and trace element analysis. The results show that the relationship between mechanical strength and the degree of alteration, irrespective of whether this is due to weathering or hydrothermal alteration, can be described by an exponential equation. This implies that the mechanical strength decreases rapidly even at low degrees of alteration. Granite Na2O, CaO, K2O, and SiO2 contents were lowered due to weathering, whereas Fe2O3T contents increased significantly due to Fe2+ oxidation. Based on the hypothesis that Al and Zr are immobile during the hydrothermal alteration, the mobility indexes of various elements were calculated for the hydrothermally altered samples. In general, TiO2, K2O, Fe2O3T, Th, Hf, Co, Ni, and V contents were unaffected by hydrothermal alteration; Na2O, Sr, Nd, Sm, and Pb contents were lowered by hydrothermal alteration; and SiO2, Rb, Cr, U, Zn, Mn, and Cs contents were increased due to reactions with the hydrothermal fluids. Even immobile elements, such as Sm, Nd, V, and Cr, were mobilized by high-temperature hydrothermal fluids. To assess the degree of hydrothermal alteration, a new model is required that can account for the effects of the different mineral components.