scholarly journals Melting behind the front of the shock wave

2019 ◽  
Vol 23 (Suppl. 2) ◽  
pp. 519-524 ◽  
Author(s):  
Evgeny Kraus ◽  
Ivan Shabalin
Keyword(s):  
Equation Of State ◽  
Solid Phase ◽  
Functional Dependence ◽  
Melting Curve ◽  
Configurational Entropy ◽  
Thermodynamic Characteristics ◽  
Melting Process ◽  
Shock Adiabat ◽  
Wide Range ◽  
Minimum Number

A simple caloric model of the equation of state is proposed to describe thermodynamic properties of solid materials with phase transitions with the minimum number of parameters as initial data. Thermodynamic characteristics are calculated in the wide range of densities and pressures. The equation of state of the solid phase was modified by introducing configurational entropy, which made it possible to describe a liquid medium by the same functional dependence, but with its initial parameters. This allowed us not only to construct the equation of state for the liquid, but also to determine the dependence of the melting point on pressure as the boundary between the phases with the corresponding state. It is shown that the melting process is practically not noticeable on the shock adiabat in the pressure - volume plane; however, sharp adiabatic breaks are observed in the temperature - pressure plane. The calculated position of the melting curve agrees with the experimental data found; although this does not fully justify the conclusion about the accuracy of the calculation of the liquid phase adiabat, but fully confirms the qualitative picture.

scholarly journals Equation of state for rhodium at high pressures

2021 ◽  
Vol 2057 (1) ◽  
pp. 012118
Author(s):  
K V Khishchenko
Keyword(s):  
Experimental Data ◽  
Numerical Simulation ◽  
Equation Of State ◽  
Internal Energy ◽  
Specific Volume ◽  
High Pressures ◽  
Thermodynamic Characteristics ◽  
Wide Range ◽  
Hydrodynamic Processes

Abstract An equation of state has been developed for rhodium in a wide range of changes in the specific volume and internal energy. The results of calculations of the thermodynamic characteristics of this metal are presented in comparison with the available experimental data at high pressures. This equation of state can be used in the numerical simulation of hydrodynamic processes under intense impulse influences on matter.

Few-Parameter Equation of State of the Shock Adiabat with Allowance for Melting

2008 ◽  
Vol 3 (4) ◽  
pp. 52-63
Author(s):  
Evgeny I. Kraus
Keyword(s):  
Solid State ◽  
Equation Of State ◽  
Temperature Dependence ◽  
Thermodynamic Functions ◽  
Melting Curve ◽  
Shock Adiabat ◽  
Elastic Component ◽  
Configuration Entropy ◽  
Model Equations ◽  
State Body

The model equations for thermodynamic functions of liquid status based on volume and temperature dependence of Gruneisen coefficient are offered. Thermal components are described by the Debye’s model. Despite the perfect analogy to solid-state body the distinction in an elastic component of energy and pressures is taken into consideration when deriving the equations. The configuration entropy is embedded into thermodynamic functions of liquid. It describes a disorderliness measure of liquid and results in the final values of the entropy when temperature formally amounts to zero. The melting curve as the boundary between phases is constructed.

Evaluation of the accuracy indicators in determination of the coating thickness by crater grinding method

2020 ◽  
Vol 86 (7) ◽  
pp. 39-44
Author(s):  
K. V. Gogolinsky ◽  
A. E. Ivkin ◽  
V. V. Alekhnovich ◽  
A. Yu. Vasiliev ◽  
A. E. Tyurnina ◽  
...  
Keyword(s):  
Coating Thickness ◽  
Functional Dependence ◽  
Measurement Procedure ◽  
Metrological Certification ◽  
Measuring Instruments ◽  
Properties Of Coatings ◽  
Special Equipment ◽  
Grinding Method ◽  
Accuracy Of Measurements ◽  
Wide Range

Thickness is one of the key indicators characterizing the quality and functional properties of coatings. Various indirect methods (electromagnetic, radiation, optical) most often used in practice to measure thickness are based on the functional dependence of a particular physical parameter of the system «base – coating» on the coating thickness. The sensitivity of these procedures to the certain properties of coatings imposes the main restriction to the accuracy of measurements. Therefore, the development and implementation of the approaches based on direct measurements of geometric parameters of the coating appears expedient. These methods often belong to the class of «destructive» and, in addition to measuring instruments, require the use of special equipment. To ensure the uniformity of measurements in the laboratory or technological control, these methods are isolated as a separate procedure (method) and must undergo metrological certification in accordance with GOST R 8.563–2009. We present implementation, metrological certification and practical application of the method for measuring thickness of coatings by crater-grinding method. The principles of technical implementation of test equipment, measurement procedure and calculation formulas are described. The results of evaluating the accuracy indicators of the proposed procedure by calculation and experimental methods are presented. In both cases, the relative error did not exceed 6%. The applicability of the developed technique is shown for a wide range of coating materials (from soft metals to superhard ceramics) of different thickness (with from units to hundreds of micrometers). Apart from the goals of process control and outgoing inspection, the method can be recommended as a reference measurement procedure for calibration of measures and adjusting samples for various types of thickness gauges.

Analysis of Aromatic Amines in Industrial Wastewater by Capillary Gas Chromatography-Mass Spectrometry

2000 ◽  
Vol 35 (2) ◽  
pp. 245-262 ◽  
Author(s):  
Francis I. Onuska ◽  
Ken A. Terry ◽  
R. James Maguire
Keyword(s):  
Gas Chromatography ◽  
Aromatic Amines ◽  
Methylene Chloride ◽  
Solid Phase ◽  
Stationary Phases ◽  
Gas Chromatography Mass Spectrometry ◽  
Substituted Anilines ◽  
Environmental Media ◽  
Solid Phase Extraction Cartridge ◽  
Wide Range

Abstract The analysis of aromatic amines, particularly benzidines, at trace levels in environmental media has been difficult because of the lack of suitable deactivated capillary column stationary phases for gas chromatography. This report describes the use of an improved type of column as well as a method for the analysis of anilines and benzidines in water, wastewater and sewage samples. Extraction procedures are applicable to a wide range of compounds that are effectively partitioned from an aqueous matrix into methylene chloride, or onto a solid-phase extraction cartridge. The extracted analytes are also amenable to separation on a capillary gas chromatographic column and transferable to the mass spectrometer. These contaminants are converted to their N-trifluoroacetyl derivatives. Aniline and some substituted anilines, and 3,3’-dichlorobenzidine and benzidine were determined in 24-h composite industrial water, wastewater, primary sludge and final effluent samples at concentrations from 0.03 up to 2760 µg/L.

Recent Application of Polystyrene-supported Triphenylphosphine in Solid-Phase Organic Synthesis

2019 ◽  
Vol 23 (6) ◽  
pp. 643-678
Author(s):  
Lalthazuala Rokhum ◽  
Ghanashyam Bez
Keyword(s):  
Organic Synthesis ◽  
Combinatorial Chemistry ◽  
Solid Phase ◽  
Recent Application ◽  
Organic Transformations ◽  
Solid Phase Organic Synthesis ◽  
Wide Range ◽  
Fast Development ◽  
Polymer Supported

Recent years have witnessed a fast development of solid phase synthetic pathways, a variety of solid-supported reagent and its applications in diverse synthetic strategies and pharmaceutical applicability’s. Polymer-supported triphenylphosphine is getting a lot of applications owing to the speed and simplicity in the process. Furthermore, ease of recyclability and reuse of polymer-supported triphenylphosphine added its advantages. This review covers a wide range of useful organic transformations which are accomplished using cross-linked polystyrene-supported triphenylphosphine with the aim of giving renewed interest in the field of organic and medicinal-combinatorial chemistry.

Asymptotic for LS estimators in the EV regression model for dependent errors

Filomat ◽  
2017 ◽  
Vol 31 (15) ◽  
pp. 4845-4856
Author(s):  
Konrad Furmańczyk
Keyword(s):  
Regression Model ◽  
Functional Dependence ◽  
Dependent Data ◽  
Errors In Variables ◽  
Mixing Conditions ◽  
Asymptotic Results ◽  
Dependence Measure ◽  
Wide Range ◽  
Ev Regression Model ◽  
Linear And Nonlinear

We study consistency and asymptotic normality of LS estimators in the EV (errors in variables) regression model under weak dependent errors that involve a wide range of linear and nonlinear time series. In our investigations we use a functional dependence measure of Wu [16]. Our results without mixing conditions complete the known asymptotic results for independent and dependent data obtained by Miao et al. [7]-[10].

scholarly journals Towards the Dependence on Parameters for the Solution of the Thermostatted Kinetic Framework

Axioms ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 59
Author(s):  
Bruno Carbonaro ◽  
Marco Menale
Keyword(s):  
Complex System ◽  
Continuous Dependence ◽  
Social Role ◽  
Probability Distributions ◽  
Functional Dependence ◽  
Transition Probability ◽  
Classical Mechanics ◽  
Human Society ◽  
Wide Range ◽  
Probability Densities

A complex system is a system involving particles whose pairwise interactions cannot be composed in the same way as in classical Mechanics, i.e., the result of interaction of each particle with all the remaining ones cannot be expressed as a sum of its interactions with each of them (we cannot even know the functional dependence of the total interaction on the single interactions). Moreover, in view of the wide range of its applications to biologic, social, and economic problems, the variables describing the state of the system (i.e., the states of all of its particles) are not always (only) the usual mechanical variables (position and velocity), but (also) many additional variables describing e.g., health, wealth, social condition, social rôle ⋯, and so on. Thus, in order to achieve a mathematical description of the problems of everyday’s life of any human society, either at a microscopic or at a macroscpoic scale, a new mathematical theory (or, more precisely, a scheme of mathematical models), called KTAP, has been devised, which provides an equation which is a generalized version of the Boltzmann equation, to describe in terms of probability distributions the evolution of a non-mechanical complex system. In connection with applications, the classical problems about existence, uniqueness, continuous dependence, and stability of its solutions turn out to be particularly relevant. As far as we are aware, however, the problem of continuous dependence and stability of solutions with respect to perturbations of the parameters expressing the interaction rates of particles and the transition probability densities (see Section The Basic Equations has not been tackled yet). Accordingly, the present paper aims to give some initial results concerning these two basic problems. In particular, Theorem 2 reveals to be stable with respect to small perturbations of parameters, and, as far as instability of solutions with respect to perturbations of parameters is concerned, Theorem 3 shows that solutions are unstable with respect to “large” perturbations of interaction rates; these hints are illustrated by numerical simulations that point out how much solutions corresponding to different values of parameters stay away from each other as t→+∞.

scholarly journals Recent Developments in the Determination of Biomarkers of Tobacco Smoke Exposure in Biological Specimens: A Review

2021 ◽  
Vol 18 (4) ◽  
pp. 1768
Author(s):  
Hernâni Marques ◽  
Pedro Cruz-Vicente ◽  
Tiago Rosado ◽  
Mário Barroso ◽  
Luís A. Passarinha ◽  
...  
Keyword(s):  
Tobacco Smoke ◽  
Solid Phase ◽  
Smoke Exposure ◽  
Tobacco Smoke Exposure ◽  
World Health ◽  
Second Hand Smoke ◽  
Tobacco Exposure ◽  
Wide Range ◽  
Recent Developments

Environmental tobacco smoke exposure (ETS) and smoking have been described as the most prevalent factors in the development of certain diseases worldwide. According to the World Health Organization, more than 8 million people die every year due to exposure to tobacco, around 7 million due to direct ETS and the remaining due to exposure to second-hand smoke. Both active and second-hand exposure can be measured and controlled using specific biomarkers of tobacco and its derivatives, allowing the development of more efficient public health policies. Exposure to these compounds can be measured using different methods (involving for instance liquid- or gas-chromatographic procedures) in a wide range of biological specimens to estimate the type and degree of tobacco exposure. In recent years, a lot of research has been carried out using different extraction methods and different analytical equipment; this way, liquid–liquid extraction, solid-phase extraction or even miniaturized procedures have been used, followed by chromatographic analysis coupled mainly to mass spectrometric detection. Through this type of methodologies, second-hand smokers can be distinguished from active smokers, and this is also valid for e-cigarettes and vapers, among others, using their specific biomarkers. This review will focus on recent developments in the determination of tobacco smoke biomarkers, including nicotine and other tobacco alkaloids, specific nitrosamines, polycyclic aromatic hydrocarbons, etc. The methods for their detection will be discussed in detail, as well as the potential use of threshold values to distinguish between types of exposure.

scholarly journals A high-throughput and sensitive methodology for the quantification of urinary 8-hydroxy-2′-deoxyguanosine: measurement with gas chromatography-mass spectrometry after single solid-phase extraction

2004 ◽  
Vol 380 (2) ◽  
pp. 541-548 ◽  
Author(s):  
Hai-Shu LIN ◽  
Andrew M. JENNER ◽  
Choon Nam ONG ◽  
Shan Hong HUANG ◽  
Matthew WHITEMAN ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Solid Phase Extraction ◽  
Healthy Subjects ◽  
Solid Phase ◽  
Large Population ◽  
Urine Samples ◽  
Gas Chromatography Mass Spectrometry ◽  
Phase Extraction ◽  
Freeze Dried ◽  
Wide Range

8-Hydroxy-2´-deoxyguanosine (8OHdG) is a widely used biomarker for the measurement of endogenous oxidative DNA damage. A sensitive method for the quantification of 8OHdG in urine by single solid-phase extraction and GC-MS (gas chromatography with MS detection) using selective ion monitoring is described in the present study. After solid-phase extraction, samples are freeze-dried, derivatized by trimethylsilylation and analysed by GC-MS. The urinary 8OHdG was quantified using heavy isotope dilution with [18O]8OHdG. The recovery of 8OHdG after the solid-phase extraction ranged from 70 to 80% for a wide range of urinary 8OHdG levels. Using 1 ml of urine, the limit of quantification was >2.5 nM (2.5 pmol/ml) and the calibration curve was linear in the range 2.5–200 nM. This method was applied to measure 8OHdG in urine samples from 12 healthy subjects. The intra- and inter-day variations were <9%. Urinary 8OHdG levels in spot urine samples from four healthy subjects were also measured for 1 week and, again, the variation was small. The presence of H2O2 in urine did not cause artifactual formation of 8OHdG. Since this assay is simple, rapid, sensitive and reproducible, it seems suitable to be used as a routine methodology for the measurement of urinary excretion of 8OHdG in large population studies.

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