High-Performance Polymeric Materials

1987 ◽  
Author(s):  
J. E. Mark
Keyword(s):  
High Performance ◽  
Polymeric Materials

A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

Molecular materials for micro-electronics

2000 ◽  
Vol 78 (3) ◽  
pp. 231-241 ◽  
Author(s):  
M D'Iorio
Keyword(s):  
High Performance ◽  
Organic Materials ◽  
Coming Of Age ◽  
Polymeric Materials ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Plastic Electronics ◽  
Organic Light ◽  
Recent Developments

Molecular organic materials have had an illustrious past but the ability to deposit these as homogeneous thin films has rejuvenated the field and led to organic light-emitting diodes (OLEDs) and the development of an increasing number of high-performance polymers for nonlinear and electronic applications. Whereas the use of organic materials in micro-electronics was restricted to photoresists for patterning purposes, polymeric materials are coming of age as metallic interconnects, flexible substrates, insulators, and semiconductors in all-plastic electronics. The focus of this topical review will be on organic light-emitting devices with a discussion of the most recent developments in electronic devices.PACS Nos.: 85.60Jb, 78.60Fi, 78.55Kz, 78.66Qn, 73.61Ph, 72.80Le

High-performance polymer composites with enhanced mechanical and thermal properties from cyanate ester/benzoxazine resin and short Kevlar/glass hybrid fibers

2018 ◽  
Vol 31 (6) ◽  
pp. 719-732 ◽  
Author(s):  
Abdeldjalil Zegaoui ◽  
Mehdi Derradji ◽  
Abdul Qadeer Dayo ◽  
Aboubakr Medjahed ◽  
Hui-yan Zhang ◽  
...  
Keyword(s):  
Thermal Properties ◽  
High Performance ◽  
Hybrid Composites ◽  
Glass Fibers ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Cyanate Ester ◽  
Resin Matrix ◽  
Mechanical And Thermal Properties ◽  
Hybrid Fibers

The investigation and design of new polymeric materials with an astonishing combination of properties are nowadays of great importance to facilitate the manufacturing process of high-quality products intended to be utilized in different applications and technical fields. For this intent, novel high-performance blend composites composed of the cyanate ester/benzoxazine resin blend reinforced by different proportions of silane-surface modified Kevlar and glass fibers were successfully fabricated by a compression molding technique and characterized by different experimental tests. The mechanical test results revealed that the bending and impact strength properties were considerably improved when increasing the amount of the hybrid fibers. The studied materials also presented excellent thermal stabilities as compared to the unfilled blend’s properties. With respect to the properties of the reinforcing systems, these improvements seen in either the mechanical or thermal properties could be due to the good dispersion as well as excellent adhesion of the reinforcing fibers inside the resin matrix, which were further evidenced by the Fourier transform infrared spectroscopy and scanning electron microscopy results. Consequently, the improved mechanical and thermal properties promote the use of the fabricated hybrid composites in domestic and industrial applications requiring functional materials with advanced properties for aerospace and military applications.

Thermal Contact Resistance of Phase Change and Grease Type Polymeric Materials

2000 ◽  
Author(s):  
Ravi S. Prasher ◽  
Craig Simmons ◽  
Gary Solbrekken
Keyword(s):  
Thermal Conductivity ◽  
Contact Resistance ◽  
Phase Change ◽  
High Performance ◽  
Phase Change Materials ◽  
Thermal Contact ◽  
Polymeric Materials ◽  
Thermal Interface Material ◽  
Heat Spreader ◽  
Thermal Grease

Abstract Thermal interface material (TIM) between the die and the heat spreader or between the heat spreader and the heat sink in any electronic package plays a very important role in the thermal management of electronic cooling. Due to increased power and power density high-performance TIMs are sought every day. Phase change materials (PCM) seem to be very good alternative to traditionally used thermal greases because of various reasons. These phase change materials also have the advantage of being reworked easily without damaging the die. Typically these phase change materials are polymer based and are particle laden to enhance their thermal conductivity. The thermal conductivity of these materials is relatively well understood than their contact resistance. Current work focuses on explicitly measuring the contact resistance and the thermal conductivity of a particular phase change TIM and some silicon-based greases. Effect of various parameters, which can affect the contact resistance of theses TIMs and Greases, are also captured. The steady state measurements of the thermal conductivity and the contact resistance was done on an interface tester. In general the work on the contact resistance of fluid-like polymer based TIM, such as thermal grease or phase change polymer has been experimental in the past. A semi-analytical model, which captures the various parameters affecting the contact resistance of two class of materials; the phase change and the thermal grease is also developed in this paper. This model fits very well with the experimental data.

A novel combination of Mirage and FTIR spectroscopy for nondestructive characterization of high performance polymeric materials

1998 ◽  
Vol 11 (2) ◽  
pp. 129-134 ◽  
Author(s):  
Pandey ◽  
Boccara ◽  
Ajay Kumar ◽  
Fournier
Keyword(s):  
Ftir Spectroscopy ◽  
High Performance ◽  
Polymeric Materials ◽  
Nondestructive Characterization

scholarly journals Enhanced O2/N2 Separation of Mixed-Matrix Membrane Filled with Pluronic-Compatibilized Cobalt Phthalocyanine Particles

Membranes ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 75 ◽  
Author(s):  
S. A. S. C. Samarasinghe ◽  
Chong Yang Chuah ◽  
H. Enis Karahan ◽  
G. S. M. D. P. Sethunga ◽  
Tae-Hyun Bae
Keyword(s):  
High Performance ◽  
Polymeric Materials ◽  
Polymeric Membranes ◽  
Air Separation ◽  
Industrial Processes ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Mixed Matrix ◽  
Interfacial Defects ◽  
The Matrix

Membrane-based air separation (O2/N2) is of great importance owing to its energy efficiency as compared to conventional processes. Currently, dense polymeric membranes serve as the main pillar of industrial processes used for the generation of O2- and N2-enriched gas. However, conventional polymeric membranes often fail to meet the selectivity needs owing to the similarity in the effective diameters of O2 and N2 gases. Meanwhile, mixed-matrix membranes (MMMs) are convenient to produce high-performance membranes while keeping the advantages of polymeric materials. Here, we propose a novel MMM for O2/N2 separation, which is composed of Matrimid® 5218 (Matrimid) as the matrix, cobalt(II) phthalocyanine microparticles (CoPCMPs) as the filler, and Pluronic® F-127 (Pluronic) as the compatibilizer. By the incorporation of CoPCMPs to Matrimid, without Pluronic, interfacial defects were formed. Pluronic-treated CoPCMPs, on the other hand, enhanced O2 permeability and O2/N2 selectivity by 64% and 34%, respectively. We explain the enhancement achieved with the increase of both O2 diffusivity and O2/N2 solubility selectivity.

scholarly journals Experimental research in automobile non-pneumatic tire force heterogeneity

2018 ◽  
Vol 224 ◽  
pp. 02019 ◽  
Author(s):  
Vladimir Mazur
Keyword(s):  
High Speed ◽  
High Performance ◽  
High Efficiency ◽  
Motor Vehicle ◽  
Heavy Traffic ◽  
Polymeric Materials ◽  
Air Pressure ◽  
Motor Vehicles ◽  
Tire Force ◽  
Excess Air

Simplicity and high efficiency of a wheeled mover as a mechanism for converting rotational motion into a translatory one have conditioned its wide application in overland machines including motor vehicles. However a wheel with a non-pneumatic tyre (NPT) has a sufficient drawback lying in termination of a wheeled machine movement at the excess air pressure loss. Moreover, the loss of excess air pressure in a pneumatic tyre of traditional design at high speed of movement of a motor vehicle can lead to a traffic accident with heavy consequences. The stop of a motor vehicle to change a wheel on a heavy traffic roadway or roadside also poses a threat. These reasons determine the necessity of both well-known design improvements and search for the new wheeled mover design solutions to enhance a motor vehicle safety, the use of wheels with non-pneumatic tyres of elastic polymeric materials being one of them. Safety enhancement by means of non-pneumatic tyre use along with keeping the high performance of wheeled machine operational properties, is an important scientific and technical task that determines the research urgency.

Stereosequenced crystalline polyhydroxyalkanoates from diastereomeric monomer mixtures

Science ◽  
2019 ◽  
Vol 366 (6466) ◽  
pp. 754-758 ◽  
Author(s):  
Xiaoyan Tang ◽  
Andrea H. Westlie ◽  
Eli M. Watson ◽  
Eugene Y.-X. Chen
Keyword(s):  
Energy Cost ◽  
High Performance ◽  
Polymeric Materials ◽  
Powerful Method ◽  
Purification Process ◽  
Separation And Purification ◽  
Material Loss ◽  
Stereogenic Centers

Stereoselective polymerization of chiral or prochiral monomers is a powerful method to produce high-performance stereoregular crystalline polymeric materials. However, for monomers with two stereogenic centers, it is generally necessary to separate diastereomers before polymerization, resulting in substantial material loss and added energy cost associated with the separation and purification process. Here we report a diastereoselective polymerization methodology enabled by catalysts that directly polymerize mixtures of eight-membered diolide (8DL) monomers with varying starting ratios of chiral racemic (rac) and achiral meso diastereomers into stereosequenced crystalline polyhydroxyalkanoates with isotactic and syndiotactic stereodiblock or stereotapered block microstructures. These polymers show enhanced ductility and toughness relative to polymers of pure rac-8DL, subject to tuning by variation of the diastereomeric ratio and structure of the 8DL monomers.

Indole-based high-performance polymeric materials with enhanced mechanical and thermal properties via cation-π interaction

2019 ◽  
Vol 32 (6) ◽  
pp. 662-668
Author(s):  
Xiao-fang Guan ◽  
Cong Liao ◽  
Li Yang ◽  
Guan-jun Chang
Keyword(s):  
Thermal Stability ◽  
Heat Resistance ◽  
Self Assembly ◽  
High Performance ◽  
Mechanical Performance ◽  
Polymeric Materials ◽  
Design Strategy ◽  
Mechanical And Thermal Properties ◽  
Innovative Design ◽  
High Performance Polymers

The preparation of high-performance polymeric materials with both excellent overall mechanical properties and heat resistance remains a considerable challenge. Inspired by the delicate self-assembly processes in nature, a facile strategy is reported for the preparation of high-performance polymeric materials with enhanced mechanical strength and improved thermal stability. In this instance, we successfully constructed a cation- π cross-linked polyimide (Na-poly(aryl indole) imide (Na-PINI)) film with enhanced mechanical performance and heat resistance (∼490°C). This work presents an innovative design strategy for realizing robust polymeric materials with integrated strength and thermal stability; the cation- π interaction is demonstrated to be a new method that may achieve many useful properties for high-performance polymers.

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