scholarly journals Geological sequestration of CO2 in a water-bearing reservoir in hydrate-forming conditions

Author(s):  
Raghvendra Pratap Singh ◽  
Karanpal Singh Shekhawat ◽  
Malay K. Das ◽  
Krishnamurthy Muralidhar

Higher concentration of carbon dioxide in the atmospheric air is a major environmental challenge and requires immediate attention for quicker mitigation. In that respect, the novel idea of CO2 sequestration in geological settings is worth examining from a quantitative perspective. In the present study, numerical simulation of CO2 injection into a porous reservoir is performed. The selected reservoir presents suitable thermodynamic conditions for CO2 hydrate formation. Unsteady simulations are carried out in one space dimension under isothermal and non-isothermal frameworks. An additional simulation of CO2 injection in a depleted methane hydrate reservoir is also reported. In the present study, the response of the reservoir to storage of CO2 is analyzed with respect to four parameters – reservoir porosity, initial water saturation and reservoir temperature and injection pressure. Quantities of interest are hydrate formation patterns and the cumulative CO2 mass sequestration in the reservoir as a function of time. Numerical experiments show that the initial water saturation is an important parameter as it affects both CO2 gas migration and hydrate formation. Isothermal simulation yields results that are similar to the non-isothermal model, thus suggesting that the isothermal assumption may be adopted for future CO2 injection studies. Hydrate formation rate of CO2 near the injection well is found to be one order of magnitude higher than the interior but its magnitude is quite small when compared to water and gas saturations. Higher injection pressure leads to a continuous increase in injected mass of CO2 primarily due to increased gas density, though an increase in hydrate formation near the injection well is also observed. Lower reservoir temperature supports a higher amount of hydrate formation from the injected mass of CO2 and is clearly desirable.

Energies ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1997
Author(s):  
Xingbo Li ◽  
Yu Liu ◽  
Hanquan Zhang ◽  
Bo Xiao ◽  
Xin Lv ◽  
...  

An apparatus for the analysis of pressure cores containing gas hydrates at in situ pressures was designed, and a series of experiments to determine the compressional wave response of hydrate-bearing sands were performed systematically in the laboratory. Considering the difficulties encountered in performing valid laboratory tests and in recovering intact hydrate bearing sediment samples, the laboratory approach enabled closer study than the marine environment due to sample recovery problems. The apparatus was designed to achieve in situ hydrate formation in bearing sediments and synchronous ultrasonic detection. The P-wave velocity measurements enabled quick and successive ultrasonic analysis of pressure cores. The factors influencing P-wave velocity (Vp), including hydrate saturation and formation methodology, were investigated. By controlling the initial water saturation and gas pressure, we conducted separate experiments for different hydrate saturation values ranging from 2% to 60%. The measured P-wave velocity varied from less than 1700 m/s to more than 3100 m/s in this saturation range. The hydrate saturation can be successfully predicted by a linear fitting of the attenuation (Q−1) to the hydrate saturation. This approach provided a new method for acoustic measurement of the hydrate saturation when the arrival time of the first wave cannot be directly distinguished. Our results demonstrated that the specially designed non-embedded ultrasonic detection apparatus could determine the hydrate saturation and occurrence patterns in pressure cores, which could assist further hydrate resource exploration and detailed core analyses.


SPE Journal ◽  
2014 ◽  
Vol 19 (04) ◽  
pp. 674-686 ◽  
Author(s):  
N.. Rezaei ◽  
A.. Firoozabadi

Summary This work presents experimental results and interpretation of injection pressure and recovery performance of waterflooding in strongly water-wet fired Berea cores saturated with n-heptane. The experiments were conducted at constant injection rate at room conditions, and the effects of injection rate and initial water saturation on the oil-recovery performance and dynamic-injection pressure were investigated. Elements of surprise were observed in the injection-pressure data. The pressure profiles showed four distinct regimes, each governed by capillary or viscous forces. At low capillary numbers (Ca=uμ/σ<10–6), capillarity governed two pressure regimes, corresponding to the core inlet and outlet. In the early part of waterflooding, pressure stayed constant for a considerable time before hydrodynamic pressure gradient could overcome the capillary pressure gradient. After viscous forces dominated, a linear increase in injection pressure over time was observed up to breakthrough time. A sudden pressure rise was observed close to breakthrough because of capillary retention at the core outlet. The pressure became constant after the breakthrough when the water- and oil-saturation distributions were stabilized. Changing the injection rate by an order of magnitude in the range from 2.2 to 22.2 pore volumes (PV)/D (equivalent to Ca = 10–7 to 10–6) did not appreciably change the oil-recovery performance; similar breakthrough time and final oil recovery were observed. The effect of initial water saturation was also investigated. When lowering the initial water saturation beyond that established in oil flooding, production performance and injection pressure were similar to those of a core without the initial water saturation. The injection pressure at breakthrough was found to decrease with increase of the initial water saturation. Waterflooding was modeled by including the capillary pressure and excellent agreement was obtained with experimental results of production and injection pressure. We find that in the absence of in-situ saturation measurements, the injection pressure is a better variable for tuning the model parameters compared with the production history alone.


Fuel ◽  
2021 ◽  
Vol 292 ◽  
pp. 120193
Author(s):  
Shunsuke Sakurai ◽  
Ben Hoskin ◽  
Joel Choi ◽  
Tomoya Nonoue ◽  
Eric F. May ◽  
...  

Author(s):  
Sotirios Nik Longinos ◽  
Mahmut Parlaktuna

Abstract This study investigates the effects of types of impellers and baffles on methane hydrate formation. Induction time, water conversion to hydrates (hydrate yield), hydrate formation rate and hydrate productivity are components that were estimated. The initial hydrate formation rate is generally higher with the use of Ruston turbine (RT) with higher values 28.93 × 10−8 mol/s in RT/RT with full baffle (FB) experiment, but the decline rate of hydrate formation was also high compared to up-pumping pitched blade turbine (PBTU). Power consumption is higher also in RT/RT and PBT/RT with higher value 392,000 W in PBT/RT with no baffle (NB) experiment compared to PBT/PBT and RT/PBT experiments respectively. Induction time values are higher in RT/RT experiments compared to PBT/PBT ones. Hydrate yield is always smaller when there is no baffle in all four groups of experiments while the higher values exist in experiments with full baffle. It should be noticed that PBT is the same with PBTU, since all experiments with mixed flow have upward trending.


2021 ◽  
Author(s):  
Nandana Ramabhadra Agastya

Abstract We aim to find a universal method and/or parameter to quantify impact of overall heterogeneity on waterflood performance. For this purpose, we combined the Lorenz coefficient, horizontal permeability to vertical permeability ratio, and thief zone permeability to average permeability ratio, with a radar chart. The area of the radar chart serves as a single parameter to rank reservoirs according to heterogeneity, and correlates to waterflood performance. The parameters investigated are vertical and horizontal permeability. Average porosity, initial water saturation, and initial diagonal pressure ratio are kept constant. Computer based experiments are used over the course of this entire research. We conducted permeability studies that demonstrate the effects of thief zones and crossflow. After normalizing these parameters into a number between 0 and 1, we then plot them on a radar chart. A reservoir's overall degree of heterogeneity can be inferred using the radar chart area procedure discussed in this study. In general, our simulations illustrate that the larger the radar chart area, the more heterogenous the reservoir is, which in turn yields higher water cut trends and lower recovery factors. Computer simulations done during this study also show that the higher the Lorenz coefficient, the higher the probability of a thief zone to exist. Simulations done to study crossflow also show certain trends with respect to under tonguing and radar chart area.


Author(s):  
Casper Hadsbjerg ◽  
Kristian Krejbjerg

When the oil and gas industry explores subsea resources in remote areas and at high water depths, it is important to have advanced simulation tools available in order to assess the risks associated with these expensive projects. A major issue is whether hydrates will form when the hydrocarbons are transported to shore in subsea pipelines, since the formation of a hydrate plug might shut down a pipeline for an extended period of time, leading to severe losses. The industry practices a conservative approach to hydrate plug prevention, which is the addition of inhibitors to ensure that hydrates cannot form under pipeline pressure and temperature conditions. The addition of inhibitors to subsea pipelines is environmentally unfriendly and also a very costly procedure. Recent efforts has therefore focused on developing models for the hydrate formation rate (hydrate kinetics models), which can help determine how fast hydrates might form a plug in a pipeline, and whether the amount of inhibitor can be reduced without increasing the risk of hydrate plug formation. The main variables determining whether hydrate plugs form in a pipeline are: 1) the ratio of hydrocarbons to water, 2) the composition of the hydrocarbons, 3) the flowrates/flow regimes in the pipeline, 4) the amount of inhibitor in the system. Over the lifetime of a field, all 4 variables will change, and so will the challenge of hydrate plug prevention. This paper will examine the prevention of hydrate plugs in a pipeline, seen from a hydrate kinetics point of view. Different scenarios that can occur over the lifetime of a field will be investigated. Exemplified through a subsea field development, a pipeline simulator that considers hydrate formation in a pipeline is used to carry out a study to shed light on the most important issues to consider as conditions change. The information gained from this study can be used to cut down on inhibitor dosage, or possibly completely remove the need for inhibitor.


Geophysics ◽  
2020 ◽  
Vol 85 (4) ◽  
pp. H51-H60
Author(s):  
Feng Zhou ◽  
Iraklis Giannakis ◽  
Antonios Giannopoulos ◽  
Klaus Holliger ◽  
Evert Slob

In oil drilling, mud filtrate penetrates into porous formations and alters the compositions and properties of the pore fluids. This disturbs the logging signals and brings errors to reservoir evaluation. Drilling and logging engineers therefore deem mud invasion as undesired and attempt to eliminate its adverse effects. However, the mud-contaminated formation carries valuable information, notably with regard to its hydraulic properties. Typically, the invasion depth critically depends on the formation porosity and permeability. Therefore, if adequately characterized, mud invasion effects could be used for reservoir evaluation. To pursue this objective, we have applied borehole radar to measure mud invasion depth considering its high radial spatial resolution compared with conventional logging tools, which then allows us to estimate the reservoir permeability based on the acquired invasion depth. We investigate the feasibility of this strategy numerically through coupled electromagnetic and fluid modeling in an oil-bearing layer drilled using freshwater-based mud. Time-lapse logging is simulated to extract the signals reflected from the invasion front, and a dual-offset downhole antenna mode enables time-to-depth conversion to determine the invasion depth. Based on drilling, coring, and logging data, a quantitative interpretation chart is established, mapping the porosity, permeability, and initial water saturation into the invasion depth. The estimated permeability is in a good agreement with the actual formation permeability. Our results therefore suggest that borehole radar has significant potential to estimate permeability through mud invasion effects.


2021 ◽  
Author(s):  
Xinpu Shen

Abstract This paper presents an integrated workflow for feasibility study of cuttings reinjection (CRI) based on 3D geomechanics analysis. Solutions of various mechanical variables obtained with 3D geomechanics analysis at various level of scale are used as basis for designing parameters of CRI. Solutions of geomechanics analysis provide basis for a feasibility study and/or design of CRI: solution of 3D geostress distribution and the effective stress ratio are the essential factors for selecting the best location of injection well; solution of 1D geomechanics analysis provides basis for choice of true vertical depth (TVD) interval for injection sections; and hydraulic fracturing performed in the framework of 3D geomechanics analysis provides the most accurate solution for both the injection pressure window and fault reactivation related to CRI as well as estimation of seismic behavior. Example of feasibility study of cuttings reinjection with the integrated workflow proposed here is presented with data from a case in offshore West Africa. Solutions of geomechanics analysis are used for decision making at various stages of CRI. There are several faults in this region. The location of the injection well is chosen at a place with principal stress ratio's value at 0.68. The interval of injection well section is chosen as a 140-ft section with center at TVD = 6,700 ft. The numerical solution of injection pressure window is defined with 46 MPa as lower bound and 80 MPa as upper bound. The width of the fracture is 0.069 m, and length and height are 4,000 m and 100 m respectively. The accommodation volume of fluid with cuttings is 2.76×104 m3. The maximum magnitude of Richter scale of the seismicity corresponding to the fault reactivation is 3.15. The case study described in this paper provides an integrated workflow for feasibility study of CRI based on 3D geomechanics analysis. A best practice for this type of CRI design is also presented.


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