Existence of organic micropollutants in the environment due to wastewater reuse and biosolids application

2020 ◽  
pp. 145-157
Author(s):  
Athanasios S. Stasinakis
Keyword(s):  
Wastewater Reuse ◽  
Organic Micropollutants ◽  
Biosolids Application

scholarly journals Fate and Toxicity of Carbamazepine and Its Degradation By-Products During Coupling of Ozonation and Nanofiltration for Urban Wastewater Reuse

2021 ◽  
Vol 2 ◽  
Author(s):  
Z. Amadou Yacouba ◽  
G. Lesage ◽  
J. Mendret ◽  
F. Zaviska ◽  
E. Petit ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Recovery Rate ◽  
Advanced Oxidation Processes ◽  
Vibrio Fischeri ◽  
Removal Rate ◽  
Wastewater Reuse ◽  
Organic Micropollutants ◽  
Urban Wastewater ◽  
By Products

Occurrence of emerging organic micropollutants in water bodies and their effects are a concern related to quality of reused water. Advanced oxidation processes have demonstrated promising results to address this challenge. Nonetheless, these processes may lead to the generation of more toxic oxidation by-products. The aim of this study was to investigate the coupling of ozonation and nanofiltration (NF) applied to carbamazepine (CBZ). It consisted in monitoring the degradation and fate of CBZ and its subsequent by-products, their fate and toxicity. CBZ was completely degraded after 5 min of ozonation and six identified transformation by-products were formed: I (hydroxycarbamazepine), BQM [1-(2-benzaldehyde)-4-hydro-(1H, 3H)-quinazoline-2-one], II (2-(1H)-quinazolinone), BaQM [1-(2-benzoic acid)-4-hydro-(1H, 3H)-quinazoline-2-one], BQD [1-(2-benzaldehyde)-(1H, 3H)-quinazoline-2,4-dione] and BaQD [1-(2-benzoic acid)-(1H, 3H)-quinazoline-2,4-dione]. Mineralization rate of ozonation never exceeded 12% even with high ozone dose. Bioassays with Vibrio fischeri revealed that BQM and BQD are responsible for toxicity. NF is able to remove total organic carbon with removal rate up to 93% at 85% of permeate recovery rate. CBZ and its different ozonation by-products were almost completely retained by NF, except the II, which had an MW slightly lower than the membrane molecular weight cut-off, for which the removal rate was still between 80 and 96% depending on the recovery rate.

Resorcinarene Cavitand Polymers for the Remediation of Halomethanes and 1,4-Dioxane

2019 ◽  
Author(s):  
Luke Skala ◽  
Anna Yang ◽  
Max Justin Klemes ◽  
Leilei Xiao ◽  
William Dichtel
Keyword(s):  
Drinking Water ◽  
Activated Carbon ◽  
High Capacity ◽  
The United States ◽  
Water Sources ◽  
Disinfection Byproducts ◽  
Porous Polymer ◽  
Organic Micropollutants ◽  
Executive Summary ◽  
Regulatory Limits

<p>Executive summary: Porous resorcinarene-containing polymers are used to remove halomethane disinfection byproducts and 1,4-dioxane from water.<br></p><p><br></p><p>Disinfection byproducts such as trihalomethanes are some of the most common micropollutants found in drinking water. Trihalomethanes are formed upon chlorination of natural organic matter (NOM) found in many drinking water sources. Municipalities that produce drinking water from surface water sources struggle to remain below regulatory limits for CHCl<sub>3</sub> and other trihalomethanes (80 mg L<sup>–1</sup> in the United States). Inspired by molecular CHCl<sub>3</sub>⊂cavitand host-guest complexes, we designed a porous polymer comprised of resorcinarene receptors. These materials show higher affinity for halomethanes than a specialty activated carbon used for trihalomethane removal. The cavitand polymers show similar removal kinetics as activated carbon and have high capacity (49 mg g<sup>–1</sup> of CHCl<sub>3</sub>). Furthermore, these materials maintain their performance in real drinking water and can be thermally regenerated under mild conditions. Cavitand polymers also outperform activated carbon in their adsorption of 1,4-dioxane, which is difficult to remove and contaminates many public water sources. These materials show promise for removing toxic organic micropollutants and further demonstrate the value of using supramolecular chemistry to design novel absorbents for water purification.<br></p>

Innovative education and training for community-based water protection units

2012 ◽  
Vol 7 (4) ◽  
Author(s):  
Frederick Kakembo
Keyword(s):  
Wastewater Reuse ◽  
Education And Training ◽  
Economic Incentives ◽  
Community Action ◽  
Health Improvement ◽  
Wastewater Management ◽  
Water Protection ◽  
Community Based ◽  
And Training ◽  
Innovative Education

The paper explores the centrality of community-based education and training in addressing constraints and opportunities for wastewater management in Uganda. To be sustainable, wastewater management need to be conceived in terms of socio-economic incentives, community action, group pressure and social capital. It is assumed that communities could be motivated to undertake sustainable wastewater disposal activities if concrete benefits are demonstrated. The benefits include among others; reducing expenditure on health; improvement of the fisheries sector and the use of wastewater for crop farming. The paper is based on a study that analyzed the role of socio-economic incentives and Public-Private-Partnership (PPP) in sustainable management of wastewater. Data was collected through personal interviews, documents analysis and review of recent studies on wastewater reuse in Uganda. Focus was put on districts of Mukono, Buikwe and Kayunga in central Uganda. Findings reveal that in line with the Hydro-Social-Health cycle, physical, social, political, economic, and cultural factors converge to influence wastewater management. The paper duly describes innovative education and training approaches based on Communal Water Protection Units (COWAPU) facilitated by multidisciplinary Water Professionals and Educators (WAPE).It is concluded that it is possible to operate a complete sanitation system without subsidies.

Modelling of bacterial removal in wastewater storage reservoir for irrigation purposes: a case study in Sicily, Italy

2003 ◽  
Vol 3 (4) ◽  
pp. 169-175 ◽  
Author(s):  
S. Barbagallo ◽  
F. Brissaud ◽  
G.L. Cirelli ◽  
S. Consoli ◽  
P. Xu
Keyword(s):  
Municipal Wastewater ◽  
High Reliability ◽  
Low Cost ◽  
Public Awareness ◽  
Storage System ◽  
Wastewater Reuse ◽  
Order Kinetic ◽  
Aquifer Recharge ◽  
Mediterranean Countries ◽  
Storage Reservoirs

In arid and semiarid regions the reclamation and reuse of municipal wastewater can play a strategic role in alleviating water resources shortages. Public awareness is growing about the need to recycle and reuse water for increasing supply availability. Many wastewater reuse projects have been put in operation in European and Mediterranean countries adopting extensive treatment systems such as aquifer recharge, lagooning, constructed wetlands, and storage reservoirs, mainly for landscape and agricultural irrigation. In agricultural reuse systems, there is an increasing interest in extensive technologies because of their high reliability, and easy and low cost operation and maintenance. Wastewater storage reservoirs have become the option selected in many countries because of the advantages they present in comparison with other treatment alternatives, namely the coupling of two purposes, stabilization and seasonal regulation. This paper describes an example of a wastewater storage system, built in Caltagirone (Sicily, Italy). The storage results in a tertiary treatment of a continuous inlet flow of activated sludge effluents. The prediction of the microbiological water quality has been evaluated by means of a non-steady-state first-order kinetic model. Single and multiple regressions were applied to determine the main variables that most significantly affected die-off coefficients. The proposed model has been calibrated using the results of a field monitoring carried out during a period from March to October 2000.

Giardia and Virus Monitoring of Sewage Effluent in the State of Arizona

1989 ◽  
Vol 21 (3) ◽  
pp. 43-47 ◽  
Author(s):  
Joan B. Rose ◽  
Ricardo De Leon ◽  
Charles P. Gerba
Keyword(s):  
United States ◽  
Produced Water ◽  
Wastewater Reuse ◽  
Limited Resource ◽  
The State ◽  
Sewage Effluent ◽  
Sand Filtration ◽  
Southwestern United States ◽  
Treatment Facilities ◽  
Giardia Cysts

Arizona, located in the arid Southwestern United States, is heavily dependent on groundwater. In order to protect this limited resource, wastewater reuse has been implemented. Virus and Giardia monitoring of wastewater used for irrigation has also been initiated as a means for controlling the public's exposure to these pathogens. Treatment facilities must produce wastewater with no detectable Giardia cysts and one virus plaque forming unit (pfu) per 40 liters (L) for unrestricted reuse. For restricted reuse, 125 pfu/40 L is allowed. Methods based on filtration were used to monitor facilities at monthly, quarterly or biannual frequencies. Results after two years of monitoring are presented. All 11 treatment facilities produced water meeting the virus standard of 125 pfu/40 L. Only plants which used sand filtration and disinfection achieved consistent levels of virus below 1 pfu/40 L. Out of 70 samples, 74% contained no detectable viruses. Giardia was detected in 29 to 50% of the samples. Most plants would need to upgrade their treatment in order to meet standards for unrestricted irrigation.

Water Quality and Health

1991 ◽  
Vol 23 (1-3) ◽  
pp. 201-209 ◽  
Author(s):  
W. Kreisel
Keyword(s):  
Water Quality ◽  
Developing Countries ◽  
Drinking Water ◽  
Water Supply ◽  
Human Health ◽  
Pollution Control ◽  
Wastewater Reuse ◽  
Water Supplies ◽  
Minimum Quality Standards ◽  
Quality Guidelines

Water quality can affect human health in various ways: through breeding of vectors, presence of pathogenic protozoa, helminths, bacteria and viruses, or through inorganic and organic chemicals. While traditional concern has been with pathogens and gastro-intestinal diseases, chemical pollutants in drinking-water supplies have in many instances reached proportions which affect human health, especially in cases of chronic exposure. Treatment of drinking-water, often grossly inadequate in developing countries, is the last barrier of health protection, but control at source is more effective for pollution control. Several WHO programmes of the International Drinking-Water Supply and Sanitation Decade have stimulated awareness of the importance of water quality in public water supplies. Three main streams have been followed during the eighties: guidelines for drinking-water quality, guidelines for wastewater reuse and the monitoring of freshwater quality. Following massive investments in the community water supply sector to provide people with adequate quantities of drinking-water, it becomes more and more important to also guarantee minimum quality standards. This has been recognized by many water and health authorities in developing countries and, as a result, WHO cooperates with many of them in establishing water quality laboratories and pollution control programmes.

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