scholarly journals Mechanical and thermal behavior of plantain peel powder filled recycled polyethylene composites

2021 ◽  
Vol 32 (2) ◽  
pp. 114-119
Author(s):  
Joseph Jacob ◽  
Paul Andrew P. Mamza
Keyword(s):  
Room Temperature ◽  
Mechanical Analysis ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Compression Moulding ◽  
Melt Mixing ◽  
Load Bearing ◽  
Creep Analysis ◽  
Immersion Period ◽  
Higher Temperature

Abstract In the arduous search for ways to clean up the environment and produce viable materials from waste plastics; plantain peel powder filled low density polyethylene wastes (wLDPE) were developed through melt mixing and compression moulding techniques. Optimum properties were determined at 15, 55 and 30 % formulation of plantain peel powder, and Kankara clay respectively. Composition with optimum properties has tensile strength of 55.5 MPa, flexural strength of 50.45 MPa and elastic modulus of 2.30 GPa with corresponding minimal water absorption of 0.95% after 30 days immersion period at room temperature. The thermal properties investigated by Dynamic Mechanical Analysis showed that the composite has better thermal stability at higher temperature than wLDPE. Similarly, through creep analysis, the composite was observed to have better load bearing capability at elevated temperature than waste low density polyethylene material. These results indicate that incorporation of treated plantain peel powder and Kankara clay into wLDPE enhanced the mechanical, thermal and creep resistance of wLDPE. This implies load bearing capability and potential suitability for different wall tiles applications.

Effect of Cobalt Stearate and Vegetable Oil on Uv and Biodegradation of Linear Low-Density Poly(Ethylene)-Poly(Vinyl Alcohol) Blends

2011 ◽  
Vol 2 (4) ◽  
pp. 131-148 ◽  
Author(s):  
Francis Vidya ◽  
Subin S. Raghul ◽  
Sarita G Bhat ◽  
Eby Thomas Thachil
Keyword(s):  
Vegetable Oil ◽  
Vinyl Alcohol ◽  
Water Soluble ◽  
Poly Vinyl Alcohol ◽  
Low Density ◽  
Compression Moulding ◽  
Melt Mixing ◽  
Degradation Behaviour ◽  
Moulding Process ◽  
Poly Ethylene

The main objective of this study was to enhance the rate of UV and biodegradation of polyethylene by incorporating biodegradable materials and prooxidants. Prooxidants such as transition metal complexes are capable of initiating photooxidation and polymer chain cleavage, rendering the product more susceptible to biodegradation. In this work, the effect of (1) a metallic photoinitiator, cobalt stearate, and (2) different combinations of cobalt stearate and vegetable oil on the photooxidative degradation of linear low-density poly(ethylene)-poly(vinyl alcohol) (LLDPE/PVA) blend films has been investigated. For this, film-grade LLDPE was blended with different proportions of PVA. PVA is widely used in the industrial field, and recently it has attracted increasing attention as a water-soluble biodegradable polymer. Cobalt stearate and vegetable oil were added to the blends as prooxidants. The blends were prepared by melt mixing in a Thermo HAAKE Polylab system. Thin films containing these additives were prepared by a subsequent compression moulding process. The effect of UV exposure on LLDPE/PVA films in the presence as well as absence of these additives was investigated. Tensile properties, FTIR spectra, and scanning electron microscopy (SEM) were employed to investigate the degradation behaviour. It was found

Exploration on compatibilizing effect of nonionic, anionic, and cationic surfactants on mechanical, morphological, and chemical properties of high-density polyethylene/low-density polyethylene/cellulose biocomposites

2015 ◽  
Vol 30 (6) ◽  
pp. 855-884 ◽  
Author(s):  
AK Sudari ◽  
AA Shamsuri ◽  
ES Zainudin ◽  
PM Tahir
Keyword(s):  
Mechanical Properties ◽  
High Density Polyethylene ◽  
Sodium Stearate ◽  
High Density ◽  
Low Density Polyethylene ◽  
Hexadecyltrimethylammonium Bromide ◽  
Low Density ◽  
Scanning Calorimetry ◽  
Melt Mixing ◽  
Compatibilizing Effect

Three types of surfactants, specifically cationic, anionic, and nonionic, at different weight percentages were added into high-density polyethylene/low-density polyethylene/cellulose (HDPE/LDPE/cellulose) biocomposites via melt mixing. The cationic and anionic surfactants which are hexadecyltrimethylammonium bromide (HTAB) and sodium stearate (SS), respectively, were added from 4 to 20 wt%, whereas the nonionic surfactant which is sorbitan monostearate (SM) was added from 1 to 5 wt%. The mechanical testing results exhibited that the addition of HTAB increased tensile strength and tensile modulus, while SS deteriorated mechanical properties, while SM increased impact strength and tensile extension of the biocomposites. Based on the mechanical properties results, optimum weight percentages of HTAB and SM were 12 wt% and 4 wt%, respectively. The scanning electron microscopic micrographs displayed that the amount of cellulose fillers pullout decreased with the addition of HTAB, followed by SM, but it increased with SS. Fourier transform infrared spectra, X-ray diffractometer patterns, thermogravimetric analysis results, and differential scanning calorimetry thermograms have confirmed the presence of physical interactions only with the addition of HTAB and SM. Based on the results, compatibilizing effect was found in HTAB, whereas SM has not showed compatibilizing effect but instead plasticizing effect. However, neither compatibilizing nor plasticizing effect was exhibited by SS.

Effects of reactive melt mixing on the morphology and thermal behavior of linear low-density polyethylene/rubber blends

2008 ◽  
Vol 109 (2) ◽  
pp. 1014-1021 ◽  
Author(s):  
Maurizio Penco ◽  
Stefania Della Sciucca ◽  
Elisa Passaglia ◽  
Guido Giordani ◽  
Serena Coiai ◽  
...  
Keyword(s):  
Thermal Behavior ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Melt Mixing ◽  
Rubber Blends ◽  
Reactive Melt

Electrical and rheological properties of carbon black and carbon fiber filled low-density polyethylene/ethylene vinyl acetate composites

2018 ◽  
Vol 25 (4) ◽  
pp. 715-723 ◽  
Author(s):  
Xingchi Xu ◽  
Tingwei Wang
Keyword(s):  
Carbon Fiber ◽  
Carbon Black ◽  
Vinyl Acetate ◽  
Great Influence ◽  
Complex Viscosity ◽  
Ethylene Vinyl Acetate ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Melt Mixing ◽  
Significant Difference

Abstract In this study conductive composites of low-density polyethylene (LDPE)/ethylene-vinyl acetate (EVA) filled with carbon black (CB) and carbon fiber (CF) were prepared by melt-mixing method. The morphological, rheological, and electrical properties of CB filled composites were compared with CF filled composites by digital multimeter, scanning electron microscope, rotational rheometer, etc. The composites filled with different fillers have same percolation threshold but the EVA concentration has different effect on the two systems. For CB filled composites the increase in EVA concentration decreased resistivity first and reached lowest point when the LDPE:EVA ratio was 70:30; then the resistivity increased, but for CF filled composites the resistivity continued to decrease. The differences were caused by the diverse morphological and filler distribution of two different composite systems. The rheological behaviors of two types of composites also had significant difference; the value of complex viscosity of CB filled composites was about two orders of magnitude more than CF filled composites in low frequency region. It was because CB particles was nano-scale and had large surface area, so it had great influence on the value of complex viscosity of composites.

Morphology and Mechanical Properties of LDPE, EVA and Fly Ash Composites

2020 ◽  
Vol 869 ◽  
pp. 76-81
Author(s):  
Vu Minh Trong ◽  
Bui Dinh Hoan
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Ethylene Vinyl Acetate ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Melt Mixing ◽  
Elongation At Break ◽  
Acetate Copolymer ◽  
Ethylene Vinyl Acetate Copolymer ◽  
Morphology And Mechanical Properties

The fly ash from Pha Lai power plant was modified by vinyltrimetoxysilan (VTMS). The polymer composites based on low-density polyethylene (LDPE), ethylene vinyl acetate copolymer (EVA) and fly ash (FA) without and with vinyltrimetoxysilan (VTMS) modification were prepared by melt mixing in a Haake Rheomixer. The tensile strength and elongation at break of the LDPE/EVA/VFA composites were also higher than those of the LDPE/EVA/FA composites. The FESEM images proved that FA-VTMS particles disperse more regularly in the polymer matrix in comparison with FA without VTMS modification. In addition, the surface modification of the FA reduced the size of agglomeration of FA particles.

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