scholarly journals Modeling of corrosive atmospheres for evaluation of the efficiency of volatile inhibitors

2018 ◽  
Vol 84 (7) ◽  
pp. 42-46
Author(s):  
V. I. Vigdorovich ◽  
L. E. Tsygankova ◽  
E. Yu. Shel ◽  
N. V. Shel ◽  
L. G. Knyazeva ◽  
...  

A method of modeling aggressive atmospheres used for different tests in corrosive environments close as possible to actual full-scale conditions is proposed. The method provides simulation of air atmospheres containing gaseous corrosion stimulants (CS) as microcomponents of air. The content of SCs in such atmospheres (both separately and together) can be set and maintained at an unchanged level within a wide range for as long as desired. The method is based on Henry’s equation characterizing concentration of the gas dissolved in a liquid phase as a function of the gas partial pressure in the equilibrium gas medium with allowance for the solubility of the corrosion stimulants in water in conditions under consideration. The procedure is easy to use and does not require long special training. Samples of corrosion stimulants NH3, CO2, and H2S are considered. Experimental results characterizing the corrosion rate of St3 carbon steel and copper with one or several CS simultaneously present in air atmosphere, as well as data on the efficiency of volatile inhibitors of «IFHAN» series under similar conditions are presented.

Author(s):  
B. J. Hockey

Ceramics, such as Al2O3 and SiC have numerous current and potential uses in applications where high temperature strength, hardness, and wear resistance are required often in corrosive environments. These materials are, however, highly anisotropic and brittle, so that their mechanical behavior is often unpredictable. The further development of these materials will require a better understanding of the basic mechanisms controlling deformation, wear, and fracture.The purpose of this talk is to describe applications of TEM to the study of the deformation, wear, and fracture of Al2O3. Similar studies are currently being conducted on SiC and the techniques involved should be applicable to a wide range of hard, brittle materials.


2020 ◽  
Vol 69 (4) ◽  
pp. 102-106
Author(s):  
Shota Ohki ◽  
Shingo Mineta ◽  
Mamoru Mizunuma ◽  
Soichi Oka ◽  
Masayuki Tsuda

Alloy Digest ◽  
1987 ◽  
Vol 36 (2) ◽  

Abstract SAE 1020 is a low-carbon steel combining good machinability, workability and weldability. It is carburized for use in case-hardened components and it is used for a wide range of applications in the hot-worked, cold-worked, normalized or quenched-and-tempered conditions. Its many uses include bolts, rods, plate applications, machinery components, case-hardened parts, spinning tools and trimming dies. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on low temperature performance and corrosion resistance as well as heat treating, machining, joining, and surface treatment. Filing Code: CS-113. Producer or source: Carbon steel mills.


Alloy Digest ◽  
1984 ◽  
Vol 33 (2) ◽  

Abstract AISI 1566 is a high-carbon (nominally 0.66% carbon) steel containing 0.85-0.15% manganese. Its hardenability is low and on austenitizing and liquid quenching it develops a hard (martensitic) surface with a soft, ductile core. It can be used in the hot-rolled, annealed, normalized, cold-worked or liquid-quenched-and-tempered condition for a wide range of applications. It has good machinability and good workability. Its many uses include springs, shafts, hand tools, railway parts and agricultural machinery. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: CS-100. Producer or source: Carbon steel mills.


CORROSION ◽  
1966 ◽  
Vol 22 (5) ◽  
pp. 143-146 ◽  
Author(s):  
W. McLEOD ◽  
R. R. ROGERS

Abstract Corrosion rate data are presented for low carbon steel in (1) a combination of sulfur dioxide, water vapor and air, and (2) aqueous solutions of sulfurous acid in the absence of air, at ordinary temperature. Information as to the nature of the corrosion products is presented and it is shown that this depends on the place in which the corrosion takes place to an important extent.


Synlett ◽  
2021 ◽  
Author(s):  
Ao Li ◽  
Bin Pan ◽  
Mu Chao ◽  
Na Wang ◽  
Yu-Long Li ◽  
...  

A visible-light-induced direct α-oxygenation of N-substituted tetrahydroisoquinoline derivatives has been successfully developed. Metalloporphyrin (ZnTPP) has been identified as an effective and inexpensive photocatalyst for this transformation with a wide range of substrates. This protocol provides a convenient route to afford the desired products in moderate to good yields at room temperature under air atmosphere.


2009 ◽  
Vol 417-418 ◽  
pp. 417-420 ◽  
Author(s):  
Shigenobu Kainuma ◽  
Kunihiro Sugitani ◽  
Yoshihiro Ito ◽  
In Tae Kim

The purpose of this research is to propose a method for evaluating the time-dependent corrosion behavior of carbon steel plates using an atmospheric corrosion monitor (ACM) corrosion sensor consisting of a Fe/Ag-galvanic couple. Atmospheric exposure tests were carried out on steel plates for periods of 6, 12, and 24-months on the island of Okinawa in Japan. The Specimens were mounted on racks at angles of 0, 45 and 90 to the horizontal to obtain corrosion data in various corrosive environments. In addition, the environments of the skyward- and groundward-facing surfaces of the specimens were monitored using ACM sensors. The sensor outputs were recorded during the exposure tests.


2005 ◽  
Vol 495-497 ◽  
pp. 1591-1596 ◽  
Author(s):  
Vladimir Luzin ◽  
S. Banovic ◽  
Thomas Gnäupel-Herold ◽  
Henry Prask ◽  
R.E. Ricker

Low carbon steel (usually in sheet form) has found a wide range of applications in industry due to its high formability. The inner and outer panels of a car body are good examples of such an implementation. While low carbon steel has been used in this application for many decades, a reliable predictive capability of the forming process and “springback” has still not been achieved. NIST has been involved in addressing this and other formability problems for several years. In this paper, texture produced by the in-plane straining and its relationship to springback is reported. Low carbon steel sheet was examined in the as-received condition and after balanced biaxial straining to 25%. This was performed using the Marciniak in-plane stretching test. Both experimental measurements and numerical calculations have been utilized to evaluate anisotropy and evolution of the elastic properties during forming. We employ several techniques for elastic property measurements (dynamic mechanical analysis, static four point bending, mechanical resonance frequency measurements), and several calculation schemes (orientation distribution function averaging, finite element analysis) which are based on texture measurements (neutron diffraction, electron back scattering diffraction). The following objectives are pursued: a) To test a range of different experimental techniques for elastic property measurements in sheet metals; b) To validate numerical calculation methods of the elastic properties by experiments; c) To evaluate elastic property changes (and texture development) during biaxial straining. On the basis of the investigation, recommendations are made for the evaluation of elastic properties in textured sheet metal.


Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 128
Author(s):  
Jixiang Dai ◽  
Yi Li ◽  
Hongbo Ruan ◽  
Zhuang Ye ◽  
Nianyao Chai ◽  
...  

In this paper, WO3-Pd2Pt-Pt nanocomposite films were deposited on a single mode fiber as the hydrogen sensing material, which changes its reflectivity under different hydrogen concentration. The reflectivity variation was probed and converted to an electric signal by a pair of balanced InGaAs photoelectric detectors. In addition, the performance of the WO3-Pd2Pt-Pt composite film was investigated under different optical powers, and the irrigating power was optimized at 5 mW. With the irrigation of this optical power, the hydrogen sensitive film exhibits quick response toward 100 ppm hydrogen in air atmosphere at a room temperature of 25 °C. The experimental results demonstrate a high resolution at 5 parts per million (ppm) within a wide range from 100 to 5000 ppm in air. This simple and compact sensing system can detect hydrogen concentrations far below the explosion limit and provide early alert for hydrogen leakage, showing great potential in hydrogen-related applications.


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