Novel Electro Polymerization Method to Synthesized Anti-corrosion Coated Layer on Stainless Steel Surface from (N-Benzothiazolyl Maleamic Acid) and Study its Biological Activity

2018 ◽  
Vol 9 (3) ◽  
Author(s):  
Muna I Khalaf ◽  
Khulood A Saleh ◽  
Khalil S Khalil
Keyword(s):  
Stainless Steel ◽  
Chemical Structure ◽  
Inhibition Efficiency ◽  
Steel Plate ◽  
Polymeric Coating ◽  
Stainless Steel Surface ◽  
Plate Electrode ◽  
Before And After ◽  
Maleamic Acid ◽  
Polymerization Method

Electro polymerization of N-benzothiazolyl maleamic acid (NBM) was carried out on stainless steel plate electrode in a protic medium of monomer aqueous solution using electrochemical oxidation procedure in electrochemical cell.Spectroscopic characterization techniques were investigated to obtain information about the chemical structure of polymer. The anti-corrosion action of polymer was investigated on stainless steel by electrochemical polarization method. In addition, the effect of adding nanomaterial (TiO2, ZnO (bulk-nano)) to monomer solution on the corrosion behavior of stainless steel was investigated. The results obtained showed that the corrosion rate of S-steel increased with temperature increase from 293K to 323K and the values of inhibition efficiency by coating polymer increase with nanomaterial addition. Apparent energies of activation have been calculated for the corrosion process of S-steel in acidic medium before and after polymeric coating. Furthermore were studied the effect of the preparing polymer on some strain of bacteria.

Wear Properties of Paste Boronized 316 Stainless Steel Before and After Shot Blasting Process

2014 ◽  
Vol 11 (2) ◽  
pp. 75
Author(s):  
Muhamad Hafizuddin Mohamad Basir ◽  
Bulan Abdullah ◽  
Siti Khadijah Alias
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Surface Deformation ◽  
Wear Behaviour ◽  
Stainless Steel Surface ◽  
Shot Blasting ◽  
Wear Properties ◽  
Deformation Method ◽  
316 Stainless Steel ◽  
Before And After

This research investigates and analyzes wear properties of 316 stainless steel before and after applying paste boronizing process and to investigate the effect of shot blasting process in enhancing boron dispersion into the steel. In order to enhance the boron dispersion into 316 stainless steel, surface deformation method by shot blasting process was deployed. Boronizing treatment was conducted using paste medium for 8 hours under two different temperatures which were 8500C and 9500C. Wear behaviour was evaluated using pin-on-disc test for abrasion properties. The analysis on microstructure, X-ray Diffraction (XRD) and density were also carried out before and after applying boronizing treatment. Boronizing process that had been carried out on 316 stainless steel increases the wear resistance of the steel compared to the unboronized 316 stainless steel. The effect of boronizing treatment together with the shot blasting process give a greater impact in increasing the wear resistance of 316 stainless steel. This is mainly because shot blasted samples initiated surface deformation that helped more boron dispersion due to dislocation of atom on the deformed surface. Increasing the boronizing temperature also increases the wear resistance of 316 stainless steel. In industrial application, the usage of the components that have been fabricated using the improved 316 stainless steel can be maximized because repair and replacement of the components can be reduced as a result of improved wear resistance of the 316 stainless steel.

Oxidation Characteristics of Various Nickel Composite Coated on Ferritic Stainless Steel

2013 ◽  
Vol 789 ◽  
pp. 455-459
Author(s):  
Asep Ridwan Setiawan ◽  
Raden Dadan Ramdan ◽  
Budi Prawara ◽  
Steven Steven ◽  
Rochim Suratman
Keyword(s):  
Stainless Steel ◽  
Ferritic Stainless Steel ◽  
Sol Gel ◽  
Substrate Material ◽  
Stainless Steel Surface ◽  
Service Temperature ◽  
X Ray Diffraction ◽  
Composite Layers ◽  
Oxidation Characteristics ◽  
Before And After

The present works concerns in developing alternative interconnect material for solid oxide fuel cell (SOFC) application. For this purpose, ferritic stainless steel is used as the substrate material while various nickel composite layers were coated on the substrate in order to improve its oxidation resistance at SOFC application temperature. Nickel layers were deposited on ferritic stainless steel by high velocity oxy-fuel (HVOF) method. In order to create nickel-oxide layer, the coated samples is then heated at temperature of 950°C for 1 hour, wherease sol-gel coating was performed on the coated samples in order to create nickel manganese oxide spinnel composite layers. All samples were then oxidized at temperature 800°C for 8 hours, in order to evaluate their oxidation characteristics at SOFC service temperature. Before and after oxidation, x-ray diffraction (XRD) and scanning electron microscope (SEM) were performed to all samples. It was observed that coated samples effectively inhibit the formation of chromium oxide that normally occurs on stainless steel surface at SOFC service temperature.

scholarly journals Exploring the corrosion inhibition capability of FAP-based ionic liquids on stainless steel

2020 ◽  
Vol 7 (7) ◽  
pp. 200580
Author(s):  
Julius Kim A. Tiongson ◽  
Kim Christopher C. Aganda ◽  
Dwight Angelo V. Bruzon ◽  
Albert P. Guevara ◽  
Blessie A. Basilia ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Ionic Liquids ◽  
Corrosion Inhibition ◽  
Surface Characterization ◽  
Protective Coatings ◽  
Stainless Steel Surface ◽  
Imidazolium Cations ◽  
Before And After ◽  
Steel Surfaces ◽  
Materials Failure

Corrosion is clearly one of the more common causes of materials failure in stainless steel. To manage corrosion, chemical inhibitors are often used for prevention and control. Ionic liquids due to their hydrophobic and corrosion-resistant property are being explored as alternative protective coatings and anti-corrosion materials. In this particular study, ionic liquids containing functionalized imidazolium cations and tris(pentafluoroethyl)trifluorophosphate (FAP) anions were investigated for their ability to inhibit corrosion on stainless steel surfaces in acidic environment. Using surface characterization techniques, specifically scanning electron microscopy and energy-dispersive X-ray (EDX), the morphology and the elemental composition of the steel surfaces before and after corrosion were determined. Contact angle measurements were also performed to determine how these ionic liquids were able to wet the stainless steel surface. In addition, potentiodynamic studies were carried out to ensure that corrosion inhibition has occurred. Results show that these ionic liquids were able to inhibit corrosion on the stainless steel surfaces. This indicates promise in the use of these FAP-based ionic liquids for corrosion management in stainless steel.

scholarly journals Thermodynamic and Optimization Studies of Castor Leaf Extract as Corrosion Inhibitor on Stainless Steel (301)

2020 ◽  
Vol 17 (3) ◽  
pp. 229-238
Author(s):  
A.O. Okewale ◽  
A.T. Adebayo
Keyword(s):  
Activation Energy ◽  
Weight Loss ◽  
Stainless Steel ◽  
Leaf Extract ◽  
Inhibition Efficiency ◽  
Desirability Function ◽  
Activation Parameters ◽  
Quadratic Model ◽  
Stainless Steel Surface ◽  
Hcl Concentration

Inhibition of stainless steel corrosion in acidic medium with castor leaf extract was studied using the Gravimetric measurement. The mechanisms of inhibition, influence of temperature on inhibition efficiency and weight loss were determined for temperature range 40 oC – 80 oC at 7 hours  immersion time. An increased in temperature showed a decreased in the inhibition efficiency of the castor leaf extract which resulted to increase in weight loss of the stainless steel. The value of rate constant for the corrosion process ranges from 0.333 – 1.225 hr−1, this is seen to be directly relative to the inhibitor concentrations. Activation energy, enthalpy of activation, and entropy values ranges from 74.000 - 136.377 kJ/mol, 71.820 – 133.620 kJ/mol, and 9.860 – 178.110 J/molK respectively. Rise in activation energy with inhibitor concentration confirmed physisorption adsorption mechanism for stainless steel surface corrosion. In order to obtain the optimum weight loss, optimization of the process variables was carried out using the Box – Behnken Design plan and desirability function of response surface methodology (RSM). Four parameters were varied viz; time of immersion, HCl concentration, inhibitor’s concentration, and temperature alongside their effects on weight loss of the stainless steel were verified. The optimal conditions predicted from the second order quadratic model were time (9.10 hours), HCl concentration (3.97 M), concentration of inhibitor (240.90 ppm), and temperature (78.67 oC) with 2.978 g as the weight loss. Statistically, the results showed that 95.03% of the variation in total weight loss of stainless steel can be connected to the experimental variables examined. Keywords: Weight loss, activation parameters, adsorption, optimization, stainless steel, castor leaf

scholarly journals Electrochemical Polymerization and Biological Activity of 4-(Nicotinamido)-4-Oxo-2-Butenoic Acid as An Anticorrosion Coating on A 316L Stainless Steel Surface

2021 ◽  
pp. 729-741
Author(s):  
Sana A. Habeeb ◽  
Khulood A. Saleh
Keyword(s):  
Stainless Steel ◽  
Biological Activity ◽  
Fourier Transforms ◽  
Electrochemical Polymerization ◽  
Polymeric Coating ◽  
Stainless Steel Surface ◽  
Nano Materials ◽  
Chemical Polarization ◽  
Anticorrosion Coating ◽  
Butenoic Acid

In this study, poly4-(nicotinamido)-4-oxo-2-butenoic acid (PNOE) was prepared by the electro polymerization of 4-(nicotinamido)-4-oxo-2-butenoic acid (NOE) monomer on a 316 stainless steel (St.St) which acts as an anticorrosion coating.  Fourier transforms infrared (FTIR), atomic force microscopy (AFM), scanning electron microscopy (SEM), and cyclic voltammetry were used to diagnose the structure and the properties of the prepared polymer layer. The corrosion behavior of the uncoated and coated 316  St.St were evaluated by using an electro chemical polarization technique in 0.2 M hydrochloric acid  solution as a corrosive medium at a temperature range of 293 to 323 K. Nano materials, such as nano ZnO and graphene were added in different concentrations to the monomer solution for improving  the corrosion resistance  of the 316 St.St surface. The results showed that the values of protection efficiencies of the polymeric coating were increased after adding the nano materials. The kinetic and thermodynamic activation parameters were also calculated and the biological activity of the polymer film against Gram negative and positive bacteria was studied.

scholarly journals Functional Antimicrobial Surface Coatings Deposited onto Nanostructured 316L Food-Grade Stainless Steel

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1055
Author(s):  
Gonzalez A. S. ◽  
Riego Á. ◽  
Vega V. ◽  
García J. ◽  
Galié S. ◽  
...  
Keyword(s):  
Stainless Steel ◽  
316L Stainless Steel ◽  
Electrochemical Techniques ◽  
Functional Materials ◽  
Atomic Layer ◽  
Thin Layers ◽  
Nanoporous Structure ◽  
Stainless Steel Surface ◽  
Functional Coatings ◽  
Food Grade

In our study, we demonstrated the performance of antimicrobial coatings on properly functionalized and nanostructured 316L food-grade stainless steel pipelines. For the fabrication of these functional coatings, we employed facile and low-cost electrochemical techniques and surface modification processes. The development of a nanoporous structure on the 316L stainless steel surface was performed by following an electropolishing process in an electrolytic bath, at a constant anodic voltage of 40 V for 10 min, while the temperature was maintained between 0 and 10 °C. Subsequently, we incorporated on this nanostructure additional coatings with antimicrobial and bactericide properties, such as Ag nanoparticles, Ag films, or TiO2 thin layers. These functional coatings were grown on the nanostructured substrate by following electroless process, electrochemical deposition, and atomic layer deposition (ALD) techniques. Then, we analyzed the antimicrobial efficiency of these functionalized materials against different biofilms types (Candida parapsilosis, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and Staphylococcus epidermidis). The results of the present study demonstrate that the nanostructuring and surface functionalization processes constitute a promising route to fabricate novel functional materials exhibiting highly efficient antimicrobial features. In fact, we have shown that our use of an appropriated association of TiO2 layer and Ag nanoparticle coatings over the nanostructured 316L stainless steel exhibited an excellent antimicrobial behavior for all biofilms examined.

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