scholarly journals The Effect of Calcium Silicate on The Phosphorus Sorption Characteristics of Andisols Lembang West Java

2008 ◽  
Vol 10 (1) ◽  
pp. 14-19 ◽  
Author(s):  
Arief Hartono
Keyword(s):  
Calcium Silicate ◽  
Dry Weight ◽  
Phosphorus Sorption ◽  
Sorption Kinetic ◽  
Sorption Data ◽  
Kinetic Experiment ◽  
P Sorption ◽  
Randomized Design ◽  
Set Up ◽  
Sorption Characteristics

The effect of calcium silicate CaSiOJ the phosphorus (P) sorption characteristics were studied in Andisols Lembang.The amount of 0, 2.5 and 5% CaSiOJ (calcium silicate) or 0, 7.5 and 15 g calcium silicate per pot was added to the 300 g(oven-dry weight) soil and incubated for one month. A completely randomized design in double replication was set up. After one month incubation, P sorption and P sorption kinetic experiments were conducted The results of P sorption experiment showed that P sorption data were satisfactorily described by the Langmuir equation. which was used to determine P sorption maxima, bonding energies and P sorbed at 0.2 mg P £"' (standard P requirement). The application of calcium silicate did not affect significantly P sorption maxima but decreased significantly the P bonding energies. Calcium silicate also decreased significantly the standard P requirements. As for P sorption kinetic experiment. the results showed that application of 5% calcium silicate decreased significantly the rate constant of P sorption and P sorbed maximum at given amount of added P. The results suggested that the application of calcium silicate to the Andisols made added P was more available for plant.

PHOSPHORUS SORPTION KINETIC ON ACID UPLAND SMECTITIC SOIL AMENDED WITH CALCIUM CARBONATE AND CALCIUM SILICATE

2019 ◽  
Vol 11 (2) ◽  
pp. 58-62
Author(s):  
Arief Hartono
Keyword(s):  
Calcium Carbonate ◽  
Rate Constant ◽  
Soil Ph ◽  
Calcium Silicate ◽  
Chemical Properties ◽  
Order Kinetic ◽  
Phosphorus Sorption ◽  
Sorption Kinetic ◽  
P Sorption ◽  
Exchangeable Al

Acid upland smectitic soil is identified by high amount of exchangeable Al due to the weathering of aluminum (Al) octahedral layer by H+ saturation and by very low phosphorus (P) status.  Calcium carbonate (CaCO3) and calcium silicate (CaSiO3) were commonly used to decrease exchangeable Al and increase soil pH.  Laboratory experiments were conducted with clayey smectitic Typic Paleudults from Gajrug region, West Java.  The CaCO3 and CaSiO3 were added at rates to replace 0, 1.5 or 3 times of exchangeable Al. After one month of incubation, P sorption kinetic experiments were conducted.   The changes in some chemical properties after one month incubation showed that both CaCO3 and CaSiO3 increased the soil pH, exchangeable Ca, and base saturation  but did not increase the cation exchange capacity.  The results of the experiment showed that both CaCO3 and CaSiO3 decreased the rate constant value of first order kinetic equation (k) and the P sorbed maximum (a) at given amount of added P compared to Control.The CaCO3 was better than CaSiO3 in decreasing k values and on the contrary for a values. The decrease in P maximum sorption and the rate constant of the soil amended with CaSiO3 and CaCO3 due to occupation of P sorption sites by silicates and hydroxyl ions. The CaCO3with the rate to replace 1.5 x exchangeable Al was recommended to decrease the rate constant of P sorption. However, the CaSiO3 at the rate to replace 3 x exchangeable Al was recommended to decrease the maximum P sorption.

scholarly journals Growth performance of jute (Corchorus capsularies L.) as influenced by different organic manures

2021 ◽  
Vol 6 (1) ◽  
pp. 17-24
Author(s):  
U Qulsum ◽  
FF Meem ◽  
RS Promi ◽  
JR Zaman ◽  
MF Ara ◽  
...  
Keyword(s):  
Green Manure ◽  
Poultry Manure ◽  
Dry Weight ◽  
Growth And Yield ◽  
Local Market ◽  
Branch Number ◽  
Organic Manures ◽  
Randomized Design ◽  
Different Types ◽  
Set Up

A pot experiment was carried out in 2019 in the net house of the Department of Soil, Water and Environment, University of Dhaka, to evaluate the growth and yield of Jute plants (Corchorus capsularies L.) by applying different types of organic manures. Eight different types of organic manures viz. ACI, BGF-1, Mazim, Vermicompost, Shufola, GTS, Green and Poultry manures were collected from the local market. The experiment was set up following a completely randomized design (CRD) with nine treatments and three replications consisting of twenty-seven pots. Significant variation was observed in different growth and yield contributing characters. The highest plant height (19.83cm) in poultry manure, leaf number (8.33/plant) was observed in Green manure, leaf area (21.93 cm2 / plant) in Poultry manure, fresh weight (3.18g) and dry weight (2.25 g) were found in Poultry manure, stem girth (1.67 cm/plant) in Vermicompost, branch number (8.6/plant) in Green manure. The highest nutrient uptake by plants (kg/ha) occurred in Poultry manure. The overall best growth was observed in Poultry manure. J. Biodivers. Conserv. Bioresour. Manag. 2020, 6(1): 17-24

Mechanisms for altering phosphorus sorption characteristics induced by low-molecular-weight organic acids

2016 ◽  
Vol 96 (3) ◽  
pp. 289-298 ◽  
Author(s):  
Yongzhuang Wang ◽  
Joann K. Whalen ◽  
Xin Chen ◽  
Yanhong Cao ◽  
Bin Huang ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Organic Acids ◽  
Low Molecular Weight ◽  
Minor Effect ◽  
Phosphorus Sorption ◽  
Sorption Data ◽  
P Fractionation ◽  
Soil P ◽  
P Sorption ◽  
A Minor

Exudation of low-molecular-weight organic acids (LMWOAs) from plant roots enhances phosphorus (P) acquisition from soil, either by dissolving P fixed in secondary minerals or by reducing P sorption to organo-minerals. How LMWOAs may modify P sorption in soils with contrasting pH is not well understood, much less the mechanisms involved. The effects of three common LMWOAs (oxalic, citric, and malic acids) on P sorption in calcareous, neutral, and acidic soils were studied in batch experiments, followed by sequential P fractionation to elucidate the mechanisms whereby LMWOAs alter P sorption. The sorption data of the three soils fitted better to the Freundlich equation (r2 = 0.325–0.994, P < 0.05) than the Langmuir and linear equations. Oxalic, citric, and malic acids at 10 mmol kg−1 soil decreased the Freundlich P sorption parameters Kf and n, which represent P sorption capacity and energy, due to the fact that LMWOAs reduced P sorption in NaHCO3-Pi (soil soluble and exchangeable Pi, 23.8–30.9%) and NaOH-Pi (Fe-Pi and Al-Pi, 21.6–54.2%) fractions of the three soils. Comparing acidified P-LMWOAs solutions with the pH-adjusted P-LMWOAs solutions (pH = 7) had a minor effect on P sorption. Our results indicated that the reduction in soil P sorption was due to ligand exchange and chelation of LMWOAs with Fe and Al minerals, and the acid strength of LMWOAs had a minor effect on P sorption in calcareous, neutral, and acid soils.

Phosphorus sorption in relation to soil properties for the major soil types of South-Western Australia

Soil Research ◽  
1991 ◽  
Vol 29 (5) ◽  
pp. 603 ◽  
Author(s):  
B Singh ◽  
RJ Gilkes
Keyword(s):  
Regression Analysis ◽  
Western Australia ◽  
Stepwise Regression ◽  
Clay Content ◽  
Soil Types ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
Agricultural Areas ◽  
Langmuir And Freundlich Equations ◽  
Sorption Characteristics

The P sorption characteristics of 97 soils that are representative of the agricultural areas of Western Australia were described using Langmuir and Freundlich equations. The Langmuir P maximum (xm) ranged from 11 to 2132 �g g-1 soil and the Freundlich k coefficient ranged from 1 to 1681. Clay content, DCB Fe and Al, oxalate Fe and AL, and pyrophosphate Al were positively related to xm and k. By using stepwise regression analysis, the combination of DCB and oxalate-soluble A1 predicted more than 75% Of the variation in the P sorption coefficients. Reactive Al compounds may thus be responsible for much of the P sorption by these soils. Soil pH in 1 M NaF (pH 8.2), which is normally used for the detection of allophanic material, was strongly related to the P sorption coefficients and might therefore be used as a quick test for predicting the P sorption capacity of soils.

Influence of biosolids on phosphorus sorption characteristics of a Vertisol in comparison with manures and fertilizer

2007 ◽  
Vol 87 (5) ◽  
pp. 511-521 ◽  
Author(s):  
Babasola Ajiboye ◽  
Olalekan O Akinremi ◽  
Geza J Racz ◽  
Donald N Flaten
Keyword(s):  
Sorption Isotherm ◽  
Single Point ◽  
Chemical Properties ◽  
Similar Proportion ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
P Loss ◽  
Degree Of P Saturation ◽  
Labile P ◽  
Sorption Characteristics

Regulation of manure application in Manitoba has raised the question of whether or not biosolids application should be regulated in the same way. This study examined the effects of biosolids (BIO) applications on P sorption characteristics of a Vertisol in comparison with dairy cattle (DAIRY) and hog (HOG) manures, and monoammonium phosphate (MAP) fertilizer using the classical sorption isotherm and single point sorption index. Pertinent chemical properties and degree of P saturation (DPS) were also determined. The sorption maximum (Smax) in the control was reduced from 655 mg kg-1, to a range of 536–655 mg kg-1 with BIO, 559–650 mg kg-1 with MAP, 402–568 mg kg-1 with DAIRY, and 350–587 mg kg-1 with HOG depending upon the rate of P added. The lower DPS in the soil amended with BIO suggests a lower risk of P loss with biosolids compared with manures. The higher P sorption capacity of biosolids-amended soils compared with soils amended with manures suggest that Ca added with BIO increased the number of P sorption sites by a similar proportion to the amount of P added. Key words: Biosolids, P sorption isotherm, degree of P saturation, labile P, non-labile P

scholarly journals Phosphorus Sorption in Soils Overlying Basement Complex Rock, Alluvium, Coastal Plain Sand and Imo Shale Parent Materials

2021 ◽  
pp. 41-54
Author(s):  
Robert Ehi Orhue ◽  
Adams Emomu ◽  
Esohe Obazuaye ◽  
Aimiesomon Michael Erhayimwen ◽  
Ajayi Gboyega Bepo
Keyword(s):  
Coastal Plain ◽  
Soil Samples ◽  
Phosphorus Sorption ◽  
Basement Complex ◽  
Parent Materials ◽  
P Sorption ◽  
Benin City ◽  
Randomized Design ◽  
Significant Difference ◽  
Sorption Index

This study aimed at evaluating phosphorus (P) sorption capacities in Soils overlying basement complex Rock (A), Alluvium (B), coastal plain sand (C) and Imo shale (C) parent materials. Completely randomized design was used to collect soil samples from 5 depths in 3 replications from Idanre, Koko, NIFOR and Uhomora in Nigeria. Samples collected were analyzed in the central analytical laboratory of the Nigerian Institute for Oil palm Research, Benin City, Nigeria between march 2016 and September 2017. 60 soil samples were equilibrated in 25 ml of 0.01 M CaCl2 containing various concentration of P as KH2PO4  to give 0, 50, 100, 150, 200 and 250 mg/L P for 24 hours (h)  at room temperature 25 ± 2 oC. Genstat statistical package was used to calculate Analysis of variance, correlation of Phosphorus sorption index (PSI) with soil properties, coefficient of variation, means separation and Least Significant difference (LSD). The rate and %P adsorption increased with increasing concentration of P added to the soils. The P sorption capacities of the soils considering Freundlich model decreased in the order of D > B > C >A. %P adsorbed was highest in D soils with value of 15.19% for 100 mg/kg P added. The PSI correlated with organic carbon r = -0.58 P ≤ .05 in C soils, r = 0.44 P ≤ .05 in D soils, it also correlated with N r = -0.58 P ≤ .05 in C Soils, K r = 0.57 P ≤ .05, r = 0.49 P ≤ .05 in C and D soils respectively. D soils sorbed more P than other soils hence the D soils will require more P fertilization to attain optimum P concentration in soil solution, however further study is required to determine the form of P sorbed by these parent materials.

Effects of animal effluents on the phosphorus sorption characteristics of soils

Soil Research ◽  
1997 ◽  
Vol 35 (2) ◽  
pp. 365 ◽  
Author(s):  
I. C. R. Holford ◽  
C. Hird ◽  
R. Lawrie
Keyword(s):  
Sorption Capacity ◽  
Poultry Manure ◽  
Effluent Treatment ◽  
Total Carbon ◽  
Degree Of Saturation ◽  
Phosphorus Sorption ◽  
Soil P ◽  
P Sorption ◽  
P Leaching ◽  
Sorption Characteristics

Two groups of soils were examined to determine the effects of dairy, pig, or sewage effluent and other materials containing phosphorus (P) on their P sorption characteristics, using the Langmuir equation to estimate values of both sorption capacity and sorption strength. There were 19 soils (0-15 cm) from 6 sites in the Williams River catchment and 3 soils (0-100 cm) from Bermagui, all from coastal New South Wales. Effluent usually decreased P sorption capacities of the Williams River soils, and in 3 soils the capacities were reduced to zero. Sorption strength was reduced substantially by effluent treatment in all soils except one, which had received effluent for only 3 years. Sorption strength, but not necessarily capacity, was also lower after treatment with poultry manure or chicken litter than after treatment with superphosphate only. Where effluent did not decrease sorption capacity there was a substantial increase in total carbon and iron, both of which could increase sorption capacities. After 3 years of effluent treatment of the Bermagui soil, sorption capacities had been reduced in the top 70 cm depth, the extent of the reduction varying from 17% at 0-7 · 5 cm depth to 38% at 40-70 cm depth. Sorption strength was reduced in the top 40 cm depth only. After 12 years of effluent treatment, sorption capacities and strength had also decreased at the deeper sampling depths (to 100 cm), and the average reduction in capacity was about 40%. These results suggest that P leaching will begin well before the total sorption capacity has been saturated. There was a direct and significant correlation between the sorption strength of the untreated soil and the percentage saturation reached before leaching began. Further saturation of the sorption complex appears to be slow after this degree of saturation has been reached, and it seems that P leaching exceeds adsorption during this phase. There was also a negative correlation between sorption strength and KCl-soluble P in all soils, suggesting that soil P solubility and potential saturation are both controlled by this characteristic.

scholarly journals Freundlich and Langmuir Isotherm Studies of Phosphorus Sorption unto Soils Derived from Basement Complex Rock, Alluvium, Coastal Plain Sand and Shale Parent Materials

2021 ◽  
pp. 27-36
Author(s):  
Adams Emomu ◽  
Esohe Ehis-Iyoha ◽  
Emmanuel Ochuko Ufinomue ◽  
Donald Okpo Odidi ◽  
Sandra Amen Ighedosa
Keyword(s):  
Coastal Plain ◽  
Soil Samples ◽  
Phosphorus Sorption ◽  
Adsorption Model ◽  
Basement Complex ◽  
Sorption Data ◽  
Freundlich Model ◽  
Parent Materials ◽  
P Sorption ◽  
Benin City

To provide information on best model to predict Phosphorus (P) Sorption unto Soils derived from Basement Complex Rock, Alluvium, Coastal Plain Sand and Imo Shale Parent Materials in 3 states of Nigeria. Completely randomized design was used to collect surface soil samples in 3 replications from 4 locations in Nigeria. Samples were collected from Idanre, Koko, NIFOR and Uhonmora in Ondo, Delta and Edo states Nigeria, laboratory analysis was carried out in the Central analytical laboratory of Nigerian Institute for Oil-Palm Research (NIFOR) Benin City, Nigeria between march 2016 and September 2017. Soil samples were equilibrated in 25 ml of 0.01 M CaCl2 containing various concentration of P as KH2PO4  to give 0, 50, 100, 150, 200 and 250 mg/L P for 24 hours (h) at room temperature 25 ± 2oC. 3 drops of CHCl3 was added to inhibit P mineralization. The suspension was shaken for 24 h on a reciprocating mechanical shaker, centrifuged at 7000 rpm After equilibration, decanted and P determined using spectrophotometer. The sorption data were fitted to linear Freundlich and Langmuir sorption isotherm. Considering the Freundlich model, P adsorption capacity (a) and P sorption energy (n) was highest in soils B (1400 mg kg-1) and (2.806 L kg-1) respectively. The Freundlich model fitted better to the data obtained with average root mean square error (RMSE) and R2 value of 0.69 and 0.951 respectively, as against average RMSE and R2 value of 1.60 and 0.883 respectively obtained from Langmuir model. The sorption data fitted well to Freundlich and Langmuir isotherms of which Freundlich Adsorption model was found to be better based on lowest RMSE (0.69) and highest regression (R2 = 0.951) value. Freundlich model should be adopted to determine P sorption characteristics of the soils studied. These predictors, however, need further works to validate reliability.

scholarly journals Phosphorus Sorption Characteristics of Luvisols and Nitisols in North Ethiopian Soils

2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Ashebir Getie ◽  
Alemayehu Kiflu ◽  
Gashaw Meteke
Keyword(s):  
Clay Content ◽  
Fertilizer Application ◽  
Application Rate ◽  
Soil Types ◽  
Phosphorus Sorption ◽  
Sorption Data ◽  
P Sorption ◽  
Fertilizer Application Rate ◽  
P Fertilizer ◽  
Sorption Parameters

Crop response to phosphorus (P) application is often erratic in most acidic soil types. The main processes for P losses from agricultural fields are fixation, crop removal, erosion, surface runoff, and subsurface leaching. The purpose of this experiment was to evaluate adsorption properties of selected soils, determine the external phosphorous requirements (EPRs) of the soils, and identify factors contributing to P sorption in two soils in North Ethiopia. In this experiment, separately weighed 1 g soil samples were equilibrated with KH2PO4 at rates of 0.5, 5, 10, 20, 30, 40, and 50 mg PL−1. The P sorption data were fitted well with both Langmuir and Freundlich models with average r2 values of 0.91 and 0.88, respectively. The adsorption maximum (Xm) of the Langmuir isotherm ranged from 588.20 mg P kg−1 soil in Luvisols to 833.3 mg P kg−1 soil in Nitisols. The EPRL values ranged between 86.20 to 93.28 mg P kg−1 for soils of the study area. Among the soil properties, clay content and Ex. Al were positively correlated with Xm. The path analysis revealed that clay, pH, and Av. P had a direct effect on P sorption parameters. The EPRL of the studied soils was 3.44 to 3.6 times greater than the blanket P fertilizer rate recommendation. It is concluded that P sorption models can effectively be used to discriminate soils based on P fixation ability. The result further indicates that the current P fertilizer application rate of 50 kg P ha−1 being practiced across all soil types should be revised after validating the models and EPR values estimated in this study for each soil both under greenhouse and in-the-field conditions.

scholarly journals Phosphate sorption parameters in relation to soil properties in some major agricultural soils of India

2016 ◽  
Vol 14 (1) ◽  
pp. 1-9 ◽  
Author(s):  
I Rashmi ◽  
VRR Parama ◽  
AK Biswas
Keyword(s):  
Soil Properties ◽  
Agricultural Soils ◽  
Clay Content ◽  
Phosphate Adsorption ◽  
Phosphorus Sorption ◽  
Sorption Data ◽  
K Value ◽  
P Sorption ◽  
Indian Representative ◽  
Sorption Parameters

Phosphorus sorption characteristics of some Indian representative agricultural soils belonging to four soil orders namely Vertisol, Inceptisol, Alfisol and Ultisol were investigated for adsorption behaviour of P and sorption data were fitted to Langmuir and Freundlich equations. The Langmuir constant i.e. adsorption maxima was highest for Vertisol (716.85 ?g g-1), followed by Ultisol (633.3 ?g g-1), Alfisol (501.46 ?g g-1) and Inceptisol (522.93 ?g g-1) respectively. The Freundlich ‘k’ value for Vertisol, Inceptisol, Alfisol and Ultisol were 159.12, 59.41, 110.57 and 181.36 ?g g-1 respectively, whereas the ‘n’ values were 2.05, 1.92, 2.49 and 3.07 g ml-1 respectively. The phosphate adsorption isotherm gave good fit adopting Langmuir (r2 = 0.96 to 0.99) and Freundlich (r2= 0.95 to 0.99) for the four soils. Phosphorus sorption maxima was significantly correlated with clay (r2=0.70), Al (r2= 0.73) and Fe (r2=0.81) forms, MPBC (r2=0.67) and Freundlich constants (r2=0.82). Among the various soil properties which correlated with P sorption maxima of significance was clay content (r2=0.97) was significantly correlated. The study illustrated that P sorption isotherm in relation to soil properties can be used as a tool of P management in sustainable crop production.SAARC J. Agri., 14(1): 1-9 (2016)

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