Effect of the pH influent conditions in fixed-film reactors for anaerobic thermophilic treatment of wine-distillery wastewater

2005 ◽  
Vol 51 (1) ◽  
pp. 183-189 ◽  
Author(s):  
M. Pérez-García ◽  
L.I. Romero-García ◽  
R. Rodríguez-Cano ◽  
D. Sales-Márquez
Keyword(s):  
Retention Time ◽  
Hydraulic Retention Time ◽  
Oxygen Demand ◽  
High Rate ◽  
Organic Load ◽  
Substrate Removal ◽  
Load Rate ◽  
Fixed Film ◽  
Thermophilic Conditions ◽  
Distillery Wastewater

In anaerobic treatments, the pH conditions affect the efficacy and operation of the process. The main purpose of this research is to compare the effect of the pH influent on the performance of a high rate technology at laboratory scale, upflow anaerobic fixed-film reactor, treating distillery wastewater (wine vinasses) in thermophilic conditions. The results obtained shown that the pH influent influences the performance of the biodegradation process: the depurative efficiency is higher for the operation with alkaline influent. The operation with acid influent allows us to operate at organic loading rates (OLR) around 5.6 kgCOD/m3/d (hydraulic retention time: 1.5 days), maintaining total Chemical Oxygen Demand removals (CODr) of 77.2%; the operation with alkaline influent allows total CODr of 76.8% working at OLR around 10.5 kgCOD/m3/d. The greatest efficiency of substrate removal was 87.5% for OLR 3.2 kgCOD/m3/d and hydraulic retention time of 4.0 days operating with alkaline influent. Therefore, the operation with alkaline influent implicates senior levels of purifying efficiency for similar organic load rate.

scholarly journals The Start-Up of Continuous Biohydrogen Production from Cheese Whey: Comparison of Inoculum Pretreatment Methods and Reactors with Moving and Fixed Polyurethane Carriers

2021 ◽  
Vol 11 (2) ◽  
pp. 510
Author(s):  
Elza R. Mikheeva ◽  
Inna V. Katraeva ◽  
Andrey A. Kovalev ◽  
Dmitriy A. Kovalev ◽  
Alla N. Nozhevnikova ◽  
...  
Keyword(s):  
Cheese Whey ◽  
Hydraulic Retention Time ◽  
Continuous Production ◽  
Oxygen Demand ◽  
Organic Load ◽  
Anaerobic Sludge ◽  
Acid Pretreatment ◽  
Methanogenic Activity ◽  
Start Up ◽  
Load Rate

This article presents the results of the start-up of continuous production of biohydrogen from cheese whey (CW) in an anaerobic filter (AF) and anaerobic fluidized bed (AFB) with a polyurethane carrier. Heat and acid pretreatments were used for the inactivation of hydrogen-scavengers in the inoculum (mesophilic and thermophilic anaerobic sludge). Acid pretreatment was effective for thermophilic anaerobic sludge to suppress methanogenic activity, and heat treatment was effective for mesophilic anaerobic sludge. Maximum specific yields of hydrogen, namely 178 mL/g chemical oxygen demand (COD) and 149 mL/g COD for AFB and AF, respectively, were obtained at the hydraulic retention time (HRT) of 4.5 days and organic load rate (OLR) of 6.61 kg COD/(m3 day). At the same time, the maximum hydrogen production rates of 1.28 and 1.9 NL/(L day) for AF and AFB, respectively, were obtained at the HRT of 2.02 days and OLR of 14.88 kg COD/(m3 day). At the phylum level, the dominant taxa were Firmicutes (65% in AF and 60% in AFB), and at the genus level, Lactobacillus (40% in AF and 43% in AFB) and Bifidobacterium (24% in AF and 30% in AFB).

High rate anaerobic thermophilic technologies for distillery wastewater treatment

2005 ◽  
Vol 51 (1) ◽  
pp. 191-198 ◽  
Author(s):  
M. Pérez-García ◽  
L.I. Romero-García ◽  
R. Rodríguez-Cano ◽  
D. Sales-Márquez
Keyword(s):  
Fluidized Bed ◽  
Packed Bed ◽  
High Rate ◽  
Loading Rates ◽  
Sintered Glass ◽  
Stable Conditions ◽  
Fixed Film ◽  
Thermophilic Conditions ◽  
Distillery Wastewater ◽  
Film Reactor

In this paper, performance of two high rate technologies, upflow anaerobic fixed-film reactor and fluidized bed laboratory-scale, treating distillery wastewater (wine vinasses ) at anaerobic thermophilic conditions have been compared. The results obtained show that the stationary packed bed, with a corrugated plastic support, operated under stable conditions at organic loading rates (OLR0) around 20 kgCOD/m3/d, gives maximal total CODr of 76% at OLR0 of 6.29 kgCOD/m3/d; the fluidized bed reactor, operated on open pore sintered-glass media, gives total CODr of 96% at OLR0 of 5.88 kgCOD/m3/d. The anaerobic fluidized bed technology is more effective than the upflow anaerobic fixed-film technology due, fundamentally, to this technology favouring the transport of microbial cells from the bulk to the surface and enhancing the contact between the microorganism-substrate phases. In this sense, the stationary packed bed technology is adequate for the treatment of easily biodegradable wastewater, or for the cases where elevated percentages of CODr removal are not required, while the fluidized bed technology is especially suitable for treatment of hazardous wastes with recalcitrant compositions.

scholarly journals The effect of CO2 addition and hydraulic retention time on pathogens removal in HRAPs

2020 ◽  
Vol 82 (6) ◽  
pp. 1184-1192
Author(s):  
Graziele Ruas ◽  
Sarah Lacerda Farias ◽  
Priscila G. Scarcelli ◽  
Mayara L. Serejo ◽  
Marc A. Boncz
Keyword(s):  
Retention Time ◽  
Hydraulic Retention Time ◽  
Oxygen Demand ◽  
Biomass Productivity ◽  
High Rate ◽  
Nitrogen And Phosphorus ◽  
Total Organic Nitrogen ◽  
E Coli ◽  
Bacterial Removal ◽  
Co2 Addition

Abstract The influence of CO2 addition and hydraulic retention time (5 and 7 days) on removal of Pseudomonas aeruginosa, Clostridium perfringens, Staphylococcus sp., Enterococcus sp., and Escherichia coli was evaluated in a system with three parallel 21 L high rate algal ponds. Both the addition of CO2 and an increase in HRT had no significant influence on bacterial removal, but bacterial removal was higher than found in previous studies. The removal was 3.4–3.8, 2.5–3.7, 2.6–3.1, 2.2–2.6 and 1.3–1.7 units log for P. aeruginosa, E. coli, Enterococcus sp., C. perfringens, and for Staphylococcus sp., respectively. Although CO2 addition did not increase disinfection, it did significantly increase biomass productivity (by ≈60%) and settleability (by ≈350%). Additionally, even at the lower 5-day hydraulic retention time, CO2 addition improves removal of chemical oxygen demand (COD), total organic carbon (TOC), total organic nitrogen and phosphorus by 97, 91, 12 and 50%, respectively.

Kinetic evaluation of nitrification performance in an immobilized cell membrane bioreactor

2016 ◽  
Vol 73 (12) ◽  
pp. 2904-2912 ◽  
Author(s):  
D. Güven ◽  
E. Ubay Çokgör ◽  
S. Sözen ◽  
D. Orhon
Keyword(s):  
Residence Time ◽  
Retention Time ◽  
Model Calibration ◽  
Membrane Bioreactor ◽  
Hydraulic Retention Time ◽  
Membrane Bioreactors ◽  
High Rate ◽  
Immobilized Cell ◽  
Chemical Cleaning ◽  
Kinetic Evaluation

Abstract High rate membrane bioreactor (MBR) systems operated at extremely low sludge ages (superfast membrane bioreactors (SFMBRs)) are inefficient to achieve nitrogen removal, due to insufficient retention time for nitrifiers. Moreover, frequent chemical cleaning is required due to high biomass flux. This study aims to satisfy the nitrification in SFMBRs by using sponge as carriers, leading to the extension of the residence time of microorganisms. In order to test the limits of nitrification, bioreactor was run under 52, 5 and 2 days of carrier residence time (CRT), with a hydraulic retention time of 6 h. Different degrees of nitrification were obtained for different CRTs. Sponge immobilized SFMBR operation with short CRT resulted in partial nitrification indicating selective dominancy of ammonia oxidizers. At higher CRT, simultaneous nitrification–denitrification was achieved when accompanying with oxygen limitation. Process kinetics was determined through evaluation of the results by a modeling study. Nitrifier partition in the reactor was also identified by model calibration.

Working Parameters Optimization of Hydrolysis-acidogenesis reactor in two stage anaerobic digestion of slaughterhouse Wastewater for Biogas Production

2020 ◽  
Author(s):  
Dejene Tsegaye Bedane ◽  
Mohammed Mazharuddin Khan ◽  
Seyoum Leta Asfaw
Keyword(s):  
Anaerobic Digestion ◽  
Working Conditions ◽  
Retention Time ◽  
Hydraulic Retention Time ◽  
Loading Rate ◽  
Oxygen Demand ◽  
Organic Loading Rate ◽  
Organic Loading ◽  
Slaughterhouse Wastewater ◽  
Working Parameters

Abstract Background : Wastewater from agro-industries such as slaughterhouse is typical organic wastewater with high value of biochemical oxygen demand, chemical oxygen demand, biological organic nutrients (Nitrogen and phosphate) which are insoluble, slowly biodegradable solids, pathogenic and non-pathogenic bacteria and viruses, parasite eggs. Moreover it contains high protein and putrefies fast leading to environmental pollution problem. This indicates that slaughterhouses are among the most environmental polluting agro-industries. Anaerobic digestion is a sequence of metabolic steps involving consortiums of several microbial populations to form a complex metabolic interaction network resulting in the conversation of organic matter into methane (CH 4 ), carbon dioxide (CO 2 ) and other trace compounds. Separation of the phase permits the optimization of the organic loading rate and HRT based on the requirements of the microbial consortiums of each phase. The purpose of this study was to optimize the working conditions for the hydrolytic - acidogenic stage in two step/phase anaerobic digestion of slaughterhouse wastewater. The setup of the laboratory scale reactor was established at Center for Environmental Science, College of Natural Science with a total volume of 40 liter (36 liter working volume and 4 liter gas space). The working parameters for hydrolytic - acidogenic stage were optimized for six hydraulic retention time 1-6 days and equivalent organic loading rate of 5366.43 – 894.41 mg COD/L day to evaluate the effect of the working parameters on the performance of hydrolytic – acidogenic reactor. Result : The finding revealed that hydraulic retention time of 3 day with organic loading rate of 1,788.81 mg COD/L day was a as an optimal working conditions for the parameters under study for the hydrolytic - acidogenic stage. The degree of hydrolysis and acidification were mainly influenced by lower hydraulic retention time (higher organic loading rate) and highest values recorded were 63.92 % at hydraulic retention time of 3 day and 53.26% at hydraulic retention time of 2 day respectively. Conclusion : The finding of the present study indicated that at steady state the concentration of soluble chemical oxygen demand and total volatile fatty acids increase as hydraulic retention time decreased or organic loading rate increased from 1 day hydraulic retention time to 3 day hydraulic retention time and decreases as hydraulic retention time increase from 4 to 6 day. The lowest concentration of NH 4 + -N and highest degree of acidification was also achieved at hydraulic retention time of 3 day. Therefore, it can be concluded that hydraulic retention time of 3 day/organic loading rate of 1,788.81 mg COD/L .day was selected as an optimal working condition for the high performance and stability during the two stage anaerobic digestion of slaughterhouse wastewater for the hydrolytic-acidogenic stage under mesophilic temperature range selected (37.5℃). Keywords : Slaughterhouse Wastewater, Hydrolytic – Acidogenic, Two Phase Anaerobic Digestion, Optimal Condition, Agro-processing wastewater

scholarly journals Effect of hydraulic retention time on chemical oxygen demand and total nitrogen removal in intermittently aerated constructed wetlands

2020 ◽  
Vol 15 (3) ◽  
pp. 1 ◽  
Author(s):  
Isabela Pires da Silva ◽  
Gabriela Barbosa da Costa ◽  
João Gabriel Thomaz Queluz ◽  
Marcelo Loureiro Garcia
Keyword(s):  
Chemical Oxygen Demand ◽  
Constructed Wetlands ◽  
Total Nitrogen ◽  
Total Phosphorus ◽  
Constructed Wetland ◽  
Retention Time ◽  
Hydraulic Retention Time ◽  
Subsurface Flow ◽  
Oxygen Demand ◽  
Intermittent Aeration

   This study evaluated the effect of hydraulic retention time on chemical oxygen demand (COD) and total nitrogen (TN) removal in an intermittently aerated constructed wetlands. Two horizontal subsurface-flow constructed wetlands were used: one without aeration and the other aerated intermittently (1 hour with aeration/7 hours without aeration). Both systems were evaluated treating domestic wastewater produced synthetically. The flow rate into the two CWs was 8.6 L day-1 having a hydraulic retention time of 3 days. The results show that the intermittently aerated constructed wetland were highly efficient in removing COD (98.25%), TN (83.60%) and total phosphorus (78.10%), while the non-aerated constructed wetland showed lower efficiencies in the removal of COD (93.89%), TN (48.60%) and total phosphorus (58.66). These results indicate, therefore, that intermittent aeration allows the simultaneous occurrence of nitrification and denitrification processes, improving the removal of TN in horizontal subsurface-flow constructed wetlands. In addition, the use of intermittent aeration also improves the performance of constructed wetlands in removing COD and total phosphorus.

scholarly journals Influence of a new ornamental species (Spathiphyllum blandum) on the removal of COD, nitrogen, phosphorus and fecal coliforms: a mesocosm wetland study with PET and tezontle substrates

2020 ◽  
Vol 81 (5) ◽  
pp. 961-970 ◽  
Author(s):  
Luis Sandoval ◽  
Florentina Zurita ◽  
Oscar Andrés Del Ángel-Coronel ◽  
Jacel Adame-García ◽  
José Luis Marín-Muñíz
Keyword(s):  
Developing Countries ◽  
New Species ◽  
Retention Time ◽  
Hydraulic Retention Time ◽  
Oxygen Demand ◽  
Fecal Coliforms ◽  
Contaminated Water ◽  
A New Species ◽  
Nitrogen Phosphorus ◽  
Ornamental Species

Abstract The objective of this study was to evaluate the influence of a new species of plant (Spathiphyllum blandum) in the elimination of chemical oxygen demand (COD), nitrogen, phosphorus and fecal coliforms (FCs) in mesocosms of wetlands with polyethylene terephthalate (PET) and tezontle substrates under a tropical climate. The experiments were developed at the mesocosm level in 20 experimental units; 10 were planted with Spathiphyllum blandum, five in PET substrates and five in tezontle, and 10 more were used as controls without vegetation, of which five contained tezontle and five contained PET. The systems were fed with contaminated water from the river Sordo, with a hydraulic retention time of 3 days for 12 months; samples were taken in the influent and effluents of the mesocosms every 2 weeks, with the purpose of evaluating the removal of contaminants. The results showed that presence of this species tended to improve or significantly improved the removal of COD, NH4-N, PO4-P, and FCs by 7%, 16%, 29% and 12%, respectively. It was also possible to confirm that the presence of this species reduced the rate of denitrification. These results confirm that in developing countries it is feasible to find new wetland species to be used for wastewater phytoremediation.

scholarly journals Optimising the Hydraulic Retention Time in a Pilot-Scale Microbial Electrolysis Cell to Achieve High Volumetric Treatment Rates Using Concentrated Domestic Wastewater

Molecules ◽  
2020 ◽  
Vol 25 (12) ◽  
pp. 2945 ◽  
Author(s):  
Daniel D. Leicester ◽  
Jaime M. Amezaga ◽  
Andrew Moore ◽  
Elizabeth S. Heidrich
Keyword(s):  
Retention Time ◽  
Hydraulic Retention Time ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Direct Analysis ◽  
Pilot Scale ◽  
Electrolysis Cell ◽  
Treatment Technique ◽  
Microbial Electrolysis Cell ◽  
Microbial Electrolysis

Bioelectrochemical systems (BES) have the potential to deliver energy-neutral wastewater treatment. Pilot-scale tests have proven that they can operate at low temperatures with real wastewaters. However, volumetric treatment rates (VTRs) have been low, reducing the ability for this technology to compete with activated sludge (AS). This paper describes a pilot-scale microbial electrolysis cell (MEC) operated in continuous flow for 6 months. The reactor was fed return sludge liquor, the concentrated filtrate of anaerobic digestion sludge that has a high chemical oxygen demand (COD). The use of a wastewater with increased soluble organics, along with optimisation of the hydraulic retention time (HRT), resulted in the highest VTR achieved by a pilot-scale MEC treating real wastewater. Peak HRT was 0.5-days, resulting in an average VTR of 3.82 kgCOD/m3∙day and a 55% COD removal efficiency. Finally, using the data obtained, a direct analysis of the potential savings from the reduced loading on AS was then made. Theoretical calculation of the required tank size, with the estimated costs and savings, indicates that the use of an MEC as a return sludge liquor pre-treatment technique could result in an industrially viable system.

Optimization of a mainstream nitritation-denitritation process and anammox polishing

2015 ◽  
Vol 72 (4) ◽  
pp. 632-642 ◽  
Author(s):  
Pusker Regmi ◽  
Becky Holgate ◽  
Dana Fredericks ◽  
Mark W. Miller ◽  
Bernhard Wett ◽  
...  
Keyword(s):  
Retention Time ◽  
Pilot Plant ◽  
Municipal Wastewater ◽  
Ammonia Oxidation ◽  
Inorganic Nitrogen ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
High Rate ◽  
Anammox Bacteria ◽  
Tin Removal

This paper deals with an almost 1-year long pilot study of a nitritation-denitritation process that was followed by anammox polishing. The pilot plant treated real municipal wastewater at ambient temperatures. The effluent of high-rate activated sludge process (hydraulic retention time, HRT = 30 min, solids retention time = 0.25 d) was fed to the pilot plant described in this paper, where a constant temperature of 23 °C was maintained. The nitritation-denitritation process was operated to promote nitrite oxidizing bacteria out-selection in an intermittently aerated reactor. The intermittent aeration pattern was controlled using a strategy based on effluent ammonia and nitrate + nitrite concentrations. The unique feature of this aeration control was that fixed dissolved oxygen set-point was used and the length of aerobic and anoxic durations were changed based on the effluent ammonia and nitrate + nitrite concentrations. The anaerobic ammonia oxidation (anammox) bacteria were adapted in mainstream conditions by allowing the growth on the moving bed bioreactor plastic media in a fully anoxic reactor. The total inorganic nitrogen (TIN) removal performance of the entire system was 75 ± 15% during the study at a modest influent chemical oxygen demand (COD)/NH4+-N ratio of 8.9 ± 1.8 within the HRT range of 3.1–9.4 h. Anammox polishing contributed 11% of overall TIN removal. Therefore, this pilot-scale study demonstrates that application of the proposed nitritation-denitritation system followed by anammox polishing is capable of relatively high nitrogen removal without supplemental carbon and alkalinity at a low HRT.

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