Mass and charge conservation check in dynamic models: application to the new ADM1 model

2006 ◽  
Vol 53 (1) ◽  
pp. 225-240 ◽  
Author(s):  
M. de Gracia ◽  
L. Sancho ◽  
J.L. García-Heras ◽  
P. Vanrolleghem ◽  
E. Ayesa
Keyword(s):  
Organic Matter ◽  
Anaerobic Digestion ◽  
Dynamic Models ◽  
Nitrogen Release ◽  
Mass Fluxes ◽  
Systematic Methodology ◽  
Mass Fractions ◽  
Model Components ◽  
Definition Of ◽  
Elemental Mass

This paper proposes a systematic methodology for the analysis of the mass and charge balances in dynamic models expressed using the Petersen matrix notation. This methodology is based on the definition of the model components via elemental mass fractions and in the estimation of the COD as a function of the redox equations associated with these elements. This approach makes the automatic calculation of all the stoichiometric coefficients under different measuring units and the study of COD, charge or mass fluxes easier. As an example of its application this methodology was applied to the ADM1 in order to illustrate its usefulness for the analysis of organic matter characterisation, nitrogen release or biogas composition in anaerobic digestion. The application of the methodology for a rigorous integration of different IWA models is proposed for further study.

New mathematical procedure for the automatic estimation of influent characteristics in WWTPs

2007 ◽  
Vol 56 (8) ◽  
pp. 95-106 ◽  
Author(s):  
P. Grau ◽  
S. Beltrán ◽  
M. de Gracia ◽  
E. Ayesa
Keyword(s):  
A Priori ◽  
Measurement Data ◽  
Experimental Information ◽  
Extended Model ◽  
Automatic Estimation ◽  
Mass Fractions ◽  
Model Components ◽  
Influent Characterization ◽  
Elemental Mass

This paper proposes a new methodology for the automatic characterization of the influent wastewater in WWTP. With this methodology, model components are automatically estimated by means of optimization algorithms combining a-priori knowledge of the expected wastewater composition with experimental information from the available measurement data. The characterization is carried out based on an extended model components list in which components are described by means their elemental mass fractions. This allows an easy establishment of relationships between model components with experimental data and also, to obtain a general methodology applicable to any model used for wastewater biological treatments. The characterization of the wastewater influent of Galindo-Bilbao according this methodology has demonstrated its validity and the easy application to the ASM1 model influent characterization.

ADM1-based methodology for the characterisation of the influent sludge in anaerobic reactors

2006 ◽  
Vol 54 (4) ◽  
pp. 157-166 ◽  
Author(s):  
E. Huete ◽  
M. de Gracia ◽  
E. Ayesa ◽  
J.L. Garcia-Heras
Keyword(s):  
Pilot Scale ◽  
Process Models ◽  
Unit Process ◽  
Anaerobic Reactors ◽  
Secondary Sludge ◽  
Mass Fractions ◽  
Mathematical Algorithms ◽  
Model Components ◽  
Elemental Characterisation ◽  
Elemental Mass

This paper presents a systematic methodology to characterise the influent sludge in terms of the ADM1 components from the experimental measurements traditionally used in wastewater engineering. For this purpose, a complete characterisation of the model components in their elemental mass fractions and charge has been used, making a rigorous mass balance for all the process transformations and enabling the future connection with other unit-process models. It also makes possible the application of mathematical algorithms for the optimal characterisation of several components poorly defined in the ADM1 report. Additionally, decay and disintegration have been necessarily uncoupled so that the decay proceeds directly to hydrolysis instead of producing intermediate composites. The proposed methodology has been applied to the particular experimental work of a pilot-scale CSTR treating real sewage sludge, a mixture of primary and secondary sludge. The results obtained have shown a good characterisation of the influent reflected in good model predictions. However, its limitations for an appropriate prediction of alkalinity and carbon percentages in biogas suggest the convenience of including the elemental characterisation of the process in terms of carbon in the analytical program.

Sludge minimization by disintegration at different wastewater treatment plants

2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Luchien Luning ◽  
Paul Roeleveld ◽  
Victor W.M. Claessen
Keyword(s):  
Organic Matter ◽  
Wastewater Treatment ◽  
Anaerobic Digestion ◽  
Sewage Sludge ◽  
New Technologies ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
Biological Degradation ◽  
Ongoing Research ◽  
Sludge Minimization

In recent years new technologies have been developed to improve the biological degradation of sewage sludge by anaerobic digestion. The paper describes the results of a demonstration of ultrasonic disintegration on the Dutch Wastewater Treatment Plant (WWTP) Land van Cuijk. The effect on the degradation of organic matter is presented, together with the effect on the dewatering characteristics. Recommendations are presented for establishing research conditions in which the effect of sludge disintegration can be determined in a more direct way that is less sensitive to changing conditions in the operation of the WWTP. These recommendations have been implemented in the ongoing research in the Netherlands supported by the National Institute for wastewater research (STOWA).

scholarly journals Co-Digestion of Rice Straw with Cow Manure in an Innovative Temperature Phased Anaerobic Digestion Technology: Performance Evaluation and Trace Elements

Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2561
Author(s):  
Furqan Muhayodin ◽  
Albrecht Fritze ◽  
Oliver Christopher Larsen ◽  
Marcel Spahr ◽  
Vera Susanne Rotter
Keyword(s):  
Trace Elements ◽  
Anaerobic Digestion ◽  
Greenhouse Gas ◽  
Rice Straw ◽  
Methane Yield ◽  
Methane Formation ◽  
Cow Manure ◽  
Volatile Solids ◽  
Mass Fractions ◽  
Cu And Zn

Rice straw is an agricultural residue produced in abundant quantities. Open burning and plowing back the straw to the fields are common practices for its disposal. In-situ incorporation and burning cause emissions of greenhouse gas and particulate matter. Additionally, the energy potential of rice straw is lost. Anaerobic digestion is a technology that can be potentially used to utilize the surplus rice straw, provide renewable energy, circulate nutrients available in the digestate, and reduce greenhouse gas emissions from rice paddies. An innovative temperature phased anaerobic digestion technology was developed and carried out in a continuous circulating mode of mesophilic and hyperthermophilic conditions in a loop digester (F1). The performance of the newly developed digester was compared with the reference digester (F2) working at mesophilic conditions. Co-digestion of rice straw was carried out with cow manure to optimize the carbon to nitrogen ratio and to provide the essential trace elements required by microorganisms in the biochemistry of methane formation. F1 produced a higher specific methane yield (189 ± 37 L/kg volatile solids) from rice straw compared to F2 (148 ± 36 L/kg volatile solids). Anaerobic digestion efficiency was about 90 ± 20% in F1 and 70 ± 20% in F2. Mass fractions of Fe, Ni, Co, Mo, Cu, and Zn were analyzed over time. The mass fractions of Co, Mo, Cu, and Zn were stable in both digesters. While mass fractions of Fe and Ni were reduced at the end of the digestion period. However, no direct relationship between specific methane yield and reduced mass fraction of Fe and Ni was found. Co-digestion of rice straw with cow manure seems to be a good approach to provide trace elements except for Se.

scholarly journals A Framework Based on Finite Element Method (FEM) for Modelling and Assessing the Affection of the Local Thermal Weather Factors on the Performance of Anaerobic Lagoons for the Natural Treatment of Swine Wastewater

Water ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 882
Author(s):  
Saulo Brito-Espino ◽  
Alejandro Ramos-Martín ◽  
Sebastian O. Pérez-Báez ◽  
Carlos Mendieta-Pino ◽  
Federico Leon-Zerpa
Keyword(s):  
Finite Element Method ◽  
Finite Element ◽  
Organic Matter ◽  
Anaerobic Digestion ◽  
Environmental Sustainability ◽  
Diffusion Reaction ◽  
Swine Wastewater ◽  
Natural Treatment ◽  
Element Method ◽  
Anaerobic Lagoons

Anaerobic lagoons are natural wastewater treatment systems suitable for swine farms in small communities due to its low operational and building costs, as well as for the environmental sustainability that these technologies enable. The local weather is one of the factors which greatly influences the efficiency of the organic matter degradation within anaerobic lagoons, since microbial growth is closely related to temperature. In this manuscript, we propose a mathematical model which involves the two-dimensional Stokes, advection–diffusion-reaction and heat transfer equations for an unstirred fluid flow. Furthermore, the Anaerobic Digestion Model No1 (ADM1), developed by the International Water Association (IWA), has been implemented in the model. The partial differential equations resulting from the model, which involve a large number of state variables that change according to the position and the time, are solved through the use of the Finite Element Method. The results of the simulations indicated that the methodology is capable of predicting reasonably well the steady-state of the concentrations for all processes that take place in the anaerobic digestion and for each one of the variables considered; cells, organic matter, nutrients, etc. In view of the results, it can be concluded that the model has significant potential for the design and the study of anaerobic cells’ behaviour within free flow systems.

On Extension of “Heatline” and “Massline” Concepts to Reacting Flows Through Use of Conserved Scalars

2002 ◽  
Vol 124 (4) ◽  
pp. 791-799 ◽  
Author(s):  
Achintya Mukhopadhyay ◽  
Xiao Qin ◽  
Suresh K. Aggarwal ◽  
Ishwar K. Puri
Keyword(s):  
Diffusion Coefficients ◽  
Reacting Flows ◽  
Scalar Transport ◽  
Zero Gravity ◽  
Two Dimensional ◽  
Total Enthalpy ◽  
Mass Fractions ◽  
New Formulation ◽  
Elemental Mass ◽  
Qualitative Picture

A new formulation for extending the concept of heatlines and masslines to reacting flows through use of conserved scalars has been proposed. The formulation takes into account the distinct diffusion coefficients of different species. Results have been obtained for a number of two-dimensional nonreacting and reacting free shear flows under normal and zero gravity. For nonreacting flows, total enthalpy and elemental mass fractions have been used as the transported conserved scalars. For reacting flows, mixture fractions, defined as normalized elemental mass fractions and enthalpy, have been employed. The results show this concept to be a useful tool for obtaining better insights into the global qualitative picture of scalar transport for both nonreacting and reacting flows.

scholarly journals Effects of sulfonamide antibiotics on digestion performance and microbial community during swine manure anaerobic digestion

2020 ◽  
Vol 26 (1) ◽  
Author(s):  
Shaona Wang ◽  
Kang Du ◽  
Rongfang Yuan ◽  
Huilun Chen ◽  
Fei Wang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Anaerobic Digestion ◽  
Dissolved Organic Matter ◽  
Methane Production ◽  
Volatile Fatty Acids ◽  
High Throughput Sequencing ◽  
Batch Reactor ◽  
Inhibition Mechanism ◽  
Sulfonamide Antibiotics ◽  
High Concentration

The effects of four types of sulfonamide antibiotics (SAs), including sulfaquinoxaline, sulfamethoxazole, sulfamethoxydiazine and sulfathiazole, on the digestion performance during anaerobic digestion process were studied using a lab-scale anaerobic sequencing batch reactor, and the changes of the community structure in the presence of SAs were investigated with the help of high throughput sequencing. The results indicated that when SAs were added, the hydrolytic acidification process was inhibited, and the accumulation of volatile fatty acids (VFAs) was induced, resulting in the suppression of methane production. However, the inhibition mechanism of different SAs was quite different. The inhibitory effect of high concentration of SAs on the hydrolysis of solid particulate matter into dissolved organic matter followed the order of sulfaquinoxaline > sulfamethoxydiazine > sulfathiazole > sulfamethoxazole. SAs have obvious inhibitory effects on acidification and methanation of dissolved organic matter, especially sulfathiazole. The richness and the community composition of the microorganism including bacteria and archaea in the digestion system were affected by SAs. Under the effect of SAs, the relative abundance of many microorganisms is negatively correlated with methane production, among which Methanobrevibacter, a kind of Archaea, had the greatest influence on methane production.

scholarly journals Historical Perspective of the Addition of Magnetic Nanoparticles Into Anaerobic Digesters (2014-2021)

2021 ◽  
Vol 3 ◽  
Author(s):  
Eudald Casals ◽  
Raquel Barrena ◽  
Edgar Gonzalez ◽  
Xavier Font ◽  
Antoni Sánchez ◽  
...  
Keyword(s):  
Organic Matter ◽  
Magnetic Nanoparticles ◽  
Anaerobic Digestion ◽  
Historical Perspective ◽  
Research Field ◽  
Organic Wastes ◽  
Anaerobic Digesters ◽  
Anaerobic Digestion Process ◽  
Digestion Process ◽  
Iron Based

The addition of magnetic nanoparticles to batch anaerobic digestion was first reported in 2014. Afterwards, the number of works dealing with this subject has been increasing year by year. The discovery of the enhancement of anaerobic digestion by adding iron-based nanoparticles has created a multidisciplinary emerging research field. As a consequence, in the last years, great efforts have been made to understand the enhancement mechanisms by which magnetic nanoparticles (NPs) addition enhances the anaerobic digestion process of numerous organic wastes. Some hypotheses point to the dissolution of iron as essential iron for anaerobic digestion development, and the state of oxidation of iron NPs that can reduce organic matter to methane. The evolution and trends of this novel topic are discussed in this manuscript. Perspectives on the needed works on this topic are also presented.

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