scholarly journals Archaeometric studies on a Pompeian blue glass fragment from Regio I, Insula 14 for the characterization of glassmaking technology

Author(s):  
Monica Gelzo ◽  
Gaetano Corso ◽  
Alessandro Vergara ◽  
Manuela Rossi ◽  
Oto Miedico ◽  
...  

Abstract A Pompeian glass sample found in Reg. I, Insula 14, during the 1950’s Pompeii excavation was examined by Raman and Fourier transformed infrared spectroscopy, scanning electron microscopy, and inductively coupled plasma mass spectrometry. The analyzed specimen was selected based on its intense blue color and its well-preserved aspect. The purpose of the work was the chemical characterization of Pompeii’s glass in correlation to the actual knowledge of Roman glassmaking technology from the Mediterranean area. The results suggested that the Pompeii’s glass was a soda-lime-silica glass, but with a higher calcium content that, given the low content of lead, was used to stabilize the glass. The sample was in origin produced most likely as non-decolorized primary raw materials from eastern Mediterranean sites. Moreover, the intense blue color was related to the use mainly of cobalt, present in a weighty amount, and likely used as important coloring agents in the ancient secondary glass-making workshop.

2019 ◽  
Vol 323 (2) ◽  
pp. 861-874
Author(s):  
Predrag Kuzmanović ◽  
Nataša Todorović ◽  
Jovana Nikolov ◽  
Jovana Knežević ◽  
Bojan Miljević

2012 ◽  
Vol 358 (23) ◽  
pp. 3280-3288 ◽  
Author(s):  
S. Petrescu ◽  
M. Constantinescu ◽  
E.M. Anghel ◽  
I. Atkinson ◽  
M. Olteanu ◽  
...  

2019 ◽  
Vol 11 (7) ◽  
pp. 1995 ◽  
Author(s):  
Sabrina Cajamarca ◽  
Douglas Martins ◽  
Juscimar da Silva ◽  
Mariana Fontenelle ◽  
Ítalo Guedes ◽  
...  

Several agro-industrial, livestock, and food wastes can be recycled to create biofertilizers. This diversity of raw materials can result in nutritional imbalance and an increase in heavy metal content, which could make the final product unfeasible. Thus, the chemical characterization of the raw materials and their influence on the sustainable and safe production of biofertilizers need to be better understood. In this context, the objective of the present study was to evaluate the chemical characteristics of agro-industrial residues used in the manufacture of an aerobic liquid biofertilizer. We analyzed the macronutrient, micronutrient, and trace metal contents of seven waste products used as raw materials to create a biofertilizer. In addition, a survey of secondary biofertilizer data from different residues was carried out that showed great heterogeneity in the chemical compositions of these residues, which has a direct impact on the agronomic efficiency of these biofertilizers. The characterization revealed that some materials may be contaminants of the soil, due to high levels of trace metals, especially cadmium. We conclude that the generation of detailed inventories, such as those of the nutrient and heavy metal contents of the raw materials and biofertilizers produced, is indispensable for the correct recommendation of biologically-based inputs in agriculture.


Coatings ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1091
Author(s):  
Alexandra Inberg ◽  
Dana Ashkenazi ◽  
Yishai Feldman ◽  
Omri Dvir ◽  
Deborah Cvikel

Fragments of decorated floor tiles were retrieved from the Akko Tower shipwreck, Israel. Most tiles were made of bright brown fired clay with a white glaze decorated with colored stenciled motifs (Type A); and others consisted of a red-brown fired clay body, coated with a brown pigment covered with transparent brown glaze (Type B). This study aimed to characterize the two tile types; to reveal information concerning the manufacturing process; and to determine the origin of their raw material. A multidisciplinary approach was used, including light microscopy, SEM-EDS, electron probe microanalysis with wavelength-dispersive X-ray spectroscopy (EPMA-WDS), XRD, Raman spectroscopy, and time-of-flight secondary ion mass spectrometry (TOF-SIMS) analyses. The characterization of both tile types demonstrated the use of different raw materials. The Type A tiles were covered with tin-opacified majolica glaze and colored with various mixtures of pigments. The blue color was due to pigment rich in cobalt; the yellow color was due to Naples yellow and lead-tin yellow I minerals; and the green, orange, and brown colors were all prepared by mixing the Naples yellow pigment with different minerals. These majolica glaze tiles were probably manufactured in Sicily. The brown coating of the Type B tiles was due to pigment rich in lead and iron minerals. These tiles were produced with different manufacturing processes, and apparently made in France.


Clay Minerals ◽  
2009 ◽  
Vol 44 (1) ◽  
pp. 1-17 ◽  
Author(s):  
E. M. M. Marwa ◽  
S. Hillier ◽  
C. M. Rice ◽  
A. A. Meharg

AbstractVermiculite minerals are locally available in the Mozambique Belt of Tanzania but are not currently commercially exploited. In part this may be due to lack of any precise characterization. This study was carried out as a first step to assess the suitability of these vermiculites for crop production by characterization of their mineralogical and chemical compositions. X-ray diffraction and scanning electron microscopy combined with an energy-dispersive X-ray system were used to establish the mineralogy. Electron microprobe analysis and inductively coupled plasma-mass spectrometry were used to study the chemical compositions and to identify any possible issues related to chemical composition that might affect their use if applied as soil conditioners. The samples were characterized as vermiculites and hydrobiotites with a wide variety of accessory minerals. Accessory minerals that might be of some concern are galena, fibrous amphiboles and sepiolite. The total levels of Ni in all vermiculites, and Cr in some, were also found to be high relative to common European standards and this might limit their potential as soil conditioners. It is clear that a field assessment of the bioavailability of various elements would be necessary before decisions relating to potential agricultural use could be made.


2019 ◽  
Vol 323 (3) ◽  
pp. 1451-1457 ◽  
Author(s):  
V. Sharma ◽  
R. Acharya ◽  
S. K. Samanta ◽  
M. Goswami ◽  
H. K. Bagla ◽  
...  

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