scholarly journals Unambiguous Identification of Key Molecular Species in Deposits Responsible for Increased Pollution from Internal Combustion Engines

Author(s):  
Max K. Edney ◽  
Joseph S. Lamb ◽  
Matteo Spanu ◽  
Emily F. Smith ◽  
Elisabeth Steer ◽  
...  

<p>Clean and efficient internal combustion engine performance will play a significant role in the move to a decarbonized energy system. Currently, fuel deposit formation on engine components negatively impacts CO2 and pollutant emissions, where previous attempts at deposit characterization afforded non-diagnostic chemical assignments. Here, we uncover the identity and 3D spatial distribution of molecular species from gasoline, diesel injector and filter deposits with the 3D OrbiSIMS technique. Alkylbenzyl sulfonates, derived from lubricant oil contamination in the engine fuel cycle, were common to samples, we evidence transformation of the native sulfonate to longer chain species by reaction with fuel fragments in the gasoline deposit. Inorganic salts, identified in both diesel deposits, were prevalent throughout the injector deposits depth. We identified common polycyclic aromatic hydrocarbons up to C66H20, these were prevalent in the gasoline deposits lower depths. This work will enable deposit mitigation by unravelling their chemical composition, spatial distribution, and origins.</p>

2020 ◽  
Author(s):  
Max K. Edney ◽  
Joseph S. Lamb ◽  
Matteo Spanu ◽  
Emily F. Smith ◽  
Elisabeth Steer ◽  
...  

<p>Clean and efficient internal combustion engine performance will play a significant role in the move to a decarbonized energy system. Currently, fuel deposit formation on engine components negatively impacts CO2 and pollutant emissions, where previous attempts at deposit characterization afforded non-diagnostic chemical assignments. Here, we uncover the identity and 3D spatial distribution of molecular species from gasoline, diesel injector and filter deposits with the 3D OrbiSIMS technique. Alkylbenzyl sulfonates, derived from lubricant oil contamination in the engine fuel cycle, were common to samples, we evidence transformation of the native sulfonate to longer chain species by reaction with fuel fragments in the gasoline deposit. Inorganic salts, identified in both diesel deposits, were prevalent throughout the injector deposits depth. We identified common polycyclic aromatic hydrocarbons up to C66H20, these were prevalent in the gasoline deposits lower depths. This work will enable deposit mitigation by unravelling their chemical composition, spatial distribution, and origins.</p>


Author(s):  
Abazar Shamekhi ◽  
Nima Khatibzadeh ◽  
Amir H. Shamekhi

Nowadays, increased attention has been focused on internal combustion engine fuels. Regarding environmental effects of internal combustion engines particularly as pollutant sources and depletion of fossil fuel resources, compressed natural gas (CNG) has been introduced as an effective alternative to gasoline and diesel fuel in many applications. A high research octane number allows combustion at higher compression ratios without knocking and good emission characteristics of HC and CO are major benefits of CNG as an engine fuel. In this paper, CNG as an alternative fuel in a spark ignition engine has been considered. Engine performance and exhaust emissions have been experimentally studied for CNG and gasoline in a wide range of the engine operating conditions.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 996
Author(s):  
Venera Giurcan ◽  
Codina Movileanu ◽  
Adina Magdalena Musuc ◽  
Maria Mitu

Currently, the use of fossil fuels is very high and existing nature reserves are rapidly depleted. Therefore, researchers are turning their attention to find renewable fuels that have a low impact on the environment, to replace these fossil fuels. Biogas is a low-cost alternative, sustainable, renewable fuel existing worldwide. It can be produced by decomposition of vegetation or waste products of human and animal biological activity. This process is performed by microorganisms (such as methanogens and sulfate-reducing bacteria) by anaerobic digestion. Biogas can serve as a basis for heat and electricity production used for domestic heating and cooking. It can be also used to feed internal combustion engines, gas turbines, fuel cells, or cogeneration systems. In this paper, a comprehensive literature study regarding the laminar burning velocity of biogas-containing mixtures is presented. This study aims to characterize the use of biogas as IC (internal combustion) engine fuel, and to develop efficient safety recommendations and to predict and reduce the risk of fires and accidental explosions caused by biogas.


Author(s):  
Federico Perini ◽  
Anand Krishnasamy ◽  
Youngchul Ra ◽  
Rolf D. Reitz

The need for more efficient and environmentally sustainable internal combustion engines is driving research towards the need to consider more realistic models for both fuel physics and chemistry. As far as compression ignition engines are concerned, phenomenological or lumped fuel models are unreliable to capture spray and combustion strategies outside of their validation domains — typically, high-pressure injection and high-temperature combustion. Furthermore, the development of variable-reactivity combustion strategies also creates the need to model comprehensively different hydrocarbon families even in single fuel surrogates. From the computational point of view, challenges to achieving practical simulation times arise from the dimensions of the reaction mechanism, that can be of hundreds species even if hydrocarbon families are lumped into representative compounds, and thus modeled with non-elementary, skeletal reaction pathways. In this case, it is also impossible to pursue further mechanism reductions to lower dimensions. CPU times for integrating chemical kinetics in internal combustion engine simulations ultimately scale with the number of cells in the grid, and with the cube number of species in the reaction mechanism. In the present work, two approaches to reduce the demands of engine simulations with detailed chemistry are presented. The first one addresses the demands due to the solution of the chemistry ODE system, and features the adoption of SpeedCHEM, a newly developed chemistry package that solves chemical kinetics using sparse analytical Jacobians. The second one aims to reduce the number of chemistry calculations by binning the CFD cells of the engine grid into a subset of clusters, where chemistry is solved and then mapped back to the original domain. In particular, a high-dimensional representation of the chemical state space is adopted for keeping track of the different fuel components, and a newly developed bounding-box-constrained k-means algorithm is used to subdivide the cells into reactively homogeneous clusters. The approaches have been tested on a number of simulations featuring multi-component diesel fuel surrogates, and different engine grids. The results show that significant CPU time reductions, of about one order of magnitude, can be achieved without loss of accuracy in both engine performance and emissions predictions, prompting for their applicability to more refined or full-sized engine grids.


Author(s):  
Tomoyuki Hosaka ◽  
Taisuke Sugii ◽  
Eiji Ishii ◽  
Kazuhiro Oryoji ◽  
Yoshihiro Sukegawa

The improved fuel economy and low pollutant emissions are highly demanded for internal combustion engines. Gasoline Direct Injection (GDI) engine is the one of promising devices for highly efficient engine. However, GDI engines generally tend to emit more Particulate Matter (PM) than Port Fuel Injection (PFI) engine because the fuel sprayed from the injector can easily attach to the wall, which is the major origin of PM. Therefore, the precise analysis of the fuel/air mixture formation and the prediction of emissions are required. From the view of industrial use, Computational Fluid Dynamics (CFD) becomes a necessary tool for the various analyses including the fuel/air mixture formation, spray attachment on the cylinder wall, the in-cylinder turbulence formation, the combustion and emission etc. In our previous study, the flow and spray simulation in internal combustion engine has been conducted using OpenFOAM®, the open-source CFD toolbox. Since the engine involves the dynamic motion such as valve and piston, the morphing and mapping approach was employed. Furthermore, by virtue of open-source code, we have developed the methodology of the hybrid simulation from the internal nozzle flow to the fuel/air mixture in order to take into account detailed breakup process nearby injector nozzle. We expand the above research to the combustion simulation. For the combustion model, the Hyperbolic Tangent Approximation (HTA) model is adopted. The HTA model has a simple form of equation and one can easily implement; moreover, the HTA model has the following features: 1. capability of both laminar and turbulent flow, 2. the clearness of analytical derivation based on the functional approximation of the reaction progress variable distribution in a one-dimensional laminar flame. In the current study, the premixed flame is studied on a gasoline combustion engine. The simulations for in-cylinder engine are conducted with different Air/Fuel (A/F) ratio conditions, and the results are compared with the experimental results. The in-cylinder pressure agrees well with experimental results and the validity of the current methodology is confirmed.


Author(s):  
Samiddha Palit ◽  
Bijan Kumar Mandal ◽  
Sudip Ghosh ◽  
Arup Jyoti Bhowal

Fast depletion of the conventional petroleum-based fossil fuel reserves and the detrimental effects of the pollutant emissions associated with the combustion of these fuels in internal combustion (IC) engines propelled the exploration and development of alternative fuels for internal combustion engines. Biodiesel has been identified as one of the most promising alternative fuels for IC engines. This paper discusses about the advantages and disadvantages of biodiesel vis-a-vis the conventional petro-diesel and presents the energetic performances and emission characteristics of CI engine using biodiesel and biodiesel-petrodiesel blends as fuels. An overview of the current research works carried out by several researchers has been presented in brief. A review of the performance analysis suggests that biodiesel and its blends with conventional diesel have comparable brake thermal efficiencies. The energy balance studies show that biodiesel returns more than 3 units of energy for each unit used in its production. However, the brake specific fuel consumption increases by about 9–14% compared to diesel fuel. But, considerable improvement in environmental performance is obtained using biodiesel. There is significant reduction in the emissions of unburned hydrocarbons, polyaromatic hydrocarbons (PAHs), soot, particulates, carbon monoxide, carbon dioxide and sulphur dioxide with biodiesel. But the NOx emission is more with biodiesel compared to diesel. A case study with Jatropha biodiesel as fuel and the current development status, both global and Indian, of biodiesel as a CI engine fuel have been included in the paper.


2019 ◽  
Vol 178 (3) ◽  
pp. 27-37 ◽  
Author(s):  
Denys STEPANENKO ◽  
Zbigniew KNEBA

The mathematical description of combustion process in the internal combustion engines is a very difficult task, due to the variety of phenomena that occurring in the engine from the moment when the fuel-air mixture ignites up to the moment when intake and exhaust valves beginning open. Modeling of the combustion process plays an important role in the engine simulation, which allows to predict in-cylinder pressure during the combustion, engine performance and environmental impact with high accuracy. The toxic emissions, which appears as a result of fuels combustion, are one of the main environmental problem and as a result the air pollutant regulations are increasingly stringent, what makes the investigation of the combustion process to be a relevant task.


Author(s):  
Г.Д. КОКОРЕВ ◽  
Е.А. ЖУРАВЛЕВА

В исследовании рассмотрены некоторые составляющие технической эксплуатации автомобильной техники (АТ), связанные с диагностированием топливной аппаратуры двигателей внутреннего сгорания (ДВС), причем с целью осуществления неразрушающего контроля предлагается применять ультразвуковую и акустико-эмиссионную системы технического диагностирования.Необходимо констатировать, что при рассмотрении соотношений, показывающих взаимосвязь акустических и физико-механических параметров материалов, в основном используется временной интервал, и при его некорректном измерении получаем низкую информативность и невысокую точность акустических методов определения механических характеристик. При разработке методики использованы принципы спектрального анализа импульсов, отраженных от исследуемых элементов АТ, на которых опирается также метод разработки как аппаратного так и программного обеспечения для обработки полученных сигналов. Результаты предыдущих исследований дают основание полагать, что применение преобразований Фурье обеспечивает получение достоверной информации, основанной на акустических сигналах, если последовательность измерений составляет около 10 секунд. Опыт разработчиков системы свидетельствует о высокой информативности параметров распространения рэлеевских волн. В связи с этим система была укомплектована специально разработанным малобазным датчиком рэлеевских волн. Регистрированные отраженные сигналы в последующем обрабатываются пакетом прикладных программ. Данный преобразователь может быть эффективно использован в задачах контроля накопления повреждений в материале элементов АТ, подвергаемых упруго-пластическим и усталостным воздействиям.Принцип действия системы основан на стробоскопическом эффекте восстановления отраженных импульсов, которые получаются в результате «облучения» материала обследуемого элемента АТ зондирующими импульсами в указанной полосе частот. The study considers some components of technical operation of automotive equipment (at) related to the diagnosis of fuel equipment of internal combustion engines, and for the purpose of non-destructive testing, it is proposed to use ultrasonic and acoustic emission systems for technical diagnostics. It should be noted that when considering the relations showing the relationship between acoustic and physical-mechanical parameters of materials, the time interval is mainly measured, and if the measurement is incorrect, the relationship between the acoustic and physical-mechanical parameters of the material often gives low information content and low accuracy of acoustic methods for determining mechanical characteristics. When developing the technique, the principles of spectral analysis of pulses refl ected from the studied at elements are used, which also support the method of developing both hardware and software for processing the received signals. The results of previous studies suggest that the use of Fourier transforms provides reliable information based on acoustic signals, if the measurement sequence is about 10 seconds. The experience of the system developers shows that the parameters of Rayleigh wave propagation are highly informative. In this regard, the system was equipped with a specially developed low-base relay wave sensor. The registration of refl ected signals is then processed by a package of application programs. This Converter can be effectively used in the tasks of monitoring the accumulation of damage in the material of at elements subjected to elastic-plastic and fatigue effects. The principle of operation of the system is based on the stroboscopic effect of recovery of refl ected pulses, which are obtained as a result of "irradiation" of the material being examined by the at element with probing pulses in the specifi ed frequency band.


2016 ◽  
Vol 822 ◽  
pp. 169-174
Author(s):  
Alexandru Mihai Dima ◽  
Dragos Tutunea ◽  
Marin Bica

The automotive industry represents one of the most important segments of the world economy that has to be in a continue development. The latest procedures for determination of an internal combustion engine performance have a big acquisition cost and demand special conditions even if the tested engine has smaller dimensions. The present paper presents other accessible solutions for this matter.


Author(s):  
Stephen A. Ciatti ◽  
Thomas Wallner ◽  
Henry Ng ◽  
William F. Stockhausen ◽  
Brad Boyer

Although hydrogen is considered one of the most promising future energy carriers, there are several challenges to achieving a “hydrogen economy,” including finding a practical, efficient, cost-effective end-use device. Using hydrogen as a fuel for internal combustion engines is seen as a bridging technology toward a large-scale hydrogen infrastructure. To facilitate high-efficiency, high-power-density use of hydrogen with near-zero emissions in an internal combustion engine, detailed analysis of the hydrogen combustion process is necessary. This paper presents thermodynamic results regarding engine performance and emissions behavior during investigations performed on a single-cylinder research engine fueled by pressurized gaseous hydrogen. Avoiding combustion anomalies is one of the necessary steps to further improve the hydrogen engine power output at high-load operation while, at the same time, reducing fuel consumption and emissions during part-load operation. The overall target of the investigations is an improved combustion concept especially designed for hydrogen-engine-powered vehicles. Future activities include performing optical imaging of hydrogen combustion by using an endoscope. We will also investigate supercharged external mixture formation, as well as hydrogen direct-injection operation.


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