scholarly journals Research on Syntheses and Properties of Water-soluble Symmetrical Squarylium Double-cyanine Dyes

2015 ◽  
Vol 9 (1) ◽  
pp. 113-118
Author(s):  
Xinding Yao ◽  
Ruina Fang ◽  
Hongjian Pang ◽  
Guoji Liu
Keyword(s):  
Raw Materials ◽  
Stokes Shift ◽  
Blue Shift ◽  
Cyanine Dyes ◽  
Water Soluble ◽  
Cyanine Dye ◽  
Squaric Acid ◽  
Diethyl Ester ◽  
Shift Effect ◽  
Photo Stability

In this paper, 2,3,3-trimethyl-3H-indolin was synthesized by phenylhydrazine and 3-methyl-2-butanone as raw materials in the acetic acid reacted with different nitrogenalkylating reagents. Semi mono-cyanine dye and semi dicyanine dye were prepared with the help of squaric acid diethyl ester. The spectral properties of the target products were checked. The results show that compared with symmetrical squarylium mono-indocyanine dyes with the same substituent, the photo-stability of the bi-cyanine dyes were much better. When dissolved in water, the dye showed shorter maximum absorption wavelength, shorter maximum emission wavelength and shorter Stokes shift and apparent aggregation. In protic solvents, dye spectra showed a blue shift effect with an increase of solution polarity, while in aprotic solvents, dye spectrum showed a red shift with solution polarity increased. Among different solvents, the photostability of the dye in methanol is strongest.

DETERMINATION OF CORROSION INFLUENCE ON FUEL METAL, OBTAINED FROM SECONDARY POLYMER RAW MATERIALS

2021 ◽  
pp. 48-56
Author(s):  
K. Сhevchenko ◽  
A. Grigorov ◽  
I. Sinkevich
Keyword(s):  
Raw Materials ◽  
Petroleum Products ◽  
Copper Plate ◽  
Water Soluble ◽  
Synthetic Fuels ◽  
Laboratory Setup ◽  
Corrosive Effect ◽  
Preliminary Preparation ◽  
Sulfur Containing

The article proposes to determine the corrosion effect on fuel metals under dynamic conditions, when washing the prepared copper plate of a certain size, a significant amount of fuel at a certain speed and temperature of the study. This approach will significantly reduce the duration of the study (up to 100 minutes) and is closer to the real conditions of contact of the fuel with a metal surface, in comparison with the standardized method, which is widely used today. Using the proposed laboratory setup, the study was subjected to fuel (200–360 °C), which was obtained by thermal destruction of secondary polymer raw materials, in particular polypropylene. The obtained results showed that the investigated fuel, despite the temperature, the amount of circulating fuel and its water content, does not have a corrosive effect on the copper plate, which can be explained by the absence of corrosive substances in the fuel: water-soluble mineral acids and alkalis, active sulfur compounds and organic acids. However, it should be kept in mind that in polyolefin raw materials, in the form of contamination, there may be products made of other materials, such as rubber and polyvinyl chloride. This can happen when the sorting technology is violated or during the preliminary preparation of raw materials and, in turn, will contribute to the increase in sulfur-containing and chlorine-containing compounds in the fuel, which are characterized by high corrosion activity and should be necessarily removed from the fuel. Note that the fuel obtained from secondary polymer raw materials, in the absence of sulfur-containing and chlorine-containing compounds, is quite promising for the creation on its basis of modern synthetic fuels, analogues of classic petroleum products.

scholarly journals Assessing protopectin transformation potential of plant tissue using a zoned criterion space

2020 ◽  
Vol 8 (2) ◽  
pp. 349-361
Author(s):  
Vladimir Kondratenko ◽  
Tatyana Kondratenko ◽  
Andrey Petrov ◽  
Georgy Belozerov
Keyword(s):  
Boundary Conditions ◽  
Plant Tissue ◽  
Raw Materials ◽  
Water Soluble ◽  
Biologically Active ◽  
Plant Raw Materials ◽  
Criterion Space ◽  
Transformation Potential ◽  
Fragmentation Potential ◽  
Pectin Substances

Introduction. The existing diversity of plant raw materials and products predetermine the prospects of studying their potential as sources of pectin substances. However all current classifications are either fragmented or inconsistent. Study objects and methods. Our theoretical ivestigation aimed to develop an adequate classification for all taxa of plant origin, as well as their tissues and derivatives as pectin-containing materials. We developed criteria for assessing transformation potential of the protopectin complex based on the mass fractions of biologically active non-uronide components, native water-soluble pectin, the protopectin complex, and pectin substances. Individual boundary conditions were based on individual pectin potential, protopectin fragmentation potential, and pectin isolation potential. Results and discussion. Based on the boundary conditions, we defined an universal criterion space that included a set of points M in the coordinates expressed by three main criteria. According to individual boundary conditions, the criterion space was divided, or zoned, into four domains corresponding to protopectin fragmentation potential. They were characterized by: 1) lack of pectin potential, 2) ineffective protopectin fragmentation, 3) ineffective isolation of fragmentation products, and 4) effective isolation. Finally, we developed a generalized algorithm to determine the location of points M[μ1, μ2 , μ3 ] in the zoned criterion space, characterizing the plant tissue. Conclusion. Our approach can be used to assess any plant tissue for its protopectin transformation potential, which determines the technological influence on its pectin potential. This approach is universal, i.e., applicable to both plant tissue and its derivatives.

scholarly journals Particle size-dependent fluorescence properties of water-soluble organic compounds (WSOC) and their atmospheric implications on the aging of WSOC

2021 ◽  
Author(s):  
Juanjuan Qin ◽  
Jihua Tan ◽  
Xueming Zhou ◽  
Yanrong Yang ◽  
Yuanyuan Qin ◽  
...  
Keyword(s):  
Particle Size ◽  
Organic Compounds ◽  
Fine Particles ◽  
Stokes Shift ◽  
Bimodal Distribution ◽  
Dominant Mode ◽  
Water Soluble ◽  
Atmospheric Particle ◽  
Humification Degree ◽  
Transformation Processes

Abstract. Water-soluble organic compounds (WSOC) are essential in atmospheric particle formation, migration, and transformation processes. Size-segregated atmospheric particles were collected in a rural area of Beijing. Excitation-emission matrix (EEM) fluorescence spectroscopy was used to investigate the sources and optical properties of WSOC. Sophisticated data analysis on EEM data was performed to characteristically estimate the underlying connections among aerosol particles in different sizes. The WSOC concentrations and average fluorescence intensity (AFI) showed monomodal distribution in winter and bimodal distribution in summer, with dominant mode between 0.26 to 0.44 µm for both seasons. The EEM spectra of size-segregated WSOC were different among variant particle sizes, which could be the results of changing sources and/or chemical transformation of organics. Size distributions of fluorescence regional intensity (region Ⅲ and Ⅴ) and HIX indicate that humification degree or aromaticity of WSOC was highest between 0.26 to 0.44 µm. The Stokes shift (SS) and the harmonic mean of the excitation and emission wavelengths (WH) reflected that π-conjugated systems were high between 0.26 to 0.44 µm as well. The parallel factor analysis (PARAFAC) results showed that humic-like substances were abundant in fine particles (< 1 µm) and peaked at 0.26–0.44 µm. All evidence supported that the humification degree of WSOC increased in submicron mode (< 0.44 µm) and decreased gradually. Thus, it was conjectured that condensation of organics still goes on in submicron mode, resulting in the highest humification degree exhibit in particle size between 0.26 to 0.44 µm rather than < 0.26 µm. Synthetically analyzing 3-dimensional fluorescence data could efficiently present the secondary transformation processes of WSOC.

Synthesis of PEG derivatives bearing aminophenyl and their application for liquid-phase synthesis of water-soluble unsymmetrical cyanine dyes

Tetrahedron ◽  
2009 ◽  
Vol 65 (27) ◽  
pp. 5257-5264 ◽  
Author(s):  
Lin-Ling Jiang ◽  
Bao-Lin Li ◽  
Feng-Ting Lv ◽  
Li-Fang Dou ◽  
Liu-Chang Wang
Keyword(s):  
Liquid Phase ◽  
Cyanine Dyes ◽  
Water Soluble ◽  
Phase Synthesis

Preparation and ESR Properties of Silicon Nitride Nanowires

2012 ◽  
Vol 164 ◽  
pp. 69-72
Author(s):  
Jin Chen ◽  
Xiao Gang Wang ◽  
Hai Yan Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Phase Composition ◽  
Silicon Nitride ◽  
Oxidation Resistance ◽  
Raw Materials ◽  
Blue Shift ◽  
Ftir Spectra ◽  
Structure Phase ◽  
Ammonia Atmosphere ◽  
Main Component

We prepared Solid silicon nitride nanowires using carbon nanotubes as precursors., Si and SiO2 were used as raw materials,the reaction was carried out in ammonia atmosphere The structure, phase composition, ESR properties and oxidation resistance of the sample were investigated. The results showed that the sizes of the nanorods are 60–80 nm in diameter and up to several microns in length. In the products α-Si3N4 is the main component; the FTIR spectra of the silicon nitride nanowires have blue shift phenomena;The ESR properties show that the as made materials contains a large number of unpaired electrons

Improving Safety when Extracting Water-soluble Ores by Optimizing the Parameters of the Backfill Mass

2021 ◽  
pp. 53-59
Author(s):  
M.M. Khayrutdinov ◽  
◽  
Ch.B. Kongar-Syuryun ◽  
A.M. Khayrutdinov ◽  
Yu.S. Tyulyaeva ◽  
...  
Keyword(s):  
Strain State ◽  
Raw Materials ◽  
Research Work ◽  
Integrated Approach ◽  
Water Soluble ◽  
Mining Operations ◽  
Stress Strain ◽  
Mining System ◽  
Stress Strain State ◽  
Geological Conditions

The results of the scientific and research work devoted to modeling the stress-strain state of the mining system of an underground mine using the finite element method in the FLAC3D software are presented in the article. The possibility of using room-and-pillar mining with backfill with the abandonment of chain pillars is justified. The results are presented concerning the research results of the quantitative assessment of the mass using the von Mises equation and Norton' power law of creep to estimate the contour stress. It becomes possible to determine the sequence of mining of the deposit area and the stage-by-stage filling of the stopes at the stage of mining design due to the high accuracy of modeling the stress-strain state of the mass near mining operations using FLAC3D software. The proposed approach is possible when evaluating the geotechnical state of the rock mass when using the mining systems with various methods of support of the mined-out area: natural; artificial; with the collapse of ores and enclosing rocks, as well as when calculating the combined method of deposit development. A differentiated approach to assessing the state of the mass is possible considering difficult mining and geological conditions, conditions of increased rock pressure, abundant water influx, increased fracturing of rocks by introducing additional conditions into the model depending on its geotechnical state. Variant of the comprehensive exploitation of mineral resources was proposed considering the total value of natural and man-made geo-resources of the area being mined. The possibility of rational use of the mined-out space with the use of various positive qualities of geo-resources at their manmade transformation is also considered. An assessment of the mineral and raw materials potential of the mined area is given with a proposal for the prospects of increasing the integrated approach of excavation, increasing the life of the mining enterprise and the complexity of developing this area.

DEVELOPMENT OF THE COMPOUNDING OF SOFT DRINK ON THE BASIS OF VEGETABLE RAW MATERIALS AND AMBER ACID

2018 ◽  
Author(s):  
Л.Л. ГАНИЖЕВА ◽  
Н.Н. БЕЛИНА ◽  
А.Н. МАТВИЕНКО ◽  
Р.Д. ГАНИЖЕВ ◽  
С.В. НЕГИНА ◽  
...  
Keyword(s):  
Theoretical Basis ◽  
Physicochemical Parameters ◽  
Raw Materials ◽  
Soft Drink ◽  
Water Soluble ◽  
Milk Thistle ◽  
Lemon Balm ◽  
Vegetable Raw Materials ◽  
Dry Water

Теоретически обосновано создание безалкогольного напитка «Янтарная фея», в состав которого входят янтарная и лимонная кислоты, серебро, а также сухие водорастворимые экстракты семян расторопши и листьев мелиссы. Разработана рецептура безалкогольного напитка «Янтарная фея». Приведены данные, характеризующие органолептические и физико-химические показатели напитка. The theoretical basis for creating a soft drink Amber Fairy is presented. A soft drink Amber Fairy includes amber and citric acids, silver and dry water-soluble extracts of seeds of milk thistle and lemon balm leaves. The recipe of soft drink Amber Fairy is developed. The data characterizing organoleptic and physicochemical parameters of the drink are presented.

STUDY OF PROTEIN FRACTIONS OF HIGH-TEMPERATURE HYDROLYZATES OBTAINED FROM SMOKED SPRAT HEADS

Fisheries ◽  
2020 ◽  
Vol 2020 (2) ◽  
pp. 113-117
Author(s):  
Olga Mezenova ◽  
Vladimir Wolkov ◽  
Larisa Baydalinova ◽  
Natalia Mezenova ◽  
Svetlana Agafonova ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Chemical Composition ◽  
Raw Materials ◽  
Weight Fraction ◽  
Water Soluble ◽  
Protein Fractions ◽  
Raw Material ◽  
Organoleptic Characteristics ◽  
Pre Treatment ◽  
Peptide Fractions

The authors study three fractions obtained as a result of hydrolysis of smoked sprat heads (under temperature of 130oC and presser of 0.25 MPa) – fat, protein water-soluble, and protein-and-mineral ones. Waste from sprat production of two fish canning complexes of the Kaliningrad Region - “RosCon” and “Kolkhoz for the Motherland” - was used as raw material. Hydrolysis was carried out in an aqueous medium in two ways - with preliminary separation of fat and without this operation. The protein fraction was sublimated and its quantitative and qualitative indices were examined - mass yield, solubility, chemical composition and molecular fractional composition of the obtained peptide fractions were determined. The output of sublimated protein fractions is practically independent of the type of raw material and the method of pre-treatment and is 6.47.9% of the mass of raw materials. The chemical composition of protein fractions varies widely in terms of fat (1.4–8.3%), minerals (9.8–13.4%) and proteins (72.1–80.2%). The solubility of the peptide fractions ranged from 91-98%. The molecular weight assessment results showed a high content of a low molecular weight fraction of peptides with an MM of less than 10 kDa in all experimental samples (about 38%). This indicates a high digestibility and biological value of the obtained peptide compositions. Sublimated peptide compositions had typical organoleptic characteristics, pleasant aroma and taste of smoked fish. Ключевые

scholarly journals Fruit Seeds as Sources of Bioactive Compounds: Sustainable Production of High Value-Added Ingredients from By-Products within Circular Economy

Molecules ◽  
2019 ◽  
Vol 24 (21) ◽  
pp. 3854 ◽  
Author(s):  
Fidelis ◽  
Moura ◽  
Kabbas Junior ◽  
Pap ◽  
Mattila ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Circular Economy ◽  
Raw Materials ◽  
Scale Up ◽  
Sustainable Use ◽  
Value Added ◽  
Water Soluble ◽  
Lipophilic Compounds

The circular economy is an umbrella concept that applies different mechanisms aiming to minimize waste generation, thus decoupling economic growth from natural resources. Each year, an estimated one-third of all food produced is wasted; this is equivalent to 1.3 billion tons of food, which is worth around US$1 trillion or even $2.6 trillion when social and economic costs are included. In the fruit and vegetable sector, 45% of the total produced amount is lost in the production (post-harvest, processing, and distribution) and consumption chains. Therefore, it is necessary to find new technological and environmentally friendly solutions to utilize fruit wastes as new raw materials to develop and scale up the production of high value-added products and ingredients. Considering that the production and consumption of fruits has increased in the last years and following the need to find the sustainable use of different fruit side streams, this work aimed to describe the chemical composition and bioactivity of different fruit seeds consumed worldwide. A comprehensive focus is given on the extraction techniques of water-soluble and lipophilic compounds and in vitro/in vivo functionalities, and the link between chemical composition and observed activity is holistically explained.

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