Removal of endocrine disrupter compounds from municipal wastewater by an innovative biological technology

2008 ◽  
Vol 58 (4) ◽  
pp. 953-956 ◽  
Author(s):  
L. Balest ◽  
G. Mascolo ◽  
C. Di Iaconi ◽  
A. Lopez

The removal of selected endocrine disrupter compounds (EDCs), namely estrone(E1), 17β-estradiol (E2), 17α-ethynylestradiol (EE2), bisphenol A (BPA) and 4-tert-octylphenol (4t-OP) from municipal wastewater was investigated using a sequencing batch biofilter granular reactor (SBBGR), a new system for biological treatment based on aerobic granular biomass. This new biological treatment is characterized by high biomass concentration (up to 40 g/L), high sludge retention times (up to 6 months) and low sludge production (i.e., an order of magnitude lower than commonly reported for conventional biological technologies). The investigation was carried out comparing a demonstration SBBGR system with a conventional full-scale activated sludge process. Results showed that the SBBGR performed better than a conventional activated sludge process in removing E1, E2, BPA and 4t-OP. In fact, the average removal percentages of the above mentioned EDCs, obtained during a four month operating period, were 62.2, 68, 91.8, 77.9% and 56.4, 36.3, 71.3, 64.6% for the demonstrative SBBGR system and the conventional activated sludge process of the municipal sewage treatment plant, respectively

1994 ◽  
Vol 30 (6) ◽  
pp. 31-40 ◽  
Author(s):  
Hiroyshi Emori ◽  
Hiroki Nakamura ◽  
Tatsuo Sumino ◽  
Tadashi Takeshima ◽  
Katsuzo Motegi ◽  
...  

For the sewage treatment plants near rivers and closed water bodies in urbanized areas in Japan and European countries, there is a growing demand for introduction of advanced treatment processes for nitrogen and phosphorus from the viewpoints of water quality conservation and environmental protection. In order to remove nitrogen by the conventional biological treatment techniques, it is necessary to make a substantial expansion of the facility as compared with the conventional activated sludge process. In such urbanized districts, it is difficult to secure a site and much capital is required to expand the existing treatment plant. To solve these problems, a compact single sludge pre-denitrification process using immobilized nitrifiers was developed. Dosing the pellets, which are suitable for nitrifiers growth and physically durable, into the nitrification tank of single sludge pre-denitrification process made it possible to perform simultaneous removal of BOD and nitrogen in a retention time equal to that in the conventional activated sludge process even at the low water temperature of about 10 °C. The 3,000 m3/d full-scale conventional activated sludge plant was retrofitted and has been successfully operated.


2018 ◽  
Vol 78 (3) ◽  
pp. 644-654 ◽  
Author(s):  
J. Olsson ◽  
S. Schwede ◽  
E. Nehrenheim ◽  
E. Thorin

Abstract A mix of microalgae and bacteria was cultivated on pre-sedimented municipal wastewater in a continuous operated microalgae-activated sludge process. The excess material from the process was co-digested with primary sludge in mesophilic and thermophilic conditions in semi-continuous mode (5 L digesters). Two reference digesters (5 L digesters) fed with waste-activated sludge (WAS) and primary sludge were operated in parallel. The methane yield was slightly reduced (≈10%) when the microalgal-bacterial substrate was used in place of the WAS in thermophilic conditions, but remained approximately similar in mesophilic conditions. The uptake of heavy metals was higher with the microalgal-bacterial substrate in comparison to the WAS, which resulted in higher levels of heavy metals in the digestates. The addition of microalgal-bacterial substrate enhanced the dewaterability in thermophilic conditions. Finally, excess heat can be recovered in both mesophilic and thermophilic conditions.


2013 ◽  
Vol 807-809 ◽  
pp. 694-698
Author(s):  
Rong Xin Huang ◽  
Zhen Xing Wang ◽  
Gang Liu ◽  
Qi Jin Luo

In order to guarantee the reliability and security of reclaiming water, research on the removal efficiency of the environmental endocrine chemicals (EDCs) --the Phthalate Esters (PAEs) in conventional secondary activated sludge and wastewater reclamation and reuse process was undergoing at Harbin wastewater treatment plant (WWTP). The wastewater samples were colleted from every unit effluent of WWTP. The results showed that contamination of EDCs were presented in municipal wastewater at Harbin and the concentrations of the four PAEs were 21.01μg/L for Di-n-butyl Phthalate (DBP); 9.63μg/L for Di-n-octyl Phthalate (DnOP); 4.56μg/L for Diethyl Phthalate (DEP); 1.96μg/L for Dimethyl Phthalate (DMP) respectively in the influent. The conventional activated sludge has good removal efficiencies performance on DMP, DEP and DBP. With the increasing of molecular weight and branch chains of PAEs contaminations, the removal rate of the four PAEs in the conventional activated sludge process decreased from 99.82%(DMP),90.60%(DEP),90.10%(DBP) to the only 45.13% removal rate for DnOP, which was mostly removed from primary treatment but no from secondary activated sludge process; Coagulation-air flotation plus filtration process was not a feasible way to remove PAEs from reclaiming treatment units.


2006 ◽  
Vol 1 (3) ◽  
Author(s):  
Y. Kobayashi ◽  
M. Yasojima ◽  
K. Komori ◽  
Y. Suzuki ◽  
H. Tanaka

Pharmaceuticals resident in sewage and in the aqueous environment has begun to attract attention. The objectives of this research were to clarify the behaviour of selected human antibiotics in wastewater treatment plants, namely levofloxacin (LVFX), clarithromycin (CAM) and azithromycin (AZM) which are much used in Japan. The concentrations in raw influent of LVFX, CAM, AZM were respectively 425~981ng/L, 340~573ng/L, ND(<190 ng/L)~371ng/L. The averages of removal ratio were about 50 % for all selected antibiotics. It was suggested that selected antibiotics was not too much removed in the conventional creature processing like the conventional activated sludge process. The remarkable removals in activated sludge tank using high class treatment method were confirmed about all selected antibiotics. The rise of the concentrations of CAM and AZM was confirmed after the addition of chemical coagulants in one wastewater treatment plant. From the result of batch experiment with activated sludge, it was suggested that LVFX and AZM were removed from water mainly by the absorption to activated sludge. Also, in batch experiment with chemical coagulants, it was suggested that LVFX was removed from water and CAM, AZM were eluted a little in water by adding sulphuric acid band.


2005 ◽  
Vol 51 (1) ◽  
pp. 89-98 ◽  
Author(s):  
M. Brucculeri ◽  
D. Bolzonella ◽  
P. Battistoni ◽  
F. Cecchi

The possibility of co-treating municipal and winery wastewaters in a conventional activated sludge process was studied at full scale. The wastewater treatment plant considered in this paper operated an extended-oxidation process during vintage (four month per year) and a pre-denitrification/oxidation process during the rest of the year. The experimentation showed that good performances, in terms of COD and nitrogen removal, could be obtained in both cases: 90% and 60%, for COD and nitrogen removal, respectively. Thanks to the high solid retention times applied to the system (up to 48 days) the waste activated sludge production was low (0.20 kgMLVSS/kgCODremoved) and respiration was the main process for carbon removal. Nitrification was always satisfactory while the behaviour of the denitrification process during vintage was not totally understood and further studies are going on.


2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Young H. Yoon ◽  
Jae R. Park ◽  
Sang W. Ahn ◽  
Kwang B. Ko ◽  
Kyung J. Min ◽  
...  

Hybrid Activated Sludge Process (HASP) with IMET was developed and applied to an activated sludge process for the advanced nutrient treatment in Korea. The characteristics of nitrogen removal from the HASP were investigated through a kinetic study by batch-type experiment. Online DB analysis produced from the IMET was conducted for the nutrient removal performance in the field demonstration plant treating 10,000 m3/day in G city of Korea. In this paper, we aimed to determine the effect of increasing NHM4+-N load on the specific nitrification rate (SNR) and the specific denitrification rate (SDNR) through a batch-type experiment, and to estimate the net reaction time for the phase-transfer rate using online DB analysis in the HASP operation. Experimental results include: (1) both the nitrification and denitrification followed first-order kinetics; (2) the maximum SNR and SDNR were 4.0301 mgN/gVSS·hr and 2.785 mgN/gVSS·hr, respectively; (3) comparison of reaction rates between nitrification and denitrification from the non-linear regression analysis found that nitrification rate was higher than denitrification.


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